KR20120006061A - 크롬/알루미나 촉매를 사용하여 제조된 폴리머 및 설페이트 처리에 의한 활성 크롬/알루미나 촉매 제조 방법 - Google Patents

크롬/알루미나 촉매를 사용하여 제조된 폴리머 및 설페이트 처리에 의한 활성 크롬/알루미나 촉매 제조 방법 Download PDF

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Publication number
KR20120006061A
KR20120006061A KR1020117027588A KR20117027588A KR20120006061A KR 20120006061 A KR20120006061 A KR 20120006061A KR 1020117027588 A KR1020117027588 A KR 1020117027588A KR 20117027588 A KR20117027588 A KR 20117027588A KR 20120006061 A KR20120006061 A KR 20120006061A
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South Korea
Prior art keywords
polymer composition
chromium
catalyst
polyethylene
support
Prior art date
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Ceased
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KR1020117027588A
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English (en)
Korean (ko)
Inventor
맥스 피. 맥다니엘
케시 에스. 콜린스
엘리자베스 에이. 벤함
폴 제이. 데스라우리어스
Original Assignee
셰브론 필립스 케미컬 컴퍼니 엘피
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Publication date
Priority claimed from US10/829,850 external-priority patent/US7214642B2/en
Priority claimed from US10/829,844 external-priority patent/US7112643B2/en
Application filed by 셰브론 필립스 케미컬 컴퍼니 엘피 filed Critical 셰브론 필립스 케미컬 컴퍼니 엘피
Publication of KR20120006061A publication Critical patent/KR20120006061A/ko
Ceased legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/053Sulfates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/26Chromium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
KR1020117027588A 2004-04-22 2005-03-24 크롬/알루미나 촉매를 사용하여 제조된 폴리머 및 설페이트 처리에 의한 활성 크롬/알루미나 촉매 제조 방법 Ceased KR20120006061A (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US10/829,850 US7214642B2 (en) 2004-04-22 2004-04-22 Methods of preparing active chromium/alumina catalysts via treatment with sulfate
US10/829,844 2004-04-22
US10/829,844 US7112643B2 (en) 2004-04-22 2004-04-22 Polymers having low levels of long chain branching and methods of making the same
US10/829,850 2004-04-22

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
KR1020067024498A Division KR101121598B1 (ko) 2004-04-22 2005-03-24 크롬/알루미나 촉매를 사용하여 제조된 폴리머 및 설페이트처리에 의한 활성 크롬/알루미나 촉매 제조 방법

Publications (1)

Publication Number Publication Date
KR20120006061A true KR20120006061A (ko) 2012-01-17

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Family Applications (2)

Application Number Title Priority Date Filing Date
KR1020117027588A Ceased KR20120006061A (ko) 2004-04-22 2005-03-24 크롬/알루미나 촉매를 사용하여 제조된 폴리머 및 설페이트 처리에 의한 활성 크롬/알루미나 촉매 제조 방법
KR1020067024498A Expired - Fee Related KR101121598B1 (ko) 2004-04-22 2005-03-24 크롬/알루미나 촉매를 사용하여 제조된 폴리머 및 설페이트처리에 의한 활성 크롬/알루미나 촉매 제조 방법

Family Applications After (1)

Application Number Title Priority Date Filing Date
KR1020067024498A Expired - Fee Related KR101121598B1 (ko) 2004-04-22 2005-03-24 크롬/알루미나 촉매를 사용하여 제조된 폴리머 및 설페이트처리에 의한 활성 크롬/알루미나 촉매 제조 방법

Country Status (10)

Country Link
EP (2) EP1748842A1 (enExample)
JP (3) JP4732443B2 (enExample)
KR (2) KR20120006061A (enExample)
AU (1) AU2005240523A1 (enExample)
BR (2) BRPI0510174B1 (enExample)
CA (2) CA2564483C (enExample)
IN (1) IN2012DN02743A (enExample)
RU (1) RU2006141236A (enExample)
SG (1) SG136947A1 (enExample)
WO (1) WO2005107943A1 (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7897539B2 (en) 2007-05-16 2011-03-01 Chevron Phillips Chemical Company Lp Methods of preparing a polymerization catalyst
US7638456B2 (en) * 2007-12-18 2009-12-29 Chevron Phillips Chemical Company Lp Methods of preparing a polymerization catalyst
US7910669B2 (en) 2009-03-17 2011-03-22 Chevron Phillips Chemical Company Lp Methods of preparing a polymerization catalyst
KR101483247B1 (ko) 2013-04-23 2015-01-16 주식회사 엘지화학 폴리올레핀 중합용 촉매의 제조 방법 및 폴리올레핀 제조방법
US10246528B2 (en) 2014-01-09 2019-04-02 Chevron Phillips Chemical Company Lp Chromium (III) catalyst systems with activator-supports
US10005861B2 (en) 2016-06-09 2018-06-26 Chevron Phillips Chemical Company Lp Methods for increasing polymer production rates with halogenated hydrocarbon compounds
CN116217760A (zh) * 2018-09-17 2023-06-06 切弗朗菲利浦化学公司 铬催化剂的光处理以及相关的催化剂制备系统和聚合工艺
WO2022056146A1 (en) 2020-09-14 2022-03-17 Chevron Phillips Chemical Company Lp Transition metal-catalyzed production of alcohol and carbonyl compounds from hydrocarbons
US12134591B2 (en) 2022-10-31 2024-11-05 Chevron Phillips Chemical Company Lp Methanol production from methane utilizing a supported chromium catalyst

Family Cites Families (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3624063A (en) 1969-07-10 1971-11-30 Phillips Petroleum Co Ethylene polymerization using catalyst of controlled particle size
US3976632A (en) 1974-12-04 1976-08-24 Phillips Petroleum Company Reactivation of organochromium olefin polymerization catalyst in presence of oxygen
US4364842A (en) * 1980-12-31 1982-12-21 Phillips Petroleum Company Phosphate supported chromium catalyst
CA1172236A (en) * 1980-12-31 1984-08-07 Max P. Mcdaniel Phosphated alumina or aluminum phosphate chromium catalyst
JPS5838319A (ja) * 1981-08-31 1983-03-05 Nissan Motor Co Ltd フアンシユラウド
JPS5849706A (ja) * 1981-09-18 1983-03-24 Asahi Chem Ind Co Ltd オレフイン重合触媒
US4690990A (en) 1982-03-30 1987-09-01 Phillips Petroleum Company Polymerization process using a catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound
US4803253A (en) 1982-03-30 1989-02-07 Phillips Petroleum Company Ethylene polymer produced using a catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound
US4444966A (en) * 1982-05-05 1984-04-24 Phillips Petroleum Company Polymerization using phosphated alumina or aluminum phosphate chromium catalyst
US4806513A (en) 1984-05-29 1989-02-21 Phillips Petroleum Company Silicon and fluorine-treated alumina containing a chromium catalyst and method of producing same
US4607019A (en) 1984-12-12 1986-08-19 Exxon Research & Engineering Co. Polymerization catalyst, production and use
US4619980A (en) * 1985-04-01 1986-10-28 Phillips Petroleum Company Polymerization catalyst, method of making and use therefor
US4855271A (en) 1987-06-22 1989-08-08 Phillips Petroleum Company Catalyst and polymerization of olefins
US5200379A (en) 1990-06-07 1993-04-06 Phillips Petroleum Company Olefin polymerization using supported pentadienyl derivative-transition metal complexes
US5565175A (en) 1990-10-01 1996-10-15 Phillips Petroleum Company Apparatus and method for producing ethylene polymer
US5237025A (en) 1990-10-09 1993-08-17 Phillips Petroleum Company Process for making bimodal polyolefins using two independent particulate catalysts
CA2043904C (en) 1990-10-09 1997-10-07 Kent E. Mitchell Olefin polymerization
ES2101765T3 (es) * 1991-03-29 1997-07-16 Chevron Usa Inc Catalizadores para la polimerizacion de alfa-olefinas de ciclopentadienil-metal del grupo 6b y proceso para polimerizar alfa-olefinas.
US5244990A (en) 1992-01-07 1993-09-14 Phillips Petroleum Company Prepolymerized catalyst and use thereof
US5179178A (en) 1992-05-15 1993-01-12 Phillips Petroleum Company Olefin polymerization
JPH06248025A (ja) * 1992-12-28 1994-09-06 Sumitomo Chem Co Ltd エチレン−αオレフィン共重合体
JPH0797343A (ja) * 1993-05-19 1995-04-11 Koa Oil Co Ltd 低級オレフィンの低重合方法及び低重合用触媒
EP0734766B1 (en) 1995-03-29 2001-08-29 Koa Oil Company, Limited Olefin oligomerization catalyst, process for preparing the same, and olefin oligomerization process using the same
JPH08323207A (ja) * 1995-03-29 1996-12-10 Koa Oil Co Ltd オレフィンの低重合方法、その触媒及び触媒の製造方法
JP3114632B2 (ja) * 1995-10-31 2000-12-04 東ソー株式会社 エチレン系共重合体、その製造方法およびその組成物
JP3662729B2 (ja) * 1996-10-24 2005-06-22 日本ポリオレフィン株式会社 エチレン系重合体及び中空成形体
US6239235B1 (en) 1997-07-15 2001-05-29 Phillips Petroleum Company High solids slurry polymerization
US5998558A (en) * 1997-12-29 1999-12-07 Union Carbide Chemicals & Plastics Technology Corporation Ethylene polymers having enhanced processing ease
JP2002506095A (ja) * 1998-03-12 2002-02-26 ビーピー ケミカルズ リミテッド エチレンのホモポリマー
WO1999060033A1 (en) * 1998-05-18 1999-11-25 Phillips Petroleum Company Catalyst composition for polymerizing monomers
CN1185266C (zh) * 1999-06-17 2005-01-19 三井化学株式会社 乙烯(共)聚合物及其用途
US6828268B1 (en) * 1999-11-05 2004-12-07 Phillips Petroleum Company Polymerization catalyst systems and processes using alkyl lithium compounds as a cocatalyst
CA2338094C (en) * 2001-02-23 2009-09-15 Nova Chemicals Corporation Catalyst for olefin polymerization
JP2003105016A (ja) * 2001-07-27 2003-04-09 Japan Polyolefins Co Ltd エチレン系重合体製造用触媒、エチレン系重合体の製造方法およびエチレン−α−オレフィン共重合体
BR0213523B1 (pt) * 2001-11-23 2012-10-16 tubo plástico e uso do mesmo.
JP2003165873A (ja) * 2001-11-29 2003-06-10 Asahi Kasei Corp ポリエチレン樹脂組成物及び成形体
EP1325925A1 (en) * 2002-01-03 2003-07-09 Repsol Quimica S.A. Chromium catalysts active in olefin polymerization
US6914113B2 (en) * 2002-07-25 2005-07-05 Fina Technology, Inc. Film clarity and rheological breadth in polyethylene resins
JP2004149761A (ja) * 2002-09-02 2004-05-27 Sumitomo Chem Co Ltd エチレン重合体

Also Published As

Publication number Publication date
BRPI0510174B1 (pt) 2016-04-26
BR122015030148B1 (pt) 2017-01-31
SG136947A1 (en) 2007-11-29
CA2564483A1 (en) 2005-11-17
KR20070004988A (ko) 2007-01-09
JP5894237B2 (ja) 2016-03-23
KR101121598B1 (ko) 2012-03-16
EP2374537A3 (en) 2011-11-02
HK1132003A1 (en) 2010-02-12
BRPI0510174A (pt) 2007-10-02
CA2730830A1 (en) 2005-11-17
CA2730830C (en) 2013-09-24
JP2015013999A (ja) 2015-01-22
RU2006141236A (ru) 2008-05-27
JP2007533821A (ja) 2007-11-22
IN2012DN02743A (enExample) 2015-09-11
CA2564483C (en) 2011-09-13
WO2005107943A1 (en) 2005-11-17
EP1748842A1 (en) 2007-02-07
AU2005240523A1 (en) 2005-11-17
JP2011006714A (ja) 2011-01-13
EP2374537A2 (en) 2011-10-12
JP4732443B2 (ja) 2011-07-27

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