KR20120003453A - 이차 전기화학 전지용 전극 활물질 - Google Patents
이차 전기화학 전지용 전극 활물질 Download PDFInfo
- Publication number
- KR20120003453A KR20120003453A KR1020117024187A KR20117024187A KR20120003453A KR 20120003453 A KR20120003453 A KR 20120003453A KR 1020117024187 A KR1020117024187 A KR 1020117024187A KR 20117024187 A KR20117024187 A KR 20117024187A KR 20120003453 A KR20120003453 A KR 20120003453A
- Authority
- KR
- South Korea
- Prior art keywords
- active material
- electrode
- electrode active
- carbon
- phosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000007772 electrode material Substances 0.000 title claims abstract description 34
- 239000003792 electrolyte Substances 0.000 claims abstract description 12
- 239000000126 substance Substances 0.000 claims abstract description 5
- 239000010955 niobium Substances 0.000 claims description 83
- 239000000203 mixture Substances 0.000 claims description 66
- 239000011149 active material Substances 0.000 claims description 41
- 229910052720 vanadium Inorganic materials 0.000 claims description 39
- 229910052758 niobium Inorganic materials 0.000 claims description 31
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 19
- 230000003647 oxidation Effects 0.000 claims description 19
- 238000007254 oxidation reaction Methods 0.000 claims description 19
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 18
- 230000000737 periodic effect Effects 0.000 claims description 6
- 230000037427 ion transport Effects 0.000 claims description 2
- 229910021293 PO 4 Inorganic materials 0.000 abstract description 57
- 239000007774 positive electrode material Substances 0.000 abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 39
- 239000000463 material Substances 0.000 description 36
- 229910052799 carbon Inorganic materials 0.000 description 29
- 229910019142 PO4 Inorganic materials 0.000 description 26
- 239000010452 phosphate Substances 0.000 description 26
- 235000021317 phosphate Nutrition 0.000 description 26
- -1 cationic ions Chemical class 0.000 description 24
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 23
- 239000002002 slurry Substances 0.000 description 23
- 239000002904 solvent Substances 0.000 description 23
- 238000006243 chemical reaction Methods 0.000 description 17
- 239000007858 starting material Substances 0.000 description 17
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 16
- 239000002243 precursor Substances 0.000 description 16
- 239000000243 solution Substances 0.000 description 16
- 229910052744 lithium Inorganic materials 0.000 description 14
- 238000000034 method Methods 0.000 description 14
- 238000006467 substitution reaction Methods 0.000 description 13
- 229910052783 alkali metal Inorganic materials 0.000 description 11
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 11
- 239000001257 hydrogen Substances 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- 229910013870 LiPF 6 Inorganic materials 0.000 description 10
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 10
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- 239000000843 powder Substances 0.000 description 10
- 150000001340 alkali metals Chemical class 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 229910001868 water Inorganic materials 0.000 description 9
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 150000001768 cations Chemical class 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 6
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
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- 239000007789 gas Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000012300 argon atmosphere Substances 0.000 description 4
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- 239000003638 chemical reducing agent Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical class [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 3
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 239000006258 conductive agent Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 150000005676 cyclic carbonates Chemical class 0.000 description 3
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 150000004677 hydrates Chemical class 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 238000009830 intercalation Methods 0.000 description 3
- 235000019837 monoammonium phosphate Nutrition 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
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- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- DJHGAFSJWGLOIV-UHFFFAOYSA-K Arsenate3- Chemical class [O-][As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-K 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- 108091006149 Electron carriers Proteins 0.000 description 2
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- 102100031416 Gastric triacylglycerol lipase Human genes 0.000 description 2
- 229910004761 HSV 900 Inorganic materials 0.000 description 2
- 101000941284 Homo sapiens Gastric triacylglycerol lipase Proteins 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
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- YWJVFBOUPMWANA-UHFFFAOYSA-H [Li+].[V+5].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O Chemical compound [Li+].[V+5].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O YWJVFBOUPMWANA-UHFFFAOYSA-H 0.000 description 2
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- 229910021529 ammonia Inorganic materials 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
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- 229920005648 ethylene methacrylic acid copolymer Polymers 0.000 description 1
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- 238000011065 in-situ storage Methods 0.000 description 1
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- DEUISMFZZMAAOJ-UHFFFAOYSA-N lithium dihydrogen borate oxalic acid Chemical compound B([O-])(O)O.C(C(=O)O)(=O)O.C(C(=O)O)(=O)O.[Li+] DEUISMFZZMAAOJ-UHFFFAOYSA-N 0.000 description 1
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Inorganic materials [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
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- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- AOLPZAHRYHXPLR-UHFFFAOYSA-I pentafluoroniobium Chemical compound F[Nb](F)(F)(F)F AOLPZAHRYHXPLR-UHFFFAOYSA-I 0.000 description 1
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- 229910052698 phosphorus Inorganic materials 0.000 description 1
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- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Inorganic materials [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
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Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/45—Phosphates containing plural metal, or metal and ammonium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16999909P | 2009-04-16 | 2009-04-16 | |
| US61/169,999 | 2009-04-16 | ||
| US12/752,707 US8372540B2 (en) | 2009-04-16 | 2010-04-01 | Electrode active material for secondary electrochemical cell |
| US12/752,707 | 2010-04-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20120003453A true KR20120003453A (ko) | 2012-01-10 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020117024187A Withdrawn KR20120003453A (ko) | 2009-04-16 | 2010-04-12 | 이차 전기화학 전지용 전극 활물질 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8372540B2 (https=) |
| EP (1) | EP2419954A4 (https=) |
| JP (1) | JP5593378B2 (https=) |
| KR (1) | KR20120003453A (https=) |
| CN (1) | CN102396092A (https=) |
| CA (1) | CA2758316A1 (https=) |
| WO (1) | WO2010120690A2 (https=) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2784686C (en) | 2009-12-17 | 2018-02-20 | Phostech Lithium Inc. | Method for improving the electrochemical performances of an alkali metal oxyanion electrode material and alkali metal oxyanion electrode material obtained therefrom |
| WO2017100184A1 (en) * | 2015-12-07 | 2017-06-15 | Aquion Energy Inc. | Anode electrode including doped electrode active material and energy storage device including same |
| TWI762404B (zh) | 2021-08-17 | 2022-04-21 | 台灣立凱電能科技股份有限公司 | 二次電池正極材料的製造方法 |
| CN117638055B (zh) * | 2022-08-10 | 2024-09-10 | 比亚迪股份有限公司 | 一种电池材料及其制备方法、应用 |
| CN117550638B (zh) * | 2024-01-11 | 2024-05-17 | 淄博火炬能源有限责任公司 | 钠离子电池负极材料及其制备方法 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6514640B1 (en) * | 1996-04-23 | 2003-02-04 | Board Of Regents, The University Of Texas System | Cathode materials for secondary (rechargeable) lithium batteries |
| US5871866A (en) | 1996-09-23 | 1999-02-16 | Valence Technology, Inc. | Lithium-containing phosphates, method of preparation, and use thereof |
| US6153333A (en) * | 1999-03-23 | 2000-11-28 | Valence Technology, Inc. | Lithium-containing phosphate active materials |
| US7001690B2 (en) | 2000-01-18 | 2006-02-21 | Valence Technology, Inc. | Lithium-based active materials and preparation thereof |
| US6528033B1 (en) | 2000-01-18 | 2003-03-04 | Valence Technology, Inc. | Method of making lithium-containing materials |
| US6387568B1 (en) | 2000-04-27 | 2002-05-14 | Valence Technology, Inc. | Lithium metal fluorophosphate materials and preparation thereof |
| US8057769B2 (en) | 2000-04-27 | 2011-11-15 | Valence Technology, Inc. | Method for making phosphate-based electrode active materials |
| US6645452B1 (en) | 2000-11-28 | 2003-11-11 | Valence Technology, Inc. | Methods of making lithium metal cathode active materials |
| US7338734B2 (en) * | 2001-12-21 | 2008-03-04 | Massachusetts Institute Of Technology | Conductive lithium storage electrode |
| ATE433202T1 (de) | 2002-12-19 | 2009-06-15 | Valence Technology Inc | Aktives elektrodenmaterial und verfahren zur herstellung desselben |
| KR100904523B1 (ko) | 2002-12-26 | 2009-06-25 | 엘지디스플레이 주식회사 | 액티브 매트릭스형 유기전계발광 소자용 박막트랜지스터 |
| JP3887317B2 (ja) * | 2003-01-09 | 2007-02-28 | 株式会社東芝 | 非水電解質二次電池 |
| US7338647B2 (en) | 2004-05-20 | 2008-03-04 | Valence Technology, Inc. | Synthesis of cathode active materials |
| US20070160519A1 (en) | 2005-03-28 | 2007-07-12 | Jeremy Barker | Method Of Making Active Materials For Use In Secondary Electrochemical Cells |
| US8158090B2 (en) * | 2005-08-08 | 2012-04-17 | A123 Systems, Inc. | Amorphous and partially amorphous nanoscale ion storage materials |
| US20080305256A1 (en) | 2007-06-08 | 2008-12-11 | Conocophillips Company | Method for producing lithium vanadium polyanion powders for batteries |
| US20080303004A1 (en) | 2007-06-08 | 2008-12-11 | Conocophillips Company | Method for producing lithium transition metal polyanion powders for batteries |
| US20090035661A1 (en) | 2007-08-01 | 2009-02-05 | Jeffrey Swoyer | Synthesis of cathode active materials |
| US20090068080A1 (en) | 2007-09-06 | 2009-03-12 | Valence Technology, Inc. | Method of Making Active Materials For Use in Secondary Electrochemical Cells |
| EP2212247B1 (en) * | 2007-10-01 | 2013-07-17 | Basf Se | Process for the preparation of crystalline lithium-, vanadium- and phosphate-comprising materials |
| US20090148377A1 (en) | 2007-12-11 | 2009-06-11 | Moshage Ralph E | Process For Producing Electrode Active Material For Lithium Ion Cell |
-
2010
- 2010-04-01 US US12/752,707 patent/US8372540B2/en not_active Expired - Fee Related
- 2010-04-12 KR KR1020117024187A patent/KR20120003453A/ko not_active Withdrawn
- 2010-04-12 EP EP10764972.5A patent/EP2419954A4/en not_active Withdrawn
- 2010-04-12 CA CA2758316A patent/CA2758316A1/en not_active Abandoned
- 2010-04-12 JP JP2012506097A patent/JP5593378B2/ja not_active Expired - Fee Related
- 2010-04-12 WO PCT/US2010/030745 patent/WO2010120690A2/en not_active Ceased
- 2010-04-12 CN CN2010800169880A patent/CN102396092A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| WO2010120690A3 (en) | 2011-01-20 |
| JP5593378B2 (ja) | 2014-09-24 |
| CN102396092A (zh) | 2012-03-28 |
| CA2758316A1 (en) | 2010-10-21 |
| US20110070499A1 (en) | 2011-03-24 |
| US8372540B2 (en) | 2013-02-12 |
| JP2012524379A (ja) | 2012-10-11 |
| EP2419954A2 (en) | 2012-02-22 |
| EP2419954A4 (en) | 2013-10-02 |
| WO2010120690A2 (en) | 2010-10-21 |
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