KR20070057196A - 최적화된 액상 산화 방법 - Google Patents
최적화된 액상 산화 방법 Download PDFInfo
- Publication number
- KR20070057196A KR20070057196A KR1020077006755A KR20077006755A KR20070057196A KR 20070057196 A KR20070057196 A KR 20070057196A KR 1020077006755 A KR1020077006755 A KR 1020077006755A KR 20077006755 A KR20077006755 A KR 20077006755A KR 20070057196 A KR20070057196 A KR 20070057196A
- Authority
- KR
- South Korea
- Prior art keywords
- reaction medium
- reaction
- reactor
- reaction zone
- oxidation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B33/00—Oxidation in general
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60673204P | 2004-09-02 | 2004-09-02 | |
| US60/606,732 | 2004-09-02 | ||
| US63151904P | 2004-11-29 | 2004-11-29 | |
| US60/631,519 | 2004-11-29 | ||
| US11/154,480 US7495125B2 (en) | 2004-09-02 | 2005-06-16 | Optimized liquid-phase oxidation |
| US11/154,480 | 2005-06-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20070057196A true KR20070057196A (ko) | 2007-06-04 |
Family
ID=35482361
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020077006755A Ceased KR20070057196A (ko) | 2004-09-02 | 2005-08-29 | 최적화된 액상 산화 방법 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7495125B2 (https=) |
| EP (1) | EP1786745A1 (https=) |
| JP (1) | JP2008511641A (https=) |
| KR (1) | KR20070057196A (https=) |
| BR (1) | BRPI0514784A (https=) |
| CA (1) | CA2577055A1 (https=) |
| MX (1) | MX2007002507A (https=) |
| WO (1) | WO2006028755A1 (https=) |
Family Cites Families (266)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1902550A (en) * | 1930-01-31 | 1933-03-21 | Nat Synthetic Corp | Process of oxidizing cyclic organic compounds |
| US1936427A (en) | 1930-01-31 | 1933-11-21 | Nat Synthetic Corp | Process of oxidizing naphthalene and related condensed aromatic ring compounds |
| US2572575A (en) | 1949-09-23 | 1951-10-23 | Monsanto Chemicals | Preparation of terephthalic acid |
| US2572710A (en) | 1949-09-23 | 1951-10-23 | Monsanto Chemicals | Preparation of terephthalic acid |
| US3064044A (en) * | 1957-08-15 | 1962-11-13 | Standard Oil Co | Multistage oxidation system for preparing dicarboxylic acid |
| US3082250A (en) * | 1958-05-05 | 1963-03-19 | Standard Oil Co | Recovery of phthalic acid products |
| US3071447A (en) * | 1958-09-09 | 1963-01-01 | Whiting Corp | Hydraulic classifier |
| US3029278A (en) * | 1958-12-11 | 1962-04-10 | Standard Oil Co | Process for separation of phthalic acids |
| AT236346B (de) | 1961-01-25 | 1964-10-12 | Union Carbide Corp | Boden zum Inberührungbringen von Flüssigkeit und Gas |
| US3257363A (en) | 1961-05-22 | 1966-06-21 | Phillips Petroleum Co | Control of the composition of a reaction mixture |
| GB1007570A (en) * | 1961-07-24 | 1965-10-13 | Socaty | Process for the catalytic oxidation of xylenes or industrial mixtures of xylenes |
| BE621323A (https=) * | 1961-08-14 | |||
| US3216481A (en) | 1962-04-17 | 1965-11-09 | Badger Co | Recovery of phthalic and maleic acid from solutions |
| NL294776A (https=) * | 1962-10-06 | |||
| US3244744A (en) * | 1963-02-27 | 1966-04-05 | Standard Oil Co | Separation process for isophthalic acid and terephthalic acid |
| FR1394471A (fr) | 1963-04-30 | 1965-04-02 | Standard Oil Co | Perfectionnements aux procédés pour la préparation d'acides benzène-polycarboxyliques de haute pureté |
| GB1062482A (en) | 1963-04-30 | 1967-03-22 | Standard Oil Co | High quality phthalic acids |
| DE1276628C2 (de) * | 1963-05-20 | 1975-01-16 | Rudzki, Henryk Stanislaw, Dr., Los Angeles, Calif. (V.St.A.) | Verfahren zur herstellung von isophtalsaeure und/oder terephthalsaeure |
| US3410897A (en) | 1963-10-10 | 1968-11-12 | Maruzen Oil Company Ltd | Purification of terephthalic acid |
| US3293288A (en) | 1963-12-02 | 1966-12-20 | Exxon Research Engineering Co | Process for the separation of monobasic and dibasic aromatic acids |
| US3388157A (en) * | 1965-02-10 | 1968-06-11 | Ethyl Corp | Process for the production of dicarboxylic acids |
| NL6606774A (https=) * | 1965-05-17 | 1966-11-18 | ||
| GB1142864A (en) | 1965-11-15 | 1969-02-12 | Ici Ltd | Crystallisation process |
| US3497552A (en) * | 1966-07-18 | 1970-02-24 | Standard Oil Co | Continuous crystallization in a plurality of cooling stages using dilutions by cooled solvent of feed to each stage |
| US3549695A (en) | 1966-09-01 | 1970-12-22 | Mobil Oil Corp | Method for downflow leaching |
| US3534090A (en) | 1966-11-04 | 1970-10-13 | Mobil Oil Corp | Hydrocarbon oxidation |
| US3584039A (en) * | 1967-08-30 | 1971-06-08 | Standard Oil Co | Fiber-grade terephthalic acid by catalytic hydrogen treatment of dissolved impure terephthalic acid |
| US3556733A (en) * | 1968-04-05 | 1971-01-19 | Struthers Scientific Int Corp | Fines dissolver for crystallizers |
| FR2006269A1 (https=) | 1968-04-16 | 1969-12-26 | Celanese Corp | |
| US3850981A (en) | 1968-04-16 | 1974-11-26 | Celanese Corp | Liquid phase oxidation of p-xylene to terephthalic acid |
| US3626001A (en) | 1968-05-09 | 1971-12-07 | Atlantic Richfield Co | Method for the production of high-purity isophthalic or terephthalic acid |
| AT282466B (de) * | 1968-07-25 | 1970-06-25 | Oemv Ag | Bitumenblasverfahren und Einrichtung zur Durchführung desselben |
| DE1792402A1 (de) * | 1968-08-29 | 1971-11-11 | Dynamit Nobel Ag | Verfahren zur Durchfuehrung exothermer chemischer Reaktionen in heterogenen Gas-Fluessigkeits-Gemischen |
| GB1250222A (https=) | 1968-10-25 | 1971-10-20 | ||
| CA849014A (en) | 1968-10-25 | 1970-08-11 | Ichikawa Yataro | Apparatus for continuous gas-liquid contact and process for refining crude terephthalic acid |
| US3660476A (en) * | 1968-10-30 | 1972-05-02 | Teijin Ltd | Method for the preparation of terephthalic acid |
| US3708532A (en) * | 1968-11-04 | 1973-01-02 | Teijin Ltd | Process for the continuous purification of crude terephthalic acid |
| BE724040A (https=) | 1968-11-18 | 1969-05-02 | ||
| US3700731A (en) | 1969-02-28 | 1972-10-24 | Du Pont | Process for oxidizing xylenes to phthalic acids |
| US3629321A (en) | 1969-05-26 | 1971-12-21 | Standard Oil Co | Integration of para-xylene oxidation to terephthalic acid and its esterification to dimethyl terephthalate |
| US3683018A (en) | 1969-05-26 | 1972-08-08 | Standard Oil Co | Integrated oxidation of isomeric xylene mixture to isomeric phthalic acid mixture and separation of mixture of isomeric phthalic acids into individual isomer products |
| US3839436A (en) | 1969-05-26 | 1974-10-01 | Standard Oil Co | Integration of para-or meta-xylene oxidation to terephthalic acid or isophthalic acid and its purification by hydrogen treatment of aqueous solution |
| DE1927937A1 (de) | 1969-05-31 | 1970-12-17 | Dynamit Nobel Ag | Verfahren zur Herstellung von Benzoldicarbonsaeuren bzw. Benzoldicarbonsaeureestern |
| US3873275A (en) | 1969-09-29 | 1975-03-25 | Whiting Corp | Crystallization apparatus and method |
| BE759284A (fr) | 1969-11-24 | 1971-05-24 | Shell Int Research | Procede et appareil pour la mise en contact d'un liquide avec des particules solides |
| GB1301291A (https=) | 1969-12-01 | 1972-12-29 | ||
| US3686293A (en) | 1970-07-13 | 1972-08-22 | Giorgio Gualdi | Process for the preparation of aromatic carboxylic acids |
| JPS5328419B1 (https=) * | 1971-04-26 | 1978-08-15 | ||
| US3785779A (en) * | 1971-08-02 | 1974-01-15 | Exxon Research Engineering Co | Gas liquid inlet distributor |
| JPS5544644B2 (https=) * | 1971-09-23 | 1980-11-13 | ||
| GB1373230A (en) | 1971-12-23 | 1974-11-06 | Mitsui Petrochemical Ind | Process for producing terephthalic acid |
| JPS5234590B2 (https=) | 1971-12-28 | 1977-09-03 | ||
| NL169993C (nl) * | 1972-01-13 | 1982-09-16 | Maruzen Oil Co Ltd | Werkwijze ter bereiding van tereftaalzuur. |
| DE2217003C2 (de) * | 1972-04-08 | 1983-12-15 | Chemische Werke Hüls AG, 4370 Marl | Verfahren und Vorrichtung zur kontinuierlichen Herstellung von gesättigten aliphatischen Dicarbonsäuren |
| US3845117A (en) | 1972-12-14 | 1974-10-29 | Halcon International Inc | Process for preparation of phthalic acids |
| JPS5315377B2 (https=) | 1973-03-09 | 1978-05-24 | ||
| JPS5328421B2 (https=) | 1973-05-15 | 1978-08-15 | ||
| US3931305A (en) * | 1973-08-20 | 1976-01-06 | Standard Oil Company | Terephthalic acid recovery by continuous flash crystallization |
| JPS5328902B2 (https=) | 1973-09-14 | 1978-08-17 | ||
| US3850983A (en) | 1973-10-15 | 1974-11-26 | Standard Oil Co | Separation of terephthalic from paratoluic acid from solutions thereof in water and/or acetic acid |
| US4053506A (en) | 1975-05-02 | 1977-10-11 | Standard Oil Company (Indiana) | Production of fiber-grade terephthalic acid |
| BE847474A (fr) | 1975-10-24 | 1977-04-20 | Oxydation secondaire d'un effluent fluide de l'oxydation primaire du m-xylene ou du p-xylene, | |
| US3997620A (en) | 1975-10-28 | 1976-12-14 | Uop Inc. | Process for separating para-xylene |
| JPS5912096B2 (ja) * | 1975-10-31 | 1984-03-21 | 三菱化学株式会社 | ホウコウゾクポリカルボンサンノセイゾウホウ |
| JPS5278846A (en) * | 1975-12-25 | 1977-07-02 | Matsuyama Sekyu Kagaku Kk | Continuous production of high purity telephthalic acid |
| GB1574651A (en) * | 1976-02-24 | 1980-09-10 | Matsuyama Petrochemicals Inc | Process and apparatus for producing aromatic dicarboxylic acids |
| SU1126202A3 (ru) * | 1976-05-28 | 1984-11-23 | Институт Фор Атомэнерги (Фирма) | Способ непрерывной многостадийной кристаллизации из раствора |
| DE2623977C3 (de) | 1976-05-28 | 1979-04-12 | Nukem Gmbh, 6450 Hanau | Verfahren und Vorrichtung zur Herstellung von rieselfähigem, direkt verpressbarem Urandioxid-Pulver |
| US4081464A (en) * | 1976-07-26 | 1978-03-28 | Standard Oil Company | Iso- or terephthalic acid production in and recovery from benzoic acid-water solvent system |
| US4185073A (en) * | 1976-07-26 | 1980-01-22 | Standard Oil Company (Indiana) | Apparatus for iso- or terephthalic acid production in and recovery from benzoic acid-water solvent system |
| GB1542320A (en) * | 1976-10-26 | 1979-03-14 | Labofina Sa | Process for the preparation of aromatic dicarboxylic acids |
| NL188282C (nl) | 1977-04-04 | 1992-05-18 | Montedison Spa | Werkwijze voor de synthese van tereftaalzuur door oxyderen van p-xyleen in azijnzuuroplossing. |
| US4158738A (en) * | 1977-05-26 | 1979-06-19 | E. I. Du Pont De Nemours And Company | Process for the production of fiber-grade terephthalic acid |
| JPS5718647Y2 (https=) | 1977-11-29 | 1982-04-19 | ||
| US4482524A (en) | 1978-01-31 | 1984-11-13 | Ari Technologies, Inc. | Autocirculation apparatus |
| DE2805915C3 (de) * | 1978-02-13 | 1981-11-05 | Dynamit Nobel Ag, 5210 Troisdorf | Reaktor zur Oxidation von Gemischen aus p-Xylol und p-Toluylsäuremethylester mit sauerstoffhaltigen Gasen in flüssiger Phase |
| US4233269A (en) | 1978-11-09 | 1980-11-11 | Exxon Research & Engineering Co. | Gas liquid distributor |
| US4263448A (en) * | 1979-03-30 | 1981-04-21 | Halcon Research And Development Corp. | Process for oxidation of hydrocarbons |
| US4255590A (en) * | 1979-11-08 | 1981-03-10 | Standard Oil Company (Indiana) | Combination of pyrolysis and incineration of solid mixture of oxygen-containing aromatic compounds obtained as residue of manufacture of benzene di- and tricarboxylic acids |
| IT1129759B (it) | 1980-01-23 | 1986-06-11 | Montedison Spa | Metodo per ricuperare in forma attiva i componenti del sistema catalitico della sintesi dell'acido tereftalico |
| GB2072162B (en) | 1980-03-21 | 1984-03-21 | Labofina Sa | Process for the production and the recovery of terephthalic acid |
| DE3047101A1 (de) | 1980-12-13 | 1982-07-22 | Hoechst Ag, 6000 Frankfurt | Verfahren zum verbessern der gasverteilung in mammut-schlaufenreaktoren |
| US4342876A (en) | 1980-12-22 | 1982-08-03 | Bechtel International Corporation | Method for oxidation of p-xylene and method for preparing dimethylterephthalate |
| US4334086A (en) * | 1981-03-16 | 1982-06-08 | Labofina S.A. | Production of terephthalic acid |
| US4459365A (en) * | 1981-05-29 | 1984-07-10 | Mitsubishi Gas Chemical Company, Inc. | Method of recovering a catalytic metal |
| US4456767A (en) * | 1981-07-27 | 1984-06-26 | Rhone-Poulenc, Inc. | Solvent and catalyst recovery and recycle in the manufacture of phenoxybenzoic acid |
| US4391985A (en) * | 1981-11-16 | 1983-07-05 | Eastman Kodak Company | Process for the separation of isophthalic acid from terephthalic acid |
| EP0086019B2 (de) * | 1982-02-09 | 1989-11-29 | BBC Brown Boveri AG | Vorrichtung zur Begasung einer Flüssigkeit und Verfahren zum Betrieb der Vorrichtung |
| JPS58177106A (ja) * | 1982-04-13 | 1983-10-17 | Jgc Corp | 多段式高流速気液接触装置 |
| JPS58189134U (ja) | 1982-06-07 | 1983-12-15 | 小野 勝義 | ヘルメツト |
| JPS58189135U (ja) | 1982-06-12 | 1983-12-15 | 株式会社誠実堂製帽所 | 帽子 |
| JPS59104345A (ja) * | 1982-12-03 | 1984-06-16 | Kuraray Yuka Kk | 直接重合用に適したテレフタル酸の製造方法 |
| JPS59106435A (ja) | 1982-12-10 | 1984-06-20 | Mitsubishi Chem Ind Ltd | 高純度テレフタル酸の製法 |
| JPS5993029U (ja) | 1982-12-15 | 1984-06-23 | 株式会社東海理化電機製作所 | 照明付き押釦装置 |
| JPS59193101U (ja) | 1983-06-10 | 1984-12-21 | 谷末 洋三 | テ−プ掛け装置 |
| JPS59196705U (ja) | 1983-06-16 | 1984-12-27 | セイレイ工業株式会社 | トラクタのリフトア−ム昇降用油圧シリンダ構造 |
| JPS6036439A (ja) * | 1983-08-09 | 1985-02-25 | Mitsubishi Chem Ind Ltd | テレフタル酸の製法 |
| US4500732A (en) * | 1983-09-15 | 1985-02-19 | Standard Oil Company (Indiana) | Process for removal and recycle of p-toluic acid from terephthalic acid crystallizer solvent |
| US4769487A (en) | 1984-08-20 | 1988-09-06 | Amoco Corporation | Multistage oxidation in a single reactor |
| US4605763A (en) | 1984-08-31 | 1986-08-12 | Eastman Kodak Company | Process for the purification of terephthalic acid |
| US4777287A (en) | 1984-10-29 | 1988-10-11 | Amoco Corporation | Recycle of vaporized solvent in liquid phase oxidation of an alkyl aromatic |
| US4835307A (en) * | 1984-12-13 | 1989-05-30 | Amoco Corporation | Method and apparatus for controlling the manufacture of terephthalic acid to control the level and variability of the contaminant content and the optical density |
| US4648999A (en) * | 1985-07-22 | 1987-03-10 | M. W. Kellogg Company | Apparatus for contacting fluid with solid |
| GB8527335D0 (en) | 1985-11-06 | 1985-12-11 | Ici Plc | Fermentation process |
| US5099064A (en) * | 1985-12-30 | 1992-03-24 | Amoco Corporation | Method for increasing conversion efficiency for oxidation of an alkyl aromatic compound to an aromatic carboxylic acid |
| US4892970A (en) * | 1985-12-30 | 1990-01-09 | Amoco Corporation | Staged aromatics oxidation in aqueous systems |
| JPS62192490U (https=) | 1986-05-21 | 1987-12-07 | ||
| DE3625261A1 (de) | 1986-07-25 | 1988-02-04 | Basf Ag | Verfahren zur kontinuierlichen hydroformylierung olefinisch ungesaettigter verbindungen |
| US4769489A (en) | 1986-07-28 | 1988-09-06 | Amoco Corporation | Catalyst recovery method |
| US4914230A (en) * | 1986-07-28 | 1990-04-03 | Amoco Corporation | Catalyst recovery method |
| JPH078821B2 (ja) * | 1986-09-26 | 1995-02-01 | 三井石油化学工業株式会社 | 芳香族カルボン酸の製造方法 |
| JPH078823B2 (ja) | 1986-10-20 | 1995-02-01 | 三井石油化学工業株式会社 | 高純度テレフタル酸の製造方法 |
| US5166420A (en) | 1986-10-20 | 1992-11-24 | Mitsui Petrochemical Industries, Ltd. | Process for the production of high purity terephthalic acid |
| US4900480A (en) * | 1986-10-21 | 1990-02-13 | Union Carbide Corporation | Gas-liquid mixing |
| DE3641305C1 (de) | 1986-12-03 | 1988-03-24 | Kalk Chemische Fabrik Gmbh | Verfahren und Vorrichtung zur Herstellung einer suspendiertes Calciumcarbonat enthaltenden Ammoniumnitratloesung |
| DE3704720A1 (de) * | 1987-02-14 | 1988-08-25 | Huels Troisdorf | Verfahren und vorrichtung zur herstellung von benzolcarbonsaeuren bzw. benzoldicarbonsaeureestern |
| JPS63209702A (ja) | 1987-02-25 | 1988-08-31 | Ishikawajima Harima Heavy Ind Co Ltd | 結晶缶の運転方法 |
| JPS63237207A (ja) | 1987-03-24 | 1988-10-03 | Ube Ind Ltd | 垂直磁気記録媒体の製造方法 |
| JP2504461B2 (ja) | 1987-04-24 | 1996-06-05 | 三菱化学株式会社 | 高品質テレフタル酸の製法 |
| DE3839229A1 (de) | 1988-11-19 | 1990-05-23 | Krupp Koppers Gmbh | Verfahren zur gewinnung von p-xylol mit einer reinheit von mehr als 99,8 gew.-% |
| US5211924A (en) * | 1988-02-29 | 1993-05-18 | Amoco Corporation | Method and apparatus for increasing conversion efficiency and reducing power costs for oxidation of an aromatic alkyl to an aromatic carboxylic acid |
| US4855491A (en) | 1988-04-25 | 1989-08-08 | Amoco Corporation | Method for selectively removing process stream impurities utilizing reverse osmosis |
| US4863888A (en) | 1988-04-29 | 1989-09-05 | Amoco Corporation | Catalyst containing cobalt boron and oxygen and optionally aluminum of preparation and process |
| GB8811114D0 (en) | 1988-05-11 | 1988-06-15 | Ici Plc | Fermentation process & apparatus |
| US4855492A (en) | 1988-05-27 | 1989-08-08 | Amoco Corporation | Process for production of aromatic polycarboxylic acids |
| US4833269A (en) * | 1988-08-05 | 1989-05-23 | Amoco Corporation | Method for purifying terephthalic acid recycle streams |
| US4939297A (en) * | 1989-06-05 | 1990-07-03 | Eastman Kodak Company | Extraction process for removal of impurities from terephthalic acid filtrate |
| US5068406A (en) | 1989-09-06 | 1991-11-26 | Amoco Corporation | Compartmented oxidation method |
| US5004830A (en) * | 1989-11-29 | 1991-04-02 | Amoco Corporation | Process for oxidation of alkyl aromatic compounds |
| US5126037A (en) * | 1990-05-04 | 1992-06-30 | Union Oil Company Of California | Geopreater heating method and apparatus |
| KR920004602B1 (ko) | 1990-06-07 | 1992-06-11 | 재단법인 한국화학연구소 | 1-옥소-1, 2, 3, 4-테트라하이드로나프탈렌의 제조방법 |
| US5132450A (en) * | 1990-06-25 | 1992-07-21 | Mitsubishi Gas Chemical Company, Inc. | Process for producing high purity isophthalic acid |
| US5356600A (en) | 1990-09-24 | 1994-10-18 | Praxair Technology, Inc. | Oxygen enrichment method and system |
| US5095145A (en) * | 1990-11-05 | 1992-03-10 | Amoco Corporation | Preparation of purified terephthalic acid from waste polyethylene terephthalate |
| US5095142A (en) * | 1990-11-29 | 1992-03-10 | Amoco Corporation | Solvent recovery during production of aromatic polycarboxylic acids |
| GB9102393D0 (en) * | 1991-02-05 | 1991-03-20 | Ici Plc | Production of terephthalic acid |
| GB9104776D0 (en) | 1991-03-07 | 1991-04-17 | Ici Plc | Process for the production of terephthalic acid |
| US5175355A (en) | 1991-04-12 | 1992-12-29 | Amoco Corporation | Improved process for recovery of purified terephthalic acid |
| US5227570A (en) * | 1991-12-02 | 1993-07-13 | Taiwan Styrene Monomer Corporation | Process for separation of ethylbenzene or ethylbenzene/p-xylene from a xylene isomers mixture |
| US6489527B1 (en) | 1992-05-26 | 2002-12-03 | John Di-Yi Ou | Process for improving purity of para-xylene product |
| GB9310070D0 (en) | 1992-05-29 | 1993-06-30 | Ici Plc | Process for the production of purified terephthalic acid |
| GB9211415D0 (en) | 1992-05-29 | 1992-07-15 | Ici Plc | Process for the production of purified terephthalic acid |
| US5292934A (en) * | 1992-06-18 | 1994-03-08 | Amoco Corporation | Method for preparing aromatic carboxylic acids |
| JPH06215618A (ja) | 1993-01-12 | 1994-08-05 | Tokai Carbon Co Ltd | TiCウイスカーを含む導電性樹脂組成物の製造方法 |
| KR970000136B1 (ko) | 1993-09-28 | 1997-01-04 | 브이.피. 유리예프 | 고순도 벤젠디카르복실산 이성질체의 제조방법 |
| FR2715395B1 (fr) | 1994-01-26 | 1997-02-07 | Anjou Rech | Unite de traitement d'eau par ozonation, et installation de production d'eau ozonee correspondante |
| US5523474A (en) * | 1994-05-11 | 1996-06-04 | Praxair Technology, Inc. | Terephthalic acid production using evaporative cooling |
| US5518700A (en) | 1994-06-25 | 1996-05-21 | Shell Oil Company | Cyclonic reactor |
| JPH10503103A (ja) | 1994-07-25 | 1998-03-24 | アドバンスト・カーディオバスキュラー・システムズ・インコーポレイテッド | 潤滑性表面を有する複合体ポリエステル材料 |
| DE69422623T2 (de) | 1994-09-27 | 2000-06-29 | Chevron Chemical Co. Llc, San Francisco | Herstellung von reinem Benzol und Paraxylenen durch Kombinieren einer Aromatisierung und einer Disproportionierung von unreinem Toluol |
| US5567842A (en) | 1994-11-16 | 1996-10-22 | Mitsubishi Chemical Corporation | Process for producing terephthalic acid |
| JPH08151347A (ja) | 1994-11-28 | 1996-06-11 | Mitsubishi Chem Corp | テレフタル酸の製造法 |
| US5712412A (en) * | 1994-12-26 | 1998-01-27 | Mitsubishi Gas Chemical Co., Inc. | Process for producing highly pure terephthalic acid |
| FR2728894A1 (fr) | 1994-12-29 | 1996-07-05 | Inst Francais Du Petrole | Procede de separation de paraxylene comportant au moins deux etages de cristallisation a haute temperature |
| SI9500109A (en) * | 1995-04-05 | 1996-10-31 | Levec Janez Dipl Ing Prof Dr | Apparatus and Process for Thermal Oxidative Treatment of Waste Waters |
| GB2299767B (en) | 1995-04-07 | 1998-05-13 | Norske Stats Oljeselskap | Regneration of fischer-tropsch catalysts |
| JP3979505B2 (ja) | 1995-05-17 | 2007-09-19 | 三菱瓦斯化学株式会社 | 高純度テレフタル酸の製造方法 |
| JPH08325197A (ja) | 1995-05-30 | 1996-12-10 | Mitsubishi Gas Chem Co Inc | テレフタル酸の製造方法 |
| US5801282A (en) | 1995-06-07 | 1998-09-01 | Twenty-First Century Research Corporation | Methods of making intermediate oxidation products by controlling pre-coalescing temperature and transient temperature difference in an atomized liquid |
| US5929274A (en) * | 1995-06-07 | 1999-07-27 | Hfm International, Inc. | Method to reduce carboxybenzaldehyde isomers in terephthalic acid or isophthalic acid |
| US5767311A (en) * | 1995-06-07 | 1998-06-16 | Glitsch International, Inc. | Method and apparatus for preparing purified terephtalic acid |
| US5840968A (en) | 1995-06-07 | 1998-11-24 | Hfm International, Inc. | Method and apparatus for preparing purified terephthalic acid |
| US5580531A (en) | 1995-06-07 | 1996-12-03 | Twenty-First Century Research Corporation | Devices for making reaction products by controlling transient conversion in an atomized liquid |
| US6013835A (en) * | 1995-06-07 | 2000-01-11 | Hfm International, Inc. | Method and apparatus for preparing purified terephthalic acid |
| ES2104512B1 (es) * | 1995-09-21 | 1998-07-01 | Interquisa | Procedimiento industrial para la fabricacion de acidos carboxilicos aromaticos. |
| FR2739375B1 (fr) * | 1995-09-29 | 1997-12-05 | Inst Francais Du Petrole | Production de paraxylene a partir d'un effluent de dismutation paraselective du toluene par un procede de cristallisation associe a une adsorption en lit mobile simule |
| US5696285A (en) | 1995-12-29 | 1997-12-09 | Praxair Technology, Inc. | Production of terephthalic acid with excellent optical properties through the use of pure or nearly pure oxygen as the oxidant in p-xylene oxidation |
| US5693856A (en) | 1996-01-16 | 1997-12-02 | The Boc Group, Inc. | Production of terephthalic acid |
| CA2273958A1 (en) | 1996-01-25 | 1997-07-31 | E.I. Du Pont De Nemours And Company | Production of aromatic carboxylic acids |
| US6376733B1 (en) * | 1996-01-25 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Process for production of paraxylene |
| US5756833A (en) * | 1996-02-01 | 1998-05-26 | Amoco Corporation | Catalytic purification and recovery of dicarboxylic aromatic acids |
| ID15851A (id) * | 1996-02-13 | 1997-08-14 | Mitsubishi Chem Corp | Proses untuk menghasilkan suatu asam aromatik karboksilik |
| JPH09278709A (ja) * | 1996-02-13 | 1997-10-28 | Mitsubishi Chem Corp | 芳香族カルボン酸の製造方法 |
| TR199801626T2 (xx) | 1996-02-22 | 1999-08-23 | E.I. Du Pont De Nemours And Company | Aromatik polikarboksilik asitlerin �retilmesi. |
| US6084125A (en) | 1996-02-27 | 2000-07-04 | Praxair Technology, Inc. | Process for producing aliphatic acids using a reactor system having a shell and a tube reactor configuration to force circulation of reaction liquid |
| US5824207A (en) | 1996-04-30 | 1998-10-20 | Novetek Octane Enhancement, Ltd. | Method and apparatus for oxidizing an organic liquid |
| US6242643B1 (en) | 1996-05-17 | 2001-06-05 | Toray Industries, Inc. | Method for preparing aromatic carboxylic acids, aromatic aldehydes, and aromatic alcohols |
| US6288270B1 (en) | 1996-06-24 | 2001-09-11 | Rpc Inc. | Methods for controlling the reaction rate of a hydrocarbon to an acid by making phase-related adjustments |
| JP3757995B2 (ja) * | 1996-07-12 | 2006-03-22 | 三菱瓦斯化学株式会社 | 高純度イソフタル酸の製造方法 |
| JPH1045667A (ja) * | 1996-07-29 | 1998-02-17 | Mitsubishi Gas Chem Co Inc | 分散媒置換装置を用いた高純度テレフタル酸の製造方法 |
| CA2263605A1 (en) | 1996-08-21 | 1998-02-26 | Eustathios Vassiliou | Methods and devices for controlling the reaction by adjusting the oxidant consumption rate |
| US6133476A (en) | 1996-09-17 | 2000-10-17 | Lin; Tsong-Dar Vincent | Process for purification of aromatic polycarboxylic acids |
| ATE343400T1 (de) * | 1996-09-24 | 2006-11-15 | Merck & Co Inc | Verbindungen zur hemmung der angiogenese durch gentherapie |
| IT1288760B1 (it) | 1996-10-17 | 1998-09-24 | Fiat Ricerche | Motore elettrostatico lineare |
| US5817868A (en) | 1996-11-12 | 1998-10-06 | Twenty-First Century Research Corporation | Method and devices for controlling the oxidation of a hydrocarbon to an acid by regulating temperature/conversion relationship in multi-stage arrangements |
| ID19133A (id) | 1996-12-12 | 1998-06-18 | Praxair Technology Inc | Pengisian oksigen langsung kedalam reaktor-reaktor ruang gelembung |
| US5824819A (en) | 1996-12-18 | 1998-10-20 | Twenty-First Century Research Corporation | Methods of preparing an intermediate oxidation product from a hydrocarbon by utilizing an activated initiator |
| GB9701251D0 (en) * | 1997-01-22 | 1997-03-12 | Bp Chem Int Ltd | Process |
| JP3804150B2 (ja) | 1997-02-17 | 2006-08-02 | 三井化学株式会社 | 高純度テレフタル酸の製造方法 |
| KR100264749B1 (ko) | 1997-02-17 | 2000-09-01 | 나까니시 히로유끼 | 고순도 테레프탈산의 제조 방법 |
| DE69818651T2 (de) | 1997-02-27 | 2004-07-29 | E.I. Du Pont De Nemours And Co., Wilmington | Herstellung von terephthalsäure |
| US6288273B1 (en) | 1997-02-27 | 2001-09-11 | Basf Aktiengesellschaft | Method for producing shell catalysts for catalytic gas-phase oxidation of aromatic hydrocarbons |
| US5811363A (en) | 1997-05-02 | 1998-09-22 | Exxon Research And Engineering Company | Catalyst rejuvenation in hydrocarbon synthesis slurry with reduced slurry recontamination |
| US5817702A (en) | 1997-05-02 | 1998-10-06 | Exxon Research And Engineering Company | Hydrocarbon synthesis catalyst slurry rejuvenation with gas disengagement |
| US5811468A (en) | 1997-05-06 | 1998-09-22 | Exxon Research And Engineering Company | Combination gas disengaging downcomer-rejuvenation tube for in-situ slurry catalyst rejuvenation (LAW541) |
| US6037491A (en) * | 1997-07-25 | 2000-03-14 | Rpc Inc. | Methods and devices for controlling hydrocarbon oxidations to respective acids by adjusting the solvent to hydrocarbon ratio |
| US5939313A (en) | 1997-09-12 | 1999-08-17 | Praxair Technology, Inc. | Stationary vortex system for direct injection of supplemental reactor oxygen |
| FR2768724B1 (fr) | 1997-09-23 | 1999-12-03 | Inst Francais Du Petrole | Procede de production de paraxylene comprenant une etape d'adsorption et une etape d'isomerisation en phase liquide |
| US6004452A (en) | 1997-11-14 | 1999-12-21 | Chevron Chemical Company Llc | Process for converting hydrocarbon feed to high purity benzene and high purity paraxylene |
| CA2318741A1 (en) * | 1998-02-09 | 1999-08-12 | Ader M. Rostami | Process for treating cobalt catalyst in oxidation mixtures of hydrocarbons to dibasic acids |
| JP3664867B2 (ja) | 1998-03-13 | 2005-06-29 | 三菱重工業株式会社 | Pcb分解反応容器 |
| EP0952142B1 (en) | 1998-04-20 | 2006-10-18 | Givaudan SA | Compounds with protected hydroxy groups |
| US6362367B2 (en) * | 1998-04-21 | 2002-03-26 | Union Carbide Chemicals & Plastics Technology Corp. | Preparation of organic acids |
| US6133470A (en) | 1998-07-28 | 2000-10-17 | Mobil Oil Corporation | Integration of p-xylene production and subsequent conversion process |
| DE19837723A1 (de) | 1998-08-20 | 2000-02-24 | Phenolchemie Gmbh & Co Kg | Verfahren zur Reinigung von Abwässern aus dem Hock-Verfahren |
| US6080372A (en) * | 1998-09-11 | 2000-06-27 | Air Products And Chemicals, Inc. | Two stage reactor for continuous three phase slurry hydrogenation and method of operation |
| DE19843573A1 (de) * | 1998-09-23 | 2000-03-30 | Degussa | Blasensäule und deren Verwendung |
| WO2000023383A1 (en) | 1998-10-20 | 2000-04-27 | Boley Roger J | Method and apparatus for continuous or intermittent supply of ozonated water |
| KR100642625B1 (ko) | 1998-11-24 | 2006-11-10 | 티. 디. 빈센트 린 | 고순도 방향족 폴리카르복실산 및 이것의 유도체를 정제및 생성하는 방법 |
| US6291707B1 (en) | 1999-03-12 | 2001-09-18 | Tsong-Dar Vincent Lin | Process of purifying and producing high purity aromatic polycarboxylic acids and derivatives thereof |
| US6392091B2 (en) * | 1998-11-24 | 2002-05-21 | Tsong-Dar Vincent Lin | Process of purifying and producing high purity aromatic polycarboxylic acids |
| US6153790A (en) | 1998-12-01 | 2000-11-28 | Shell Oil Company | Method to produce aromatic dicarboxylic acids using cobalt and zirconium catalysts |
| JP2000191583A (ja) | 1998-12-25 | 2000-07-11 | Mitsui Chemicals Inc | 芳香族カルボン酸の製造方法 |
| IT1311976B1 (it) | 1999-03-25 | 2002-03-22 | Franco Codignola | Procedimento per la produzione di acidi aromatici. |
| US6143926A (en) | 1999-09-21 | 2000-11-07 | E. I. Du Pont De Nemours And Company | Process for producing pure terephthalic acid with improved recovery of precursors, solvent and methyl acetate |
| US6639104B2 (en) | 1999-12-10 | 2003-10-28 | Inca International S.P.A. | Process for the recovery of purified terephthalic acid (PTA) |
| WO2001051443A2 (en) | 2000-01-12 | 2001-07-19 | E.I. Du Pont De Nemours And Company | Method for increasing oxidation reactor production capacity |
| US6949673B2 (en) * | 2000-01-12 | 2005-09-27 | E.I. Du Pont De Nemours And Company | Process for producing carboxylic acids |
| US20010007910A1 (en) * | 2000-01-12 | 2001-07-12 | Housley Samuel D. | Process for producing carboxylic acids |
| US20020091285A1 (en) * | 2001-01-10 | 2002-07-11 | Housley Samuel Duncan | Method for increasing oxidation reactor production capacity |
| US7060853B2 (en) | 2000-01-12 | 2006-06-13 | Invista North America S.A R.L. | Method for increasing oxidation reactor production capacity |
| TR200201833T2 (tr) * | 2000-01-21 | 2002-12-23 | Bp Corporation North America Inc. | Benzoik asit ve su çözgeni içinde oksidasyon vasıtasıyla yüksek saflıkta aromatik karboksilik asit üretimi |
| JP2001226315A (ja) | 2000-02-10 | 2001-08-21 | Mitsubishi Chemicals Corp | テレフタル酸の製造方法 |
| KR100374785B1 (ko) | 2000-06-29 | 2003-03-04 | 학교법인 포항공과대학교 | 액상 산화 반응기 |
| JP4243912B2 (ja) | 2000-07-05 | 2009-03-25 | 三菱瓦斯化学株式会社 | スラリーからの結晶回収方法 |
| US6765113B2 (en) | 2000-07-19 | 2004-07-20 | E.I. Du Pont De Nemours And Company | Production of aromatic carboxylic acids |
| JP4177103B2 (ja) * | 2000-12-07 | 2008-11-05 | イーストマン ケミカル カンパニー | 管型反応器を使用する低コストポリエステルの製造方法 |
| JP2004533410A (ja) | 2001-01-10 | 2004-11-04 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | カルボン酸を製造するための改善された方法 |
| JP4809534B2 (ja) | 2001-01-22 | 2011-11-09 | 三菱瓦斯化学株式会社 | 芳香族カルボン酸の製造法 |
| US6541525B2 (en) | 2001-03-27 | 2003-04-01 | Exxonmobil Research And Engineering Company | Slurry catalyst rejuvenation in-situ in slurry reactor |
| WO2002092549A1 (en) * | 2001-05-15 | 2002-11-21 | Inca International S.P.A. | Agitation system for alkylbenzene oxidation reactors |
| US6504051B1 (en) | 2001-06-04 | 2003-01-07 | Eastman Chemical Company | Process for production of aromatic carboxylic acids with improved water removal technique |
| US7485747B2 (en) | 2001-06-04 | 2009-02-03 | Eastman Chemical Company | Two stage oxidation process for the production of aromatic dicarboxylic acids |
| US7196215B2 (en) | 2001-06-04 | 2007-03-27 | Eastman Chemical Company | Process for the production of purified terephthalic acid |
| US6689903B2 (en) | 2001-06-04 | 2004-02-10 | Eastman Chemical Company | Crystallization method for production of purified aromatic dicarboxylic acids |
| EP1422214A4 (en) | 2001-08-29 | 2007-07-11 | Mitsubishi Chem Corp | PROCESS FOR PREPARING AROMATIC DICARBOXYLIC ACID |
| CN2562866Y (zh) | 2002-02-01 | 2003-07-30 | 中国石油天然气股份有限公司 | 多级环流反应器 |
| DE10211907A1 (de) | 2002-03-18 | 2003-10-02 | Basf Ag | Oxidation von o-Xylol zu o-Tolylsäure und anderen Oxidationsprodukten durch gestaffelte Zufuhr eines sauerstoffhaltigen Gases |
| US7135596B2 (en) * | 2002-04-23 | 2006-11-14 | Bp Corporation North America Inc. | Method of removing iron contaminants from liquid streams during the manufacture and/or purification of aromatic acids |
| JP2004168716A (ja) | 2002-11-20 | 2004-06-17 | Mitsubishi Chemicals Corp | テレフタル酸の製造方法 |
| US7161027B2 (en) * | 2002-12-09 | 2007-01-09 | Eastman Chemical Company | Process for the oxidative purification of terephthalic acid |
| BR0316462A (pt) * | 2002-12-09 | 2005-10-11 | Eastman Chem Co | Processos para reduzir uma suspensão de ácido carboxìlico purificado, para purificar um produto de oxidação em estágios, para produzir um produto de ácido carboxìlico purificado, e, suspensão de ácido carboxìlico purificado |
| JP2006509044A (ja) | 2002-12-09 | 2006-03-16 | イーストマン ケミカル カンパニー | 粗製カルボン酸スラリーの精製方法 |
| US7074954B2 (en) * | 2002-12-09 | 2006-07-11 | Eastman Chemical Company | Process for the oxidative purification of terephthalic acid |
| US7132566B2 (en) * | 2003-09-22 | 2006-11-07 | Eastman Chemical Company | Process for the purification of a crude carboxylic acid slurry |
| KR20050088383A (ko) | 2002-12-16 | 2005-09-05 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 결정/침전/입자를 형성하는 기구 및 방법 |
| US20040133057A1 (en) | 2003-01-02 | 2004-07-08 | Conocophillips Company | Gaseous hydrocarbon-oxygen bubble tank mixer |
| US6825278B2 (en) | 2003-01-16 | 2004-11-30 | Resolution Specialty Materials Llc | Modified pressure sensitive adhesive |
| US6804609B1 (en) | 2003-04-14 | 2004-10-12 | Conocophillips Company | Property prediction using residual stepwise regression |
| RU2268086C2 (ru) | 2003-04-17 | 2006-01-20 | Общество с ограниченной ответственностью "Научно-исследовательский и производственный центр "ВНИПИМ-ТОС" (ООО "НИиПЦ" ВНИПИМ-ТОС") | Противоточный секционированный газлифтный реактор для газожидкостных процессов |
| US20040215036A1 (en) | 2003-04-25 | 2004-10-28 | Robert Lin | Method for heating a crude carboxylic acid slurry in a post oxidation zone by the addition of steam |
| US7153480B2 (en) | 2003-05-22 | 2006-12-26 | David Robert Bickham | Apparatus for and method of producing aromatic carboxylic acids |
| US7381386B2 (en) | 2003-06-05 | 2008-06-03 | Eastman Chemical Company | Extraction process for removal of impurities from mother liquor in the synthesis of carboxylic acid |
| US7494641B2 (en) * | 2003-06-05 | 2009-02-24 | Eastman Chemical Company | Extraction process for removal of impurities from an oxidizer purge stream in the synthesis of carboxylic acid |
| US7273950B2 (en) * | 2003-06-13 | 2007-09-25 | Tereftalatos Mexicanos, S.A. De C.V. | Process and apparatus for the efficient oxidation of alkyl aromatic compounds |
| CN1208301C (zh) | 2003-08-08 | 2005-06-29 | 中国纺织工业设计院 | 一种生产对苯二甲酸用的气升式外循环鼓泡塔氧化装置 |
| CN1228302C (zh) | 2003-10-12 | 2005-11-23 | 浙江大学 | 一种生产对苯二甲酸用的鼓泡塔氧化反应装置 |
| US7485746B2 (en) * | 2003-11-14 | 2009-02-03 | Bp Corporation North America Inc. | Staged countercurrent oxidation |
| US6838487B1 (en) | 2003-12-04 | 2005-01-04 | Rentech, Inc. | Method and apparatus for regenerating an iron-based Fischer-Tropsch catalyst |
| US7741515B2 (en) * | 2004-09-02 | 2010-06-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7504535B2 (en) * | 2004-09-02 | 2009-03-17 | Eastman Chemical Company | Optimized liquid-phase oxidation |
| US7615663B2 (en) * | 2004-09-02 | 2009-11-10 | Eastman Chemical Company | Optimized production of aromatic dicarboxylic acids |
| US20060205977A1 (en) | 2005-03-08 | 2006-09-14 | Sumner Charles E Jr | Processes for producing terephthalic acid |
| CN100417437C (zh) | 2005-11-18 | 2008-09-10 | 浙江大学 | 带有阻尼内构件的鼓泡塔反应器 |
| US7358389B2 (en) | 2006-01-04 | 2008-04-15 | Eastman Chemical Company | Oxidation system employing internal structure for enhanced hydrodynamics |
| US7501537B2 (en) | 2006-03-01 | 2009-03-10 | Eastman Chemical Company | Polycarboxylic acid production system employing oxidative digestion with reduced or eliminated upstream liquor exchange |
-
2005
- 2005-06-16 US US11/154,480 patent/US7495125B2/en not_active Expired - Fee Related
- 2005-08-29 JP JP2007530199A patent/JP2008511641A/ja active Pending
- 2005-08-29 KR KR1020077006755A patent/KR20070057196A/ko not_active Ceased
- 2005-08-29 WO PCT/US2005/030549 patent/WO2006028755A1/en not_active Ceased
- 2005-08-29 CA CA002577055A patent/CA2577055A1/en not_active Abandoned
- 2005-08-29 MX MX2007002507A patent/MX2007002507A/es active IP Right Grant
- 2005-08-29 EP EP05791296A patent/EP1786745A1/en not_active Withdrawn
- 2005-08-29 BR BRPI0514784-0A patent/BRPI0514784A/pt not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| US7495125B2 (en) | 2009-02-24 |
| WO2006028755A1 (en) | 2006-03-16 |
| MX2007002507A (es) | 2007-05-04 |
| CA2577055A1 (en) | 2006-03-16 |
| US20060047154A1 (en) | 2006-03-02 |
| EP1786745A1 (en) | 2007-05-23 |
| BRPI0514784A (pt) | 2008-06-24 |
| JP2008511641A (ja) | 2008-04-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101275465B1 (ko) | 기포탑 반응기에서의 최적화된 액상 산화 방법 | |
| KR101363707B1 (ko) | 최적화된 액상 산화를 위한 기포탑 반응기 | |
| KR101363734B1 (ko) | 최적화된 액상 산화 방법을 위한 기포탑 반응기 | |
| KR101363742B1 (ko) | 최적화된 액상 산화를 위한 기포탑 반응기 | |
| KR101169490B1 (ko) | 최적화된 액상 산화 방법 | |
| KR101281248B1 (ko) | 조질의 테레프탈산 조성물 및 이의 제조방법 | |
| KR101281444B1 (ko) | 최적화된 액상 산화 방법 | |
| KR101217412B1 (ko) | 기포탑 반응기에서의 최적화된 액상 산화 방법 | |
| KR101364801B1 (ko) | 최적화된 액상 산화 | |
| KR101281347B1 (ko) | 최적화된 액상 산화 방법 | |
| KR20070054695A (ko) | 최적화된 액상 산화 방법 | |
| KR101281408B1 (ko) | 최적화된 액상 산화 방법 | |
| CN101010267B (zh) | 优化的液相氧化 | |
| KR101392653B1 (ko) | 최적화된 액상 산화 방법 | |
| KR101392547B1 (ko) | 파라-자일렌의 최적화된 액상 산화 방법 | |
| KR101267704B1 (ko) | 최적화된 액체상 산화 방법 | |
| KR20070057196A (ko) | 최적화된 액상 산화 방법 | |
| EP2266944A2 (en) | Optimized liquid-phase oxidation of paraxylene | |
| WO2006028817A2 (en) | Optimized liquid-phase oxidation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
Patent event date: 20070323 Patent event code: PA01051R01D Comment text: International Patent Application |
|
| PG1501 | Laying open of application | ||
| A201 | Request for examination | ||
| PA0201 | Request for examination |
Patent event code: PA02012R01D Patent event date: 20100827 Comment text: Request for Examination of Application |
|
| E902 | Notification of reason for refusal | ||
| PE0902 | Notice of grounds for rejection |
Comment text: Notification of reason for refusal Patent event date: 20111227 Patent event code: PE09021S01D |
|
| N231 | Notification of change of applicant | ||
| PN2301 | Change of applicant |
Patent event date: 20120406 Comment text: Notification of Change of Applicant Patent event code: PN23011R01D |
|
| E601 | Decision to refuse application | ||
| PE0601 | Decision on rejection of patent |
Patent event date: 20121221 Comment text: Decision to Refuse Application Patent event code: PE06012S01D Patent event date: 20111227 Comment text: Notification of reason for refusal Patent event code: PE06011S01I |
|
| J201 | Request for trial against refusal decision | ||
| PJ0201 | Trial against decision of rejection |
Patent event date: 20130325 Comment text: Request for Trial against Decision on Refusal Patent event code: PJ02012R01D Patent event date: 20121221 Comment text: Decision to Refuse Application Patent event code: PJ02011S01I Appeal kind category: Appeal against decision to decline refusal Appeal identifier: 2013101002137 Request date: 20130325 |
|
| J501 | Disposition of invalidation of trial | ||
| PJ0501 | Disposition of invalidation of trial |
Appeal kind category: Appeal against decision to decline refusal Request date: 20130325 Appeal identifier: 2013101002137 |