KR20040082434A - 지글러-나타 형 고체 촉매 성분 및 촉매 시스템, 그 제조방법 및 알크-1-엔의 중합에서의 그 용도 - Google Patents
지글러-나타 형 고체 촉매 성분 및 촉매 시스템, 그 제조방법 및 알크-1-엔의 중합에서의 그 용도 Download PDFInfo
- Publication number
- KR20040082434A KR20040082434A KR10-2004-7012666A KR20047012666A KR20040082434A KR 20040082434 A KR20040082434 A KR 20040082434A KR 20047012666 A KR20047012666 A KR 20047012666A KR 20040082434 A KR20040082434 A KR 20040082434A
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- South Korea
- Prior art keywords
- compound
- solid catalyst
- catalyst component
- alk
- ene
- Prior art date
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- FSBVERYRVPGNGG-UHFFFAOYSA-N dimagnesium dioxido-bis[[oxido(oxo)silyl]oxy]silane hydrate Chemical compound O.[Mg+2].[Mg+2].[O-][Si](=O)O[Si]([O-])([O-])O[Si]([O-])=O FSBVERYRVPGNGG-UHFFFAOYSA-N 0.000 description 1
- XFAOZKNGVLIXLC-UHFFFAOYSA-N dimethoxy-(2-methylpropyl)-propan-2-ylsilane Chemical compound CO[Si](C(C)C)(OC)CC(C)C XFAOZKNGVLIXLC-UHFFFAOYSA-N 0.000 description 1
- NHYFIJRXGOQNFS-UHFFFAOYSA-N dimethoxy-bis(2-methylpropyl)silane Chemical compound CC(C)C[Si](OC)(CC(C)C)OC NHYFIJRXGOQNFS-UHFFFAOYSA-N 0.000 description 1
- VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 description 1
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002440 hydroxy compounds Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000411 inducer Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229940035429 isobutyl alcohol Drugs 0.000 description 1
- 238000002356 laser light scattering Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- HZZOEADXZLYIHG-UHFFFAOYSA-N magnesiomagnesium Chemical compound [Mg][Mg] HZZOEADXZLYIHG-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- RTKCPZYOLXPARI-UHFFFAOYSA-N magnesium;2-methylpropan-2-olate Chemical compound [Mg+2].CC(C)(C)[O-].CC(C)(C)[O-] RTKCPZYOLXPARI-UHFFFAOYSA-N 0.000 description 1
- UKZCGMDMXDLAGZ-UHFFFAOYSA-M magnesium;2-methylpropane;bromide Chemical compound [Mg+2].[Br-].C[C-](C)C UKZCGMDMXDLAGZ-UHFFFAOYSA-M 0.000 description 1
- CQRPUKWAZPZXTO-UHFFFAOYSA-M magnesium;2-methylpropane;chloride Chemical compound [Mg+2].[Cl-].C[C-](C)C CQRPUKWAZPZXTO-UHFFFAOYSA-M 0.000 description 1
- WRYKIHMRDIOPSI-UHFFFAOYSA-N magnesium;benzene Chemical compound [Mg+2].C1=CC=[C-]C=C1.C1=CC=[C-]C=C1 WRYKIHMRDIOPSI-UHFFFAOYSA-N 0.000 description 1
- IWCVDCOJSPWGRW-UHFFFAOYSA-M magnesium;benzene;chloride Chemical compound [Mg+2].[Cl-].C1=CC=[C-]C=C1 IWCVDCOJSPWGRW-UHFFFAOYSA-M 0.000 description 1
- HFTSQAKJLBPKBD-UHFFFAOYSA-N magnesium;butan-1-olate Chemical compound [Mg+2].CCCC[O-].CCCC[O-] HFTSQAKJLBPKBD-UHFFFAOYSA-N 0.000 description 1
- JOIKLQRONIZCBW-UHFFFAOYSA-N magnesium;butan-1-olate;butan-2-olate Chemical compound [Mg+2].CCCC[O-].CCC(C)[O-] JOIKLQRONIZCBW-UHFFFAOYSA-N 0.000 description 1
- XLQMOUZWUAUZJX-UHFFFAOYSA-N magnesium;butan-2-olate Chemical compound [Mg+2].CCC(C)[O-].CCC(C)[O-] XLQMOUZWUAUZJX-UHFFFAOYSA-N 0.000 description 1
- KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
- LWLPYZUDBNFNAH-UHFFFAOYSA-M magnesium;butane;bromide Chemical compound [Mg+2].[Br-].CCC[CH2-] LWLPYZUDBNFNAH-UHFFFAOYSA-M 0.000 description 1
- WSHFRLGXCNEKRX-UHFFFAOYSA-M magnesium;butane;bromide Chemical compound [Mg+2].[Br-].CC[CH-]C WSHFRLGXCNEKRX-UHFFFAOYSA-M 0.000 description 1
- VCTCXZDCRFISFF-UHFFFAOYSA-N magnesium;butane;butane Chemical compound [Mg+2].CCC[CH2-].CC[CH-]C VCTCXZDCRFISFF-UHFFFAOYSA-N 0.000 description 1
- QUXHCILOWRXCEO-UHFFFAOYSA-M magnesium;butane;chloride Chemical compound [Mg+2].[Cl-].CCC[CH2-] QUXHCILOWRXCEO-UHFFFAOYSA-M 0.000 description 1
- YNLPNVNWHDKDMN-UHFFFAOYSA-M magnesium;butane;chloride Chemical compound [Mg+2].[Cl-].CC[CH-]C YNLPNVNWHDKDMN-UHFFFAOYSA-M 0.000 description 1
- XDKQUSKHRIUJEO-UHFFFAOYSA-N magnesium;ethanolate Chemical compound [Mg+2].CC[O-].CC[O-] XDKQUSKHRIUJEO-UHFFFAOYSA-N 0.000 description 1
- GBRJQTLHXWRDOV-UHFFFAOYSA-M magnesium;hexane;chloride Chemical compound [Mg+2].[Cl-].CCCCC[CH2-] GBRJQTLHXWRDOV-UHFFFAOYSA-M 0.000 description 1
- HQDAZWQQKSJCTM-UHFFFAOYSA-M magnesium;octane;chloride Chemical compound [Mg+2].[Cl-].CCCCCCC[CH2-] HQDAZWQQKSJCTM-UHFFFAOYSA-M 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- WRZMOWGAWMKGIT-UHFFFAOYSA-N magnesium;pentan-1-olate Chemical compound [Mg+2].CCCCC[O-].CCCCC[O-] WRZMOWGAWMKGIT-UHFFFAOYSA-N 0.000 description 1
- WNJYXPXGUGOGBO-UHFFFAOYSA-N magnesium;propan-1-olate Chemical compound CCCO[Mg]OCCC WNJYXPXGUGOGBO-UHFFFAOYSA-N 0.000 description 1
- ORPJQHHQRCLVIC-UHFFFAOYSA-N magnesium;propan-2-olate Chemical compound CC(C)O[Mg]OC(C)C ORPJQHHQRCLVIC-UHFFFAOYSA-N 0.000 description 1
- DQZLQYHGCKLKGU-UHFFFAOYSA-N magnesium;propane Chemical compound [Mg+2].C[CH-]C.C[CH-]C DQZLQYHGCKLKGU-UHFFFAOYSA-N 0.000 description 1
- 238000013507 mapping Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 125000002734 organomagnesium group Chemical group 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 238000001139 pH measurement Methods 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- ANRQGKOBLBYXFM-UHFFFAOYSA-M phenylmagnesium bromide Chemical compound Br[Mg]C1=CC=CC=C1 ANRQGKOBLBYXFM-UHFFFAOYSA-M 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical group OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02075579A EP1336625A1 (en) | 2002-02-14 | 2002-02-14 | Solid catalytic component and catalytic system of the Ziegler-Natta type, process for their preparation and their use in the polymerisation of alk-1-enes |
| EP02075579.9 | 2002-02-14 | ||
| PCT/NL2003/000058 WO2003068830A1 (en) | 2002-02-14 | 2003-01-28 | Solid catalytic component and catalytic system of the ziegler-natta type, process for their preparation and their use in the polymerisation of alk-1-enes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20040082434A true KR20040082434A (ko) | 2004-09-24 |
Family
ID=27619163
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR10-2004-7012666A Ceased KR20040082434A (ko) | 2002-02-14 | 2003-01-28 | 지글러-나타 형 고체 촉매 성분 및 촉매 시스템, 그 제조방법 및 알크-1-엔의 중합에서의 그 용도 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7232785B2 (https=) |
| EP (2) | EP1336625A1 (https=) |
| JP (1) | JP2005517748A (https=) |
| KR (1) | KR20040082434A (https=) |
| CN (3) | CN101003586B (https=) |
| AU (1) | AU2003202834A1 (https=) |
| BR (1) | BR0307725A (https=) |
| CO (1) | CO5611202A2 (https=) |
| MX (1) | MXPA04007887A (https=) |
| WO (1) | WO2003068830A1 (https=) |
| ZA (1) | ZA200406484B (https=) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4982365B2 (ja) | 2004-07-30 | 2012-07-25 | サウディ ベーシック インダストリーズ コーポレイション | 高透明性のプロピレンコポリマー組成物 |
| FR2921368B1 (fr) | 2007-09-25 | 2012-10-12 | Pf Medicament | Nouveau procede de synthese de derives anticancereux de (poly) aminoalkylaminoacetamide d'epipodophyllotoxine. |
| ES2536744T3 (es) * | 2009-01-07 | 2015-05-28 | Toho Titanium Co., Ltd. | Procedimiento de fabricación de componente catalítico sólido y de catalizador para la polimerización de olefinas |
| US7619049B1 (en) * | 2009-04-13 | 2009-11-17 | Formosa Plastics Corporation, U.S.A. | Cyclic organosilicon compounds as electron donors for polyolefin catalysts |
| CN102375045A (zh) * | 2010-08-17 | 2012-03-14 | 中国石油化工股份有限公司 | 一种聚丙烯合成催化剂的评价方法 |
| EP2751059B1 (en) | 2011-08-29 | 2015-09-16 | Saudi Basic Industries Corporation | Process for preparing di-substituted succinates |
| KR101677694B1 (ko) | 2012-09-24 | 2016-11-18 | 인디언 오일 코퍼레이션 리미티드 | 올레핀의 중합을 위한 촉매 및 이의 제조 방법 |
| US9481741B2 (en) | 2012-11-26 | 2016-11-01 | Lummus Novolen Technology Gmbh | High performance Ziegler-Natta catalyst systems, process for producing such supported catalysts and use thereof |
| CN103113499B (zh) | 2013-01-30 | 2015-01-21 | 中国石油天然气股份有限公司 | 一种宽分布聚烯烃催化剂及其制备和应用 |
| WO2015091151A1 (en) | 2013-12-20 | 2015-06-25 | Saudi Basic Industries Corporation | Polyolefin composition |
| US10696829B2 (en) | 2013-12-20 | 2020-06-30 | Saudi Basic Industries Corporation | Heterophasic propylene copolymer |
| CN104356264B (zh) * | 2014-10-22 | 2017-01-11 | 上海化工研究院 | 一种烯烃聚合催化剂及其制备方法和应用 |
| CN113527555B (zh) * | 2020-04-21 | 2023-04-11 | 中国石油化工股份有限公司 | 含环氧树脂的催化剂组分及其制备方法和应用 |
| CN115975077B (zh) * | 2021-10-15 | 2024-06-04 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组分及催化剂和应用 |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5441985A (en) * | 1977-09-09 | 1979-04-03 | Mitsui Petrochem Ind Ltd | Polymerization or copolymerization of olefin |
| US4263168A (en) * | 1979-01-10 | 1981-04-21 | Imperial Chemical Industries Limited | Olefine polymerization catalyst |
| JPS6037804B2 (ja) * | 1979-04-11 | 1985-08-28 | 三井化学株式会社 | オレフイン重合触媒用担体の製法 |
| JPS5611908A (en) * | 1979-07-11 | 1981-02-05 | Mitsui Petrochem Ind Ltd | Preparation of olefin polymer |
| JPS5950246B2 (ja) * | 1979-10-16 | 1984-12-07 | 三井化学株式会社 | 成形用オレフイン共重合体の製法 |
| US5025072A (en) * | 1981-12-04 | 1991-06-18 | Mobil Oil Corporation | Highly active catalyst composition for polymerizing alpha-olefins |
| US4481301A (en) | 1981-12-04 | 1984-11-06 | Mobil Oil Corporation | Highly active catalyst composition for polymerizing alpha-olefins |
| US4605638A (en) | 1981-12-04 | 1986-08-12 | Mobil Oil Corporation | Highly active catalyst composition for polymerizing alpha-olefins |
| US5330949A (en) * | 1985-06-17 | 1994-07-19 | Idemitsu Petrochemical Company, Ltd. | Method for producing polyolefin |
| EP0240254A3 (en) * | 1986-03-31 | 1989-07-26 | Exxon Chemical Patents Inc. | Polymerization catalyst, production and use |
| FI76099C (fi) * | 1986-09-29 | 1988-09-09 | Neste Oy | Katalytkomponenter foer polymerisationskatalyter foer -olefiner och foerfarande foer framstaellning av dessa. |
| DE3730717A1 (de) * | 1987-09-12 | 1989-03-23 | Basf Ag | Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems |
| US4983694A (en) * | 1988-05-31 | 1991-01-08 | Mobil Oil Corporation | Process for polymerizing olefins to form polymers of narrow molecular weight distribution |
| US5126302A (en) * | 1990-04-30 | 1992-06-30 | Quantum Chemical Corporation | Olefin polymerization catalyst and methods |
| US5064796A (en) * | 1991-01-07 | 1991-11-12 | Exxon Chemical Patents Inc. | Support adjuvant for improved vanadium polymerization catalyst |
| US5470812A (en) * | 1991-11-06 | 1995-11-28 | Mobil Oil Corporation | High activity polyethylene catalysts prepared with alkoxysilane reagents |
| US6291384B1 (en) * | 1991-11-06 | 2001-09-18 | Mobil Oil Corporation | High activity catalyst prepared with alkoxysilanes |
| US5336652A (en) | 1991-11-06 | 1994-08-09 | Mobil Oil Corporation | High activity polyethylene catalysts prepared with alkoxysilane reagents |
| US5514634A (en) | 1991-11-06 | 1996-05-07 | Mobil Oil Corporation | High activity polyethylene catalysts |
| US5939348A (en) | 1991-11-06 | 1999-08-17 | Mobil Oil Corporation | Catalyst for the manufacture of polythylene with a narrow molecular weight distribution |
| JPH05214034A (ja) * | 1992-02-04 | 1993-08-24 | Ube Ind Ltd | エチレン共重合体の製造方法 |
| US5529965A (en) * | 1994-10-28 | 1996-06-25 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| US6218331B1 (en) * | 1995-03-29 | 2001-04-17 | Equistar Chemicals, L.P. | Polymer-supported catalyst for olefin polymerization |
| ES2114335T3 (es) | 1995-08-09 | 1998-05-16 | Basf Ag | Sistemas catalizadores del tipo de los catalizadores de ziegler-natta. |
| CA2233659C (en) * | 1995-10-06 | 2007-12-04 | Mobil Oil Corporation | Catalyst for the manufacture of polyethylene with a narrow molecular weight distribution |
| DE19623226A1 (de) * | 1996-06-11 | 1997-12-18 | Basf Ag | Katalysatorsysteme vom Typ der Ziegler-Natta-Katalysatoren |
| DE19722569A1 (de) * | 1997-05-28 | 1998-12-03 | Basf Ag | Statistische Propylencopolymerisate |
| US6825293B1 (en) * | 2001-08-20 | 2004-11-30 | Nova Chemicals (International) S.A. | Polymer control through co-catalyst |
| US6831032B2 (en) * | 2002-08-19 | 2004-12-14 | Novolen Technology Holdings C.V. | Ziegler-Natta catalyst and methods of making and using same |
| US7838605B2 (en) * | 2003-10-17 | 2010-11-23 | Univation Technologies, Llc | Polymerization monitoring and control using improved leading indicators |
-
2002
- 2002-02-14 EP EP02075579A patent/EP1336625A1/en not_active Withdrawn
-
2003
- 2003-01-28 AU AU2003202834A patent/AU2003202834A1/en not_active Abandoned
- 2003-01-28 EP EP03701946A patent/EP1476479A1/en not_active Withdrawn
- 2003-01-28 US US10/504,702 patent/US7232785B2/en not_active Expired - Fee Related
- 2003-01-28 WO PCT/NL2003/000058 patent/WO2003068830A1/en not_active Ceased
- 2003-01-28 CN CN2007100017017A patent/CN101003586B/zh not_active Expired - Fee Related
- 2003-01-28 JP JP2003567956A patent/JP2005517748A/ja active Pending
- 2003-01-28 CN CNA038068087A patent/CN1643001A/zh active Pending
- 2003-01-28 BR BR0307725-0A patent/BR0307725A/pt not_active IP Right Cessation
- 2003-01-28 KR KR10-2004-7012666A patent/KR20040082434A/ko not_active Ceased
- 2003-01-28 MX MXPA04007887A patent/MXPA04007887A/es active IP Right Grant
- 2003-01-28 CN CN200910163479A patent/CN101659716A/zh active Pending
-
2004
- 2004-08-16 ZA ZA200406484A patent/ZA200406484B/en unknown
- 2004-09-14 CO CO04091272A patent/CO5611202A2/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| EP1336625A1 (en) | 2003-08-20 |
| CN101659716A (zh) | 2010-03-03 |
| CO5611202A2 (es) | 2006-02-28 |
| WO2003068830A1 (en) | 2003-08-21 |
| AU2003202834A1 (en) | 2003-09-04 |
| CN101003586A (zh) | 2007-07-25 |
| ZA200406484B (en) | 2005-06-21 |
| EP1476479A1 (en) | 2004-11-17 |
| US20050202959A1 (en) | 2005-09-15 |
| BR0307725A (pt) | 2005-01-25 |
| MXPA04007887A (es) | 2005-06-17 |
| US7232785B2 (en) | 2007-06-19 |
| JP2005517748A (ja) | 2005-06-16 |
| CN1643001A (zh) | 2005-07-20 |
| CN101003586B (zh) | 2010-10-06 |
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