KR20020030262A - 조사 경화 피복물용 매팅화제 - Google Patents
조사 경화 피복물용 매팅화제 Download PDFInfo
- Publication number
- KR20020030262A KR20020030262A KR1020017013004A KR20017013004A KR20020030262A KR 20020030262 A KR20020030262 A KR 20020030262A KR 1020017013004 A KR1020017013004 A KR 1020017013004A KR 20017013004 A KR20017013004 A KR 20017013004A KR 20020030262 A KR20020030262 A KR 20020030262A
- Authority
- KR
- South Korea
- Prior art keywords
- matting agent
- composition
- matting
- range
- wax
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/42—Gloss-reducing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Paints Or Removers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Description
화합물 | 양 |
1. 라로머 PO 83F(아민-변형된 폴리에테르 아크릴레이트) | 85.5 g |
2. 이르가큐어(상표, Irgacure) 500 | 4.5 g |
3. 매팅화제 | 10.0 g |
2000 rpm/5분에서 분산; 24㎛ K-Bar로 적용 | |
경화 | 선 속도 10 m/분; 수은 램프 120W; 1회 통과 |
화합물 | 양 |
1. 에베크릴 270(우레탄 아크릴레이트) | 55.2 g |
2. 트리프로필렌글리콜 디아크릴레이트(TPGDA) 가교결합제 | 128.8 g |
⇒2000rpm에서 5분 혼합시킴 | |
3. 벤조페논 | 7.36g |
4. 이르가큐어 651 개시제 | 3.68g |
5. 매팅화제 | 8.0 g |
2000 rpm/5분에서 분산; 24㎛ K-Bar로 적용 | |
경화 | 선 속도 10 m/분; 수은 램프 120W; 1회 통과 |
매팅화제 | 공극부피(ml/g) | 표면적(m2/g) | 중량 중간입자 크기(㎛) | 왁스 유형 | 왁스 함량 |
본 발명 | 1.10 | 380 | 3.70 | 피셔-트롭시 | 20% |
비교예 1 | 1.01 | 380 | 7.12 | 피셔-트롭시 | 10% |
비교예 2 | 2.1 | 270 | 3.29 | 피셔-트롭시 | 20% |
비교예 3 | 1.8 | 285 | 7.9 | 폴리에틸렌 왁스 | 12% |
매팅화제 | 중량 중간 입자 크기(㎛) | 공극부피(ml/g) | 왁스 함량 | 8% 현탁액의상대 점도 | 광택 단위 30에서매팅 효율 |
본 발명 | 3.70 | 1.10 | 20 | 1.52 | 0.54 |
비교예 1 | 7.12 | 1.10 | 10 | 2.50 | 1.26 |
비교예 2 | 3.29 | 2.1 | 20 | 1.55 | 0.84 |
비교예 3 | 7.9 | 1.8 | 12 | 3.37 | 1.00 |
실로이드 ED 30 | 6.5 | 1.8 | 10 | 4.41 | 1.06 |
매팅화제 | 중량 중간 입자크기(㎛) | 공극부피(ml/g) | 왁스 함량 | 10% 현탁액의상대 점도 | 10% 현탁액의60°에서 매팅화 |
본 발명 | 3.7 | 1.10 | 20 | 8.47 | 69 |
비교예 1 | 7.12 | 1.10 | 10 | 4.21 | 75 |
비교예 2 | 3.29 | 2.1 | 20 | 9.24 | 71 |
비교예 3 | 7.9 | 1.8 | 12 | 19.39 | 73 |
실로이드 ED 30 | 6.5 | 1.8 | 10 | 27.27 | 80 |
Claims (19)
- 2 내지 12㎛ 범위의 중간 입자 크기, 총 조성물의 약 15 내지 30 중량% 범위의 왁스 함량 및 약 0.8 내지 1.4 cc/g 범위의 실리카 공극 부피를 갖는, 실리카 및 왁스를 포함하는 매팅화제(matting agent) 조성물.
- 제 1 항에 있어서,왁스 함량이 약 18 내지 22 중량%인 매팅화제 조성물.
- 제 1 항에 있어서,왁스 융점이 60 내지 120℃의 범위인 매팅화제 조성물.
- 제 1 항에 있어서,왁스 융점이 60 내지 90℃의 범위인 매팅화제 조성물.
- 제 3 항에 있어서,왁스가 파라핀이고 융점이 60 내지 90℃의 범위인 매팅화제 조성물.
- 제 1 항에 있어서,중간 입자 크기가 약 2 내지 5㎛인 매팅화제 조성물.
- 제 2 항에 있어서,중간 입자 크기가 약 2 내지 5㎛인 매팅화제 조성물.
- 제 1 항에 있어서,실리카 공극 부피가 약 0.9 내지 약 1.2 cc/g의 범위인 매팅화제 조성물.
- 제 2 항에 있어서,실리카 공극 부피가 약 0.9 내지 약 1.2 cc/g의 범위인 매팅화제 조성물.
- 제 7 항에 있어서,실리카 공극 부피가 약 0.9 내지 약 1.2 cc/g의 범위인 매팅화제 조성물.
- 조사 경화성 성분 및 제 1 항 내지 제 10 항중 어느 한 항에 따른 매팅화제 성분을 포함하는 피복 조성물.
- 제 11 항에 있어서,조사 경화성 성분이 아크릴레이트를 포함하는 피복 조성물.
- 제 11 항에 있어서,조사 경화성 성분이 자외선 조사에의 노출에 의해 경화될 수 있는 피복 조성물.
- 제 11 항에 있어서,조사 경화성 성분이 전자 빔 조사에 의해 경화될 수 있는 피복 조성물.
- 제 13 항 또는 제 14 항에 있어서,경화 개시제를 추가로 포함하는 피복 조성물.
- 제 13 항에 있어서,조사 경화성 성분이 아크릴레이트를 포함하고 피복 조성물이 매팅화제 성분 2 중량% 이하를 포함하는 피복 조성물.
- 기재 및 기재상에 제 11 항 내지 제 16 항중 어느 한 항에 따른 조성물로부터 제조된 피복물을 포함하는 피복된 기재.
- 제 17 항에 있어서,피복물이 제 16 항의 피복물로부터 제조되고 60°에서 광택 단위 약 20의 매팅 효율을 갖는 피복된 기재.
- 제 16 항에 있어서,피복물이 아민-변형된 폴리에테르 아크릴레이트로부터 제조되고, 피복물이 매팅화제 성분 약 12 중량% 이하를 포함하는 조성물로부터 제조되며, 60°에서 광택 단위 약 60 이하의 매팅 효율을 갖는 피복된 기재.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12900799P | 1999-04-13 | 1999-04-13 | |
US60/129,007 | 1999-04-13 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20020030262A true KR20020030262A (ko) | 2002-04-24 |
KR100646459B1 KR100646459B1 (ko) | 2006-11-14 |
Family
ID=22438053
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020017013004A KR100646459B1 (ko) | 1999-04-13 | 2000-04-11 | 조사 경화 피복물용 매팅화제 |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP1171531B1 (ko) |
JP (1) | JP4671568B2 (ko) |
KR (1) | KR100646459B1 (ko) |
CN (1) | CN1322072C (ko) |
AT (1) | ATE243239T1 (ko) |
AU (1) | AU1408101A (ko) |
DE (1) | DE60003415T2 (ko) |
DK (1) | DK1171531T3 (ko) |
ES (1) | ES2200971T3 (ko) |
PT (1) | PT1171531E (ko) |
TW (1) | TWI255285B (ko) |
WO (1) | WO2001004217A2 (ko) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NZ511223A (en) * | 2000-08-23 | 2002-10-25 | Degussa | Process for covering silica with wax at temperatures between 40 deg and 250 deg celsius whereupon the milling process is performed simultaneously |
EP1182233B1 (de) * | 2000-08-23 | 2004-09-08 | Degussa AG | Verfahren zur Belegung von Kieselsäuren mit Wachsen |
US8410197B2 (en) | 2001-07-06 | 2013-04-02 | W. R. Grace & Co. -Conn. | Organic-containing particulate having elevated auto-ignition temperatures |
CN101044023B (zh) * | 2004-10-22 | 2010-05-05 | 三菱丽阳株式会社 | 热成形用消光丙烯酸树脂膜状物、其制造方法以及含有其的层叠体 |
SI2099873T1 (sl) | 2006-12-07 | 2016-02-29 | Grace Gmbh & Co. Kg | Matirno sredstvo |
CA2800935A1 (en) | 2010-07-30 | 2012-02-02 | Dsm Ip Assests B.V. | D1486 low gloss radiation curable coating for concrete floors |
US9546285B2 (en) | 2010-11-18 | 2017-01-17 | Basf Coatings Gmbh | Polyurethane coating composition, multilayer surface coatings having a matt surface produced therefrom and processes for producing the multilayer surface coatings |
EP3144353A1 (en) * | 2015-09-15 | 2017-03-22 | Allnex Belgium, S.A. | Radiation curable compositions for low gloss coatings |
CN106800812A (zh) * | 2017-02-08 | 2017-06-06 | 广州市新稀冶金化工有限公司 | 一种改性二氧化硅复合消光粉及其制备方法 |
CA3065173A1 (en) * | 2017-06-02 | 2018-12-06 | W. R. Grace & Co.-Conn. | Silica based matting agents and methods of making and using the same |
BR112020002310B1 (pt) * | 2017-08-03 | 2024-01-23 | W.R. Grace & Co.-Conn | Agente fosqueante para composições de revestimento aquosas,método para prepará-lo, composição de revestimento compreendendo dito agente, substratos revestidos com a mesma e método para preparar um substrato revestido |
JP7353469B2 (ja) * | 2019-08-30 | 2023-09-29 | ダブリュー・アール・グレース・アンド・カンパニー-コーン | シリカベースの艶消し配合物ならびにその作製および使用方法 |
WO2021220687A1 (ja) | 2020-04-28 | 2021-11-04 | 東ソー・シリカ株式会社 | エネルギー線硬化型塗料艶消し用疎水性シリカゲル |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE119929T1 (de) * | 1990-02-14 | 1995-04-15 | Grace Gmbh | Si02-mattierungsmittel, verfahren zu seiner herstellung und seine verwendung. |
EP0541359B1 (en) * | 1991-11-07 | 1995-07-19 | Crosfield Limited | Silica products |
GB9517607D0 (en) * | 1995-08-29 | 1995-11-01 | Unilever Plc | Silica products and uv curable systems |
GB9712591D0 (en) * | 1997-06-16 | 1997-08-20 | Unilever Plc | Matting paste for cationic systems |
-
2000
- 2000-04-11 JP JP2001509424A patent/JP4671568B2/ja not_active Expired - Lifetime
- 2000-04-11 EP EP00976206A patent/EP1171531B1/en not_active Expired - Lifetime
- 2000-04-11 DE DE60003415T patent/DE60003415T2/de not_active Expired - Lifetime
- 2000-04-11 ES ES00976206T patent/ES2200971T3/es not_active Expired - Lifetime
- 2000-04-11 WO PCT/IB2000/001752 patent/WO2001004217A2/en active IP Right Grant
- 2000-04-11 PT PT00976206T patent/PT1171531E/pt unknown
- 2000-04-11 AT AT00976206T patent/ATE243239T1/de active
- 2000-04-11 CN CNB008088268A patent/CN1322072C/zh not_active Expired - Lifetime
- 2000-04-11 AU AU14081/01A patent/AU1408101A/en not_active Abandoned
- 2000-04-11 KR KR1020017013004A patent/KR100646459B1/ko active IP Right Grant
- 2000-04-11 DK DK00976206T patent/DK1171531T3/da active
- 2000-04-12 TW TW089106814A patent/TWI255285B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
AU1408101A (en) | 2001-01-30 |
EP1171531B1 (en) | 2003-06-18 |
DE60003415T2 (de) | 2004-04-22 |
WO2001004217A3 (en) | 2001-08-23 |
ATE243239T1 (de) | 2003-07-15 |
ES2200971T3 (es) | 2004-03-16 |
EP1171531A2 (en) | 2002-01-16 |
JP4671568B2 (ja) | 2011-04-20 |
CN1322072C (zh) | 2007-06-20 |
WO2001004217A9 (en) | 2001-09-20 |
CN1355830A (zh) | 2002-06-26 |
WO2001004217A2 (en) | 2001-01-18 |
KR100646459B1 (ko) | 2006-11-14 |
TWI255285B (en) | 2006-05-21 |
DE60003415D1 (de) | 2003-07-24 |
JP2003522219A (ja) | 2003-07-22 |
DK1171531T3 (da) | 2003-09-29 |
PT1171531E (pt) | 2003-11-28 |
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