KR20010068611A - Capacitor forming method - Google Patents

Capacitor forming method Download PDF

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Publication number
KR20010068611A
KR20010068611A KR1020000000620A KR20000000620A KR20010068611A KR 20010068611 A KR20010068611 A KR 20010068611A KR 1020000000620 A KR1020000000620 A KR 1020000000620A KR 20000000620 A KR20000000620 A KR 20000000620A KR 20010068611 A KR20010068611 A KR 20010068611A
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South Korea
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film
interlayer insulating
insulating film
oxide film
etching
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KR1020000000620A
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Korean (ko)
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반강현
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박종섭
주식회사 하이닉스반도체
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Priority to KR1020000000620A priority Critical patent/KR20010068611A/en
Publication of KR20010068611A publication Critical patent/KR20010068611A/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L28/00Passive two-terminal components without a potential-jump or surface barrier for integrated circuits; Details thereof; Multistep manufacturing processes therefor
    • H01L28/40Capacitors
    • H01L28/60Electrodes
    • H01L28/82Electrodes with an enlarged surface, e.g. formed by texturisation
    • H01L28/90Electrodes with an enlarged surface, e.g. formed by texturisation having vertical extensions
    • H01L28/91Electrodes with an enlarged surface, e.g. formed by texturisation having vertical extensions made by depositing layers, e.g. by depositing alternating conductive and insulating layers

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
  • Semiconductor Memories (AREA)

Abstract

PURPOSE: A forming method of a capacitor is provided to simplify processes by decreasing polysilicon forming processes into one time, and reduce process period and manufacturing costs and enable high integrity by forming node contacts preventing short-circuit with lower wiring. CONSTITUTION: In the first step, the first interlayer insulating layer(22) is formed on a semiconductor substrate(21), then a second interlayer insulating layer(24) and a conductive layer are sequentially deposited, bit lines(25) are formed by patterning the conductive layer, and then the first nitride layer(26), the third interlayer insulating layer(27) and the second nitride layer(28) are sequentially deposited. In the second step, node contact holes are formed by etching the second nitride layer(28), the third interlayer insulating layer(27), the first nitride layer(26) and the second interlayer insulating layer(24), and then an oxide(29) is deposited. In the third step, polysilicon(30) is formed on the oxide and the second nitride layer and an insulating layer is formed and then the polysilicon is exposed by etch-back. In the fourth step, the residual insulating layer and oxide are removed by wet etching.

Description

커패시터 형성방법{CAPACITOR FORMING METHOD}Capacitor Formation Method {CAPACITOR FORMING METHOD}

본 발명은 커패시터 형성방법에 관한 것으로, 특히 고집적 메모리소자를 형성하기위해서 폴리실리콘 하드마스크와 폴리측벽을 사용하지 않으면서도 노광장비의 한계해상력보다 미세한 콘택을 형성할 수 있음은 물론이고 하부 배선과 절연을 유지하고, 공정을 단순화 하기에 적당하도록 한 커패시터 형성방법에 관한 것이다.The present invention relates to a method for forming a capacitor, and in particular, to form a highly integrated memory device, it is possible to form a contact finer than the limit resolution of an exposure apparatus without using a polysilicon hard mask and a poly side wall, as well as insulation with a lower wiring. And a capacitor forming method suitable for simplifying the process.

종래 커패시터 형성방법의 일실시예를 도 1a 내지 도 1c의 수순단면도를 참고하여 설명하면 다음과 같다.An embodiment of the conventional capacitor forming method will be described below with reference to the procedure cross-sectional view of FIGS. 1A to 1C.

먼저, 도 1a에 도시한 바와 같이 소자가 형성된 반도체기판(1) 상부에 제 1층간절연막(2)을 증착하고 상기 소자의 특정부분에 접속되도록 폴리플러그(3)를 형성한 후 그 상부전면에 차례로 제 2층간절연막(4), 도전막을 증착하고, 상기 도전막을 패터닝하여 비트라인(5)을 형성한 다음 상기 구조물 상부전면에 차례로 제 1질화막(6), 제 3층간절연막(7)을 증착한다.First, as shown in FIG. 1A, a first interlayer insulating film 2 is deposited on a semiconductor substrate 1 on which an element is formed, and a poly plug 3 is formed to be connected to a specific portion of the element. The second interlayer insulating film 4 and the conductive film are sequentially deposited, and the conductive film is patterned to form the bit line 5, and then the first nitride film 6 and the third interlayer insulating film 7 are sequentially deposited on the upper surface of the structure. do.

그 다음, 도 1b에 도시한 바와 같이 제 2층간절연막(7) 상부에 제 1폴리실리콘(8)을 형성하고 상기 폴리플러그(3)가 형성된 영역에 맞추어 사진식각공정으로 식각한다.Next, as shown in FIG. 1B, the first polysilicon 8 is formed on the second interlayer insulating film 7 and etched by a photolithography process in accordance with the region where the polyplug 3 is formed.

그리고, 상기 구조물 상부에 제 2폴리실리콘(9)을 형성하고 이를 에치백하여 상기 제 1폴리실리콘(8)의 식각된 측면에 측벽을 형성한 후 이를 하드마스크로 상기 폴리플러그(3)와 연결되도록 제 3층간절연막(7), 제 1질화막(6), 제2층간절연막(4)을 식각하여 콘택홀을 형성한다.In addition, a second polysilicon 9 is formed on the structure and etched back to form sidewalls on the etched side of the first polysilicon 8 and then connected to the polyplug 3 with a hard mask. The third interlayer insulating film 7, the first nitride film 6, and the second interlayer insulating film 4 are etched to form contact holes.

그 다음, 도 1c에 도시한 바와 같이 상기 형성한 콘택홀을 도전성물질로 채우고 이를 상기 제 3층간절연막(7)이 드러나도록 에치백하면서 상기 제 1폴리실리콘(8) 및 제 2폴리실리콘(9)을 제거하여 노드콘택(10)을 형성하고, 그 상부전면에 제 2질화막(11)을 증착한 후 그 상부에 산화막(12)을 높이 형성한다.Subsequently, as shown in FIG. 1C, the formed contact hole is filled with a conductive material, and the first polysilicon 8 and the second polysilicon 9 are etched back to expose the third interlayer insulating film 7. ), The node contact 10 is formed, the second nitride film 11 is deposited on the upper surface thereof, and the oxide film 12 is formed high on the upper surface of the node contact 10.

그 다음, 도 1d에 도시한 바와 같이 커패시터가 형성될 위치에 맞추어 노드콘택(10)이 드러나도록 차례로 산화막(12), 제 2질화막(11)을 식각하고, 상기 구조물 상부전면에 제 3폴리실리콘(13)을 형성한 후 그 상부에 절연막(14)을 높이 형성하고, 상기 제 3폴리실리콘(13)이 드러나도록 에치백한다.Next, as illustrated in FIG. 1D, the oxide layer 12 and the second nitride layer 11 are sequentially etched so that the node contact 10 is exposed to the position where the capacitor is to be formed, and the third polysilicon is formed on the upper surface of the structure. After forming (13), the insulating film 14 is formed high on the upper portion thereof, and etched back so that the third polysilicon 13 is exposed.

그 다음, 도 1e에 도시한 바와 같이 상기과정으로 드러난 제 3폴리실리콘(13)을 식각하고, 잔류하는 산화막(12) 및 절연막(14)을 습식식각으로 제거한다.Next, as shown in FIG. 1E, the third polysilicon 13 exposed by the above process is etched, and the remaining oxide film 12 and the insulating film 14 are removed by wet etching.

상기와 같은 공정으로 커패시터 하부전극을 형성하기 위해서 폴리실리콘을 4번 증착해야한다.Polysilicon must be deposited four times to form a capacitor lower electrode by the above process.

상기한 바와 같은 종래 커패시터 형성방법은 0.2~0.15㎛ 디자인 룰의 반도체 소자를 구현하기 위해서 DUV(Deep Ultra Violet)노광원을 이용한 패터닝방법은 0.25㎛이하에서는 미소패턴의 구현상 균일한 크기를 유지하기 힘들고, 고가의 장비를 배제하기 위하여 I선 노광원을 이용하고 하드마스크와 측벽을 이용한방법은 공정시간과 제조단가를 높이는 원인이 된다.Conventional capacitor formation method as described above is a patterning method using a DUV (Deep Ultra Violet) exposure source to implement a semiconductor device of 0.2 ~ 0.15㎛ design rule to maintain a uniform size in the implementation of a micro pattern below 0.25㎛ The use of I-line exposure sources and the use of hard masks and sidewalls to eliminate difficult and expensive equipment is a cause of increasing process time and manufacturing costs.

또한, 노드콘택과 하부배선의 단락을 방지하기위해 산화막을 측벽으로 사용하는 방법과 질화막을 이용한 자기정렬방식을 이용한 공정이 도입되고 있으나 공정을 추가해야 하므로 양산성과 제조원가 측면에서 비 효율적인 문제점이 있었다.In addition, a method using an oxide film as a sidewall and a self-aligning method using a nitride film have been introduced to prevent a short circuit between the node contact and the lower interconnection, but there is a problem in terms of productivity and manufacturing cost because of the additional process.

본 발명은 상기한 바와 같은 종래의 문제점을 해결하기 위하여 창안한 것으로, 본 발명의 목적은 종래 4회에 달하는 폴리실리콘 형성을 1회로 줄임으로써 공정을 단순화함은 물론이고, 노광장비의 한계해상도보다 미세하면서도 하부배선과 의 단락을 방지할 수 있는 노드콘택을 형성함으로써 공정시간 및 제조원가를 줄이고 고집적이 가능한 커패시터 형성방법을 제공하는데 있다.The present invention was devised to solve the conventional problems as described above, and the object of the present invention is to simplify the process by reducing the polysilicon formation to four times of the prior art, as well as to simplify the process, rather than the limit resolution of the exposure equipment. The present invention provides a method of forming a capacitor capable of reducing process time and manufacturing cost and forming a highly integrated node by forming a node contact that can prevent a short circuit with a lower wiring.

도 1은 종래 커패시터 형성방법을 보인 수순단면도.1 is a cross-sectional view showing a conventional capacitor forming method.

도 2는 본 발명 일실시예의 수순단면도.Figure 2 is a cross-sectional view of the procedure of an embodiment of the present invention.

*** 도면의 주요부분에 대한 부호의 설명 ****** Explanation of symbols for main parts of drawing ***

21 : 반도체기판 22 : 제 1층간절연막21 semiconductor substrate 22 first interlayer insulating film

23 : 폴리플러그 24 : 제 2층간절연막23 poly plug 24 second interlayer insulating film

25 : 비트라인 26 : 제 1질화막25 bit line 26 first nitride film

27 : 제 3층간절연막 28 : 제 2질화막27: third interlayer insulating film 28: second nitride film

29 : 산화막 30 : 폴리실리콘29: oxide film 30: polysilicon

31 : 절연막31: insulating film

상기한 바와 같은 본 발명의 목적을 달성하기 위한 커패시터 형성방법은 소자가 형성된 반도체기판 상부에 제 1층간절연막을 증착하고 상기 소자의 특정부분에 접속되도록 폴리플러그를 형성한 후 그 상부전면에 차례로 제 2층간절연막, 도전막을 증착하고, 상기 도전막을 패터닝하여 비트라인을 형성한 다음 상기 구조물 상부전면에 차례로 제 1질화막, 제 3층간절연막, 제 2질화막을 증착하는 제 1공정과; 상기 형성한 폴리플러그가 드러나도록 사진식각공정을 통해 상기 제 2질화막, 제 3층간절연막, 제 1질화막, 제 2층간절연막을 식각하여 노드콘택홀을 형성하고, 그 상부에 산화막을 높이 증착하는 제 2공정과; 상기 형성한 산화막 및 제 2질화막의 일부를 커패시터가 형성될 위치에 맞추어 식각하여 패터닝하면서 상기 폴리플러그가 드러나도록 한 후 그 상부전면에 폴리실리콘을 형성하고, 그 상부에 절연막을 형성한 다음 이를 상기 폴리실리콘이 드러나도록 에치백하는 제 3공정과; 상기 잔류하는 절연막 및 산화막을 습식식각으로 제거하는 제 4공정으로 이루어지는 것을 특징으로한다.A capacitor forming method for achieving the object of the present invention as described above is to deposit a first interlayer insulating film on the semiconductor substrate on which the device is formed, and to form a polyplug to be connected to a specific part of the device, and then sequentially A first step of depositing a two-layer insulating film and a conductive film, patterning the conductive film to form a bit line, and then depositing a first nitride film, a third interlayer insulating film, and a second nitride film on the entire upper surface of the structure; Forming a node contact hole by etching the second nitride film, the third interlayer insulating film, the first nitride film, and the second interlayer insulating film through a photolithography process so that the formed polyplug is exposed, and forming an oxide film thereon. 2 step; A portion of the formed oxide film and the second nitride film are etched and patterned in accordance with the position at which the capacitor is to be formed to expose the polyplug, and then polysilicon is formed on the upper surface thereof, and an insulating film is formed thereon. A third step of etching back to reveal the polysilicon; And a fourth step of removing the remaining insulating film and the oxide film by wet etching.

상기한 바와 같은 본 발명에의한 커패시터 형성방법을 도 2a 내지 도 2d에 도시한 수순단면도를 일 실시예로하여 상세히 설명하면 다음과 같다.The method of forming a capacitor according to the present invention as described above will be described in detail with reference to a procedure cross-sectional view shown in FIGS. 2A to 2D as an embodiment.

먼저, 도 2a에 도시한 바와 같이 소자가 형성된 반도체기판(21) 상부에 제 1층간절연막(22)을 증착하고 상기 소자의 특정부분에 접속되도록 폴리플러그(23)를 형성한다.First, as shown in FIG. 2A, a first interlayer insulating film 22 is deposited on the semiconductor substrate 21 on which the device is formed, and a polyplug 23 is formed to be connected to a specific portion of the device.

그리고, 상기 폴리플러그(23) 상부전면에 차례로 제 2층간절연막(24), 도전막을 증착하고, 상기 도전막을 패터닝하여 비트라인(25)을 형성한 후 상기 구조물 상부전면에 차례로 제 1질화막(26), 제 3층간절연막(27), 제 2질화막(28)을 증착한다.The second interlayer insulating film 24 and the conductive film are sequentially deposited on the upper surface of the polyplug 23, the conductive film is patterned to form a bit line 25, and the first nitride film 26 is sequentially formed on the upper surface of the structure. ), The third interlayer insulating film 27 and the second nitride film 28 are deposited.

그 다음, 도 2b에 도시한 바와 같이 상기 형성한 폴리플러그(23)가 드러나도록 사진식각공정을 통해 상기 제 2질화막(28), 제 3층간절연막(27), 제 1질화막(26), 제 2층간절연막(24)을 식각하여 노드콘택홀을 형성하고, 그 상부에 산화막(29)을 높이 증착한다.Next, as shown in FIG. 2B, the second nitride film 28, the third interlayer insulating film 27, the first nitride film 26, and the first nitride film are exposed through a photolithography process so that the formed polyplug 23 is exposed. The interlayer insulating film 24 is etched to form a node contact hole, and an oxide film 29 is deposited on the upper portion.

이때, 상기 콘택홀 형성을 위한 사진식각공정에서 제 1질화막(26)에 의해 식각이 둔해지므로 그 하부 제 2층간절연막(24)은 0.05㎛정도 작게 패터닝된다.At this time, since the etching is dull by the first nitride layer 26 in the photolithography process for forming the contact hole, the lower second interlayer insulating layer 24 is patterned to be 0.05 μm small.

그리고, 상기 산화막(29)은 플라즈마 화학기상증착방식(Plasma Enhanced Chemical Vapor Deposition)으로 증착하면서 기 형성된 노드콘택홀에는 스탭커버리지의 한계에 의해 보이드가 생기도록 형성하는데, 이는 후속공정에서 상기산화막(29)으로 막힌 노드콘택홀을 다시 식각하여 상기 폴리플러그(23)를 드러나도록 해야하기 때문에 식각이 쉽도록 하기 위함이다.In addition, the oxide layer 29 is formed by plasma enhanced chemical vapor deposition, and voids are formed in the previously formed node contact holes due to the limitation of step coverage, which is performed in a subsequent process. This is to facilitate etching because the poly plug 23 is exposed by etching again the node contact hole blocked by).

그 다음, 도 2c에 도시한 바와 같이 상기 형성한 산화막(29) 및 제 2질화막(28)의 일부를 커패시터가 형성될 위치에 맞추어 식각하여 패터닝하면서 상기 폴리플러그(23)가 드러나도록 한다.Next, as shown in FIG. 2C, the polyplug 23 is exposed while etching and patterning a portion of the formed oxide film 29 and the second nitride film 28 according to the position where the capacitor is to be formed.

이때, 상기 산화막(29)과 제 2질화막(28)의 식각비율을 조정하여 커패시터 하부전극이 형성될 위치에 맞추어 산화막(29)을 패터닝한 후에, 드러나는 제 2질화막(28)의 식각을 억제하면서 상기 폴리플러그(23)가 드러나도록 콘택홀 내부에 잔류하는 산화막(29)을 식각하여 노드콘택홀 측면에 산화막(29) 측벽을 형성한다.At this time, after adjusting the etch rate of the oxide film 29 and the second nitride film 28 to pattern the oxide film 29 in accordance with the position where the capacitor lower electrode is to be formed, while suppressing the etching of the exposed second nitride film 28. The oxide layer 29 remaining inside the contact hole is etched to expose the poly plug 23 to form sidewalls of the oxide layer 29 on the side of the node contact hole.

그리고, 상기 구조물 상부전면에 폴리실리콘(30)을 형성하고, 그 상부에 절연막(31)을 형성한 후 상기 폴리실리콘(30)이 드러나도록 에치백한다.Then, the polysilicon 30 is formed on the upper surface of the structure, the insulating film 31 is formed on the upper portion and then etched back so that the polysilicon 30 is exposed.

그 다음, 도 2d에 도시한 바와 같이 상기 잔류하는 절연막(31) 및 산화막(29)을 습식식각으로 제거한다.Then, as shown in FIG. 2D, the remaining insulating film 31 and the oxide film 29 are removed by wet etching.

상기 설명한 본 발명 일실시예의 공정에서 커패시터 하부전극을 형성하기 위해서는 한번의 폴리실리콘 증착만이 필요하다.Only one polysilicon deposition is required to form the capacitor lower electrode in the process of the embodiment of the present invention described above.

상기한 바와 같은 본 발명 커패시터 형성방법은 저가 장비인 I선 노광기를 이용하여 미세한 콘택홀 형성이 가능하면서도 종래 4회에 달하는 폴리실리콘 형성을 1회로 줄임으로써 공정을 단순화함은 물론이고, 노드콘택과 하부배선과의 단락을 방지함으로써 공정시간 및 제조원가를 줄이고 집적도를 높일 수 있는 효과가 있다.As described above, the capacitor forming method of the present invention enables the formation of fine contact holes using an I-line exposure machine, which is a low-cost device, but also simplifies the process by reducing the number of polysilicon formations up to four times, as well as node contact and By preventing the short circuit with the lower wiring there is an effect that can reduce the process time and manufacturing cost and increase the degree of integration.

Claims (3)

소자가 형성된 반도체기판 상부에 제 1층간절연막을 증착하고 상기 소자의 특정부분에 접속되도록 폴리플러그를 형성한 후 그 상부전면에 차례로 제 2층간절연막, 도전막을 증착하고, 상기 도전막을 패터닝하여 비트라인을 형성한 다음 상기 구조물 상부전면에 차례로 제 1질화막, 제 3층간절연막, 제 2질화막을 증착하는 제 1공정과; 상기 형성한 폴리플러그가 드러나도록 사진식각공정을 통해 상기 제 2질화막, 제 3층간절연막, 제 1질화막, 제 2층간절연막을 식각하여 노드콘택홀을 형성하고, 그 상부에 산화막을 높이 증착하는 제 2공정과; 상기 형성한 산화막 및 제 2질화막의 일부를 커패시터가 형성될 위치에 맞추어 식각하여 패터닝하면서 상기 폴리플러그가 드러나도록 한 후 그 상부전면에 폴리실리콘을 형성하고, 그 상부에 절연막을 형성한 다음 상기 폴리실리콘이 드러나도록 에치백하는 제 3공정과; 상기 잔류하는 절연막 및 산화막을 습식식각으로 제거하는 제 4공정으로 이루어지는 것을 특징으로 하는 커패시터 형성방법.A first interlayer insulating film is deposited on the semiconductor substrate on which the device is formed, a polyplug is formed so as to be connected to a specific portion of the device, and then a second interlayer insulating film and a conductive film are deposited on the upper surface thereof in turn, and the bit line is patterned by patterning the conductive film. Forming a first nitride film, a third interlayer insulating film, and a second nitride film on the upper surface of the structure; Forming a node contact hole by etching the second nitride film, the third interlayer insulating film, the first nitride film, and the second interlayer insulating film through a photolithography process so that the formed polyplug is exposed, and forming an oxide film thereon. 2 step; A portion of the formed oxide film and the second nitride film are etched and patterned in accordance with the position where the capacitor is to be formed to expose the polyplug, and then polysilicon is formed on the upper surface thereof, and an insulating film is formed thereon. A third step of etching back so that the silicon is exposed; And a fourth step of removing the remaining insulating film and the oxide film by wet etching. 제 1항에 있어서, 상기 제 2공정에서 산화막은 플라즈마 화학기상증착방식으로 증착하면서 기 형성된 노드콘택홀에는 상기 산화막의 스탭커버리지 한계에 의해 보이드가 생기도록 형성하는 것을 특징으로하는 커패시터 형성방법.The method of claim 1, wherein the oxide film is deposited by plasma chemical vapor deposition in the second step, and the void is formed in the previously formed node contact hole due to the step coverage limit of the oxide film. 제 1항에 있어서, 상기 제 3공정에서 상기 산화막과 제 2질화막의 식각비율을조정하여 커패시터 하부전극이 형성될 위치에 맞추어 산화막을 패터닝한 후에, 드러나는 제 2질화막의 식각을 억제하면서 상기 폴리플러그가 드러나도록 콘택홀 내부에 잔류하는 산화막을 식각하여 노드콘택홀 측면에 산화막 측벽을 형성하도록 하는것을 특징으로하는 커패시터 형성방법.The polyplug of claim 1, wherein after adjusting the etch rate of the oxide film and the second nitride film in the third process to pattern the oxide film according to a position where a capacitor lower electrode is to be formed, the polyplug is suppressed while the etching of the exposed second nitride film is suppressed. And etching the oxide film remaining inside the contact hole so that the oxide film sidewall is formed on the side of the node contact hole.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100418573B1 (en) * 2001-09-14 2004-02-11 주식회사 하이닉스반도체 Method for fabricating semiconductor device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100418573B1 (en) * 2001-09-14 2004-02-11 주식회사 하이닉스반도체 Method for fabricating semiconductor device
US6777305B2 (en) 2001-09-14 2004-08-17 Hynix Semiconductor Inc. Method for fabricating semiconductor device

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