KR102626996B1 - 에폭시 접착제를 위한 블로킹된 폴리우레탄 강인화제 - Google Patents
에폭시 접착제를 위한 블로킹된 폴리우레탄 강인화제 Download PDFInfo
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- KR102626996B1 KR102626996B1 KR1020187008091A KR20187008091A KR102626996B1 KR 102626996 B1 KR102626996 B1 KR 102626996B1 KR 1020187008091 A KR1020187008091 A KR 1020187008091A KR 20187008091 A KR20187008091 A KR 20187008091A KR 102626996 B1 KR102626996 B1 KR 102626996B1
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- 241000894007 species Species 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
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- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
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- 239000004094 surface-active agent Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
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- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- 239000004639 urea-formaldehyde foam Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3215—Polyhydroxy compounds containing aromatic groups or benzoquinone groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/69—Polymers of conjugated dienes
- C08G18/698—Mixtures with compounds of group C08G18/40
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/8064—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/8064—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with monohydroxy compounds
- C08G18/8067—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with monohydroxy compounds phenolic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
- C08G18/8077—Oximes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
- C08G18/808—Monoamines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polyurethanes Or Polyureas (AREA)
- Epoxy Resins (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562216399P | 2015-09-10 | 2015-09-10 | |
| US62/216,399 | 2015-09-10 | ||
| PCT/US2016/050342 WO2017044402A1 (en) | 2015-09-10 | 2016-09-06 | Blocked polyurethane tougheners for epoxy adhesives |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20180052645A KR20180052645A (ko) | 2018-05-18 |
| KR102626996B1 true KR102626996B1 (ko) | 2024-01-19 |
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| US (2) | US20180251633A1 (https=) |
| EP (1) | EP3347391B1 (https=) |
| JP (1) | JP2018532820A (https=) |
| KR (1) | KR102626996B1 (https=) |
| CN (1) | CN107922570B (https=) |
| BR (1) | BR112018003350B1 (https=) |
| WO (1) | WO2017044402A1 (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110892033B (zh) * | 2017-06-23 | 2022-04-15 | Ddp特种电子材料美国公司 | 高温环氧粘合剂配制品 |
| EP3655450B1 (en) * | 2017-07-21 | 2022-08-31 | Huntsman Advanced Materials Americas LLC | Urea terminated butadiene polymers and butadiene acrylonitrile copolymers |
| US11820922B2 (en) * | 2017-10-18 | 2023-11-21 | Ddp Specialty Electronic Materials Us, Llc | Adhesive composition |
| JP7187347B2 (ja) * | 2019-02-26 | 2022-12-12 | 株式会社カネカ | 硬化性エポキシ樹脂組成物、及びそれを用いた積層体 |
| US20220195267A1 (en) * | 2019-06-18 | 2022-06-23 | Ddp Specialty Electronic Materials Us, Llc | One-component toughened epoxy adhesives with improved humidity resistance |
| EP4107203A1 (en) * | 2020-02-19 | 2022-12-28 | Covestro LLC | Flexibilizing capped prepolymers |
| EP3892659A1 (de) | 2020-04-08 | 2021-10-13 | Covestro Deutschland AG | Mit aus cashewnuss-schalenöl erhältlichen phenolen blockierte, niedrigviskose isocyanat-prepolymere, verfahren zur deren herstellung und deren verwendung |
| JPWO2022034877A1 (https=) * | 2020-08-12 | 2022-02-17 | ||
| KR102297539B1 (ko) * | 2020-08-25 | 2021-09-02 | 한국화학연구원 | 에폭시 접착제 조성물을 위한 트리블록 구조의 폴리우레탄 강인화제 |
| JP2024512348A (ja) * | 2021-03-05 | 2024-03-19 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | 衝撃耐性、耐応力性、及び溶接性を備えたエポキシ接着剤 |
| WO2022235802A1 (en) | 2021-05-05 | 2022-11-10 | Dow Global Technologies Llc | Thermal interface materials |
| KR102705627B1 (ko) * | 2022-01-20 | 2024-09-11 | 한국화학연구원 | 비스페놀-z를 이용한 폴리올과 폴리우레탄합성 및 물성연구 |
| CN116854884B (zh) * | 2023-07-13 | 2025-07-25 | 中路交科科技股份有限公司 | 一种路桥高韧环氧用增韧剂、制备方法及其使用方法 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1259897A (en) | 1985-04-02 | 1989-09-26 | Madan M. Bagga | Bonding process using curable epoxide resin adhesive |
| JP2003064157A (ja) * | 2001-08-24 | 2003-03-05 | Sumitomo Bakelite Co Ltd | エポキシ樹脂組成物及び半導体装置 |
| CN1823105B (zh) * | 2003-06-04 | 2010-05-05 | 克拉通聚合物研究有限公司 | 由氢化的嵌段共聚物制备的制品 |
| US7557169B2 (en) | 2003-07-07 | 2009-07-07 | Dow Global Technologies, Inc. | Capping isocyanate prepolymer or polyisocyanate/polyether polyol or polyamine mixture |
| EP2843022B1 (en) | 2003-07-07 | 2020-12-16 | Dow Global Technologies LLC | Adhesive epoxy composition and process for applying it |
| EP1498441A1 (de) * | 2003-07-16 | 2005-01-19 | Sika Technology AG | Hitzehärtende Zusammensetzungen mit Tieftemperatur-Schlagzähigkeitsmodifikatoren |
| DE602005020260D1 (de) * | 2005-06-02 | 2010-05-12 | Dow Global Technologies Inc | Schlagzähmodifizierter Strukturklebstoff auf Epoxid Basis |
| EP1876194A1 (de) * | 2006-06-30 | 2008-01-09 | Sika Technology AG | Hitzehärtende Zusammensetzung geeignet zum Verkleben von beschichteten Substraten |
| US7759435B2 (en) * | 2006-09-26 | 2010-07-20 | Loctite (R&D) Limited | Adducts and curable compositions using same |
| EP1916270A1 (de) * | 2006-10-24 | 2008-04-30 | Sika Technology AG | Hitzehärtende Epoxidharzzusammensetzung mit blockiertem Polyurethanprepolymer |
| EP1916272A1 (de) | 2006-10-24 | 2008-04-30 | Sika Technology AG | Hitzehärtende Epoxidharzzusammensetzung enthaltend ein blockiertes und ein epoxidterminiertes Polyurethanprepolymer |
| DE502007002766D1 (de) * | 2007-11-14 | 2010-03-18 | Sika Technology Ag | Hitzehärtende Epoxidharzzusammensetzung enthaltend nichtaromatische Harnstoffe als Beschleuniger |
| WO2009094295A1 (en) * | 2008-01-22 | 2009-07-30 | Dow Global Technologies Inc. | Structural epoxy resin adhesives containing epoxide-functional, polyphenol-extended elastomeric tougheners |
| ATE484547T1 (de) | 2008-01-30 | 2010-10-15 | Sika Technology Ag | Auswaschbeständige hitzehärtende epoxidharzklebstoffe |
| EP2110397A1 (de) | 2008-04-16 | 2009-10-21 | Sika Technology AG | Auf amphiphilen Block-Copolymer basierendes Polyurethan-Polymer und dessen Verwendung als Schlagzähigkeitsmodifikator |
| EP2128182A1 (de) | 2008-05-28 | 2009-12-02 | Sika Technology AG | Hitzehärtende Epoxidharzzusammensetzung enthaltend einen Beschleuniger mit Heteroatomen |
| EP2655516B1 (en) * | 2010-12-26 | 2018-12-26 | Dow Global Technologies LLC | Structural epoxy resin adhesives containing chain-extended elastomeric tougheners capped with phenol, polyphenol or aminophenol compounds |
| MX2015005866A (es) * | 2012-11-08 | 2016-02-05 | Basf Se | Eteres de diglicidilo de derivados de 2-fenil-1, 3-propandiol y oligomeros de estos como resinas epoxi curables. |
| WO2014072515A1 (de) * | 2012-11-12 | 2014-05-15 | Sika Technology Ag | Neue schlagzähigkeitsmodifikatoren für epoxy-basierte klebstoffe |
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2016
- 2016-09-06 BR BR112018003350-2A patent/BR112018003350B1/pt active IP Right Grant
- 2016-09-06 JP JP2018508154A patent/JP2018532820A/ja active Pending
- 2016-09-06 WO PCT/US2016/050342 patent/WO2017044402A1/en not_active Ceased
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- 2016-09-06 EP EP16767105.6A patent/EP3347391B1/en active Active
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| Publication number | Publication date |
|---|---|
| CN107922570B (zh) | 2021-11-30 |
| BR112018003350A2 (https=) | 2018-10-02 |
| BR112018003350B1 (pt) | 2022-06-14 |
| EP3347391A1 (en) | 2018-07-18 |
| EP3347391B1 (en) | 2020-10-21 |
| WO2017044402A1 (en) | 2017-03-16 |
| US20200181404A1 (en) | 2020-06-11 |
| KR20180052645A (ko) | 2018-05-18 |
| JP2018532820A (ja) | 2018-11-08 |
| US20180251633A1 (en) | 2018-09-06 |
| CN107922570A (zh) | 2018-04-17 |
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