KR102470347B1 - 1개 또는 다수개의 말단-기능성화된 분지를 가지는 폴리올레핀의 제조 방법 - Google Patents

1개 또는 다수개의 말단-기능성화된 분지를 가지는 폴리올레핀의 제조 방법 Download PDF

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KR102470347B1
KR102470347B1 KR1020177020265A KR20177020265A KR102470347B1 KR 102470347 B1 KR102470347 B1 KR 102470347B1 KR 1020177020265 A KR1020177020265 A KR 1020177020265A KR 20177020265 A KR20177020265 A KR 20177020265A KR 102470347 B1 KR102470347 B1 KR 102470347B1
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hydrocarbyl
metal
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polyolefin
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KR20170108959A (ko
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로버트 두샤또
밀루드 부야히
리디아 야신스카-발츠
마틴 알렉산더 주이드벨트
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사빅 글로벌 테크놀러지스 비.브이.
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/09—Long chain branches
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
KR1020177020265A 2014-12-23 2015-12-23 1개 또는 다수개의 말단-기능성화된 분지를 가지는 폴리올레핀의 제조 방법 Active KR102470347B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14200124.7 2014-12-23
EP14200124.7A EP3037437A1 (en) 2014-12-23 2014-12-23 Process for the preparation of a polyolefin having one or multiple end-functionalized branches.
PCT/EP2015/081207 WO2016102694A1 (en) 2014-12-23 2015-12-23 Process for the preparation of a polyolefin having one or multiple end-functionalized branches

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KR20170108959A KR20170108959A (ko) 2017-09-27
KR102470347B1 true KR102470347B1 (ko) 2022-11-23

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US (1) US10465018B2 (enExample)
EP (2) EP3037437A1 (enExample)
JP (1) JP7115852B2 (enExample)
KR (1) KR102470347B1 (enExample)
CN (1) CN107223138B (enExample)
SA (1) SA517381806B1 (enExample)
WO (1) WO2016102694A1 (enExample)

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WO2017039994A1 (en) 2015-08-31 2017-03-09 Exxonmobil Chemical Patents Inc. Aluminum alkyls with pendant olefins on clays
US10618988B2 (en) 2015-08-31 2020-04-14 Exxonmobil Chemical Patents Inc. Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof
JP2018525507A (ja) * 2015-08-31 2018-09-06 エクソンモービル・ケミカル・パテンツ・インク ビニル連鎖移動剤の使用によって製造されたポリマー
WO2017039995A1 (en) * 2015-08-31 2017-03-09 Exxonmobil Chemical Patents Inc. Aluminum alkyls with pendant olefins for polyolefin reactions
EP3387047B1 (en) 2015-12-09 2020-01-01 SABIC Global Technologies B.V. Process for the preparation of polyolefin-based graft copolymers comprising a first long chain branched polyolefin block and one or multiple polymer side chains
US10927196B2 (en) 2016-06-30 2021-02-23 Exxonmobil Chemical Patents Inc. Long chain branched polypropylene via polymerization with aluminum vinyl transfer agent
US10562987B2 (en) 2016-06-30 2020-02-18 Exxonmobil Chemical Patents Inc. Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents
US10626200B2 (en) 2017-02-28 2020-04-21 Exxonmobil Chemical Patents Inc. Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof
WO2018160278A1 (en) * 2017-03-01 2018-09-07 Exxonmobil Chemical Patents Inc. Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof
EP3728351A1 (en) * 2017-12-22 2020-10-28 SABIC Global Technologies B.V. Process for preparation of ethylene and propylene ionomer
SG11202005532YA (en) 2017-12-29 2020-07-29 Dow Global Technologies Llc Capped dual-headed organoaluminum compositions
CN109467660B (zh) * 2018-10-06 2021-03-02 天津大学 利用链穿梭方法合成聚(乙烯-r-降冰片烯/乙烯)多嵌段共聚物
BR112021012845A2 (pt) * 2018-12-28 2021-09-28 Dow Global Technologies Llc Composição curável, e, artigo
WO2020140064A1 (en) * 2018-12-28 2020-07-02 Dow Global Technologies Llc Organometallic chain transfer agents
CN111116811B (zh) * 2020-01-03 2022-07-05 天津大学 一种1-丁烯/降冰片烯共聚物及其制备方法
WO2022029213A1 (en) * 2020-08-06 2022-02-10 Total Research & Technology Feluy Process for preparing ethylene polymers having long chain branches
US12195563B2 (en) * 2020-12-29 2025-01-14 Exxonmobil Chemical Patents Inc. Polyolefin-based ionomers and production thereof
CN117083307A (zh) * 2021-04-30 2023-11-17 陶氏环球技术有限责任公司 磺酰卤封端的聚乙烯的合成

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US20170355787A1 (en) 2017-12-14
CN107223138B (zh) 2020-10-23
JP2018500430A (ja) 2018-01-11
US10465018B2 (en) 2019-11-05
EP3237461A1 (en) 2017-11-01
KR20170108959A (ko) 2017-09-27
CN107223138A (zh) 2017-09-29
SA517381806B1 (ar) 2021-01-14
EP3037437A1 (en) 2016-06-29
JP7115852B2 (ja) 2022-08-09
WO2016102694A1 (en) 2016-06-30

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