CN107223138B - 用于制备具有一个或多个末端官能化的分支的聚烯烃的方法 - Google Patents

用于制备具有一个或多个末端官能化的分支的聚烯烃的方法 Download PDF

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CN107223138B
CN107223138B CN201580075823.3A CN201580075823A CN107223138B CN 107223138 B CN107223138 B CN 107223138B CN 201580075823 A CN201580075823 A CN 201580075823A CN 107223138 B CN107223138 B CN 107223138B
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hydrocarbyl
metal
group
bis
polyolefin
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CN107223138A (zh
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R·达查特奥
M·鲍雅伊
L·甲辛斯卡-沃尔克
M·A·祖德维尔德
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SABIC Global Technologies BV
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/09—Long chain branches
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
CN201580075823.3A 2014-12-23 2015-12-23 用于制备具有一个或多个末端官能化的分支的聚烯烃的方法 Active CN107223138B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14200124.7 2014-12-23
EP14200124.7A EP3037437A1 (en) 2014-12-23 2014-12-23 Process for the preparation of a polyolefin having one or multiple end-functionalized branches.
PCT/EP2015/081207 WO2016102694A1 (en) 2014-12-23 2015-12-23 Process for the preparation of a polyolefin having one or multiple end-functionalized branches

Publications (2)

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CN107223138A CN107223138A (zh) 2017-09-29
CN107223138B true CN107223138B (zh) 2020-10-23

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US (1) US10465018B2 (enExample)
EP (2) EP3037437A1 (enExample)
JP (1) JP7115852B2 (enExample)
KR (1) KR102470347B1 (enExample)
CN (1) CN107223138B (enExample)
SA (1) SA517381806B1 (enExample)
WO (1) WO2016102694A1 (enExample)

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WO2017039994A1 (en) 2015-08-31 2017-03-09 Exxonmobil Chemical Patents Inc. Aluminum alkyls with pendant olefins on clays
CN107922527A (zh) 2015-08-31 2018-04-17 埃克森美孚化学专利公司 用于聚烯烃反应的具有悬垂烯烃的铝烷基
US10618988B2 (en) 2015-08-31 2020-04-14 Exxonmobil Chemical Patents Inc. Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof
WO2017039993A1 (en) * 2015-08-31 2017-03-09 Exxonmobil Chemical Patents Inc. Polymers produced via use of vinyl transfer agents
EP3387047B1 (en) * 2015-12-09 2020-01-01 SABIC Global Technologies B.V. Process for the preparation of polyolefin-based graft copolymers comprising a first long chain branched polyolefin block and one or multiple polymer side chains
US10927196B2 (en) 2016-06-30 2021-02-23 Exxonmobil Chemical Patents Inc. Long chain branched polypropylene via polymerization with aluminum vinyl transfer agent
US10562987B2 (en) 2016-06-30 2020-02-18 Exxonmobil Chemical Patents Inc. Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents
US10626200B2 (en) 2017-02-28 2020-04-21 Exxonmobil Chemical Patents Inc. Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof
US10676551B2 (en) * 2017-03-01 2020-06-09 Exxonmobil Chemical Patents Inc. Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof
ES2980718T3 (es) * 2017-12-22 2024-10-02 Sabic Global Technologies Bv Procedimiento de preparación de un copolímero de olefina funcionalizada semicristalino
US11613600B2 (en) 2017-12-29 2023-03-28 Dow Global Technologies Llc Capped dual-headed organoaluminum compositions
CN109467660B (zh) * 2018-10-06 2021-03-02 天津大学 利用链穿梭方法合成聚(乙烯-r-降冰片烯/乙烯)多嵌段共聚物
US20220073540A1 (en) * 2018-12-28 2022-03-10 Dow Global Technologies Llc Curable compositions comprising unsaturated polyolefins
ES3040148T3 (en) * 2018-12-28 2025-10-28 Dow Global Technologies Llc Organometallic chain transfer agents
CN111116811B (zh) * 2020-01-03 2022-07-05 天津大学 一种1-丁烯/降冰片烯共聚物及其制备方法
WO2022029213A1 (en) * 2020-08-06 2022-02-10 Total Research & Technology Feluy Process for preparing ethylene polymers having long chain branches
US12195563B2 (en) * 2020-12-29 2025-01-14 Exxonmobil Chemical Patents Inc. Polyolefin-based ionomers and production thereof
EP4330295A1 (en) * 2021-04-30 2024-03-06 Dow Global Technologies LLC Synthesis of sulfonyl halide terminated polyethylene

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Publication number Publication date
US10465018B2 (en) 2019-11-05
SA517381806B1 (ar) 2021-01-14
WO2016102694A1 (en) 2016-06-30
EP3037437A1 (en) 2016-06-29
US20170355787A1 (en) 2017-12-14
EP3237461A1 (en) 2017-11-01
KR20170108959A (ko) 2017-09-27
EP3237461B1 (en) 2026-03-18
JP7115852B2 (ja) 2022-08-09
CN107223138A (zh) 2017-09-29
KR102470347B1 (ko) 2022-11-23
JP2018500430A (ja) 2018-01-11

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