KR102279651B1 - 코어-쉘 공중합체, 이의 제조방법 및 이를 포함하는 열가소성 수지 조성물 - Google Patents

코어-쉘 공중합체, 이의 제조방법 및 이를 포함하는 열가소성 수지 조성물 Download PDF

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KR102279651B1
KR102279651B1 KR1020180141167A KR20180141167A KR102279651B1 KR 102279651 B1 KR102279651 B1 KR 102279651B1 KR 1020180141167 A KR1020180141167 A KR 1020180141167A KR 20180141167 A KR20180141167 A KR 20180141167A KR 102279651 B1 KR102279651 B1 KR 102279651B1
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weight
parts
shell
formula
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KR20200056888A (ko
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이광진
김윤호
남상일
선경복
이창노
한상훈
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주식회사 엘지화학
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Priority to PCT/KR2019/013391 priority patent/WO2020101182A1/ko
Priority to JP2020541447A priority patent/JP6961830B2/ja
Priority to US16/966,672 priority patent/US11912804B2/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/28—Emulsion polymerisation with the aid of emulsifying agents cationic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/38—Esters containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/38—Esters containing sulfur
    • C08F220/382—Esters containing sulfur and containing oxygen, e.g. 2-sulfoethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/22—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L27/24—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment halogenated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/40—Redox systems

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
KR1020180141167A 2018-11-15 2018-11-15 코어-쉘 공중합체, 이의 제조방법 및 이를 포함하는 열가소성 수지 조성물 Active KR102279651B1 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
KR1020180141167A KR102279651B1 (ko) 2018-11-15 2018-11-15 코어-쉘 공중합체, 이의 제조방법 및 이를 포함하는 열가소성 수지 조성물
PCT/KR2019/013391 WO2020101182A1 (ko) 2018-11-15 2019-10-11 코어-쉘 공중합체, 이의 제조방법 및 이를 포함하는 열가소성 수지 조성물
JP2020541447A JP6961830B2 (ja) 2018-11-15 2019-10-11 コア−シェル共重合体、その製造方法、およびそれを含む熱可塑性樹脂組成物
US16/966,672 US11912804B2 (en) 2018-11-15 2019-10-11 Core-shell copolymer, method for preparing the same and thermoplastic resin composition including the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020180141167A KR102279651B1 (ko) 2018-11-15 2018-11-15 코어-쉘 공중합체, 이의 제조방법 및 이를 포함하는 열가소성 수지 조성물

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KR20200056888A KR20200056888A (ko) 2020-05-25
KR102279651B1 true KR102279651B1 (ko) 2021-07-19

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US (1) US11912804B2 (enExample)
JP (1) JP6961830B2 (enExample)
KR (1) KR102279651B1 (enExample)
WO (1) WO2020101182A1 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022187193A1 (en) * 2021-03-05 2022-09-09 Rohm And Haas Company Impact modifier with improved flammability
CN116917360A (zh) * 2021-03-05 2023-10-20 罗门哈斯公司 具有改善的可燃性的抗冲改性剂的制备
CN117209947B (zh) * 2023-09-26 2024-03-15 广州美村橡胶科技股份有限公司 一种水管密封用复合改性三元乙丙橡胶材料及其制备方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
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MX168323B (es) 1986-10-21 1993-05-18 Rohm & Haas Modificadores de impacto de nucleo cubierto para resinas estirenicas
US5186993A (en) * 1991-10-11 1993-02-16 Rohm And Haas Company Polymer blends
US5451624A (en) * 1994-02-15 1995-09-19 Rohm And Haas Company Stabilized modifier and impact modified thermoplastics
KR0141779B1 (ko) * 1994-08-05 1998-07-01 구자홍 요소측정용 바이오센서 및 그 제조방법
KR100479322B1 (ko) * 2001-11-15 2005-03-30 주식회사 엘지화학 아크릴계 충격보강제의 제조방법 및 이를 포함한열안정성이 향상된 피브이씨 조성물
KR101127099B1 (ko) * 2008-11-27 2012-03-23 제일모직주식회사 이방 전도성 필름용 조성물 및 이를 이용한 이방 전도성 필름
KR101391048B1 (ko) 2010-09-06 2014-05-02 주식회사 엘지화학 메틸메타크릴레이트­부타디엔­스티렌계 그라프트 공중합체, 이의 제조방법 및 이를 포함하는 ｐｖｃ 조성물
KR101620134B1 (ko) 2013-02-01 2016-05-13 주식회사 엘지화학 수용성 공단량체를 사용한 그라프트 공중합체 및 이의 제조방법 및 이를 포함하는 염화비닐수지 조성물
KR101644752B1 (ko) * 2014-09-16 2016-08-01 주식회사 엘지화학 열가소성 수지 조성물 및 이로부터 제조된 열가소성 수지 성형품
KR101751931B1 (ko) * 2014-12-24 2017-06-28 대상 주식회사 전분계 중합체 입자 에멀젼 및 이의 제조방법
CN108028379A (zh) 2015-09-28 2018-05-11 日本瑞翁株式会社 非水系二次电池电极用粘结剂组合物、非水系二次电池电极用浆料组合物、非水系二次电池用电极及非水系二次电池
KR102068650B1 (ko) 2017-01-24 2020-01-21 주식회사 엘지화학 그라프트 공중합체, 이의 제조방법, 이를 포함하는 열가소성 수지 조성물 및 성형품
KR102248039B1 (ko) * 2018-07-13 2021-05-04 주식회사 엘지화학 코어-쉘 공중합체 제조방법, 이로부터 제조된 코어-쉘 공중합체 및 이를 포함하는 수지 조성물
KR102363986B1 (ko) * 2018-11-16 2022-02-16 주식회사 엘지화학 코어-쉘 공중합체, 이의 제조방법 및 이를 포함하는 열가소성 수지 조성물

Also Published As

Publication number Publication date
JP6961830B2 (ja) 2021-11-05
WO2020101182A1 (ko) 2020-05-22
JP2021511429A (ja) 2021-05-06
US11912804B2 (en) 2024-02-27
US20210032391A1 (en) 2021-02-04
KR20200056888A (ko) 2020-05-25

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