KR102154046B1 - 연속식 중합에 의한 공액디엔계 중합체의 제조방법 - Google Patents

연속식 중합에 의한 공액디엔계 중합체의 제조방법 Download PDF

Info

Publication number
KR102154046B1
KR102154046B1 KR1020170140413A KR20170140413A KR102154046B1 KR 102154046 B1 KR102154046 B1 KR 102154046B1 KR 1020170140413 A KR1020170140413 A KR 1020170140413A KR 20170140413 A KR20170140413 A KR 20170140413A KR 102154046 B1 KR102154046 B1 KR 102154046B1
Authority
KR
South Korea
Prior art keywords
reactor
conjugated diene
polymer
decanoate
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020170140413A
Other languages
English (en)
Korean (ko)
Other versions
KR20190046518A (ko
Inventor
유석준
박성호
최수영
안정헌
Original Assignee
주식회사 엘지화학
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 주식회사 엘지화학 filed Critical 주식회사 엘지화학
Priority to KR1020170140413A priority Critical patent/KR102154046B1/ko
Priority to EP17929788.2A priority patent/EP3702378B1/en
Priority to US16/627,540 priority patent/US10982026B2/en
Priority to CN201780092489.1A priority patent/CN110785444B/zh
Priority to JP2020520024A priority patent/JP7015386B2/ja
Priority to PCT/KR2017/015490 priority patent/WO2019083092A1/ko
Publication of KR20190046518A publication Critical patent/KR20190046518A/ko
Application granted granted Critical
Publication of KR102154046B1 publication Critical patent/KR102154046B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
KR1020170140413A 2017-10-26 2017-10-26 연속식 중합에 의한 공액디엔계 중합체의 제조방법 Active KR102154046B1 (ko)

Priority Applications (6)

Application Number Priority Date Filing Date Title
KR1020170140413A KR102154046B1 (ko) 2017-10-26 2017-10-26 연속식 중합에 의한 공액디엔계 중합체의 제조방법
EP17929788.2A EP3702378B1 (en) 2017-10-26 2017-12-26 Method of preparing conjugated diene-based polymer by continuous polymerization
US16/627,540 US10982026B2 (en) 2017-10-26 2017-12-26 Method of preparing conjugated diene-based polymer by continuous polymerization
CN201780092489.1A CN110785444B (zh) 2017-10-26 2017-12-26 通过连续聚合制备共轭二烯类聚合物的方法
JP2020520024A JP7015386B2 (ja) 2017-10-26 2017-12-26 連続式重合による共役ジエン系重合体の製造方法
PCT/KR2017/015490 WO2019083092A1 (ko) 2017-10-26 2017-12-26 연속식 중합에 의한 공액디엔계 중합체의 제조방법

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020170140413A KR102154046B1 (ko) 2017-10-26 2017-10-26 연속식 중합에 의한 공액디엔계 중합체의 제조방법

Publications (2)

Publication Number Publication Date
KR20190046518A KR20190046518A (ko) 2019-05-07
KR102154046B1 true KR102154046B1 (ko) 2020-09-09

Family

ID=66247493

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020170140413A Active KR102154046B1 (ko) 2017-10-26 2017-10-26 연속식 중합에 의한 공액디엔계 중합체의 제조방법

Country Status (6)

Country Link
US (1) US10982026B2 (cg-RX-API-DMAC7.html)
EP (1) EP3702378B1 (cg-RX-API-DMAC7.html)
JP (1) JP7015386B2 (cg-RX-API-DMAC7.html)
KR (1) KR102154046B1 (cg-RX-API-DMAC7.html)
CN (1) CN110785444B (cg-RX-API-DMAC7.html)
WO (1) WO2019083092A1 (cg-RX-API-DMAC7.html)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102742692B1 (ko) * 2019-10-11 2024-12-16 주식회사 엘지화학 연속식 중합에 의한 변성 공액디엔계 중합체의 제조방법
KR102523121B1 (ko) * 2020-01-31 2023-04-19 주식회사 엘지화학 공액디엔계 중합체의 연속 제조 시스템
WO2022065902A1 (ko) * 2020-09-25 2022-03-31 주식회사 엘지화학 네오디뮴 촉매화 공액디엔계 중합체 및 이를 포함하는 고무 조성물
WO2023193943A1 (en) 2022-04-08 2023-10-12 Arlanxeo Deutschland Gmbh Branched modified diene rubbers

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4136244A (en) * 1974-12-23 1979-01-23 Compagnie Generale Des Etablissements Michelin Continuous solution polymerization process
FR2295972A1 (fr) * 1974-12-23 1976-07-23 Michelin & Cie Polymerisation ou copolymerisation en solution d'un ou plusieurs dienes conjugues avec eventuellement un ou plusieurs composes vinylaromatiques
US4843120A (en) * 1986-09-29 1989-06-27 The Goodyear Tire & Rubber Company Rubber composition
US5194491A (en) * 1989-05-30 1993-03-16 Mitsubishi Monsanto Chemical Company Process for producing rubber-modified styrene resin, and resin composition
JPH072808A (ja) 1990-12-06 1995-01-06 Roussel Uclaf チアゾリルアルコキシアクリル酸エステルからなる殺虫剤及び（又は）殺ダニ剤組成物
JP3175350B2 (ja) 1992-10-15 2001-06-11 ジェイエスアール株式会社 高ビニル結合を有するブタジエン系重合体の連続重合方法
US6444762B1 (en) * 1996-08-19 2002-09-03 Basf Aktiengesellschaft Anionic polymerization process
US5955537A (en) * 1998-02-13 1999-09-21 The Goodyear Tire & Rubber Company Continuous polymerization process
JP4038916B2 (ja) * 1999-02-03 2008-01-30 Ｊｓｒ株式会社 共役ジエン系重合体の製造方法
US6372863B1 (en) * 1999-08-12 2002-04-16 The Goodyear Tire & Rubber Company Synthesis of styrene-butadiene rubber
AU2000261797A1 (en) * 2000-07-27 2002-02-13 Jsr Corporation 1,2-polybutadiene, thermoplastic elastomer composition and polymer composition
JP4761697B2 (ja) * 2000-10-25 2011-08-31 旭化成ケミカルズ株式会社 水添重合体
DE10105401A1 (de) * 2001-02-07 2002-08-22 Bayer Ag Kontinuierliches Verfahren zur Herstellung von Elastomeren
US6627715B2 (en) * 2001-08-16 2003-09-30 The Goodyear Tire & Rubber Company Group IIa metal containing catalyst system
US6617406B2 (en) * 2001-08-30 2003-09-09 The Goodyear Tire & Rubber Company Synthesis of elastomeric high trans-1,4-polybutadiene
US7754831B2 (en) * 2002-12-25 2010-07-13 Mitsubishi Rayon Co., Ltd. Vinyl polymer, process for producing vinyl polymer, thermosetting coating composition, and coating material
US7064171B1 (en) * 2005-09-22 2006-06-20 The Goodyear Tire & Rubber Company Non-random styrene-butadiene rubber
BRPI0914173B1 (pt) 2008-06-20 2019-05-14 Bridgestone Corporation Catalisadores para preparação de cis 1,4-polidienos
EP2495266A1 (en) * 2011-03-04 2012-09-05 Styron Deutschland GmbH High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof
KR101469268B1 (ko) 2011-12-28 2014-12-05 제일모직주식회사 공액 디엔으로부터 열가소성 수지를 연속적으로 제조하는 방법 및 그로부터 제조된 열가소성 수지
KR101683332B1 (ko) * 2013-09-06 2016-12-06 주식회사 엘지화학 플러깅이 감소된 부타디엔 고무의 제조방법 및 제조장치
SG11201610196TA (en) * 2014-08-20 2017-03-30 Versalis Spa Process for the preparation of diene polymers or random vinyl arene-diene copolymers
WO2016080766A1 (ko) * 2014-11-20 2016-05-26 주식회사 엘지화학 공액 디엔계 중합체의 제조방법
KR101796360B1 (ko) 2014-11-20 2017-11-09 주식회사 엘지화학 공액 디엔계 중합체의 제조방법
KR101653574B1 (ko) * 2014-12-11 2016-09-08 주식회사 엘지화학 변성 공역디엔계 중합체, 이를 포함하는 변성 고무 조성물 및 변성 공역디엔계 중합체의 제조방법
CN107075039B (zh) 2014-12-24 2019-06-21 株式会社Lg化学 制备二烯类橡胶胶乳的方法和包含该橡胶胶乳的丙烯腈-丁二烯-苯乙烯接枝共聚物
KR101745788B1 (ko) * 2015-01-05 2017-06-09 주식회사 엘지화학 변성 공역디엔계 중합체, 이를 포함하는 변성 고무 조성물 및 변성 공역디엔계 중합체의 제조방법
KR20160150052A (ko) * 2015-06-19 2016-12-28 주식회사 엘지화학 변성 아크릴로니트릴-부타디엔-스티렌계 수지의 제조방법 및 이로부터 제조된 변성 아크릴로니트릴-부타디엔-스티렌계 수지
KR101946482B1 (ko) * 2015-10-22 2019-02-11 주식회사 엘지화학 폴리부타디엔의 제조 장치
KR20170053467A (ko) * 2015-11-06 2017-05-16 주식회사 엘지화학 부타디엔 고무의 연속제조방법 및 이를 이용한 부타디엔 고무의 연속제조장치
KR102068651B1 (ko) 2015-12-23 2020-01-21 주식회사 엘지화학 공액디엔 고무질 중합체의 제조방법
KR101857392B1 (ko) * 2017-01-03 2018-06-19 주식회사 엘지화학 변성 공액디엔계 중합체 제조방법

Also Published As

Publication number Publication date
EP3702378A1 (en) 2020-09-02
JP7015386B2 (ja) 2022-02-02
KR20190046518A (ko) 2019-05-07
US20200123288A1 (en) 2020-04-23
US10982026B2 (en) 2021-04-20
CN110785444A (zh) 2020-02-11
EP3702378B1 (en) 2021-06-23
JP2020536999A (ja) 2020-12-17
WO2019083092A1 (ko) 2019-05-02
EP3702378A4 (en) 2020-09-09
CN110785444B (zh) 2022-09-06

Similar Documents

Publication Publication Date Title
KR102173756B1 (ko) 변성 공액디엔계 중합체의 제조방법
KR102122470B1 (ko) 변성제 및 이로부터 유래된 작용기를 포함하는 변성 공액디엔계 중합체
KR102295653B1 (ko) 공액디엔계 중합체 및 이의 제조방법
KR102109837B1 (ko) 변성 공액디엔계 중합체 및 이의 제조방법
KR102314628B1 (ko) 연속식 중합에 의한 공액디엔계 중합체의 제조방법
KR102193437B1 (ko) 공액디엔 중합용 촉매의 제조방법, 촉매 및 이를 이용한 공액디엔계 중합체의 제조방법
KR102281111B1 (ko) 공액디엔계 중합체의 제조방법
JP7015386B2 (ja) 連続式重合による共役ジエン系重合体の製造方法
KR102123081B1 (ko) 변성 공액디엔계 중합체 및 이의 제조방법
KR102213173B1 (ko) 연속식 중합에 의한 공액디엔계 중합체의 제조방법
KR102921288B1 (ko) 네오디뮴 촉매화 공액디엔계 중합체 및 이를 포함하는 고무 조성물
KR102123079B1 (ko) 변성 공액디엔계 중합체 및 이의 제조방법
KR102384834B1 (ko) 촉매 조성물, 이의 제조방법, 이를 이용한 공액디엔계 중합체의 제조방법 및 상기 중합체의 제조방법으로부터 제조된 공액디엔계 중합체
KR20210052318A (ko) 변성제, 변성 공액디엔계 중합체 및 이의 제조방법
KR102595111B1 (ko) 변성 공액디엔계 중합체, 이의 제조방법 및 이를 포함하는 고무 조성물
KR102923646B1 (ko) 공액디엔계 중합체, 이의 제조방법 및 상기 중합체를 포함하는 고무 조성물
KR102666895B1 (ko) 변성 공액디엔계 중합체의 제조방법
KR102188725B1 (ko) 신규 화합물 및 이의 유래 작용기를 포함하는 변성 공액디엔계 중합체
KR20210033933A (ko) 변성 공액디엔계 중합체의 제조방법
KR102778122B1 (ko) 변성 공액디엔계 중합체, 이의 제조방법 및 이를 포함하는 고무 조성물
KR20220041760A (ko) 네오디뮴 촉매화 공액디엔계 중합체 및 이를 포함하는 고무 조성물
KR102185352B1 (ko) 변성 공액디엔계 중합체 및 이의 제조방법
KR20210036081A (ko) 변성 공액디엔계 중합체의 제조방법
KR102509140B1 (ko) 변성 공액디엔계 중합체, 이의 제조방법 및 이를 포함하는 고무 조성물
KR102757739B1 (ko) 변성 공액디엔계 중합체, 이의 제조방법 및 이를 포함하는 고무 조성물

Legal Events

Date Code Title Description
PA0109 Patent application

St.27 status event code: A-0-1-A10-A12-nap-PA0109

R18-X000 Changes to party contact information recorded

St.27 status event code: A-3-3-R10-R18-oth-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-3-3-R10-R18-oth-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

R18-X000 Changes to party contact information recorded

St.27 status event code: A-3-3-R10-R18-oth-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U11-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-OTH-PR1001 (AS PROVIDED BY THE NATIONAL OFFICE)

Year of fee payment: 7