KR102089479B1 - N-치환된 술폭시민 피리딘 n-옥시드의 제조 - Google Patents

N-치환된 술폭시민 피리딘 n-옥시드의 제조 Download PDF

Info

Publication number
KR102089479B1
KR102089479B1 KR1020147036274A KR20147036274A KR102089479B1 KR 102089479 B1 KR102089479 B1 KR 102089479B1 KR 1020147036274 A KR1020147036274 A KR 1020147036274A KR 20147036274 A KR20147036274 A KR 20147036274A KR 102089479 B1 KR102089479 B1 KR 102089479B1
Authority
KR
South Korea
Prior art keywords
formula
compound
methyl
ethyl
oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020147036274A
Other languages
English (en)
Korean (ko)
Other versions
KR20150032539A (ko
Inventor
더글라스 씨 블랜드
로날드 로쓰
피터 엘 존슨
티모씨 씨 존슨
Original Assignee
다우 아그로사이언시즈 엘엘씨
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 다우 아그로사이언시즈 엘엘씨 filed Critical 다우 아그로사이언시즈 엘엘씨
Publication of KR20150032539A publication Critical patent/KR20150032539A/ko
Application granted granted Critical
Publication of KR102089479B1 publication Critical patent/KR102089479B1/ko
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/89—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members with hetero atoms directly attached to the ring nitrogen atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Pest Control & Pesticides (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Pyridine Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020147036274A 2012-06-30 2013-06-13 N-치환된 술폭시민 피리딘 n-옥시드의 제조 Expired - Fee Related KR102089479B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261666807P 2012-06-30 2012-06-30
US201261666808P 2012-06-30 2012-06-30
US61/666,808 2012-06-30
US61/666,807 2012-06-30
PCT/US2013/045556 WO2014004094A1 (en) 2012-06-30 2013-06-13 Production of n-substituted sulfoximine pyridine n-oxides

Publications (2)

Publication Number Publication Date
KR20150032539A KR20150032539A (ko) 2015-03-26
KR102089479B1 true KR102089479B1 (ko) 2020-03-17

Family

ID=49778790

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020147036274A Expired - Fee Related KR102089479B1 (ko) 2012-06-30 2013-06-13 N-치환된 술폭시민 피리딘 n-옥시드의 제조

Country Status (18)

Country Link
US (1) US9000180B2 (https=)
EP (1) EP2866564B1 (https=)
JP (1) JP6387000B2 (https=)
KR (1) KR102089479B1 (https=)
CN (1) CN104582488A (https=)
AR (1) AR092849A1 (https=)
AU (1) AU2013280925B2 (https=)
BR (1) BR112014033006B8 (https=)
CA (1) CA2876192C (https=)
CO (1) CO7160112A2 (https=)
HK (1) HK1209278A1 (https=)
IL (1) IL236478A0 (https=)
IN (1) IN2014DN11218A (https=)
MX (1) MX352996B (https=)
NZ (1) NZ702523A (https=)
RU (1) RU2628287C2 (https=)
WO (1) WO2014004094A1 (https=)
ZA (1) ZA201408994B (https=)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2013281006B2 (en) * 2012-06-30 2016-09-29 Corteva Agriscience Llc Pyridine N-oxides and processes for their preparation
CN105503672A (zh) * 2015-12-06 2016-04-20 杨秀娟 一种药物中间体芳基砜类化合物的合成方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100282243B1 (ko) * 1992-07-23 2001-02-15 이시하라 겐조 아미드화합물및그의염,이들의제조방법및이들을함유하는살충조성물

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4050921A (en) 1976-04-16 1977-09-27 Uniroyal Inc. Regulation of the natural growth or development of plants with 2-sulfinyl or 2-sulfonyl pyridine N-oxide compounds
US4212870A (en) 1979-06-18 1980-07-15 Gulf Oil Corporation 1-(2,6-Dichlorobenzoyl)-3-(5-chloro-2-pyridinyl-N-oxide)urea and use as insecticide
OA09122A (en) * 1988-07-08 1991-10-31 Schering Agrochemicals Ltd Triazole insecticides.
IL99445A (en) * 1990-09-18 1996-06-18 Ciba Geigy Ag Picoline oxides process for their preparation and insecticidal and acaricidal compositions containing them
JP2001515888A (ja) * 1997-09-08 2001-09-25 ノバルティス アクチエンゲゼルシャフト 農薬としてのヘテロ環式化合物
ID27165A (id) * 1998-04-08 2001-03-08 Novaris Ag Herbisida-herbisida n-piridonil
DE10130397A1 (de) * 2001-06-23 2003-01-09 Bayer Cropscience Gmbh Herbizide substituierte Pyridine, Verfahren zu ihrer Herstellung und ihre Verwendung als Herbzide und Pflanzenwachstumsregulatoren
WO2003027099A1 (en) * 2001-09-21 2003-04-03 E. I. Du Pont De Nemours And Company Arthropodicidal anthranilamides
JP4453320B2 (ja) * 2002-09-30 2010-04-21 萬有製薬株式会社 Ｎ−置換−２−オキソジヒドロピリジン誘導体
JP2004238307A (ja) * 2003-02-04 2004-08-26 Ishihara Sangyo Kaisha Ltd アミド系化合物又はその塩、それらの製造方法及びそれらを含有する有害動物防除剤
JP2005162732A (ja) * 2003-11-13 2005-06-23 Bayer Cropscience Ag 殺虫性ニコチノイルカーバメート類
ES2611018T3 (es) * 2004-04-08 2017-05-04 Dow Agrosciences Llc Sulfoximinas N-sustituidas insecticidas
PL1907382T3 (pl) * 2005-07-26 2016-01-29 Bial Portela & Ca Sa Pochodne nitrokatecholowe jako inhibitory COMT
TW201309635A (zh) 2006-02-10 2013-03-01 Dow Agrosciences Llc 殺蟲性之ｎ-取代（６-鹵烷基吡啶-３-基）烷基磺醯亞胺（二）
TWI383973B (zh) 2006-08-07 2013-02-01 Dow Agrosciences Llc 用於製備２-取代-５-（１-烷硫基）烷基吡啶之方法
CN101501027A (zh) * 2006-08-22 2009-08-05 巴斯夫欧洲公司 噻吩磺酸吡啶甲基酰胺
TWI387585B (zh) 2006-09-01 2013-03-01 Dow Agrosciences Llc 殺蟲性之ｎ-取代（雜芳基）烷基烴基硫亞胺
US7511149B2 (en) 2007-02-09 2009-03-31 Dow Agrosciences Llc Process for the oxidation of certain substituted sulfilimines to insecticidal sulfoximines
US7868027B2 (en) 2007-02-26 2011-01-11 Dow Agrosciences Llc Process for the preparation of certain substituted sulfilimines
US8193222B1 (en) 2007-02-26 2012-06-05 Dow AgroSciences, L.L.C. Process for the preparation of certain substituted sulfilimines
JP2009029787A (ja) * 2007-06-22 2009-02-12 Ishihara Sangyo Kaisha Ltd Ｎ−フェニル−メタナミン誘導体及びこれを含有する有害生物防除剤
US8288589B2 (en) * 2007-07-27 2012-10-16 Dow Agrosciences, Llc Pesticides and uses thereof
EP2268615B1 (en) 2008-03-03 2016-08-17 Dow AgroSciences LLC Pesticides
MX2011000196A (es) 2008-07-01 2011-03-24 Dow Agrosciences Llc Proceso mejorado para la preparacion de alquilpiridinas 2-trifluorometil-5-(1-sustituidas).
WO2010074747A1 (en) * 2008-12-26 2010-07-01 Dow Agrosciences, Llc Stable insecticide compositions and methods for producing same
JP2013500246A (ja) * 2009-07-24 2013-01-07 ビーエーエスエフ ソシエタス・ヨーロピア 無脊椎動物系害虫防除用ピリジン誘導体化合物
EP2468097A1 (en) * 2010-12-21 2012-06-27 Bayer CropScience AG Use of Isothiazolecarboxamides to create latent host defenses in a plant
JP6469569B2 (ja) * 2012-06-30 2019-02-13 ダウ アグロサイエンシィズ エルエルシー 昆虫防除作用をもつｎ−置換スルフィルイミンおよびスルホキシイミンピリジンｎ−オキシド
AU2013281006B2 (en) * 2012-06-30 2016-09-29 Corteva Agriscience Llc Pyridine N-oxides and processes for their preparation

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100282243B1 (ko) * 1992-07-23 2001-02-15 이시하라 겐조 아미드화합물및그의염,이들의제조방법및이들을함유하는살충조성물

Also Published As

Publication number Publication date
NZ702523A (en) 2016-07-29
CA2876192C (en) 2021-01-05
AU2013280925A1 (en) 2014-12-18
KR20150032539A (ko) 2015-03-26
MX352996B (es) 2017-12-15
BR112014033006B1 (pt) 2020-03-03
ZA201408994B (en) 2016-08-31
WO2014004094A1 (en) 2014-01-03
MX2014015696A (es) 2015-08-06
JP6387000B2 (ja) 2018-09-05
CO7160112A2 (es) 2015-01-15
CA2876192A1 (en) 2014-01-03
US9000180B2 (en) 2015-04-07
RU2628287C2 (ru) 2017-08-15
BR112014033006B8 (pt) 2022-10-11
CN104582488A (zh) 2015-04-29
JP2015522588A (ja) 2015-08-06
BR112014033006A2 (pt) 2017-06-27
EP2866564B1 (en) 2020-02-12
US20140005406A1 (en) 2014-01-02
IN2014DN11218A (https=) 2015-10-02
RU2015102949A (ru) 2016-08-20
IL236478A0 (en) 2015-02-26
HK1209278A1 (en) 2016-04-01
EP2866564A4 (en) 2016-02-24
AR092849A1 (es) 2015-05-06
AU2013280925B2 (en) 2016-09-29
EP2866564A1 (en) 2015-05-06

Similar Documents

Publication Publication Date Title
JP6254646B2 (ja) テトラゾール置換されたアントラニルアミド誘導体およびこれら誘導体の新規な結晶多形体の製造方法
CN102702082A (zh) 2-取代的-5-((1-烷硫基)烷基)吡啶的制备方法
KR102089479B1 (ko) N-치환된 술폭시민 피리딘 n-옥시드의 제조
JPH04128275A (ja) Ｎ―ベンジルアミド類およびこれを有効成分とする殺虫、殺ダニ剤
JP6372560B2 (ja) ピラゾール化合物の製造方法
JP2020172439A (ja) 縮合複素環化合物の製造方法
DE69408950T2 (de) N-Pyrazolylcarbamatderivate und Fungizide für Landwirtschaft und Gartenbau, die diese als aktive Bestandteile erhalten, Produktion und Zwischenprodukte
JP2003192675A (ja) 殺センチュウ性トリフルオロブテニルイミダゾールチオエーテル誘導体
JPS62174087A (ja) 選択性除草化合物
RU2628339C2 (ru) Пиридин-n-оксиды и способы их получения
CN102952080B (zh) 一种含有苯联杂环的醚类化合物及其用途
CN102442968B (zh) 一种丁烯醚类化合物及其应用
CN102442969B (zh) 一种丁炔醚类化合物及其应用
CN104193656B (zh) 一种β-二羰基砜类化合物及其制备方法
JPS6248681A (ja) ニトロメチレン誘導体の製造方法
JPH11349557A (ja) ジフルオロアルケン誘導体、その製法及び農園芸用の有害生物防除剤
JPH03251582A (ja) イミダゾ［１，２―ａ］ピリジル化合物
CN111303062A (zh) 一种苯甲酰胺类化合物及其作为除草剂的用途
JPH0426682A (ja) アルキルアミノピリミジン誘導体、その製造法及び殺虫・殺ダニ・殺線虫剤
CN108003133A (zh) 一种2-羟基-6-氟硫色酮类化合物及其合成方法和在除草中的应用
HK1174028A (en) Process for the preparation of 2-substituted-5-(1-alkylthio)alkylpyridines

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

D13-X000 Search requested

St.27 status event code: A-1-2-D10-D13-srh-X000

D14-X000 Search report completed

St.27 status event code: A-1-2-D10-D14-srh-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PN2301 Change of applicant

St.27 status event code: A-5-5-R10-R13-asn-PN2301

St.27 status event code: A-5-5-R10-R11-asn-PN2301

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20250311

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

H13 Ip right lapsed

Free format text: ST27 STATUS EVENT CODE: N-4-6-H10-H13-OTH-PC1903 (AS PROVIDED BY THE NATIONAL OFFICE); TERMINATION CATEGORY : DEFAULT_OF_REGISTRATION_FEE

Effective date: 20250311

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20250311