KR101930736B1 - 높은 유속 및 순환율로 제조된 폴리아이소부틸렌 - Google Patents

높은 유속 및 순환율로 제조된 폴리아이소부틸렌 Download PDF

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KR101930736B1
KR101930736B1 KR1020147011073A KR20147011073A KR101930736B1 KR 101930736 B1 KR101930736 B1 KR 101930736B1 KR 1020147011073 A KR1020147011073 A KR 1020147011073A KR 20147011073 A KR20147011073 A KR 20147011073A KR 101930736 B1 KR101930736 B1 KR 101930736B1
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loop reactor
polymer
polyisobutylene
reaction
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KR20140086983A (ko
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소헬 케이 샤이크
알프레드 추
패트릭 엘 브래들리
길버트 디 발데즈
페기 제이 마카탄가이
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티피씨 그룹 엘엘씨
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1812—Tubular reactors
    • B01J19/1837—Loop-type reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1868—Stationary reactors having moving elements inside resulting in a loop-type movement
    • B01J19/1881—Stationary reactors having moving elements inside resulting in a loop-type movement externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00054—Controlling or regulating the heat exchange system
    • B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2219/00065—Pressure measurement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00081—Tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00191—Control algorithm
    • B01J2219/00211—Control algorithm comparing a sensed parameter with a pre-set value
    • B01J2219/0022—Control algorithm comparing a sensed parameter with a pre-set value calculating difference
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00191—Control algorithm
    • B01J2219/00222—Control algorithm taking actions
    • B01J2219/00227—Control algorithm taking actions modifying the operating conditions
    • B01J2219/00229—Control algorithm taking actions modifying the operating conditions of the reaction system
    • B01J2219/00231—Control algorithm taking actions modifying the operating conditions of the reaction system at the reactor inlet

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
KR1020147011073A 2011-10-26 2012-10-10 높은 유속 및 순환율로 제조된 폴리아이소부틸렌 Active KR101930736B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161551526P 2011-10-26 2011-10-26
US61/551,526 2011-10-26
PCT/US2012/059464 WO2013062758A1 (en) 2011-10-26 2012-10-10 Polyisobutylene prepared at high velocity and circulation rate

Publications (2)

Publication Number Publication Date
KR20140086983A KR20140086983A (ko) 2014-07-08
KR101930736B1 true KR101930736B1 (ko) 2018-12-19

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KR1020147011073A Active KR101930736B1 (ko) 2011-10-26 2012-10-10 높은 유속 및 순환율로 제조된 폴리아이소부틸렌

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US (2) US8946361B2 (enExample)
EP (1) EP2771369B1 (enExample)
JP (1) JP6126612B2 (enExample)
KR (1) KR101930736B1 (enExample)
CN (1) CN104024280B (enExample)
AR (1) AR088527A1 (enExample)
BR (1) BR112014009478B1 (enExample)
CA (1) CA2853063A1 (enExample)
MX (1) MX338900B (enExample)
MY (1) MY185146A (enExample)
SG (1) SG11201401508QA (enExample)
WO (1) WO2013062758A1 (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104024280B (zh) * 2011-10-26 2016-01-20 Tpc集团有限责任公司 以高速度和高循环速率制备的聚异丁烯
KR101523568B1 (ko) * 2013-05-16 2015-05-28 대림산업 주식회사 반응성 폴리부텐 및 비반응성 폴리부텐의 선택적 제조장치 및 방법
KR102143673B1 (ko) 2013-07-09 2020-08-11 다우 글로벌 테크놀로지스 엘엘씨 개선된 펠렛 유동능을 갖는 에틸렌/알파-올레핀 인터폴리머
CN104193858B (zh) * 2014-08-22 2016-06-15 山东鸿瑞新材料科技有限公司 连续聚合生产聚异丁烯的方法和自动控制系统
CN104945545A (zh) * 2015-06-30 2015-09-30 清华大学 一种高反应活性聚异丁烯的制备方法
WO2017151339A1 (en) 2016-03-03 2017-09-08 Tpc Group Llc Low-fluoride, reactive polyisobutylene
PT3440119T (pt) 2016-04-08 2021-09-30 Ineos Europe Ag Unidade de polimerização e processo de polimerização
CN107522808B (zh) * 2016-06-21 2020-09-15 中国石油化工股份有限公司 一种乙烯-辛烯共聚物的制备方法
PL3481547T3 (pl) * 2016-07-06 2023-09-11 Ineos Europe Ag Proces polimeryzacji
US12187819B1 (en) 2023-11-15 2025-01-07 Tpc Group, Llc Compound, its preparation and use

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US20100298507A1 (en) 2009-05-19 2010-11-25 Menschig Klaus R Polyisobutylene Production Process With Improved Efficiencies And/Or For Forming Products Having Improved Characteristics And Polyisobutylene Products Produced Thereby

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CN104066752B (zh) * 2011-10-26 2016-08-24 Tpc集团有限责任公司 用低稀释剂含量的反应介质制备的聚异丁烯
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US20030096924A1 (en) 1999-09-16 2003-05-22 Texas Petrochemicals Lp Process for producing high vinylidene polyisobutylene
US20100298507A1 (en) 2009-05-19 2010-11-25 Menschig Klaus R Polyisobutylene Production Process With Improved Efficiencies And/Or For Forming Products Having Improved Characteristics And Polyisobutylene Products Produced Thereby

Also Published As

Publication number Publication date
MY185146A (en) 2021-04-30
CN104024280A (zh) 2014-09-03
US8946361B2 (en) 2015-02-03
EP2771369A4 (en) 2015-06-03
SG11201401508QA (en) 2014-05-29
MX2014005059A (es) 2014-08-22
EP2771369A1 (en) 2014-09-03
US20140235801A1 (en) 2014-08-21
CA2853063A1 (en) 2013-05-02
US9266980B2 (en) 2016-02-23
JP6126612B2 (ja) 2017-05-10
AR088527A1 (es) 2014-06-18
EP2771369B1 (en) 2017-02-15
BR112014009478A2 (pt) 2017-05-09
WO2013062758A1 (en) 2013-05-02
CN104024280B (zh) 2016-01-20
MX338900B (es) 2016-05-03
KR20140086983A (ko) 2014-07-08
US20150197584A1 (en) 2015-07-16
BR112014009478B1 (pt) 2021-09-21
JP2014532774A (ja) 2014-12-08

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