JP6126612B2 - 高い速度と循環量で調製されたポリイソブチレン - Google Patents

高い速度と循環量で調製されたポリイソブチレン Download PDF

Info

Publication number
JP6126612B2
JP6126612B2 JP2014538818A JP2014538818A JP6126612B2 JP 6126612 B2 JP6126612 B2 JP 6126612B2 JP 2014538818 A JP2014538818 A JP 2014538818A JP 2014538818 A JP2014538818 A JP 2014538818A JP 6126612 B2 JP6126612 B2 JP 6126612B2
Authority
JP
Japan
Prior art keywords
loop reactor
reaction
polyisobutylene
reaction mixture
tubes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2014538818A
Other languages
English (en)
Japanese (ja)
Other versions
JP2014532774A5 (enExample
JP2014532774A (ja
Inventor
シェイク,ソヘル・ケイ
チウ,アルフレッド
ブラッドリー,パトリック・エル
バルデス,ギルバート・ディー
マカタンゲイ,ペギー・ジェイ
Original Assignee
ティーピーシー・グループ・エルエルシー
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ティーピーシー・グループ・エルエルシー filed Critical ティーピーシー・グループ・エルエルシー
Publication of JP2014532774A publication Critical patent/JP2014532774A/ja
Publication of JP2014532774A5 publication Critical patent/JP2014532774A5/ja
Application granted granted Critical
Publication of JP6126612B2 publication Critical patent/JP6126612B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/08Butenes
    • C08F10/10Isobutene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • B01J19/1812Tubular reactors
    • B01J19/1837Loop-type reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • B01J19/1868Stationary reactors having moving elements inside resulting in a loop-type movement
    • B01J19/1881Stationary reactors having moving elements inside resulting in a loop-type movement externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/08Butenes
    • C08F110/10Isobutene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/01Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00054Controlling or regulating the heat exchange system
    • B01J2219/00056Controlling or regulating the heat exchange system involving measured parameters
    • B01J2219/00065Pressure measurement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00074Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00081Tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00074Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094Jackets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00162Controlling or regulating processes controlling the pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00191Control algorithm
    • B01J2219/00211Control algorithm comparing a sensed parameter with a pre-set value
    • B01J2219/0022Control algorithm comparing a sensed parameter with a pre-set value calculating difference
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00191Control algorithm
    • B01J2219/00222Control algorithm taking actions
    • B01J2219/00227Control algorithm taking actions modifying the operating conditions
    • B01J2219/00229Control algorithm taking actions modifying the operating conditions of the reaction system
    • B01J2219/00231Control algorithm taking actions modifying the operating conditions of the reaction system at the reactor inlet

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
JP2014538818A 2011-10-26 2012-10-10 高い速度と循環量で調製されたポリイソブチレン Active JP6126612B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161551526P 2011-10-26 2011-10-26
US61/551,526 2011-10-26
PCT/US2012/059464 WO2013062758A1 (en) 2011-10-26 2012-10-10 Polyisobutylene prepared at high velocity and circulation rate

Publications (3)

Publication Number Publication Date
JP2014532774A JP2014532774A (ja) 2014-12-08
JP2014532774A5 JP2014532774A5 (enExample) 2015-11-26
JP6126612B2 true JP6126612B2 (ja) 2017-05-10

Family

ID=48168317

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2014538818A Active JP6126612B2 (ja) 2011-10-26 2012-10-10 高い速度と循環量で調製されたポリイソブチレン

Country Status (12)

Country Link
US (2) US8946361B2 (enExample)
EP (1) EP2771369B1 (enExample)
JP (1) JP6126612B2 (enExample)
KR (1) KR101930736B1 (enExample)
CN (1) CN104024280B (enExample)
AR (1) AR088527A1 (enExample)
BR (1) BR112014009478B1 (enExample)
CA (1) CA2853063A1 (enExample)
MX (1) MX338900B (enExample)
MY (1) MY185146A (enExample)
SG (1) SG11201401508QA (enExample)
WO (1) WO2013062758A1 (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104024280B (zh) * 2011-10-26 2016-01-20 Tpc集团有限责任公司 以高速度和高循环速率制备的聚异丁烯
KR101523568B1 (ko) * 2013-05-16 2015-05-28 대림산업 주식회사 반응성 폴리부텐 및 비반응성 폴리부텐의 선택적 제조장치 및 방법
KR102143673B1 (ko) 2013-07-09 2020-08-11 다우 글로벌 테크놀로지스 엘엘씨 개선된 펠렛 유동능을 갖는 에틸렌/알파-올레핀 인터폴리머
CN104193858B (zh) * 2014-08-22 2016-06-15 山东鸿瑞新材料科技有限公司 连续聚合生产聚异丁烯的方法和自动控制系统
CN104945545A (zh) * 2015-06-30 2015-09-30 清华大学 一种高反应活性聚异丁烯的制备方法
WO2017151339A1 (en) 2016-03-03 2017-09-08 Tpc Group Llc Low-fluoride, reactive polyisobutylene
PT3440119T (pt) 2016-04-08 2021-09-30 Ineos Europe Ag Unidade de polimerização e processo de polimerização
CN107522808B (zh) * 2016-06-21 2020-09-15 中国石油化工股份有限公司 一种乙烯-辛烯共聚物的制备方法
PL3481547T3 (pl) * 2016-07-06 2023-09-11 Ineos Europe Ag Proces polimeryzacji
US12187819B1 (en) 2023-11-15 2025-01-07 Tpc Group, Llc Compound, its preparation and use

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3932371A (en) 1966-05-17 1976-01-13 Exxon Research And Engineering Company Process for preparing low bulk viscosity polymers
DE2702604C2 (de) 1977-01-22 1984-08-30 Basf Ag, 6700 Ludwigshafen Polyisobutene
GB8329082D0 (en) 1983-11-01 1983-12-07 Bp Chem Int Ltd Low molecular weight polymers of 1-olefins
US5068490A (en) 1989-08-18 1991-11-26 Amoco Corporation BF3-tertiary etherate complexes for isobutylene polymerization
DE4033196C1 (enExample) 1990-10-19 1992-04-16 Basf Ag, 6700 Ludwigshafen, De
US5286823A (en) 1991-06-22 1994-02-15 Basf Aktiengesellschaft Preparation of highly reactive polyisobutenes
DE19520078A1 (de) 1995-06-07 1996-12-12 Basf Ag Verfahren zur Herstellung von niedermolekularem, hochreaktivem Polyisobuten
US7033545B2 (en) * 1997-07-15 2006-04-25 Chevon Phillips Chemical Company, Lp Slurry polymerization reactor having large length/diameter ratio
WO2001019873A1 (en) 1999-09-16 2001-03-22 Texas Petrochemicals Lp Process for preparing polyolefin products
US6562913B1 (en) * 1999-09-16 2003-05-13 Texas Petrochemicals Lp Process for producing high vinylidene polyisobutylene
US6884858B2 (en) 1999-10-19 2005-04-26 Texas Petrochemicals Lp Process for preparing polyolefin products
DE19948947A1 (de) * 1999-10-11 2001-04-12 Basf Ag Verfahren zur kontinuierlichen Herstellung von Polyisobutenen
US7037999B2 (en) 2001-03-28 2006-05-02 Texas Petrochemicals Lp Mid-range vinylidene content polyisobutylene polymer product and process for producing the same
US6992152B2 (en) 1999-10-19 2006-01-31 Texas Petrochemicals Lp Apparatus and method for controlling olefin polymerization process
US6858188B2 (en) 2003-05-09 2005-02-22 Texas Petrochemicals, Lp Apparatus for preparing polyolefin products and methodology for using the same
DE19952031A1 (de) * 1999-10-28 2001-05-03 Basf Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
US6858690B2 (en) 1999-11-15 2005-02-22 Exxonmobil Chemical Patents Inc. Process for polymerizing cationically polymerizable monomers
DE10033412B4 (de) 2000-07-08 2012-05-24 Khs Corpoplast Gmbh Vorrichtung zur Blasformung von Behältern
DE10040618A1 (de) * 2000-08-16 2002-02-28 Basf Ag Verfahren zur Herstellung von Polyisobutenen
DE10118182A1 (de) 2001-04-11 2002-10-17 Basf Ag Verfahren zur Aufarbeitung eines flüssigen Reaktionsaustrages der kationischen Polymerisation von Isobuten
DE10243576A1 (de) 2002-09-19 2004-04-01 Basf Ag Verfahren zur Herstellung von Polyisobuten
DE10303212A1 (de) 2003-01-24 2004-08-05 Basf Ag Verfahren zur Herstellung von Polyisobuten
US7402636B1 (en) * 2007-03-23 2008-07-22 Exxonmobil Chemical Patents Inc Method and apparatus for decreasing polymer deposition
US20100298507A1 (en) 2009-05-19 2010-11-25 Menschig Klaus R Polyisobutylene Production Process With Improved Efficiencies And/Or For Forming Products Having Improved Characteristics And Polyisobutylene Products Produced Thereby
US9079990B2 (en) * 2010-06-01 2015-07-14 Exxonmobil Chemical Patents Inc. Methods of production of alkylstyrene/isoolefin polymers
SG11201401504SA (en) * 2011-10-26 2014-05-29 Tpc Group Llc Mid-range vinylidene content, high viscosity polyisobutylene polymers
CN104024280B (zh) * 2011-10-26 2016-01-20 Tpc集团有限责任公司 以高速度和高循环速率制备的聚异丁烯
CN104066752B (zh) * 2011-10-26 2016-08-24 Tpc集团有限责任公司 用低稀释剂含量的反应介质制备的聚异丁烯
CN102872786A (zh) * 2012-09-11 2013-01-16 宁波锦莱化工有限公司 一种扁形氯化反应装置

Also Published As

Publication number Publication date
MY185146A (en) 2021-04-30
CN104024280A (zh) 2014-09-03
US8946361B2 (en) 2015-02-03
EP2771369A4 (en) 2015-06-03
SG11201401508QA (en) 2014-05-29
MX2014005059A (es) 2014-08-22
EP2771369A1 (en) 2014-09-03
US20140235801A1 (en) 2014-08-21
KR101930736B1 (ko) 2018-12-19
CA2853063A1 (en) 2013-05-02
US9266980B2 (en) 2016-02-23
AR088527A1 (es) 2014-06-18
EP2771369B1 (en) 2017-02-15
BR112014009478A2 (pt) 2017-05-09
WO2013062758A1 (en) 2013-05-02
CN104024280B (zh) 2016-01-20
MX338900B (es) 2016-05-03
KR20140086983A (ko) 2014-07-08
US20150197584A1 (en) 2015-07-16
BR112014009478B1 (pt) 2021-09-21
JP2014532774A (ja) 2014-12-08

Similar Documents

Publication Publication Date Title
JP6126612B2 (ja) 高い速度と循環量で調製されたポリイソブチレン
CA2438068C (en) Mid-range vinylidene content polyisobutylene and production thereof
JP4156837B2 (ja) ポリオレフィン製品の製造方法
CN104066752B (zh) 用低稀释剂含量的反应介质制备的聚异丁烯
AU2013277339A1 (en) Polyisobutylene composition having internal vinylidene and process for preparing the polyisobutylene polymer composition
KR101930735B1 (ko) 중간 범위 비닐리덴 함량, 고 점성 폴리아이소부틸렌 중합체
JP5844864B2 (ja) ポリイソブチレンの液相重合方法
JP2006316159A (ja) ポリオレフィン製造用重合装置及びそれを用いたポリオレフィンの製造方法

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20151007

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20151007

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20160721

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20160725

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20161025

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20170309

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20170407

R150 Certificate of patent or registration of utility model

Ref document number: 6126612

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250