MX2014005059A - Poliisobutileno preparado a alta velocidad y tasa de circulacion. - Google Patents

Poliisobutileno preparado a alta velocidad y tasa de circulacion.

Info

Publication number
MX2014005059A
MX2014005059A MX2014005059A MX2014005059A MX2014005059A MX 2014005059 A MX2014005059 A MX 2014005059A MX 2014005059 A MX2014005059 A MX 2014005059A MX 2014005059 A MX2014005059 A MX 2014005059A MX 2014005059 A MX2014005059 A MX 2014005059A
Authority
MX
Mexico
Prior art keywords
high velocity
circulation rate
psi
delta
tubes
Prior art date
Application number
MX2014005059A
Other languages
English (en)
Other versions
MX338900B (es
Inventor
Sohel K Shaikh
Alfred Chiu
Patrick L Bradley
Gilbert D Valdez
Peggy J Macatangay
Original Assignee
Tpc Group Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tpc Group Llc filed Critical Tpc Group Llc
Publication of MX2014005059A publication Critical patent/MX2014005059A/es
Publication of MX338900B publication Critical patent/MX338900B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1812—Tubular reactors
    • B01J19/1837—Loop-type reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1868—Stationary reactors having moving elements inside resulting in a loop-type movement
    • B01J19/1881—Stationary reactors having moving elements inside resulting in a loop-type movement externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00054—Controlling or regulating the heat exchange system
    • B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2219/00065—Pressure measurement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00081—Tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00191—Control algorithm
    • B01J2219/00211—Control algorithm comparing a sensed parameter with a pre-set value
    • B01J2219/0022—Control algorithm comparing a sensed parameter with a pre-set value calculating difference
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00191—Control algorithm
    • B01J2219/00222—Control algorithm taking actions
    • B01J2219/00227—Control algorithm taking actions modifying the operating conditions
    • B01J2219/00229—Control algorithm taking actions modifying the operating conditions of the reaction system
    • B01J2219/00231—Control algorithm taking actions modifying the operating conditions of the reaction system at the reactor inlet

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Un método para hacer un polímero de poliisobutileno en un reactor de bucle de recirculación con uno o más tubos de reacción en contacto con un medio de transferencia de calor incluye controlar la P delta y la reacción de polimerización para proporcionar una velocidad lineal de la mezcla de reacción de al menos 3.35 metros/seg en los uno o más tubos del reactor de bucle y/o controlar la P delta y la reacción de polimerización de los pasos (b) y (c) para proporcionar una relación de recirculación de la tasa de recirculación a la tasa de alimentación de al menos 30:1; normalmente, el procedimiento utiliza una bomba de recirculación operando a un diferencial de presión de 2.46 Kg/cm2 a 4.92 Kg/cm2.
MX2014005059A 2011-10-26 2012-10-10 Poliisobutileno preparado a alta velocidad y tasa de circulacion. MX338900B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161551526P 2011-10-26 2011-10-26
PCT/US2012/059464 WO2013062758A1 (en) 2011-10-26 2012-10-10 Polyisobutylene prepared at high velocity and circulation rate

Publications (2)

Publication Number Publication Date
MX2014005059A true MX2014005059A (es) 2014-08-22
MX338900B MX338900B (es) 2016-05-03

Family

ID=48168317

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014005059A MX338900B (es) 2011-10-26 2012-10-10 Poliisobutileno preparado a alta velocidad y tasa de circulacion.

Country Status (12)

Country Link
US (2) US8946361B2 (es)
EP (1) EP2771369B1 (es)
JP (1) JP6126612B2 (es)
KR (1) KR101930736B1 (es)
CN (1) CN104024280B (es)
AR (1) AR088527A1 (es)
BR (1) BR112014009478B1 (es)
CA (1) CA2853063A1 (es)
MX (1) MX338900B (es)
MY (1) MY185146A (es)
SG (1) SG11201401508QA (es)
WO (1) WO2013062758A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2771369B1 (en) * 2011-10-26 2017-02-15 TPC Group LLC Method for preparation of polyisobutylene at high velocity and circulation rate
KR101523568B1 (ko) * 2013-05-16 2015-05-28 대림산업 주식회사 반응성 폴리부텐 및 비반응성 폴리부텐의 선택적 제조장치 및 방법
KR20200096701A (ko) 2013-07-09 2020-08-12 다우 글로벌 테크놀로지스 엘엘씨 개선된 펠렛 유동능을 갖는 에틸렌/알파-올레핀 인터폴리머
CN104193858B (zh) * 2014-08-22 2016-06-15 山东鸿瑞新材料科技有限公司 连续聚合生产聚异丁烯的方法和自动控制系统
CN104945545A (zh) * 2015-06-30 2015-09-30 清华大学 一种高反应活性聚异丁烯的制备方法
WO2017151341A1 (en) 2016-03-03 2017-09-08 Tpc Group Llc Low-fluoride, reactive polyisobutylene
KR102287128B1 (ko) * 2016-04-08 2021-08-09 이네오스 유럽 아게 중합 장치 및 중합 방법
CN107522808B (zh) * 2016-06-21 2020-09-15 中国石油化工股份有限公司 一种乙烯-辛烯共聚物的制备方法
CA3029774A1 (en) 2016-07-06 2018-01-11 Erick Dominique Daire Polymerisation process
US12187819B1 (en) 2023-11-15 2025-01-07 Tpc Group, Llc Compound, its preparation and use

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3932371A (en) 1966-05-17 1976-01-13 Exxon Research And Engineering Company Process for preparing low bulk viscosity polymers
DE2702604C2 (de) 1977-01-22 1984-08-30 Basf Ag, 6700 Ludwigshafen Polyisobutene
GB8329082D0 (en) 1983-11-01 1983-12-07 Bp Chem Int Ltd Low molecular weight polymers of 1-olefins
US5068490A (en) 1989-08-18 1991-11-26 Amoco Corporation BF3-tertiary etherate complexes for isobutylene polymerization
DE4033196C1 (es) 1990-10-19 1992-04-16 Basf Ag, 6700 Ludwigshafen, De
US5286823A (en) 1991-06-22 1994-02-15 Basf Aktiengesellschaft Preparation of highly reactive polyisobutenes
DE19520078A1 (de) 1995-06-07 1996-12-12 Basf Ag Verfahren zur Herstellung von niedermolekularem, hochreaktivem Polyisobuten
US7033545B2 (en) * 1997-07-15 2006-04-25 Chevon Phillips Chemical Company, Lp Slurry polymerization reactor having large length/diameter ratio
US6884858B2 (en) 1999-10-19 2005-04-26 Texas Petrochemicals Lp Process for preparing polyolefin products
ATE507247T1 (de) 1999-09-16 2011-05-15 Tpc Group Llc Verfahren zur herstellung von polyolefinprodukten
US6562913B1 (en) 1999-09-16 2003-05-13 Texas Petrochemicals Lp Process for producing high vinylidene polyisobutylene
DE19948947A1 (de) * 1999-10-11 2001-04-12 Basf Ag Verfahren zur kontinuierlichen Herstellung von Polyisobutenen
US6992152B2 (en) 1999-10-19 2006-01-31 Texas Petrochemicals Lp Apparatus and method for controlling olefin polymerization process
US6858188B2 (en) * 2003-05-09 2005-02-22 Texas Petrochemicals, Lp Apparatus for preparing polyolefin products and methodology for using the same
US7037999B2 (en) 2001-03-28 2006-05-02 Texas Petrochemicals Lp Mid-range vinylidene content polyisobutylene polymer product and process for producing the same
DE19952031A1 (de) * 1999-10-28 2001-05-03 Basf Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
US6858690B2 (en) 1999-11-15 2005-02-22 Exxonmobil Chemical Patents Inc. Process for polymerizing cationically polymerizable monomers
DE10033412B4 (de) 2000-07-08 2012-05-24 Khs Corpoplast Gmbh Vorrichtung zur Blasformung von Behältern
DE10040618A1 (de) * 2000-08-16 2002-02-28 Basf Ag Verfahren zur Herstellung von Polyisobutenen
DE10118182A1 (de) 2001-04-11 2002-10-17 Basf Ag Verfahren zur Aufarbeitung eines flüssigen Reaktionsaustrages der kationischen Polymerisation von Isobuten
DE10243576A1 (de) 2002-09-19 2004-04-01 Basf Ag Verfahren zur Herstellung von Polyisobuten
DE10303212A1 (de) 2003-01-24 2004-08-05 Basf Ag Verfahren zur Herstellung von Polyisobuten
US7402636B1 (en) * 2007-03-23 2008-07-22 Exxonmobil Chemical Patents Inc Method and apparatus for decreasing polymer deposition
US20100298507A1 (en) * 2009-05-19 2010-11-25 Menschig Klaus R Polyisobutylene Production Process With Improved Efficiencies And/Or For Forming Products Having Improved Characteristics And Polyisobutylene Products Produced Thereby
US9079990B2 (en) * 2010-06-01 2015-07-14 Exxonmobil Chemical Patents Inc. Methods of production of alkylstyrene/isoolefin polymers
EP2771369B1 (en) * 2011-10-26 2017-02-15 TPC Group LLC Method for preparation of polyisobutylene at high velocity and circulation rate
KR101929082B1 (ko) * 2011-10-26 2018-12-13 티피씨 그룹 엘엘씨 낮은 희석제 함량 반응 매질로 제조된 폴리아이소부틸렌
EP2771375B1 (en) * 2011-10-26 2021-03-10 TPC Group LLC Mid-range vinylidene content, high viscosity polyisobutylene polymers
CN102872786A (zh) * 2012-09-11 2013-01-16 宁波锦莱化工有限公司 一种扁形氯化反应装置

Also Published As

Publication number Publication date
EP2771369A1 (en) 2014-09-03
EP2771369B1 (en) 2017-02-15
SG11201401508QA (en) 2014-05-29
BR112014009478B1 (pt) 2021-09-21
JP2014532774A (ja) 2014-12-08
CA2853063A1 (en) 2013-05-02
CN104024280A (zh) 2014-09-03
BR112014009478A2 (pt) 2017-05-09
US20150197584A1 (en) 2015-07-16
CN104024280B (zh) 2016-01-20
MX338900B (es) 2016-05-03
KR20140086983A (ko) 2014-07-08
AR088527A1 (es) 2014-06-18
JP6126612B2 (ja) 2017-05-10
WO2013062758A1 (en) 2013-05-02
KR101930736B1 (ko) 2018-12-19
US20140235801A1 (en) 2014-08-21
US9266980B2 (en) 2016-02-23
MY185146A (en) 2021-04-30
US8946361B2 (en) 2015-02-03
EP2771369A4 (en) 2015-06-03

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