KR101890606B1 - 하이드로실릴화 촉매로 사용되는 금속착물의 현장 활성화 - Google Patents

하이드로실릴화 촉매로 사용되는 금속착물의 현장 활성화 Download PDF

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KR101890606B1
KR101890606B1 KR1020137016385A KR20137016385A KR101890606B1 KR 101890606 B1 KR101890606 B1 KR 101890606B1 KR 1020137016385 A KR1020137016385 A KR 1020137016385A KR 20137016385 A KR20137016385 A KR 20137016385A KR 101890606 B1 KR101890606 B1 KR 101890606B1
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group
formula
unsaturated
hydrosilylation
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KR20140032959A (ko
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폴 제이 치릭
아론 엠 톤드로
요하네스 쥐피 델리스
켄릭 엠 루이스
키이스 제이 웰러
수잔 에이 나이
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모멘티브 퍼포먼스 머티리얼즈 인크.
코넬 유니버시티
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C07F7/0838—Compounds with one or more Si-O-Si sequences
    • C07F7/0872—Preparation and treatment thereof
    • C07F7/0876—Reactions involving the formation of bonds to a Si atom of a Si-O-Si sequence other than a bond of the Si-O-Si linkage
    • C07F7/0878—Si-C bond
    • C07F7/0879—Hydrosilylation reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C07F7/0838—Compounds with one or more Si-O-Si sequences
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020137016385A 2010-11-24 2011-11-22 하이드로실릴화 촉매로 사용되는 금속착물의 현장 활성화 Active KR101890606B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US41708410P 2010-11-24 2010-11-24
US41706110P 2010-11-24 2010-11-24
US61/417,084 2010-11-24
US61/417,061 2010-11-24
PCT/US2011/061746 WO2012071358A2 (en) 2010-11-24 2011-11-22 In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts

Publications (2)

Publication Number Publication Date
KR20140032959A KR20140032959A (ko) 2014-03-17
KR101890606B1 true KR101890606B1 (ko) 2018-09-28

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Country Status (8)

Country Link
US (1) US8765987B2 (https=)
EP (1) EP2643329B1 (https=)
JP (1) JP5991981B2 (https=)
KR (1) KR101890606B1 (https=)
CN (1) CN103339135B (https=)
BR (1) BR112013012733A2 (https=)
TW (1) TWI473654B (https=)
WO (1) WO2012071358A2 (https=)

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KR101896423B1 (ko) * 2010-11-24 2018-10-04 모멘티브 퍼포먼스 머티리얼즈 인크. 폴리불포화 화합물의 금속-촉매 모노-하이드로실릴화
CN103347889A (zh) * 2010-11-24 2013-10-09 莫门蒂夫性能材料股份有限公司 氢化硅烷化催化剂
EP2758417A2 (en) * 2011-09-20 2014-07-30 Dow Corning Corporation Cobalt containing hydrosilylation catalysts and compositions containing the catalysts
US20140228570A1 (en) * 2011-09-20 2014-08-14 Dow Corning Corporation Hydrosilylation Catalysts Made With Terdentate Nitrogen Ligands And Compositions Containing The Catalysts
CN103814040B (zh) * 2011-09-20 2016-08-31 道康宁公司 含镍硅氢加成催化剂及含有该催化剂的组合物
JP2014532045A (ja) * 2011-09-20 2014-12-04 ダウ コーニング コーポレーションＤｏｗ Ｃｏｒｎｉｎｇ Ｃｏｒｐｏｒａｔｉｏｎ 鉄含有ヒドロシリル化触媒及びこの触媒を含有する組成物
WO2013081794A1 (en) 2011-12-01 2013-06-06 Dow Corning Corporation Hydrosilylation reaction catalysts and curable compositions and methods for their preparation and use
US9782763B2 (en) 2011-12-14 2017-10-10 Momentive Performance Materials Inc. Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity
JP6125222B2 (ja) * 2012-08-16 2017-05-10 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド コバルト触媒を用いる脱水素シリル化および架橋
BR102013016146A2 (pt) * 2012-08-16 2016-09-13 Momentive Performance Mat Inc processo para produzir um produto sililado, por desidrogenação, composição, composto e processo para produzir um material reticulado
US9447125B2 (en) 2012-08-16 2016-09-20 Momentive Performance Materials Inc. Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation
US9371340B2 (en) 2012-08-16 2016-06-21 Momentive Performance Materials Inc. Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts
US20140121427A1 (en) * 2012-10-29 2014-05-01 The Regents Of The University Of California Methods of Activating Metal Complexes for Catalysts
US9890182B2 (en) 2013-05-06 2018-02-13 Momentive Performance Materials Inc. Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts
US9371339B2 (en) 2013-05-06 2016-06-21 Momentive Performance Materials Inc. Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation
CN105228744B (zh) * 2013-05-15 2021-04-06 莫门蒂夫性能材料股份有限公司 用甲硅烷基氢化物活化金属盐及其在氢化硅烷化反应中的应用
US9708355B2 (en) 2013-06-12 2017-07-18 Arizona Board Of Regents On Behalf Of Arizona State University First-row transition metal hydrogenation and hydrosilylation catalysts
US9387468B2 (en) 2013-11-19 2016-07-12 Momentive Performance Materials Inc. Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
CN105916869B (zh) * 2013-11-19 2019-11-22 莫门蒂夫性能材料股份有限公司 钴催化剂及它们用于氢化硅烷化和脱氢硅烷化的用途
US9381506B2 (en) 2013-11-19 2016-07-05 Momentive Performance Materials Inc. Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
JP6308547B2 (ja) * 2014-02-20 2018-04-11 公立大学法人大阪市立大学 有機ケイ素化合物の製造方法
US20170190722A1 (en) * 2014-05-08 2017-07-06 Momentive Performance Materials Inc. Dialkyl cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
JP2015231965A (ja) * 2014-06-10 2015-12-24 国立研究開発法人産業技術総合研究所 有機ケイ素化合物の製造方法及び触媒組成物
JP6327426B2 (ja) 2014-08-12 2018-05-23 国立大学法人九州大学 ヒドロシリル化反応触媒
WO2016024611A1 (ja) 2014-08-12 2016-02-18 国立大学法人九州大学 ヒドロシリル化反応触媒
JP6761997B2 (ja) 2014-08-19 2020-09-30 国立大学法人九州大学 ヒドロシリル化鉄触媒
WO2017010366A1 (ja) 2015-07-14 2017-01-19 国立大学法人九州大学 ヒドロシリル化反応触媒
CN108026126B (zh) * 2015-07-24 2021-04-20 莫门蒂夫性能材料股份有限公司 使用吡啶二亚胺羧酸钴催化剂的脱氢硅烷化、氢化硅烷化和交联
KR102607033B1 (ko) 2016-01-22 2023-11-29 신에쓰 가가꾸 고교 가부시끼가이샤 신규 아이소사이아나이드 화합물 및 하이드로실릴화 반응 촉매
CN110366449B (zh) 2017-02-28 2022-10-21 国立大学法人九州大学 氢化硅烷化反应、氢化反应和氢硅烷还原反应用催化剂
US10946368B2 (en) * 2017-07-17 2021-03-16 Dow Silicones Corporation Catalyst and related methods involving hydrosilylation and dehydrogenative silylation
JP2019064950A (ja) 2017-09-29 2019-04-25 国立大学法人九州大学 コバルト錯体、その製造方法およびヒドロシリル化反応用触媒
US11273432B2 (en) 2018-05-31 2022-03-15 Arizona Board Of Regents On Behalf Of Arizona State University Beta-diketiminate manganese catalysts for hydrosilylation, hydroboration, and dehydrogenative pnictogen-silicon and pnictogen-boron bond formation
JP7630783B2 (ja) * 2019-08-29 2025-02-21 公立大学法人大阪 錯体固定化触媒
JP7777817B2 (ja) * 2020-10-08 2025-12-01 公立大学法人大阪 ヒドロシリル化反応触媒助剤

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Publication number Publication date
JP2013544824A (ja) 2013-12-19
CN103339135B (zh) 2016-09-14
EP2643329A2 (en) 2013-10-02
KR20140032959A (ko) 2014-03-17
WO2012071358A3 (en) 2012-10-11
TWI473654B (zh) 2015-02-21
EP2643329B1 (en) 2016-07-27
CN103339135A (zh) 2013-10-02
TW201235103A (en) 2012-09-01
WO2012071358A2 (en) 2012-05-31
BR112013012733A2 (pt) 2016-09-13
US20120130106A1 (en) 2012-05-24
JP5991981B2 (ja) 2016-09-14
US8765987B2 (en) 2014-07-01

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