BR112013012733A2 - ativação in situ de complexos de metal contendo ligantes de nitrogênio terdentado usados como catalisadores de hydrosililação - Google Patents
ativação in situ de complexos de metal contendo ligantes de nitrogênio terdentado usados como catalisadores de hydrosililaçãoInfo
- Publication number
- BR112013012733A2 BR112013012733A2 BR112013012733A BR112013012733A BR112013012733A2 BR 112013012733 A2 BR112013012733 A2 BR 112013012733A2 BR 112013012733 A BR112013012733 A BR 112013012733A BR 112013012733 A BR112013012733 A BR 112013012733A BR 112013012733 A2 BR112013012733 A2 BR 112013012733A2
- Authority
- BR
- Brazil
- Prior art keywords
- toothless
- metal complexes
- ligands used
- complexes containing
- situ activation
- Prior art date
Links
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title abstract 4
- 238000006459 hydrosilylation reaction Methods 0.000 title abstract 4
- 230000004913 activation Effects 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000011065 in-situ storage Methods 0.000 title abstract 2
- 239000003446 ligand Substances 0.000 title abstract 2
- 239000002184 metal Substances 0.000 title abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- 239000012018 catalyst precursor Substances 0.000 abstract 1
- 239000010970 precious metal Substances 0.000 abstract 1
- -1 silica hydride Chemical class 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
- C07F7/0872—Preparation and treatment thereof
- C07F7/0876—Reactions involving the formation of bonds to a Si atom of a Si-O-Si sequence other than a bond of the Si-O-Si linkage
- C07F7/0878—Si-C bond
- C07F7/0879—Hydrosilylation reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41708410P | 2010-11-24 | 2010-11-24 | |
| US41706110P | 2010-11-24 | 2010-11-24 | |
| PCT/US2011/061746 WO2012071358A2 (en) | 2010-11-24 | 2011-11-22 | In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR112013012733A2 true BR112013012733A2 (pt) | 2016-09-13 |
Family
ID=45319390
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112013012733A BR112013012733A2 (pt) | 2010-11-24 | 2011-11-22 | ativação in situ de complexos de metal contendo ligantes de nitrogênio terdentado usados como catalisadores de hydrosililação |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8765987B2 (https=) |
| EP (1) | EP2643329B1 (https=) |
| JP (1) | JP5991981B2 (https=) |
| KR (1) | KR101890606B1 (https=) |
| CN (1) | CN103339135B (https=) |
| BR (1) | BR112013012733A2 (https=) |
| TW (1) | TWI473654B (https=) |
| WO (1) | WO2012071358A2 (https=) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101896423B1 (ko) * | 2010-11-24 | 2018-10-04 | 모멘티브 퍼포먼스 머티리얼즈 인크. | 폴리불포화 화합물의 금속-촉매 모노-하이드로실릴화 |
| CN103347889A (zh) * | 2010-11-24 | 2013-10-09 | 莫门蒂夫性能材料股份有限公司 | 氢化硅烷化催化剂 |
| EP2758417A2 (en) * | 2011-09-20 | 2014-07-30 | Dow Corning Corporation | Cobalt containing hydrosilylation catalysts and compositions containing the catalysts |
| US20140228570A1 (en) * | 2011-09-20 | 2014-08-14 | Dow Corning Corporation | Hydrosilylation Catalysts Made With Terdentate Nitrogen Ligands And Compositions Containing The Catalysts |
| CN103814040B (zh) * | 2011-09-20 | 2016-08-31 | 道康宁公司 | 含镍硅氢加成催化剂及含有该催化剂的组合物 |
| JP2014532045A (ja) * | 2011-09-20 | 2014-12-04 | ダウ コーニング コーポレーションＤｏｗ Ｃｏｒｎｉｎｇ Ｃｏｒｐｏｒａｔｉｏｎ | 鉄含有ヒドロシリル化触媒及びこの触媒を含有する組成物 |
| WO2013081794A1 (en) | 2011-12-01 | 2013-06-06 | Dow Corning Corporation | Hydrosilylation reaction catalysts and curable compositions and methods for their preparation and use |
| US9782763B2 (en) | 2011-12-14 | 2017-10-10 | Momentive Performance Materials Inc. | Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity |
| JP6125222B2 (ja) * | 2012-08-16 | 2017-05-10 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | コバルト触媒を用いる脱水素シリル化および架橋 |
| BR102013016146A2 (pt) * | 2012-08-16 | 2016-09-13 | Momentive Performance Mat Inc | processo para produzir um produto sililado, por desidrogenação, composição, composto e processo para produzir um material reticulado |
| US9447125B2 (en) | 2012-08-16 | 2016-09-20 | Momentive Performance Materials Inc. | Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation |
| US9371340B2 (en) | 2012-08-16 | 2016-06-21 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts |
| US20140121427A1 (en) * | 2012-10-29 | 2014-05-01 | The Regents Of The University Of California | Methods of Activating Metal Complexes for Catalysts |
| US9890182B2 (en) | 2013-05-06 | 2018-02-13 | Momentive Performance Materials Inc. | Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts |
| US9371339B2 (en) | 2013-05-06 | 2016-06-21 | Momentive Performance Materials Inc. | Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation |
| CN105228744B (zh) * | 2013-05-15 | 2021-04-06 | 莫门蒂夫性能材料股份有限公司 | 用甲硅烷基氢化物活化金属盐及其在氢化硅烷化反应中的应用 |
| US9708355B2 (en) | 2013-06-12 | 2017-07-18 | Arizona Board Of Regents On Behalf Of Arizona State University | First-row transition metal hydrogenation and hydrosilylation catalysts |
| US9387468B2 (en) | 2013-11-19 | 2016-07-12 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| CN105916869B (zh) * | 2013-11-19 | 2019-11-22 | 莫门蒂夫性能材料股份有限公司 | 钴催化剂及它们用于氢化硅烷化和脱氢硅烷化的用途 |
| US9381506B2 (en) | 2013-11-19 | 2016-07-05 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| JP6308547B2 (ja) * | 2014-02-20 | 2018-04-11 | 公立大学法人大阪市立大学 | 有機ケイ素化合物の製造方法 |
| US20170190722A1 (en) * | 2014-05-08 | 2017-07-06 | Momentive Performance Materials Inc. | Dialkyl cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| JP2015231965A (ja) * | 2014-06-10 | 2015-12-24 | 国立研究開発法人産業技術総合研究所 | 有機ケイ素化合物の製造方法及び触媒組成物 |
| JP6327426B2 (ja) | 2014-08-12 | 2018-05-23 | 国立大学法人九州大学 | ヒドロシリル化反応触媒 |
| WO2016024611A1 (ja) | 2014-08-12 | 2016-02-18 | 国立大学法人九州大学 | ヒドロシリル化反応触媒 |
| JP6761997B2 (ja) | 2014-08-19 | 2020-09-30 | 国立大学法人九州大学 | ヒドロシリル化鉄触媒 |
| WO2017010366A1 (ja) | 2015-07-14 | 2017-01-19 | 国立大学法人九州大学 | ヒドロシリル化反応触媒 |
| CN108026126B (zh) * | 2015-07-24 | 2021-04-20 | 莫门蒂夫性能材料股份有限公司 | 使用吡啶二亚胺羧酸钴催化剂的脱氢硅烷化、氢化硅烷化和交联 |
| KR102607033B1 (ko) | 2016-01-22 | 2023-11-29 | 신에쓰 가가꾸 고교 가부시끼가이샤 | 신규 아이소사이아나이드 화합물 및 하이드로실릴화 반응 촉매 |
| CN110366449B (zh) | 2017-02-28 | 2022-10-21 | 国立大学法人九州大学 | 氢化硅烷化反应、氢化反应和氢硅烷还原反应用催化剂 |
| US10946368B2 (en) * | 2017-07-17 | 2021-03-16 | Dow Silicones Corporation | Catalyst and related methods involving hydrosilylation and dehydrogenative silylation |
| JP2019064950A (ja) | 2017-09-29 | 2019-04-25 | 国立大学法人九州大学 | コバルト錯体、その製造方法およびヒドロシリル化反応用触媒 |
| US11273432B2 (en) | 2018-05-31 | 2022-03-15 | Arizona Board Of Regents On Behalf Of Arizona State University | Beta-diketiminate manganese catalysts for hydrosilylation, hydroboration, and dehydrogenative pnictogen-silicon and pnictogen-boron bond formation |
| JP7630783B2 (ja) * | 2019-08-29 | 2025-02-21 | 公立大学法人大阪 | 錯体固定化触媒 |
| JP7777817B2 (ja) * | 2020-10-08 | 2025-12-01 | 公立大学法人大阪 | ヒドロシリル化反応触媒助剤 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3220972A (en) | 1962-07-02 | 1965-11-30 | Gen Electric | Organosilicon process using a chloroplatinic acid reaction product as the catalyst |
| US3159601A (en) | 1962-07-02 | 1964-12-01 | Gen Electric | Platinum-olefin complex catalyzed addition of hydrogen- and alkenyl-substituted siloxanes |
| US3775452A (en) | 1971-04-28 | 1973-11-27 | Gen Electric | Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes |
| US4729821A (en) | 1986-11-03 | 1988-03-08 | Board Of Regents, The University Of Texas System | In situ activation of catalysts by applied electrical potentials |
| CA2096114A1 (en) * | 1990-12-13 | 1992-06-14 | Larry D. Boardman | Radiation activated hydrosilylation reaction |
| IL129929A0 (en) | 1996-12-17 | 2000-02-29 | Du Pont | Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt |
| ID26574A (id) | 1998-03-12 | 2001-01-18 | Bp Chem Int Ltd | Katalis-katalis polimerisasi |
| US5986022A (en) * | 1998-04-01 | 1999-11-16 | Witco Corporation | Continuous manufacture of silicone coploymers |
| GB9819847D0 (en) | 1998-09-12 | 1998-11-04 | Bp Chem Int Ltd | Novel compounds |
| JP4883253B2 (ja) * | 2001-01-11 | 2012-02-22 | 信越化学工業株式会社 | シリコーンゴム用ポリウレタン系樹脂コート剤及びシリコーンゴム部材 |
| WO2004037415A2 (en) | 2002-09-25 | 2004-05-06 | Shell Internationale Research Maatschappij B.V. | Catalyst systems for ethylene oligomerisation to linear alpha olefins |
| US7442819B2 (en) | 2004-07-09 | 2008-10-28 | E. I. Du Pont De Nemours And Company | Catalysts for olefin polymerization or oligomerization |
| US7696269B2 (en) * | 2006-12-28 | 2010-04-13 | Momentive Performance Materials Inc. | Silated core polysulfides, their preparation and use in filled elastomer compositions |
| US8236915B2 (en) | 2009-07-10 | 2012-08-07 | Momentive Performance Materials Inc. | Hydrosilylation catalysts |
| US8415443B2 (en) | 2009-07-10 | 2013-04-09 | Momentive Performance Materials Inc. | Hydrosilylation catalysts |
-
2011
- 2011-11-22 CN CN201180065874.XA patent/CN103339135B/zh active Active
- 2011-11-22 US US13/302,236 patent/US8765987B2/en active Active
- 2011-11-22 WO PCT/US2011/061746 patent/WO2012071358A2/en not_active Ceased
- 2011-11-22 KR KR1020137016385A patent/KR101890606B1/ko active Active
- 2011-11-22 BR BR112013012733A patent/BR112013012733A2/pt not_active Application Discontinuation
- 2011-11-22 EP EP11794589.9A patent/EP2643329B1/en active Active
- 2011-11-22 JP JP2013541001A patent/JP5991981B2/ja active Active
- 2011-11-23 TW TW100142964A patent/TWI473654B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2013544824A (ja) | 2013-12-19 |
| CN103339135B (zh) | 2016-09-14 |
| EP2643329A2 (en) | 2013-10-02 |
| KR101890606B1 (ko) | 2018-09-28 |
| KR20140032959A (ko) | 2014-03-17 |
| WO2012071358A3 (en) | 2012-10-11 |
| TWI473654B (zh) | 2015-02-21 |
| EP2643329B1 (en) | 2016-07-27 |
| CN103339135A (zh) | 2013-10-02 |
| TW201235103A (en) | 2012-09-01 |
| WO2012071358A2 (en) | 2012-05-31 |
| US20120130106A1 (en) | 2012-05-24 |
| JP5991981B2 (ja) | 2016-09-14 |
| US8765987B2 (en) | 2014-07-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BR112013012733A2 (pt) | ativação in situ de complexos de metal contendo ligantes de nitrogênio terdentado usados como catalisadores de hydrosililação | |
| Hargreaves | Heterogeneous catalysis with metal nitrides | |
| AR092989A1 (es) | Mezcla de distintos bisfosfitos asimetricos y su uso como mezcla catalizadora en la hidroformilacion | |
| EA201690873A2 (ru) | Катализаторы для нефтехимического катализа | |
| GB2480914B (en) | Carbocatalysts for chemical transformations | |
| ECSP11011404A (es) | Método para la producción de carbono sólido mediante la reducción de óxidos de carbono | |
| WO2013043912A3 (en) | Iron containing hydrosilylation catalysts and compositions containing the catalysts | |
| MX377462B (es) | Aditivos para composiciones liquidas curables. | |
| EA201491067A1 (ru) | Катализаторы из нанопроволоки и способы их применения и получения | |
| IN2015DN04004A (https=) | ||
| BR112015031125A2 (pt) | novos catalisadores baseados em ferro e processo de tratamento para os mesmos para uso em reações de fischer-tropsch | |
| WO2012012495A3 (en) | Functionalization of organic molecules using metal-organic frameworks (mofs) as catalysts | |
| CO6710898A2 (es) | Ligandos fosfina para racciones cataliticas | |
| WO2013043874A3 (en) | Manganese containing hydrosilylation catalysts and compositions containing the catalysts | |
| WO2013043785A3 (en) | Nickel containing hydrosilylation catalysts and compositions containing the catalysts | |
| BR112015008071A2 (pt) | catalisadores de hidrotratamento suportado tendo atividade intensificada, método de hidrotratamento e processo de formação de catalisador suportado | |
| MY171153A (en) | Supported noble-metal-comprising catalyst for oxidative dehydrogenation or epoxidation | |
| MY182458A (en) | Hydrocarbon synthesis catalyst, its preparation process and its use | |
| IN2014DN07057A (https=) | ||
| MY170148A (en) | Oxo-nitrogenated complex of cobalt, catalytic system comprising said oxo-nitrogenated complex and process for the (co) polymerization of conjugated dienes | |
| IN2014KN01659A (https=) | ||
| WO2015087168A3 (en) | Electrocatalyst | |
| MA34179B1 (fr) | Soufre liquide a viscosite amelioree, utilise comme caloporteur | |
| BR112017005460A2 (pt) | síntese de estado sólido de catalisadores de desidrogenação oxidativa | |
| BR112013032165B8 (pt) | catalisadores |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09B | Patent application refused [chapter 9.2 patent gazette] | ||
| B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL |