BR112013012733A2 - ativação in situ de complexos de metal contendo ligantes de nitrogênio terdentado usados como catalisadores de hydrosililação - Google Patents

ativação in situ de complexos de metal contendo ligantes de nitrogênio terdentado usados como catalisadores de hydrosililação

Info

Publication number
BR112013012733A2
BR112013012733A2 BR112013012733A BR112013012733A BR112013012733A2 BR 112013012733 A2 BR112013012733 A2 BR 112013012733A2 BR 112013012733 A BR112013012733 A BR 112013012733A BR 112013012733 A BR112013012733 A BR 112013012733A BR 112013012733 A2 BR112013012733 A2 BR 112013012733A2
Authority
BR
Brazil
Prior art keywords
toothless
metal complexes
ligands used
complexes containing
situ activation
Prior art date
Application number
BR112013012733A
Other languages
English (en)
Inventor
Aaron M Tondreau
Johannes G P Delis
Keith J Weller
Kenrick M Lewis
Paul J Chirik
Susan A Nye
Original Assignee
Univ Cornell
Momentive Performance Mat Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Cornell, Momentive Performance Mat Inc filed Critical Univ Cornell
Publication of BR112013012733A2 publication Critical patent/BR112013012733A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C07F7/0838—Compounds with one or more Si-O-Si sequences
    • C07F7/0872—Preparation and treatment thereof
    • C07F7/0876—Reactions involving the formation of bonds to a Si atom of a Si-O-Si sequence other than a bond of the Si-O-Si linkage
    • C07F7/0878—Si-C bond
    • C07F7/0879—Hydrosilylation reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C07F7/0838—Compounds with one or more Si-O-Si sequences
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

ativação in situ de complexos de metal contendo ligantes de nitrogênio terdentado usados como catalisadores de hydrosililação. descrito aqui é um processo para a hidrossililação de uma composição contendo um hidreto de silila e um composto contendo pelo menos um grupo insaturado, o processo compreendendo contatar um complexo com base em metal não precioso como um precursor de catalisador com um ativador sendo um agente de redução logo antes, simultaneamente ou depois de contatar o complexo com a composição, para fazer o hidreto de silia reagir com o composto contendo pelo menos um grupo insaturado produzir um produto de hidrossililação.
BR112013012733A 2010-11-24 2011-11-22 ativação in situ de complexos de metal contendo ligantes de nitrogênio terdentado usados como catalisadores de hydrosililação BR112013012733A2 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US41708410P 2010-11-24 2010-11-24
US41706110P 2010-11-24 2010-11-24
PCT/US2011/061746 WO2012071358A2 (en) 2010-11-24 2011-11-22 In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts

Publications (1)

Publication Number Publication Date
BR112013012733A2 true BR112013012733A2 (pt) 2016-09-13

Family

ID=45319390

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112013012733A BR112013012733A2 (pt) 2010-11-24 2011-11-22 ativação in situ de complexos de metal contendo ligantes de nitrogênio terdentado usados como catalisadores de hydrosililação

Country Status (8)

Country Link
US (1) US8765987B2 (pt)
EP (1) EP2643329B1 (pt)
JP (1) JP5991981B2 (pt)
KR (1) KR101890606B1 (pt)
CN (1) CN103339135B (pt)
BR (1) BR112013012733A2 (pt)
TW (1) TWI473654B (pt)
WO (1) WO2012071358A2 (pt)

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EP2758417A2 (en) * 2011-09-20 2014-07-30 Dow Corning Corporation Cobalt containing hydrosilylation catalysts and compositions containing the catalysts
US20140249311A1 (en) * 2011-09-20 2014-09-04 Dow Corning Corporation Iron Containing Hydrosilylation Catalysts and Compositions Containing the Catalysts
EP2758408A1 (en) * 2011-09-20 2014-07-30 Dow Corning Corporation Metal containing hydrosilylation catalysts and compositions containing the catalysts
CN103958059B (zh) 2011-12-01 2017-04-26 道康宁公司 硅氢加成反应催化剂和可固化组合物及它们的制备和使用方法
US9782763B2 (en) 2011-12-14 2017-10-10 Momentive Performance Materials Inc. Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity
BR102013016146A2 (pt) * 2012-08-16 2016-09-13 Momentive Performance Mat Inc processo para produzir um produto sililado, por desidrogenação, composição, composto e processo para produzir um material reticulado
US9447125B2 (en) 2012-08-16 2016-09-20 Momentive Performance Materials Inc. Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation
US9371340B2 (en) 2012-08-16 2016-06-21 Momentive Performance Materials Inc. Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts
JP6125222B2 (ja) * 2012-08-16 2017-05-10 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド コバルト触媒を用いる脱水素シリル化および架橋
US20140121427A1 (en) * 2012-10-29 2014-05-01 The Regents Of The University Of California Methods of Activating Metal Complexes for Catalysts
WO2014182670A2 (en) 2013-05-06 2014-11-13 Momentive Performance Materials Inc. Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts
US9371339B2 (en) 2013-05-06 2016-06-21 Momentive Performance Materials Inc. Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation
EP2996804B1 (en) * 2013-05-15 2020-12-30 Momentive Performance Materials Inc. Activation of metal salts with silylhydrides and their use in hydrosilylation reactions
WO2014201082A1 (en) 2013-06-12 2014-12-18 Arizona Board Of Regents On Behalf Of Arizona State University First-row transition metal hydrogenation and hydrosilylation catalysts
WO2015077304A1 (en) * 2013-11-19 2015-05-28 Momentive Performance Materials Inc. Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
WO2015077302A1 (en) * 2013-11-19 2015-05-28 Momentive Performance Materials Inc. Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
JP2016540753A (ja) * 2013-11-19 2016-12-28 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド コバルト触媒並びにヒドロシリル化及び脱水素シリル化のためのそれらの使用
JP6308547B2 (ja) * 2014-02-20 2018-04-11 公立大学法人大阪市立大学 有機ケイ素化合物の製造方法
JP2017520519A (ja) * 2014-05-08 2017-07-27 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド ジアルキルコバルト触媒並びにヒドロシリル化および脱水素シリル化のためのそれらの使用
JP2015231965A (ja) * 2014-06-10 2015-12-24 国立研究開発法人産業技術総合研究所 有機ケイ素化合物の製造方法及び触媒組成物
JP6327426B2 (ja) 2014-08-12 2018-05-23 国立大学法人九州大学 ヒドロシリル化反応触媒
US10000515B2 (en) 2014-08-12 2018-06-19 Kyushu University, National University Corporation Hydrosilylation reaction catalyst
JP6761997B2 (ja) 2014-08-19 2020-09-30 国立大学法人九州大学 ヒドロシリル化鉄触媒
KR102564637B1 (ko) 2015-07-14 2023-08-08 고쿠리쓰다이가쿠호진 규슈다이가쿠 하이드로실릴화 반응 촉매
US10717752B2 (en) 2015-07-24 2020-07-21 Momentive Performance Materials Inc. Dehydrogenative silylation, hydrosilylation and crosslinking using pyridinediimine cobalt carboxylate catalysts
WO2017126562A1 (ja) 2016-01-22 2017-07-27 信越化学工業株式会社 新規イソシアニド化合物及びヒドロシリル化反応触媒
EP3590596B1 (en) 2017-02-28 2023-07-12 Kyushu University, National University Corporation Catalyst for hydrosilylation reaction, hydrogenation reaction, and hydrosilane reduction reaction
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Also Published As

Publication number Publication date
TW201235103A (en) 2012-09-01
EP2643329B1 (en) 2016-07-27
WO2012071358A2 (en) 2012-05-31
WO2012071358A3 (en) 2012-10-11
KR101890606B1 (ko) 2018-09-28
TWI473654B (zh) 2015-02-21
EP2643329A2 (en) 2013-10-02
JP2013544824A (ja) 2013-12-19
CN103339135B (zh) 2016-09-14
JP5991981B2 (ja) 2016-09-14
US20120130106A1 (en) 2012-05-24
US8765987B2 (en) 2014-07-01
KR20140032959A (ko) 2014-03-17
CN103339135A (zh) 2013-10-02

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Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

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