KR101829930B1 - 원유에서 금속 및 아민을 제거하는 개선된 방법 - Google Patents

원유에서 금속 및 아민을 제거하는 개선된 방법 Download PDF

Info

Publication number
KR101829930B1
KR101829930B1 KR1020127009255A KR20127009255A KR101829930B1 KR 101829930 B1 KR101829930 B1 KR 101829930B1 KR 1020127009255 A KR1020127009255 A KR 1020127009255A KR 20127009255 A KR20127009255 A KR 20127009255A KR 101829930 B1 KR101829930 B1 KR 101829930B1
Authority
KR
South Korea
Prior art keywords
crude oil
wash water
acid
emulsion
added
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020127009255A
Other languages
English (en)
Korean (ko)
Other versions
KR20120084731A (ko
Inventor
주안 엠. Iii세 가르시아
사무엘 에이. 로르도
미쉘 엘. 브라덴
Original Assignee
날코 컴퍼니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 날코 컴퍼니 filed Critical 날코 컴퍼니
Publication of KR20120084731A publication Critical patent/KR20120084731A/ko
Application granted granted Critical
Publication of KR101829930B1 publication Critical patent/KR101829930B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G17/00—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge
    • C10G17/02—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge with acids or acid-containing liquids, e.g. acid sludge
    • C10G17/04—Liquid-liquid treatment forming two immiscible phases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G17/00—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge
    • C10G17/02—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge with acids or acid-containing liquids, e.g. acid sludge
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G17/00—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge
    • C10G17/09—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge with acid salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G33/00—Dewatering or demulsification of hydrocarbon oils
    • C10G33/02—Dewatering or demulsification of hydrocarbon oils with electrical or magnetic means
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G33/00—Dewatering or demulsification of hydrocarbon oils
    • C10G33/04—Dewatering or demulsification of hydrocarbon oils with chemical means
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C10G2300/805—Water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
KR1020127009255A 2009-09-21 2010-09-17 원유에서 금속 및 아민을 제거하는 개선된 방법 Active KR101829930B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/563,583 2009-09-21
US12/563,583 US9790438B2 (en) 2009-09-21 2009-09-21 Method for removing metals and amines from crude oil
PCT/US2010/049211 WO2011035085A2 (en) 2009-09-21 2010-09-17 Improved method for removing metals and amines from crude oil

Related Child Applications (1)

Application Number Title Priority Date Filing Date
KR1020187003975A Division KR20180017242A (ko) 2009-09-21 2010-09-17 원유에서 금속 및 아민을 제거하는 개선된 방법

Publications (2)

Publication Number Publication Date
KR20120084731A KR20120084731A (ko) 2012-07-30
KR101829930B1 true KR101829930B1 (ko) 2018-02-19

Family

ID=43755717

Family Applications (3)

Application Number Title Priority Date Filing Date
KR1020127009255A Active KR101829930B1 (ko) 2009-09-21 2010-09-17 원유에서 금속 및 아민을 제거하는 개선된 방법
KR1020187003975A Ceased KR20180017242A (ko) 2009-09-21 2010-09-17 원유에서 금속 및 아민을 제거하는 개선된 방법
KR1020197016545A Ceased KR20190069605A (ko) 2009-09-21 2010-09-17 원유에서 금속 및 아민을 제거하는 개선된 방법

Family Applications After (2)

Application Number Title Priority Date Filing Date
KR1020187003975A Ceased KR20180017242A (ko) 2009-09-21 2010-09-17 원유에서 금속 및 아민을 제거하는 개선된 방법
KR1020197016545A Ceased KR20190069605A (ko) 2009-09-21 2010-09-17 원유에서 금속 및 아민을 제거하는 개선된 방법

Country Status (14)

Country Link
US (2) US9790438B2 (https=)
EP (1) EP2480636B1 (https=)
JP (1) JP5916612B2 (https=)
KR (3) KR101829930B1 (https=)
CN (1) CN102753657A (https=)
AR (1) AR078259A1 (https=)
BR (1) BR112012006382B1 (https=)
CA (1) CA2771290C (https=)
ES (1) ES2623937T3 (https=)
IN (1) IN2012DN03269A (https=)
MX (1) MX349016B (https=)
RU (1) RU2552651C2 (https=)
SG (2) SG179198A1 (https=)
WO (1) WO2011035085A2 (https=)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7497943B2 (en) 2002-08-30 2009-03-03 Baker Hughes Incorporated Additives to enhance metal and amine removal in refinery desalting processes
US8425765B2 (en) 2002-08-30 2013-04-23 Baker Hughes Incorporated Method of injecting solid organic acids into crude oil
US7955522B2 (en) * 2008-02-26 2011-06-07 General Electric Company Synergistic acid blend extraction aid and method for its use
US8399386B2 (en) * 2009-09-23 2013-03-19 Nalco Company Foamers for downhole injection
US20110089082A1 (en) * 2009-10-15 2011-04-21 Assateague Oil llc Method and device for enhanced metal and amine removal from crude oil with controlled electrostatic coalescence
US20110100877A1 (en) * 2009-11-04 2011-05-05 Assateague Oil Ilc Method and device for automated control of enhanced metal and amine removal from crude oil
US20110120913A1 (en) * 2009-11-24 2011-05-26 Assateague Oil Ilc Method and device for electrostatic desalter optimization for enhanced metal and amine removal from crude oil
US9447350B2 (en) 2010-10-29 2016-09-20 Inaeris Technologies, Llc Production of renewable bio-distillate
US9382489B2 (en) 2010-10-29 2016-07-05 Inaeris Technologies, Llc Renewable heating fuel oil
DE102010055969A1 (de) * 2010-12-23 2012-06-28 Süd-Chemie AG Verfahren zur Aufreinigung von organischen Flüssigkeiten
US9315739B2 (en) * 2011-08-18 2016-04-19 Kior, Llc Process for upgrading biomass derived products
US8524074B2 (en) * 2011-08-17 2013-09-03 Nalco Company Removal of mercury and mercuric compounds from crude oil streams
US10427069B2 (en) 2011-08-18 2019-10-01 Inaeris Technologies, Llc Process for upgrading biomass derived products using liquid-liquid extraction
FR2984912A1 (fr) * 2011-12-27 2013-06-28 Total Raffinage Marketing Procede d'extraction de metaux presents dans des fractions d'hydrocarbures.
FR2984913A1 (fr) * 2011-12-27 2013-06-28 Total Raffinage Marketing Procede d'extraction de metaux presents dans des fractions d'hydrocarbures.
CN103450925B (zh) * 2012-05-28 2015-02-25 中国石油天然气股份有限公司 一种原油络合脱钙方法
US8961780B1 (en) * 2013-12-16 2015-02-24 Saudi Arabian Oil Company Methods for recovering organic heteroatom compounds from hydrocarbon feedstocks
EA034819B1 (ru) 2014-12-23 2020-03-25 Статойл Петролеум Ас Способ удаления нафтенатов металлов из сырых углеводородных смесей
KR102341007B1 (ko) * 2015-08-21 2021-12-17 에스케이이노베이션 주식회사 탄화수소 오일로부터 금속의 제거방법
KR102250734B1 (ko) * 2015-09-25 2021-05-11 에스케이이노베이션 주식회사 원유 내의 유기산 및 금속의 제거 방법
CN109790472B (zh) * 2016-09-22 2021-06-01 Bp北美公司 从原油除去污染物
KR101813470B1 (ko) 2017-03-30 2018-01-02 주식회사 이맥솔루션 원유 내의 무기물 저감을 위한 첨가제 및 이의 응용
US10760008B2 (en) 2017-06-05 2020-09-01 Baker Hughes, A Ge Company, Llc Compositions and methods of removing contaminants in refinery desalting
WO2020218403A1 (ja) * 2019-04-26 2020-10-29 株式会社片山化学工業研究所 原油中の鉄成分量低減方法
CN114096642B (zh) 2019-07-17 2024-03-01 Bl 科技公司 在精炼厂脱盐器中去除和转化胺的方法
US11130918B2 (en) * 2019-09-17 2021-09-28 Baker Hughes Holdings Llc Metal removal from fluids
EP4326836A1 (en) 2021-04-21 2024-02-28 Ecolab Usa Inc. Crude oil demulsifier compositions and uses thereof
KR20230171948A (ko) 2021-04-21 2023-12-21 에코랍 유에스에이 인코퍼레이티드 아스팔텐 및 파라핀 분산제 조성물 및 이의 용도
US12024676B2 (en) * 2021-09-15 2024-07-02 Halliburton Energy Services, Inc. Organic acid surfactant booster for contaminant removal

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4789463A (en) 1986-08-28 1988-12-06 Chevron Research Company Demetalation of hydrocarbonaceous feedstocks using hydroxo-carboxylic acids and salts thereof
US4888108A (en) 1986-03-05 1989-12-19 Canadian Patents And Development Limited Separation of fine solids from petroleum oils and the like

Family Cites Families (74)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2175095A (en) * 1937-07-06 1939-10-03 Dow Chemical Co Treatment of wells
US2767123A (en) * 1952-07-28 1956-10-16 Exxon Research Engineering Co Treatment of gasoline for improving oxidation stability by forming peroxides in gasoline and then treating with an organic hydroxy carboxylic acid
US2792352A (en) 1953-02-19 1957-05-14 Petrolite Corp Process for breaking petroleum emulsions employing oxyalkylation derivatives of certain polyepoxide modified phenol-aldehyde resins
US2744853A (en) * 1953-06-15 1956-05-08 Texas Co Removal of metal contaminants from petroleum
US2778777A (en) * 1954-02-16 1957-01-22 Texas Co Removal of metal components from petroleum oils
US3023160A (en) * 1959-10-09 1962-02-27 Universal Oil Prod Co Refining of hydrocarbons
US3153623A (en) 1961-04-07 1964-10-20 Exxon Research Engineering Co Deashing of residua
US3150081A (en) * 1962-08-14 1964-09-22 Du Pont Method of preventing precipitation of iron compounds from an aqueous solution
US3167500A (en) * 1962-08-31 1965-01-26 Socony Mobil Oil Co Inc Removal of metal comprising contaminants from petroleum oils
US3322664A (en) * 1964-06-26 1967-05-30 Chevron Res Method of removing calcium sulfate from a hydrocarbon feed stock
US3449243A (en) * 1966-09-30 1969-06-10 Standard Oil Co Treating of heavy oils to remove metals,salts and coke forming materials employing a combination of an alcohol,organic acid and aromatic hydrocarbon
US3582489A (en) 1968-12-10 1971-06-01 Petrolite Corp Process for crude oil purification
US4164472A (en) * 1978-04-10 1979-08-14 Petrolite Corporation CaCO3 -containing dispersions
US4167214A (en) * 1978-07-13 1979-09-11 Shell Oil Company Process for stably sequestering iron while acidizing a reservoir
US4326968A (en) 1979-10-05 1982-04-27 Magna Corporation Method for breaking petroleum emulsions and the like using micellar solutions of thin film spreading agents comprising polyepoxide condensates of resinous polyalkylene oxide adducts and polyether polyols
US4342657A (en) * 1979-10-05 1982-08-03 Magna Corporation Method for breaking petroleum emulsions and the like using thin film spreading agents comprising a polyether polyol
US4276185A (en) * 1980-02-04 1981-06-30 Halliburton Company Methods and compositions for removing deposits containing iron sulfide from surfaces comprising basic aqueous solutions of particular chelating agents
US4415426A (en) 1980-09-30 1983-11-15 Exxon Research And Engineering Co. Electrodes for electrical coalescense of liquid emulsions
US4292254A (en) 1980-10-17 1981-09-29 Atlantic Richfield Company Preparation of polyisocyanates from polycarbamates
US4439345A (en) * 1981-06-11 1984-03-27 Marathon Oil Company Demulsification of a crude oil middle phase emulsion
US4411775A (en) 1981-12-02 1983-10-25 Texaco Inc. Demulsification of bitumen emulsions using water soluble epoxy-containing polyethers
US4432865A (en) * 1982-01-25 1984-02-21 Norman George R Process for treating used motor oil and synthetic crude oil
CH660882A5 (de) 1982-02-05 1987-05-29 Bbc Brown Boveri & Cie Werkstoff mit zweiweg-gedaechtniseffekt und verfahren zu dessen herstellung.
US4551239A (en) 1983-04-11 1985-11-05 Exxon Research & Engineering Co. Water based demulsifier formulation and process for its use in dewatering and desalting crude hydrocarbon oils
JPS6032888A (ja) 1983-08-04 1985-02-20 Nippon Mining Co Ltd 原油の脱塩方法
US4737265A (en) 1983-12-06 1988-04-12 Exxon Research & Engineering Co. Water based demulsifier formulation and process for its use in dewatering and desalting crude hydrocarbon oils
US4491513A (en) * 1984-04-16 1985-01-01 Exxon Research & Engineering Co. Process for beneficiating oil-shale
US4645589A (en) * 1985-10-18 1987-02-24 Mobil Oil Corporation Process for removing metals from crude
US4778590A (en) * 1985-10-30 1988-10-18 Chevron Research Company Decalcification of hydrocarbonaceous feedstocks using amino-carboxylic acids and salts thereof
US4727191A (en) 1986-07-10 1988-02-23 Ethyl Corporation Purification of (hydrocarbylthio) aromatic amines
US4778591A (en) * 1986-08-28 1988-10-18 Chevron Research Company Demetalation of hydrocarbonaceous feedstocks using carbonic acid and salts thereof
US4778589A (en) * 1986-08-28 1988-10-18 Chevron Research Company Decalcification of hydrocarbonaceous feedstocks using citric acid and salts thereof
US4778592A (en) * 1986-08-28 1988-10-18 Chevron Research Company Demetalation of hydrocarbonaceous feedstocks using amino-carboxylic acids and salts thereof
US4818410B1 (en) 1988-01-14 1998-06-30 Petrolite Corp Method of removing water soluble organics from oil process water
US4853109A (en) * 1988-03-07 1989-08-01 Chevron Research Company Demetalation of hydrocarbonaceous feedstocks using dibasic carboxylic acids and salts thereof
US4988433A (en) * 1988-08-31 1991-01-29 Chevron Research Company Demetalation of hydrocarbonaceous feedstocks using monobasic carboxylic acids and salts thereof
US5174957A (en) * 1988-09-23 1992-12-29 Betz Laboratories, Inc. Emulsion minimizing corrosion inhibitor for naphtah/water systems
US5062992A (en) * 1988-09-23 1991-11-05 Betz Laboratories, Inc. Emulsion minimizing corrosion inhibitor for naphtha/water systems
US5104578A (en) * 1988-09-23 1992-04-14 Betz Laboratories, Inc. Emulsion minimizing corrosion inhibitor for naphtha/water systems
US5176847A (en) * 1989-01-06 1993-01-05 Baker Hughes Incorporated Demulsifying composition
US4938876A (en) * 1989-03-02 1990-07-03 Ohsol Ernest O Method for separating oil and water emulsions
US5114566A (en) * 1989-03-09 1992-05-19 Betz Laboratories, Inc. Crude oil desalting process
US4992210A (en) * 1989-03-09 1991-02-12 Betz Laboratories, Inc. Crude oil desalting process
SU1666520A1 (ru) 1989-08-08 1991-07-30 Удмуртский Комплексный Отдел Татарского Государственного Научно-Исследовательского И Проектного Института Нефтяной Промышленности Способ обессоливани нефти
US5080779A (en) * 1990-08-01 1992-01-14 Betz Laboratories, Inc. Methods for removing iron from crude oil in a two-stage desalting system
US5078858A (en) * 1990-08-01 1992-01-07 Betz Laboratories, Inc. Methods of extracting iron species from liquid hydrocarbons
CN1028537C (zh) 1991-02-06 1995-05-24 中国石油化工总公司 用复合剂从烃原料中脱除金属
US5208369A (en) * 1991-05-31 1993-05-04 The Dow Chemical Company Degradable chelants having sulfonate groups, uses and compositions thereof
US5346627A (en) * 1992-03-03 1994-09-13 Nalco Chemical Company Method for removing metals from a fluid stream
US5282959A (en) * 1992-03-16 1994-02-01 Betz Laboratories, Inc. Method for the extraction of iron from liquid hydrocarbons
US5256305A (en) 1992-08-24 1993-10-26 Betz Laboratories, Inc. Method for breaking emulsions in a crude oil desalting system
US5364532A (en) * 1992-09-03 1994-11-15 Petrolite Corporation Method of removing water soluble organics from oil process water
US5637223A (en) * 1992-09-03 1997-06-10 Petrolite Corporation Method of removing water soluble organics from oil process water
US5853592A (en) * 1992-09-03 1998-12-29 Baker Hughes Incorporated Method of removing water soluble organics from oil process water with an organic acid and a mineral acid having a plurality of pKa's
US5395536A (en) 1993-05-07 1995-03-07 Baker Hughes, Inc. Wastewater organic acid removal process
US5446233A (en) 1993-09-21 1995-08-29 Nalco Chemical Company Ethylene plant caustic system emulsion breaking with salts of alkyl sulfonic acids
US5667727A (en) 1995-06-26 1997-09-16 Baker Hughes Incorporated Polymer compositions for demulsifying crude oil
US5746908A (en) 1996-02-12 1998-05-05 Phillips Petroleum Company Crude oil desalting process
US5700337A (en) 1996-03-01 1997-12-23 Mcdonnell Douglas Corporation Fabrication method for composite structure adapted for controlled structural deformation
DE19742314C2 (de) 1997-09-25 2000-06-21 Daimler Chrysler Ag Tragende Struktur
US5948242A (en) * 1997-10-15 1999-09-07 Unipure Corporation Process for upgrading heavy crude oil production
JPH11241074A (ja) 1998-02-25 1999-09-07 Union Sekiyu Kogyo Kk ナフテン酸含有油の処理方法
WO2000052114A1 (en) 1999-03-05 2000-09-08 Baker Hughes Incorporated Metal phase transfer additive composition and method
ATE313612T1 (de) 1999-11-30 2006-01-15 Ici Plc Verfahren zur behandlung von rohöl oder öl in einem raffinerieverfahren
NO316109B1 (no) * 2001-11-07 2003-12-15 Aibel As En coalescer anordning
US7497943B2 (en) * 2002-08-30 2009-03-03 Baker Hughes Incorporated Additives to enhance metal and amine removal in refinery desalting processes
CN1202208C (zh) * 2003-06-03 2005-05-18 克拉玛依市金山石油化工有限公司 烃油脱金属循环方法
US7399403B2 (en) 2004-05-03 2008-07-15 Nalco Company Decalcification of refinery hydrocarbon feedstocks
US20070125685A1 (en) 2005-12-02 2007-06-07 General Electric Company Method for removing calcium from crude oil
WO2007086661A1 (en) 2006-01-25 2007-08-02 Sk Energy Co., Ltd. Method of removing the calcium from hydrocarbonaceous oil
JP2007291164A (ja) 2006-04-21 2007-11-08 Kawasaki Kasei Chem Ltd 油状液体から金属成分を抽出除去する方法
KR101340718B1 (ko) 2006-07-10 2013-12-12 에스케이에너지 주식회사 말레인산 또는 그 유도체를 이용한 탄화수소류유분으로부터 칼슘의 제거방법
WO2008062433A2 (en) 2006-08-22 2008-05-29 Dorf Ketal Chemicals (I) Private Limited Method of removal of calcium from hydrocarbon feedstock
CN101314728B (zh) * 2007-05-31 2012-08-01 中国石油化工股份有限公司 一种烃类原料油脱铁的方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4888108A (en) 1986-03-05 1989-12-19 Canadian Patents And Development Limited Separation of fine solids from petroleum oils and the like
US4789463A (en) 1986-08-28 1988-12-06 Chevron Research Company Demetalation of hydrocarbonaceous feedstocks using hydroxo-carboxylic acids and salts thereof

Also Published As

Publication number Publication date
EP2480636A2 (en) 2012-08-01
JP5916612B2 (ja) 2016-05-11
RU2552651C2 (ru) 2015-06-10
CA2771290C (en) 2017-02-28
EP2480636A4 (en) 2016-01-06
KR20180017242A (ko) 2018-02-20
US9790438B2 (en) 2017-10-17
SG10201500128PA (en) 2015-03-30
US20110068049A1 (en) 2011-03-24
RU2012107635A (ru) 2013-10-27
CN102753657A (zh) 2012-10-24
MX349016B (es) 2017-07-06
SG179198A1 (en) 2012-04-27
BR112012006382B1 (pt) 2019-04-02
BR112012006382A2 (pt) 2016-04-05
KR20190069605A (ko) 2019-06-19
AR078259A1 (es) 2011-10-26
US20180002613A1 (en) 2018-01-04
US10023812B2 (en) 2018-07-17
JP2013505350A (ja) 2013-02-14
WO2011035085A2 (en) 2011-03-24
EP2480636B1 (en) 2017-04-12
WO2011035085A3 (en) 2011-06-16
ES2623937T3 (es) 2017-07-12
MX2012002906A (es) 2012-08-03
IN2012DN03269A (https=) 2015-10-23
CA2771290A1 (en) 2011-03-24
KR20120084731A (ko) 2012-07-30

Similar Documents

Publication Publication Date Title
KR101829930B1 (ko) 원유에서 금속 및 아민을 제거하는 개선된 방법
EP1530620B1 (en) Additives to enhance metal and amine removal in refinery desalting processes
EP2111271A1 (en) Process for removing nickel and vanadium from hydrocarbons
EP2480755A2 (en) Foamers for downhole injection
TWI482851B (zh) 協同的酸摻合物萃取助劑及其使用方法
CN100537716C (zh) 一种脱除烃原料中金属杂质的方法
KR101813470B1 (ko) 원유 내의 무기물 저감을 위한 첨가제 및 이의 응용
CN1982413A (zh) 一种脱金属剂

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

R15-X000 Change to inventor requested

St.27 status event code: A-3-3-R10-R15-oth-X000

R16-X000 Change to inventor recorded

St.27 status event code: A-3-3-R10-R16-oth-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

P22-X000 Classification modified

St.27 status event code: A-2-2-P10-P22-nap-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

A107 Divisional application of patent
PA0104 Divisional application for international application

St.27 status event code: A-0-1-A10-A18-div-PA0104

St.27 status event code: A-0-1-A10-A16-div-PA0104

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 8

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 9

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-OTH-PR1001 (AS PROVIDED BY THE NATIONAL OFFICE)

Year of fee payment: 9