KR101742825B1 - 다마신 인터커넥트에서 전자이동 저항성 개선을 위한 계면층 - Google Patents
다마신 인터커넥트에서 전자이동 저항성 개선을 위한 계면층 Download PDFInfo
- Publication number
- KR101742825B1 KR101742825B1 KR1020110004334A KR20110004334A KR101742825B1 KR 101742825 B1 KR101742825 B1 KR 101742825B1 KR 1020110004334 A KR1020110004334 A KR 1020110004334A KR 20110004334 A KR20110004334 A KR 20110004334A KR 101742825 B1 KR101742825 B1 KR 101742825B1
- Authority
- KR
- South Korea
- Prior art keywords
- layer
- copper
- substrate
- insulating film
- aluminum
- Prior art date
Links
- 239000010949 copper Substances 0.000 claims abstract description 168
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 164
- 229910052802 copper Inorganic materials 0.000 claims abstract description 163
- 229910052751 metal Inorganic materials 0.000 claims abstract description 126
- 239000002184 metal Substances 0.000 claims abstract description 126
- 239000000758 substrate Substances 0.000 claims abstract description 116
- 238000002161 passivation Methods 0.000 claims abstract description 109
- 238000000151 deposition Methods 0.000 claims abstract description 79
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 54
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000000463 material Substances 0.000 claims abstract description 43
- 150000001875 compounds Chemical class 0.000 claims abstract description 23
- 239000000376 reactant Substances 0.000 claims abstract description 23
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 22
- 239000001301 oxygen Substances 0.000 claims abstract description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910018516 Al—O Inorganic materials 0.000 claims abstract description 9
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910018509 Al—N Inorganic materials 0.000 claims abstract description 6
- 239000010410 layer Substances 0.000 claims description 513
- 238000000034 method Methods 0.000 claims description 198
- 230000008569 process Effects 0.000 claims description 127
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 38
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 37
- 238000011282 treatment Methods 0.000 claims description 33
- 239000007789 gas Substances 0.000 claims description 31
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 21
- 238000004140 cleaning Methods 0.000 claims description 21
- 238000012545 processing Methods 0.000 claims description 20
- 239000004065 semiconductor Substances 0.000 claims description 19
- 238000009832 plasma treatment Methods 0.000 claims description 16
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 13
- 239000005751 Copper oxide Substances 0.000 claims description 13
- 229910000431 copper oxide Inorganic materials 0.000 claims description 13
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 12
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 12
- 238000005229 chemical vapour deposition Methods 0.000 claims description 11
- 239000011229 interlayer Substances 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 claims description 6
- 239000012212 insulator Substances 0.000 claims description 5
- 238000002347 injection Methods 0.000 claims description 4
- 239000007924 injection Substances 0.000 claims description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 3
- 230000001681 protective effect Effects 0.000 abstract description 83
- 238000009792 diffusion process Methods 0.000 abstract description 81
- 230000004888 barrier function Effects 0.000 abstract description 78
- 239000002019 doping agent Substances 0.000 description 85
- 230000008021 deposition Effects 0.000 description 63
- 210000002381 plasma Anatomy 0.000 description 61
- 239000002243 precursor Substances 0.000 description 39
- 230000015572 biosynthetic process Effects 0.000 description 33
- 235000012431 wafers Nutrition 0.000 description 32
- 229910052796 boron Inorganic materials 0.000 description 30
- 239000000203 mixture Substances 0.000 description 29
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 26
- 229910052719 titanium Inorganic materials 0.000 description 17
- 239000010936 titanium Substances 0.000 description 17
- 150000002739 metals Chemical class 0.000 description 14
- 238000010438 heat treatment Methods 0.000 description 12
- 229910052715 tantalum Inorganic materials 0.000 description 12
- -1 bis (cyclopentadienyl) cobalt Chemical compound 0.000 description 11
- 229910052735 hafnium Inorganic materials 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- 229910045601 alloy Inorganic materials 0.000 description 10
- 239000000956 alloy Substances 0.000 description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 230000009977 dual effect Effects 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 239000006104 solid solution Substances 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 230000008859 change Effects 0.000 description 8
- 229910052707 ruthenium Inorganic materials 0.000 description 8
- 229910052718 tin Inorganic materials 0.000 description 8
- 239000011810 insulating material Substances 0.000 description 7
- 238000001465 metallisation Methods 0.000 description 7
- 150000004767 nitrides Chemical class 0.000 description 7
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 229910052750 molybdenum Inorganic materials 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000010703 silicon Substances 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 239000004480 active ingredient Substances 0.000 description 5
- 229910052787 antimony Inorganic materials 0.000 description 5
- 239000004020 conductor Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 238000009413 insulation Methods 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 5
- 238000012805 post-processing Methods 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 230000000903 blocking effect Effects 0.000 description 4
- 239000000872 buffer Substances 0.000 description 4
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 4
- 239000012159 carrier gas Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- VJDVOZLYDLHLSM-UHFFFAOYSA-N diethylazanide;titanium(4+) Chemical compound [Ti+4].CC[N-]CC.CC[N-]CC.CC[N-]CC.CC[N-]CC VJDVOZLYDLHLSM-UHFFFAOYSA-N 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 238000002513 implantation Methods 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 238000007781 pre-processing Methods 0.000 description 4
- 150000003254 radicals Chemical class 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- MNWRORMXBIWXCI-UHFFFAOYSA-N tetrakis(dimethylamido)titanium Chemical compound CN(C)[Ti](N(C)C)(N(C)C)N(C)C MNWRORMXBIWXCI-UHFFFAOYSA-N 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- QTRQHYHCQPFURH-UHFFFAOYSA-N aluminum;diethylazanide Chemical compound [Al+3].CC[N-]CC.CC[N-]CC.CC[N-]CC QTRQHYHCQPFURH-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- TUTOKIOKAWTABR-UHFFFAOYSA-N dimethylalumane Chemical compound C[AlH]C TUTOKIOKAWTABR-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 150000001247 metal acetylides Chemical class 0.000 description 3
- 238000013508 migration Methods 0.000 description 3
- 230000005012 migration Effects 0.000 description 3
- 125000000962 organic group Chemical group 0.000 description 3
- 150000002902 organometallic compounds Chemical class 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000006722 reduction reaction Methods 0.000 description 3
- 150000003346 selenoethers Chemical class 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000005137 deposition process Methods 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 150000004678 hydrides Chemical class 0.000 description 2
- 229910001507 metal halide Inorganic materials 0.000 description 2
- 150000005309 metal halides Chemical class 0.000 description 2
- 229910052987 metal hydride Inorganic materials 0.000 description 2
- 150000004681 metal hydrides Chemical class 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- ZUSRFDBQZSPBDV-UHFFFAOYSA-N n-[bis(dimethylamino)stibanyl]-n-methylmethanamine Chemical compound CN(C)[Sb](N(C)C)N(C)C ZUSRFDBQZSPBDV-UHFFFAOYSA-N 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000027756 respiratory electron transport chain Effects 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 2
- 150000004772 tellurides Chemical class 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- OXJUCLBTTSNHOF-UHFFFAOYSA-N 5-ethylcyclopenta-1,3-diene;ruthenium(2+) Chemical compound [Ru+2].CC[C-]1C=CC=C1.CC[C-]1C=CC=C1 OXJUCLBTTSNHOF-UHFFFAOYSA-N 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- CNOLUXXZJWMGOC-UHFFFAOYSA-N CN(C)[Ti](N(C)C)(N(C)C)(N(C)C)N(C)C Chemical compound CN(C)[Ti](N(C)C)(N(C)C)(N(C)C)N(C)C CNOLUXXZJWMGOC-UHFFFAOYSA-N 0.000 description 1
- OVSHQDISEQBLSB-UHFFFAOYSA-N C[Sn](C)(C)C.C[Sn](C)(C)C Chemical compound C[Sn](C)(C)C.C[Sn](C)(C)C OVSHQDISEQBLSB-UHFFFAOYSA-N 0.000 description 1
- 229910016344 CuSi Inorganic materials 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001343 alkyl silanes Chemical class 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical group [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910000085 borane Inorganic materials 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000012707 chemical precursor Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- MHLUNYHEULBRJN-UHFFFAOYSA-N cobalt(2+);pentane-2,4-dione Chemical class [Co+2].CC(=O)CC(C)=O MHLUNYHEULBRJN-UHFFFAOYSA-N 0.000 description 1
- FCEOGYWNOSBEPV-FDGPNNRMSA-N cobalt;(z)-4-hydroxypent-3-en-2-one Chemical compound [Co].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O FCEOGYWNOSBEPV-FDGPNNRMSA-N 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- DXKNERXVNFFIOM-UHFFFAOYSA-N diethylazanide;di(propan-2-yl)azanide;titanium(4+) Chemical compound CCN(CC)[Ti](N(CC)CC)(N(C(C)C)C(C)C)N(C(C)C)C(C)C DXKNERXVNFFIOM-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005121 nitriding Methods 0.000 description 1
- 239000012811 non-conductive material Substances 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 238000001020 plasma etching Methods 0.000 description 1
- 238000013001 point bending Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229910021426 porous silicon Inorganic materials 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 1
- VXKWYPOMXBVZSJ-UHFFFAOYSA-N tetramethyltin Chemical compound C[Sn](C)(C)C VXKWYPOMXBVZSJ-UHFFFAOYSA-N 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76802—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics
- H01L21/76807—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics for dual damascene structures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02041—Cleaning
- H01L21/02043—Cleaning before device manufacture, i.e. Begin-Of-Line process
- H01L21/02046—Dry cleaning only
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/02227—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process
- H01L21/02247—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by nitridation, e.g. nitridation of the substrate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/0226—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
- H01L21/02263—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
- H01L21/02271—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
- H01L21/0228—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition deposition by cyclic CVD, e.g. ALD, ALE, pulsed CVD
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02296—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer
- H01L21/02299—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer pre-treatment
- H01L21/02312—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer pre-treatment treatment by exposure to a gas or vapour
- H01L21/02315—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer pre-treatment treatment by exposure to a gas or vapour treatment by exposure to a plasma
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02612—Formation types
- H01L21/02617—Deposition types
- H01L21/0262—Reduction or decomposition of gaseous compounds, e.g. CVD
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/28008—Making conductor-insulator-semiconductor electrodes
- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28247—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon passivation or protection of the electrode, e.g. using re-oxidation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/324—Thermal treatment for modifying the properties of semiconductor bodies, e.g. annealing, sintering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76829—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers
- H01L21/76834—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers formation of thin insulating films on the sidewalls or on top of conductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plasma & Fusion (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/688,154 US8268722B2 (en) | 2009-06-03 | 2010-01-15 | Interfacial capping layers for interconnects |
US12/688,154 | 2010-01-15 | ||
US12/689,803 | 2010-01-19 | ||
US12/689,803 US7858510B1 (en) | 2008-02-28 | 2010-01-19 | Interfacial layers for electromigration resistance improvement in damascene interconnects |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20110084130A KR20110084130A (ko) | 2011-07-21 |
KR101742825B1 true KR101742825B1 (ko) | 2017-06-01 |
Family
ID=44268066
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020110004334A KR101742825B1 (ko) | 2010-01-15 | 2011-01-17 | 다마신 인터커넥트에서 전자이동 저항성 개선을 위한 계면층 |
Country Status (4)
Country | Link |
---|---|
JP (1) | JP5773306B2 (de) |
KR (1) | KR101742825B1 (de) |
CN (1) | CN102130046B (de) |
TW (2) | TW201709418A (de) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7727881B1 (en) | 2004-11-03 | 2010-06-01 | Novellus Systems, Inc. | Protective self-aligned buffer layers for damascene interconnects |
US7727880B1 (en) | 2004-11-03 | 2010-06-01 | Novellus Systems, Inc. | Protective self-aligned buffer layers for damascene interconnects |
CN103582932B (zh) | 2011-06-03 | 2017-01-18 | 诺发系统公司 | 用于互连的包含金属和硅的盖层 |
CN104008995B (zh) * | 2013-02-22 | 2017-09-01 | 中芯国际集成电路制造(上海)有限公司 | 一种半导体器件及其制备方法 |
SG11201506605XA (en) * | 2013-03-05 | 2015-09-29 | Entegris Inc | Ion implantation compositions, systems, and methods |
CN105378907A (zh) * | 2013-07-24 | 2016-03-02 | 应用材料公司 | 钴基板处理系统、设备及方法 |
CN104576514B (zh) * | 2013-10-29 | 2017-11-24 | 中芯国际集成电路制造(上海)有限公司 | 半导体器件的制备方法 |
CN104637864B (zh) * | 2013-11-14 | 2017-11-24 | 中芯国际集成电路制造(上海)有限公司 | 提高数据保持能力的方法 |
US9368448B2 (en) * | 2013-12-20 | 2016-06-14 | Applied Materials, Inc. | Metal-containing films as dielectric capping barrier for advanced interconnects |
US9465071B2 (en) * | 2014-03-04 | 2016-10-11 | Mediatek Inc. | Method and apparatus for generating featured scan pattern |
US10319908B2 (en) * | 2014-05-01 | 2019-06-11 | Crossbar, Inc. | Integrative resistive memory in backend metal layers |
US9633896B1 (en) | 2015-10-09 | 2017-04-25 | Lam Research Corporation | Methods for formation of low-k aluminum-containing etch stop films |
KR20230026514A (ko) | 2016-10-02 | 2023-02-24 | 어플라이드 머티어리얼스, 인코포레이티드 | 루테늄 라이너로 구리 전자 이동을 개선하기 위한 도핑된 선택적 금속 캡 |
US9859153B1 (en) * | 2016-11-14 | 2018-01-02 | Lam Research Corporation | Deposition of aluminum oxide etch stop layers |
CN107256845A (zh) * | 2017-05-25 | 2017-10-17 | 上海集成电路研发中心有限公司 | 一种铜互连结构及其制造方法 |
US20190127212A1 (en) * | 2017-10-31 | 2019-05-02 | Texas Instruments Incorporated | Forming a passivation coating for mems devices |
US10741440B2 (en) * | 2018-06-05 | 2020-08-11 | Lam Research Corporation | Metal liner passivation and adhesion enhancement by zinc doping |
US10707119B1 (en) * | 2019-01-14 | 2020-07-07 | Globalfoundries Inc. | Interconnect structures with airgaps and dielectric-capped interconnects |
CN111769074B (zh) * | 2019-04-02 | 2024-09-27 | 长鑫存储技术有限公司 | 半导体互连结构及其制作方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001524754A (ja) | 1997-11-26 | 2001-12-04 | アプライド マテリアルズ インコーポレイテッド | Cvdアルミニウム及びpvdアルミニウム集積を用いた新しいホール充填技術 |
JP2002164351A (ja) | 2000-09-14 | 2002-06-07 | Texas Instruments Inc | 自己整合型銅キャップ拡散障壁形成方法 |
US20050142833A1 (en) | 2003-12-30 | 2005-06-30 | Dongbuanam Semiconductor Inc. | Method of fabricating semiconductor device |
US20070145600A1 (en) | 2005-12-28 | 2007-06-28 | Hisashi Yano | Semiconductor device and manufacturing method thereof |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0765179B2 (ja) * | 1987-05-15 | 1995-07-12 | 日本電信電話株式会社 | 化学的気相成長方法 |
US6664182B2 (en) * | 2001-04-25 | 2003-12-16 | Macronix International Co. Ltd. | Method of improving the interlayer adhesion property of low-k layers in a dual damascene process |
US6518167B1 (en) * | 2002-04-16 | 2003-02-11 | Advanced Micro Devices, Inc. | Method of forming a metal or metal nitride interface layer between silicon nitride and copper |
JP2006505127A (ja) * | 2002-10-29 | 2006-02-09 | エーエスエム インターナショナル エヌ.ヴェー. | 酸素架橋構造及び方法 |
US7102232B2 (en) * | 2004-04-19 | 2006-09-05 | International Business Machines Corporation | Structure to improve adhesion between top CVD low-k dielectric and dielectric capping layer |
US7704873B1 (en) * | 2004-11-03 | 2010-04-27 | Novellus Systems, Inc. | Protective self-aligned buffer layers for damascene interconnects |
TW200802703A (en) * | 2005-11-28 | 2008-01-01 | Nxp Bv | Method of forming a self aligned copper capping layer |
DE102007004867B4 (de) * | 2007-01-31 | 2009-07-30 | Advanced Micro Devices, Inc., Sunnyvale | Verfahren zum Erhöhen der Zuverlässigkeit von kupferbasierten Metallisierungsstrukturen in einem Mikrostrukturbauelement durch Anwenden von Aluminiumnitrid |
US7754588B2 (en) * | 2007-09-28 | 2010-07-13 | Tel Epion Inc. | Method to improve a copper/dielectric interface in semiconductor devices |
-
2011
- 2011-01-13 JP JP2011004797A patent/JP5773306B2/ja active Active
- 2011-01-14 TW TW105123303A patent/TW201709418A/zh unknown
- 2011-01-14 TW TW100101507A patent/TWI612618B/zh active
- 2011-01-14 CN CN201110021170.4A patent/CN102130046B/zh active Active
- 2011-01-17 KR KR1020110004334A patent/KR101742825B1/ko active IP Right Grant
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001524754A (ja) | 1997-11-26 | 2001-12-04 | アプライド マテリアルズ インコーポレイテッド | Cvdアルミニウム及びpvdアルミニウム集積を用いた新しいホール充填技術 |
JP2002164351A (ja) | 2000-09-14 | 2002-06-07 | Texas Instruments Inc | 自己整合型銅キャップ拡散障壁形成方法 |
US20050142833A1 (en) | 2003-12-30 | 2005-06-30 | Dongbuanam Semiconductor Inc. | Method of fabricating semiconductor device |
US20070145600A1 (en) | 2005-12-28 | 2007-06-28 | Hisashi Yano | Semiconductor device and manufacturing method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN102130046A (zh) | 2011-07-20 |
KR20110084130A (ko) | 2011-07-21 |
TW201709418A (zh) | 2017-03-01 |
CN102130046B (zh) | 2015-01-14 |
TWI612618B (zh) | 2018-01-21 |
JP2011146711A (ja) | 2011-07-28 |
JP5773306B2 (ja) | 2015-09-02 |
TW201138024A (en) | 2011-11-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101742825B1 (ko) | 다마신 인터커넥트에서 전자이동 저항성 개선을 위한 계면층 | |
US7858510B1 (en) | Interfacial layers for electromigration resistance improvement in damascene interconnects | |
US7648899B1 (en) | Interfacial layers for electromigration resistance improvement in damascene interconnects | |
US8268722B2 (en) | Interfacial capping layers for interconnects | |
TWI541938B (zh) | 用於互連的含金屬及矽覆蓋層 | |
US11587829B2 (en) | Doping control of metal nitride films | |
US7704873B1 (en) | Protective self-aligned buffer layers for damascene interconnects | |
US7135403B2 (en) | Method for forming metal interconnection line in semiconductor device | |
US8865594B2 (en) | Formation of liner and barrier for tungsten as gate electrode and as contact plug to reduce resistance and enhance device performance | |
US7915166B1 (en) | Diffusion barrier and etch stop films | |
US6955983B2 (en) | Methods of forming metal interconnections of semiconductor devices by treating a barrier metal layer | |
KR20140099311A (ko) | 구리 배리어 용도들을 위한 도핑된 탄탈룸 질화물 | |
US20020132469A1 (en) | Method for forming metal wiring layer | |
US20080157375A1 (en) | Semiconductor device having a metal interconnection and method of fabricating the same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
E902 | Notification of reason for refusal | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant |