KR101582119B1 - 가교결합된 폴리프로필렌 발포체 및 이로부터 제조된 라미네이트 - Google Patents
가교결합된 폴리프로필렌 발포체 및 이로부터 제조된 라미네이트 Download PDFInfo
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- KR101582119B1 KR101582119B1 KR1020137033455A KR20137033455A KR101582119B1 KR 101582119 B1 KR101582119 B1 KR 101582119B1 KR 1020137033455 A KR1020137033455 A KR 1020137033455A KR 20137033455 A KR20137033455 A KR 20137033455A KR 101582119 B1 KR101582119 B1 KR 101582119B1
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- South Korea
- Prior art keywords
- ethylene
- foam composition
- rubber
- styrene
- polypropylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- -1 polypropylene Polymers 0.000 title claims abstract description 93
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- 239000000203 mixture Substances 0.000 claims abstract description 127
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- 239000003795 chemical substances by application Substances 0.000 claims description 31
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- 238000010438 heat treatment Methods 0.000 claims description 18
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- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 14
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- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
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- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 10
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
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- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
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- LRZPQLZONWIQOJ-UHFFFAOYSA-N 10-(2-methylprop-2-enoyloxy)decyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCCCCCOC(=O)C(C)=C LRZPQLZONWIQOJ-UHFFFAOYSA-N 0.000 description 1
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- 239000010963 304 stainless steel Substances 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- SAPGBCWOQLHKKZ-UHFFFAOYSA-N 6-(2-methylprop-2-enoyloxy)hexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCOC(=O)C(C)=C SAPGBCWOQLHKKZ-UHFFFAOYSA-N 0.000 description 1
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 1
- YJVIKVWFGPLAFS-UHFFFAOYSA-N 9-(2-methylprop-2-enoyloxy)nonyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCCCCOC(=O)C(C)=C YJVIKVWFGPLAFS-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
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- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
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- 229910000589 SAE 304 stainless steel Inorganic materials 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2266/00—Composition of foam
- B32B2266/02—Organic
- B32B2266/0214—Materials belonging to B32B27/00
- B32B2266/025—Polyolefin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2400/00—Characterised by the use of unspecified polymers
- C08J2400/26—Elastomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24967—Absolute thicknesses specified
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249987—With nonvoid component of specified composition
- Y10T428/249991—Synthetic resin or natural rubbers
- Y10T428/249992—Linear or thermoplastic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Wrappers (AREA)
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161487092P | 2011-05-17 | 2011-05-17 | |
| US61/487,092 | 2011-05-17 | ||
| US201161508232P | 2011-07-15 | 2011-07-15 | |
| US61/508,232 | 2011-07-15 | ||
| US201161569422P | 2011-12-12 | 2011-12-12 | |
| US61/569,422 | 2011-12-12 | ||
| US13/339,928 US20120295086A1 (en) | 2011-05-17 | 2011-12-29 | Crosslinked polypropylene foam sheet for improved anchorage to tpo |
| US13/339,928 | 2011-12-29 | ||
| PCT/US2011/067842 WO2012158203A1 (en) | 2011-05-17 | 2011-12-29 | Crosslinked polypropylene foam and laminates made therefrom |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20140015544A KR20140015544A (ko) | 2014-02-06 |
| KR101582119B1 true KR101582119B1 (ko) | 2016-01-04 |
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| KR1020137033455A Active KR101582119B1 (ko) | 2011-05-17 | 2011-12-29 | 가교결합된 폴리프로필렌 발포체 및 이로부터 제조된 라미네이트 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20120295086A1 (https=) |
| EP (1) | EP2709845A1 (https=) |
| JP (2) | JP6174571B2 (https=) |
| KR (1) | KR101582119B1 (https=) |
| CN (1) | CN103648772B (https=) |
| MX (1) | MX2013013336A (https=) |
| WO (1) | WO2012158203A1 (https=) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6089809B2 (ja) * | 2013-03-11 | 2017-03-08 | 東レ株式会社 | 積層体、自動車内装材、及びインストルメントパネル |
| CN104610563A (zh) * | 2013-11-05 | 2015-05-13 | 晋江凯基高分子材料有限公司 | 一种烯烃嵌段共聚物材料发泡体的制备方法与应用 |
| US9878479B2 (en) | 2013-12-30 | 2018-01-30 | Toray Plastics (America), Inc. | Method to direct compound extruded structure for the production of irradiation crosslinked polypropylene foam |
| US9663958B2 (en) | 2013-12-31 | 2017-05-30 | Toray Plastics (America), Inc. | Methods of producing foam structures from recycled metallized polyolefin material |
| US9821533B2 (en) | 2014-12-30 | 2017-11-21 | Toray Plastics (America), Inc. | Coextruded, crosslinked multilayer polyolefin foam structures from recycled metallized polyolefin material and methods of making the same |
| US9669600B2 (en) | 2014-12-30 | 2017-06-06 | Toray Plastics (America), Inc. | Coextruded, crosslinked multilayer polyolefin foam structures from recycled polyolefin foam material and methods of making the same |
| US10384388B2 (en) | 2014-12-30 | 2019-08-20 | Toray Plastics (America), Inc. | Coextruded, crosslinked multilayer polyolefin foam structures and methods of making the same |
| DE102015220034A1 (de) | 2015-10-15 | 2017-04-20 | Benecke-Kaliko Ag | Folienlaminat und Innenverkleidungsteil für Kraftfahrzeuge |
| JP6696807B2 (ja) * | 2016-03-23 | 2020-05-20 | 積水化学工業株式会社 | 積層発泡シート、及びそれを用いた成形体 |
| US11738492B2 (en) * | 2016-03-31 | 2023-08-29 | Toray Plastics (America), Inc. | Methods of producing polyolefin foam sheets and articles made thereof |
| CN106380772B (zh) * | 2016-08-30 | 2019-01-22 | 贝内克-长顺汽车内饰材料（张家港）有限公司 | 基于sebs的环保型tpo汽车内饰材料及制备方法 |
| CN106380819B (zh) * | 2016-08-30 | 2019-03-15 | 贝内克-长顺汽车内饰材料（张家港）有限公司 | 应用于汽车内饰中的超软质热塑性弹性体材料 |
| CN106393890B (zh) * | 2016-08-30 | 2018-08-07 | 贝内克-长顺汽车内饰材料（张家港）有限公司 | 一种超软质环保型tpo汽车内饰材料及其制备方法 |
| CN106393896B (zh) * | 2016-08-30 | 2018-08-07 | 贝内克-长顺汽车内饰材料（张家港）有限公司 | 一种tpo-pp复合材料 |
| US11007761B2 (en) | 2017-03-31 | 2021-05-18 | Toray Plastics (America), Inc. | Method of making coextruded, cross-linked polyolefin foam with TPU cap layers |
| CN107177242B (zh) * | 2017-05-24 | 2020-04-10 | 贝内克-长顺汽车内饰材料（张家港）有限公司 | 耐醇的热塑性聚烯烃汽车内饰材料及其制备方法 |
| US10501598B2 (en) | 2017-06-29 | 2019-12-10 | Toray Plastics (America), Inc. | Method of making coextruded, crosslinked multilayer polyolefin foam structures from recycled crosslinked polyolefin foam material |
| CN111886162B (zh) * | 2018-03-13 | 2022-10-28 | 东洋纺株式会社 | 涂布的气囊用基布、其制造方法以及用于所述制造方法的涂料组合物 |
| KR102587649B1 (ko) * | 2018-09-20 | 2023-10-13 | 다우 글로벌 테크놀로지스 엘엘씨 | 가황 고무에 에틸렌계 중합체 폼을 부착시키기 위한 결합 방법 |
| US11590677B2 (en) | 2019-03-29 | 2023-02-28 | Toray Plastics (America), Inc. | Method of making coextruded, crosslinked polyolefin foam with KEE cap layers |
| US11590730B2 (en) | 2019-03-29 | 2023-02-28 | Toray Plastics (America), Inc. | Coextruded, crosslinked polyolefin foam with KEE cap layers |
| EP3766687B1 (en) * | 2019-07-15 | 2024-10-09 | TMG Tec Plast e outros Rev p/Ind Automóvel, SA | Composite structure for airbag cover |
| CN112094599B (zh) * | 2020-11-10 | 2021-02-26 | 苏州瑞高新材料有限公司 | 一种tpo内饰表皮及其制备方法 |
| JP7817527B2 (ja) * | 2021-12-24 | 2026-02-19 | キョーラク株式会社 | 発泡成形体の製造方法 |
| WO2023058525A1 (ja) * | 2021-10-04 | 2023-04-13 | キョーラク株式会社 | 発泡成形用樹脂及びその製造方法、発泡成形体の製造方法、構造体の製造方法 |
| CN119955216B (zh) * | 2025-04-11 | 2025-07-25 | 苏州瑞高新材料股份有限公司 | 一种用于气囊爆破的免弱化聚丙烯泡棉、制备方法、应用和层状蒙皮材料 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6221526A (ja) * | 1985-07-22 | 1987-01-29 | Sanwa Kako Kk | ポリオレフイン発泡体の製造方法 |
| US4803035A (en) * | 1985-12-16 | 1989-02-07 | Exxon Chemical Patents Inc. | Method for making composite films |
| JPH0684053B2 (ja) * | 1986-05-14 | 1994-10-26 | 東レ株式会社 | 発泡体と表皮材とからなる積層体の複合成形加工方法 |
| JPH01501540A (ja) * | 1986-12-15 | 1989-06-01 | エクソン・ケミカル・パテンツ・インク | 複合フィルムの製造方法 |
| JPS63309431A (ja) * | 1987-06-11 | 1988-12-16 | Tonen Sekiyukagaku Kk | 架橋ポリプロピレン発泡体の製造方法 |
| US5254402A (en) * | 1990-11-30 | 1993-10-19 | Toray Industries, Inc. | Molding laminate |
| IN189366B (https=) * | 1996-02-12 | 2003-02-15 | Mcneil Ppc Inc | |
| TWI247777B (en) * | 1998-10-30 | 2006-01-21 | Mitsui Chemicals Inc | Crosslinked olefin elastomer foam |
| CN1131277C (zh) * | 2000-10-11 | 2003-12-17 | 中国石油化工股份有限公司 | 一种辐照交联发泡聚丙烯材料及其制备方法 |
| US20080262116A1 (en) * | 2004-05-07 | 2008-10-23 | Simpson Scott S | Cross-Linked Polypropylene Resins, Method of Making Same, and Articles Formed Therefrom |
| JP4728735B2 (ja) * | 2004-08-04 | 2011-07-20 | 三井化学株式会社 | オレフィン系熱可塑性エラストマー組成物及びその発泡体 |
| EP1752485B1 (en) * | 2005-08-08 | 2008-10-08 | Alveo AG | Soft polyolefin foams with high heat resistance |
| JP5380864B2 (ja) * | 2007-03-23 | 2014-01-08 | 東レ株式会社 | 架橋ポリオレフィン系樹脂発泡体 |
| US9260577B2 (en) * | 2009-07-14 | 2016-02-16 | Toray Plastics (America), Inc. | Crosslinked polyolefin foam sheet with exceptional softness, haptics, moldability, thermal stability and shear strength |
-
2011
- 2011-12-29 US US13/339,928 patent/US20120295086A1/en not_active Abandoned
- 2011-12-29 WO PCT/US2011/067842 patent/WO2012158203A1/en not_active Ceased
- 2011-12-29 KR KR1020137033455A patent/KR101582119B1/ko active Active
- 2011-12-29 MX MX2013013336A patent/MX2013013336A/es unknown
- 2011-12-29 CN CN201180072288.8A patent/CN103648772B/zh active Active
- 2011-12-29 JP JP2014511337A patent/JP6174571B2/ja active Active
- 2011-12-29 EP EP11811289.5A patent/EP2709845A1/en not_active Ceased
-
2017
- 2017-04-14 JP JP2017080699A patent/JP2017170905A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| JP6174571B2 (ja) | 2017-08-02 |
| EP2709845A1 (en) | 2014-03-26 |
| KR20140015544A (ko) | 2014-02-06 |
| MX2013013336A (es) | 2014-06-11 |
| CN103648772B (zh) | 2016-02-03 |
| US20120295086A1 (en) | 2012-11-22 |
| JP2014518920A (ja) | 2014-08-07 |
| CN103648772A (zh) | 2014-03-19 |
| WO2012158203A1 (en) | 2012-11-22 |
| JP2017170905A (ja) | 2017-09-28 |
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