KR101577651B1 - 신규 카다놀 기반 유기 가황제, 이의 제조방법 및 이를 이용한 타이어용 고무배합 조성물 - Google Patents
신규 카다놀 기반 유기 가황제, 이의 제조방법 및 이를 이용한 타이어용 고무배합 조성물 Download PDFInfo
- Publication number
- KR101577651B1 KR101577651B1 KR1020140041658A KR20140041658A KR101577651B1 KR 101577651 B1 KR101577651 B1 KR 101577651B1 KR 1020140041658 A KR1020140041658 A KR 1020140041658A KR 20140041658 A KR20140041658 A KR 20140041658A KR 101577651 B1 KR101577651 B1 KR 101577651B1
- Authority
- KR
- South Korea
- Prior art keywords
- cardanol
- vulcanizing agent
- integer
- organic vulcanizing
- based organic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- JOLVYUIAMRUBRK-UHFFFAOYSA-N 11',12',14',15'-Tetradehydro(Z,Z-)-3-(8-Pentadecenyl)phenol Natural products OC1=CC=CC(CCCCCCCC=CCC=CCC=C)=C1 JOLVYUIAMRUBRK-UHFFFAOYSA-N 0.000 title claims abstract description 81
- YLKVIMNNMLKUGJ-UHFFFAOYSA-N 3-Delta8-pentadecenylphenol Natural products CCCCCCC=CCCCCCCCC1=CC=CC(O)=C1 YLKVIMNNMLKUGJ-UHFFFAOYSA-N 0.000 title claims abstract description 81
- JOLVYUIAMRUBRK-UTOQUPLUSA-N Cardanol Chemical compound OC1=CC=CC(CCCCCCC\C=C/C\C=C/CC=C)=C1 JOLVYUIAMRUBRK-UTOQUPLUSA-N 0.000 title claims abstract description 81
- FAYVLNWNMNHXGA-UHFFFAOYSA-N Cardanoldiene Natural products CCCC=CCC=CCCCCCCCC1=CC=CC(O)=C1 FAYVLNWNMNHXGA-UHFFFAOYSA-N 0.000 title claims abstract description 81
- PTFIPECGHSYQNR-UHFFFAOYSA-N cardanol Natural products CCCCCCCCCCCCCCCC1=CC=CC(O)=C1 PTFIPECGHSYQNR-UHFFFAOYSA-N 0.000 title claims abstract description 81
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 73
- 239000000203 mixture Substances 0.000 title claims abstract description 46
- 229920001971 elastomer Polymers 0.000 title claims abstract description 32
- 239000005060 rubber Substances 0.000 title claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 title claims description 13
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 55
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000011593 sulfur Substances 0.000 claims abstract description 47
- 244000226021 Anacardium occidentale Species 0.000 claims abstract description 25
- 235000020226 cashew nut Nutrition 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 24
- 239000000284 extract Substances 0.000 claims abstract description 22
- 238000010058 rubber compounding Methods 0.000 claims abstract description 21
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 24
- 239000000126 substance Substances 0.000 claims description 22
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 229910052739 hydrogen Inorganic materials 0.000 claims description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 239000002904 solvent Substances 0.000 claims description 13
- 239000000047 product Substances 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 239000006229 carbon black Substances 0.000 claims description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 6
- 239000012043 crude product Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 10
- 230000008569 process Effects 0.000 abstract description 4
- 230000006872 improvement Effects 0.000 abstract description 3
- 230000003466 anti-cipated effect Effects 0.000 abstract description 2
- 239000012467 final product Substances 0.000 abstract description 2
- 238000013040 rubber vulcanization Methods 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 22
- 230000000704 physical effect Effects 0.000 description 8
- 238000005481 NMR spectroscopy Methods 0.000 description 7
- 150000001993 dienes Chemical class 0.000 description 7
- 238000004073 vulcanization Methods 0.000 description 7
- 238000005096 rolling process Methods 0.000 description 6
- 150000005671 trienes Chemical class 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 4
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- OAUXSBFJNWOKFV-UHFFFAOYSA-N [C].OS(O)(=O)=O Chemical compound [C].OS(O)(=O)=O OAUXSBFJNWOKFV-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- -1 alkyl phenol Chemical compound 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 description 1
- 235000010261 calcium sulphite Nutrition 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 235000014571 nuts Nutrition 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 125000001741 organic sulfur group Chemical group 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/375—Thiols containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/10—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton
- C07C323/11—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
- C07C323/16—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/369,799 US20160130421A1 (en) | 2013-07-12 | 2014-04-15 | Novel cardanol-based organic vulcanizing agent, method for preparing the same, and rubber compound composition for tires using the same |
| PCT/KR2014/003236 WO2015005568A1 (ko) | 2013-07-12 | 2014-04-15 | 신규 카다놀 기반 유기 가황제, 이의 제조방법 및 이를 이용한 타이어용 고무배합 조성물 |
| CN201480000565.8A CN104520369A (zh) | 2013-07-12 | 2014-04-15 | 新的基于腰果酚的有机硫化剂、其制备方法及使用其的轮胎用橡胶复合组合物 |
| IN5833DEN2014 IN2014DN05833A (enExample) | 2013-07-12 | 2014-04-15 | |
| RU2014143726A RU2014143726A (ru) | 2013-07-12 | 2014-04-15 | Новый органический вулканизирующий агент на основе карданола, способ его получения и содержащая его каучуковая композиция для шин |
| JP2015526489A JP2015527348A (ja) | 2013-07-12 | 2014-04-15 | 新規のカルダノールベース有機加硫剤、その製造方法及びそれを用いたタイヤ用ゴム配合組成物 |
| EP14729571.1A EP3020756A4 (en) | 2013-07-12 | 2014-04-15 | Novel cardanol-based organic vulcanizing agent, production method for same and blended rubber composition for tyres using same |
| TW103123555A TW201502187A (zh) | 2013-07-12 | 2014-07-09 | 新穎腰果酚系有機硬化劑,其製備方法,及由其所製造之輪胎用橡膠複合組成物 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR20130082035 | 2013-07-12 | ||
| KR1020130082035 | 2013-07-12 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020150173975A Division KR20150143398A (ko) | 2013-07-12 | 2015-12-08 | 신규 카다놀 기반 유기 가황제, 이의 제조방법 및 이를 이용한 타이어용 고무배합 조성물 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20150007930A KR20150007930A (ko) | 2015-01-21 |
| KR101577651B1 true KR101577651B1 (ko) | 2015-12-17 |
Family
ID=52570707
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020140041658A Active KR101577651B1 (ko) | 2013-07-12 | 2014-04-08 | 신규 카다놀 기반 유기 가황제, 이의 제조방법 및 이를 이용한 타이어용 고무배합 조성물 |
| KR1020150173975A Ceased KR20150143398A (ko) | 2013-07-12 | 2015-12-08 | 신규 카다놀 기반 유기 가황제, 이의 제조방법 및 이를 이용한 타이어용 고무배합 조성물 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020150173975A Ceased KR20150143398A (ko) | 2013-07-12 | 2015-12-08 | 신규 카다놀 기반 유기 가황제, 이의 제조방법 및 이를 이용한 타이어용 고무배합 조성물 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20160130421A1 (enExample) |
| EP (1) | EP3020756A4 (enExample) |
| JP (1) | JP2015527348A (enExample) |
| KR (2) | KR101577651B1 (enExample) |
| CN (1) | CN104520369A (enExample) |
| IN (1) | IN2014DN05833A (enExample) |
| RU (1) | RU2014143726A (enExample) |
| TW (1) | TW201502187A (enExample) |
| WO (1) | WO2015005568A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105733021B (zh) * | 2016-03-09 | 2019-04-02 | 中胶橡胶资源再生(青岛)有限公司 | 一种橡胶再生活化剂及其制备方法 |
| CN108607528B (zh) * | 2018-05-08 | 2021-02-05 | 东北大学 | 一种硅藻土/硫化聚合物汞离子吸附材料及其制备方法 |
| EP3868737A4 (en) * | 2018-10-16 | 2022-10-05 | China Petroleum & Chemical Corporation | PHENOLIC DERIVATIVE, METHOD FOR PREPARATION AND USE |
| CN111057042B (zh) * | 2018-10-16 | 2022-12-13 | 中国石油化工股份有限公司 | 一种酚类衍生物及其制备方法、用途 |
| CN111057041B (zh) * | 2018-10-16 | 2022-12-13 | 中国石油化工股份有限公司 | 一种硫化酚酯类衍生物及其制备方法、用途 |
| CN113493718B (zh) * | 2020-03-18 | 2023-03-10 | 中国石油化工股份有限公司 | 一种船舶用中速筒状活塞式发动机润滑油组合物及其制备方法 |
| CN113430031B (zh) * | 2020-03-23 | 2023-03-10 | 中国石油化工股份有限公司 | 一种润滑脂及其制备方法 |
| KR102399217B1 (ko) * | 2020-07-13 | 2022-05-18 | 금호석유화학 주식회사 | 기능화 가공조제, 그의 제조방법 및 그를 포함하는 고무 조성물 |
| CN113321855B (zh) * | 2021-05-06 | 2022-05-20 | 北京化工大学 | 一种低生热高耐磨白炭黑/橡胶复合材料及其制备方法和应用 |
| KR102584286B1 (ko) * | 2021-09-13 | 2023-10-05 | 금호석유화학 주식회사 | 타이어 트레드용 고무 조성물 및 그 제조방법 |
| WO2025202882A1 (en) * | 2024-03-29 | 2025-10-02 | Tata Chemicals Limited | A novel coupling agent and a process for preparing it |
| WO2025202879A1 (en) * | 2024-03-29 | 2025-10-02 | Tata Chemicals Limited | A cardanol based coupling agent and a process for preparing it |
| CN119463313B (zh) * | 2024-10-12 | 2025-09-02 | 山东华盛橡胶有限公司 | 一种高抗湿滑、低噪音的电动汽车轮胎及其制备方法 |
| CN119775642B (zh) * | 2024-12-26 | 2025-08-08 | 扬州泽创鞋业有限公司 | 一种超耐磨防滑橡胶鞋底材料及其制备方法 |
| CN120535836A (zh) * | 2025-07-04 | 2025-08-26 | 东莞市烨晟塑料有限公司 | 一种pvc用耐热钙锌稳定剂及其制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5266620A (en) | 1991-10-08 | 1993-11-30 | The Yokohama Rubber Co., Ltd. | Rubber composition |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR0179712B1 (ko) * | 1995-12-29 | 1999-05-15 | 홍건희 | 타이어 비드 필러용 고무 조성물 |
| US5760114A (en) * | 1996-08-26 | 1998-06-02 | The Goodyear Tire & Rubber Company | Rubber compound containing aminobenzylamine |
| KR100237253B1 (ko) * | 1997-07-29 | 2000-01-15 | 홍건희 | 타이어 트레드용 고무 조성물 |
| DE10004427A1 (de) * | 2000-02-02 | 2001-10-04 | Martin Stielau | Verfahren zur Herstellung von Polyurethan |
| KR20030062174A (ko) * | 2002-01-16 | 2003-07-23 | 엘지전선 주식회사 | 고내구성 고무조성물 |
| US6828383B2 (en) * | 2002-12-13 | 2004-12-07 | Occidental Petroleum | Phenolic modified resorcinolic resins for rubber compounding |
| JP5478809B2 (ja) * | 2007-03-20 | 2014-04-23 | 東洋ゴム工業株式会社 | ゴム組成物及び空気入りタイヤ |
| KR100964308B1 (ko) * | 2008-04-25 | 2010-06-16 | 금호타이어 주식회사 | 타이어 고무조성물 |
| JP5382495B2 (ja) * | 2008-08-29 | 2014-01-08 | 住友ゴム工業株式会社 | ゴム組成物およびそれを用いた空気入りタイヤ |
-
2014
- 2014-04-08 KR KR1020140041658A patent/KR101577651B1/ko active Active
- 2014-04-15 RU RU2014143726A patent/RU2014143726A/ru unknown
- 2014-04-15 WO PCT/KR2014/003236 patent/WO2015005568A1/ko not_active Ceased
- 2014-04-15 CN CN201480000565.8A patent/CN104520369A/zh active Pending
- 2014-04-15 JP JP2015526489A patent/JP2015527348A/ja active Pending
- 2014-04-15 IN IN5833DEN2014 patent/IN2014DN05833A/en unknown
- 2014-04-15 US US14/369,799 patent/US20160130421A1/en not_active Abandoned
- 2014-04-15 EP EP14729571.1A patent/EP3020756A4/en not_active Withdrawn
- 2014-07-09 TW TW103123555A patent/TW201502187A/zh unknown
-
2015
- 2015-12-08 KR KR1020150173975A patent/KR20150143398A/ko not_active Ceased
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5266620A (en) | 1991-10-08 | 1993-11-30 | The Yokohama Rubber Co., Ltd. | Rubber composition |
Also Published As
| Publication number | Publication date |
|---|---|
| US20160130421A1 (en) | 2016-05-12 |
| CN104520369A (zh) | 2015-04-15 |
| IN2014DN05833A (enExample) | 2015-05-15 |
| KR20150007930A (ko) | 2015-01-21 |
| WO2015005568A1 (ko) | 2015-01-15 |
| EP3020756A1 (en) | 2016-05-18 |
| KR20150143398A (ko) | 2015-12-23 |
| JP2015527348A (ja) | 2015-09-17 |
| TW201502187A (zh) | 2015-01-16 |
| RU2014143726A (ru) | 2016-08-10 |
| EP3020756A4 (en) | 2017-04-12 |
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