KR101577643B1 - Perfume composition for expressing the fragrance of j smilax china l. - Google Patents

Abstract

The present invention relates to a perfume composition recreating the fragrance of juniper tree and a composition for external application for skin comprising the perfume composition.
The perfume composition according to the present invention can be applied to related fragrance products (fragrance, cosmetics, body lotion, etc.) utilizing the efficacy of juniper.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a perfume composition,

The present invention relates to a perfume composition recreating the fragrance of Liliaceae (Smilax china L.) and an external preparation for skin comprising the perfume composition.

Is a deciduous broad-leaved vine plant native to sunny climates of less than 1,600m in the south of central part of Korea. Persimmon leaves grow in a semi-shade or sunny place. The height of the persimmon tree is 2 ~ 3m, the leaf is 3 ~ 12㎝ in length, the width is 2 ~ 10㎝, it is glowing, the petiole is petiole, the petiole is 0.7 ~ 2㎝ in length and the stipule is tendril. The flower is yellowish green and runs on the axil, the length of the flower is 1.5 ~ 3㎝ and the length of the small root is 1㎝. The fruit is matured in red from September to October, and it is also called "Sensation" or "Sparkle" in circular form with a diameter of about 1㎝. Young leaves and fruit are used for edible purposes and rooted medicinal uses. It is effective against dermatitis (or chronic dermatitis) due to mercury poisoning due to the detoxification effect of persimmon leaves, and it is effective for aplastic arthritis, sclerosis, cold and neuralgia. It is also effective for nephritis and cystitis, and it has other functions such as heat, dehumidification and detoxification.

Korean Patent Laid-Open Publication No. KR 2011-0076043 relates to a cosmetic composition containing Cheongmyeongjinae extract as an active ingredient. However, the above patent is directed to a cosmetic composition using a persimmon extract to improve skin damage, and a perfume composition that reproduces the scent inherent to Persimmon leaves has not been developed until now.

Korea Patent Publication No. KR-2011-0076043

It is an object of the present invention to provide a fragrance composition recreating the fragrant persimmon fragrance containing the persimmon extract as an active ingredient.

Another object of the present invention is to provide a composition for external application for skin comprising the perfume composition.

The present invention relates to a flavor composition which reproduces the fragrance of persimmon leaves containing the persimmon extract as an active ingredient.

The present invention also relates to a composition for external application for skin comprising a perfume composition recreating the fragrance of the persimmon tree.

INDUSTRIAL APPLICABILITY The present invention can provide a perfume composition which can reproduce the intrinsic fragrance of the persimmon tree and exhibits excellent palatability and aroma effect. The perfume composition according to the present invention can be applied to related perfume products (perfume, cosmetics, body lotion, etc.) utilizing the efficacy of persimmon leaves.

Figure 1 relates to 10-20 International Standard Electrode Assembly.
FIG. 2 shows an example of brain wave changes before and after inhalation using the EEG brain mapping (3D brain mapping program).
FIG. 3 is a brain map showing changes in Absolute low beta before and after inhalation of Persimmon root extract.
Fig. 4 is a brain map showing Absolute theta change before and after inhalation of the perfume composition.
Fig. 5 is a brain map showing the relative beta changes before and after perfusion of the perfume composition.
FIG. 6 is a brain map showing relative high beta changes before and after inhalation of the perfume composition.

The present invention relates to a perfume composition capable of reproducing the fragrance of persimmon leaves.

More specifically, the present invention provides a flavor composition that reproduces the fragrance of persimmon leaves containing the persimmon extract as an active ingredient.

The Persimmon extract can be extracted from Persimmon root, but is not limited thereto.

The extract can be extracted by supercritical extraction, but is not limited thereto. The main components of the extract may be at least one selected from the group consisting of acetic acid, hexanoic acid, phenylethyl alcohol, vanillin, ethyl palmitate, palmitic acid, stearic acid, oleic acid and linoleic acid, And may include all of the above main components. The components of the above extract may be those extracted from Persimmon root.

The extract comprises 0.1 to 1.0 part by weight of acetic acid, 0.5 to 1.5 parts by weight of hexanoic acid, 0.05 to 1.0 part by weight of phenylethyl alcohol, 0.2 to 1.0 part by weight of vanillin, 0.2 to 1.0 part by weight of vanillin, 1.0 to 30 parts by weight of palmitic acid, 1.0 to 3.0 parts by weight of stearic acid, 5.0 to 10.0 parts by weight of oleic acid, and 10.0 to 40.0 parts by weight of linoleic acid.

The perfume composition may further comprise natural oils and synthetic raw materials. The natural oil is not a synthetic oil produced through a synthetic process, but natural oil or natural oil, but it may be a vegetable oil. In addition, the above-mentioned synthetic raw material is a raw material which is produced by processing a natural raw material by a chemical method. The natural oil and the synthetic raw material are not limited thereto as long as they are related to the persimmon scent.

That is, the perfume composition of the present invention may contain the extract extracted from Persimmon, the natural oil or the synthetic fuel for the extract, or the natural oil and synthetic fuel for the extract (for Persimmon combination).

More specifically, the natural oil may be at least one selected from the group consisting of immortelle oil, clove oil, petroleum oil, and carotene seed oil, but is not limited thereto. When the natural oil is used, an aroma effect can be exhibited. In one embodiment of the present invention, physiological / psychological effects by the aroma effect were measured.

The natural oil may contain 1.0 to 10.0 parts by weight of emmortellal oil, 5.0 to 15.0 parts by weight of clove oil, 1.0 to 5.0 parts by weight of vegetable oil, and 1.0 to 5.0 parts by weight of carotene seed oil, based on 100 parts by weight of the whole perfume composition have.

The synthetic raw materials may be selected from the group consisting of acetic acid, hexanoic acid, phenylethyl alcohol, 4-vinyl guaiacol, benzoic acid, 5-hydroxymethyl furfural, vanillin, palmatic acid, stearic acid, oleic acid, But are not limited to, one or more members selected from the group consisting of lactic acid,

Also, the synthetic raw material may contain 0.1-1.0 parts by weight of acetic acid, 0.1-1.0 parts by weight of hexanoic acid, 0.5-1.5 parts by weight of phenylethyl alcohol, 1.0-5.0 parts by weight of 4-vinylguaiacol, 0.1 to 1.0 part by weight of benzoic acid, 0.1 to 1.0 part by weight of 5-hydroxymethyl furfural, 0.1 to 1.0 part by weight of vanillin, 4.0 to 6.0 parts by weight of palmitic acid, 1.0 to 5.0 parts by weight of stearic acid, 1.0 to 5.0 parts by weight of an acicular acid, 10.0 to 20.0 parts by weight of linoleic acid, and 5.0 to 10.0 parts by weight of myralesinoid.

The present invention also relates to a composition for external application for skin comprising a perfume composition recreating the fragrance of the persimmon tree.

The composition for external application for skin may be formulated into perfume, cosmetics, body lotion and the like, and other components may be suitably selected and compounded in order to achieve the desired effect according to the conventional art.

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail with reference to the following examples. However, the following examples are intended to illustrate the contents of the present invention, but the scope of the present invention is not limited to the following examples. Embodiments of the present invention are provided to more fully describe the present invention to those skilled in the art.

Example  One. Persimmon tree  Root Dry  Preparation of extract

The dried persimmon leaves used in this study were purchased from Korean medicinal plants. The supernatant was removed from the supernatant by adding CO2 to the supernatant extractor (ILSHIN, Korea), and the supernatant was maintained for 1 hour. Due to the characteristics of the supercritical extraction method, temperature and pressure conditions are different for each sample, so temperature conditions and pressure conditions are changed for optimal extraction conditions. Extraction was carried out at a temperature of 70 ° C by fixing the plant sample at the pressure of 400 bar which is the most extraction pressure.

Example  2. Persimmon tree  Root Dry  Analysis of extracts

2-1. GC - MS  Analysis condition

The analysis conditions of GC-MS are shown in Table 1 below.

 Condition GC (Agilent 7890) -column: HP innowax column 30m x 0.25um x 250mm
-Oven temperature: 60 占 폚, 0 min? 3 占 폚 / min? 250 mm
-injector temp: 250 ° C MS (Agilent 5975) -ion source temp: 230 DEG C
-Quard temp: 150 DEG C
-mode: TIC mold

2-2. GC - MS  Analysis

The dried persimmon root extract was as shown in Table 2 below.

ingredient content(%) acetic acid 0.1 to 1.0 hexanoic acid 0.5 to 1. 5 phenylethyl alcohol 0.05 to 1.0 vanillin 0.2 to 1.0 Ethyl palmitate 0.2 to 1.0 Palmitic acid 10.0 to 30.0 stearic acid 1.0 to 3.0 oleic acid 5.0 to 10.0 linoleic acid 10.0 to 40.0 Other 100.00

As shown in Table 2, linoleic acid, palmitic acid, vanillin, ethyl palmitate, phenylethyl alcohol, and the like were added to the dried persimmon root extract, And some other acids (acid).

Example  3. Persimmon tree  Root Dry  A combination perfume composition for reproducing the fragrance of an extract

In order to obtain the natural fragrance of the dried persimmon root extract, the combined fragrance composition was prepared using the natural oils and the synthetic materials shown in Table 3 on the basis of the composition analysis of the dried persimmon root extract.

ingredient content(%) aetic acid 0.1 to 1.0 hexanoic acid 0.1 to 1.0 phenylethyl alcohol 0.5 to 1.5 4-vinyl guaiacol 1.0 to 5.0 benzoic acid 0.1 to 1.0 5-hydroxymethyl furfural 0.1 to 1.0 vanilline 0.1 to 1.0 palmitic acid 4.0 to 6.0 stearic acid 1.0 to 5.0 oleic acid 1.0 to 5.0 linoleic acid 10.0 to 20.0 Immortelle oil 1.0 to 10.0 Clove oil 5.0 to 15.0 myrrhe resinoid 5.0 to 10.0 patchouly oil 1.0 to 5.0 Carrot seed oil 1.0 to 5.0 Other 100.0

The combined fragrance composition is a fragrance combined with a synthetic raw material and natural oil which can reproduce the fragrance of the warm feeling and richness of the dried tree roots felt in the fragrance of the persimmon root root dry extract. The combined fragrance composition was very close to the fragrance of the dried persimmon root extract of natural image.

Example 4 Physiological / Psychological Effects of Dried Radish Root Extract and Combination Fragrance Composition

The effects of neurophysiological inhalation of dried persimmon root extract and combination fragrance composition on EEG were compared and analyzed.

4-1. Experiment environment

EEG was measured in 10 subjects (5 men and 5 women). The measurement site was a 32.4m2 laboratory with a constant temperature (23˚C) and humidity (50%). Were measured.

4-2. Brain wave device

The instrument used for EEG was the QEEG-8 System (LXE3208, LAXTHA Inc. Korea). EEG signals were measured using a data collection device and an analysis program (Telescan).

4-3. How to measure

Electroencephalogram electrodes: 10-20 International Standard Electrode Attachment method was used to attach EEG electrodes to EEG electrodes, which were attached to EEG electrodes, to the prefrontal, frontal, temporal, and parietal regions of the subjects. Respectively.

4-4. Experimental Method ( Incense suction )

The vial's essential oil was poured into the stomach paper (13 cm) and kept at a distance of about 3 cm from the nose of the subject. In the state where the subject closed the eyes, the subject was inspected 1 before the incense inhalation (unstimulated) (Samples with low recovery were inhaled into the vials).

4-5. Data Analysis

We measured only the EEG signal for 35 seconds during the 1 minute measurement, processed the data by batch processing, and applied the corresponding sample T using SPSS 18.0 version statistical analysis program.

The EEG brain mapping (3D brain mapping program) is used to show EEG changes during pre-inhalation and during inhalation.

The Value 7 color bar shown on the left side of FIG. 2 shows the mean data of the EEG signals measured before and after the incense suction, and shows different averages for EEG indicators (RMB, ALB, etc.). The higher the mean value of the EEG signals measured at Fp1, Fp2, F3, F4, T3, T4, P3 and P4, the higher the color is, and the lower the average value, the lower the color. For example, when alpha wave appeared at T3 position, blue color appeared before incense suction and purple color appeared during inhalation.

Example  5. Persimmon tree  EEG changes due to inhalation of root extract

5-1. AB Measurement of an indicator

Absolute low beta power spectrum (ALB) means absolute power spectral value of low beta wave region of 12 ~ 15Hz in EEG spectrum. The low beta wave is called sensory motor rhythm (SMR wave) and is predominant in performing a relatively simple task of paying attention while minimizing the activity of the motor cortex.

EEG showed a significant decrease in the right prefrontal cortex (Fp2) (p <0.05) (Table 4). These results indicate that the concentration of the beta-wave stimulated in the right frontal region (F4) was increased by the inhalation of the root extract. This suggests that the brain that has been awakened by the decrease of low beta wave induced in the right frontal region (F4) region by relaxation of the perfume perfume combination has decreased concentration. Table 4 below shows changes in low beta waves before and after inhalation of the fragrant root extract fragrance.

Absolute low beta power spectrum (ALB) Site Inhalation N Mean SD t-test p Fp1 Before 9 4.6414 2.46396 2.034 .076 during 9 3.9379 1.92625 Fp2 Before 9 4.0848 2.10469 3.266 .011 during 9 3.5759 2.09239 F3 Before 9 5.0823 2.79343 1.387 .203 during 9 4.7585 2.62840 F4 Before 9 4.3852 2.47984 1.500 .172 during 9 4.1006 2.15392 T3 Before 9 4.4917 2.13837 .059 .954 during 9 4.4709 2.15437 T4 Before 9 3.3975 3.07599 -1.282 .236 during 9 3.9500 4.13984 P3 Before 9 9.7432 7.21089 1.498 .172 during 9 8.3376 5.44910 P4 Before 9 7.9916 7.25423 1.589 .151 during 9 6.8076 5.39906

Fp1: Left prefrontal, Fp2: Right prefrontal

F3: Left frontal, F4: Right frontal

T3: Left temporal, T4: Right temporal,

P3: Left parietal, P4: Right parietal

These results were also confirmed by the brain map. As shown in FIG. 3, it was confirmed that the blue color changed to purple in the frontal region of the right frontal area of the inhalation state before inhalation of the fragrant root extract extract. These results indicate that the brain that has been awakened by the decrease of low beta waves induced in the right frontal region (F4) at the time of inhalation of Rhizoma root extract.

Example  6. Persimmon tree  Root combination fragrance composition EEG EEG changes

6-1. Absolute theta power spectrum value

Absolute theta power spectrum (AT) index means the absolute power spectrum value of theta wave region of 4 ~ 8Hz in EEG spectrum. It is mainly associated with somatic emotional and thought activities in a deeply internalized and silent state, or when sleepy.

(P <0.05) in the right frontal lobe (F4) among the electrode attachment sites (channels) (Table 5). These results indicate that the increase in theta wave induced in the right frontal region (F4) during the inhalation of the perfused perfused perfume leads to relaxation and stabilization of the brain arousal state. Table 5 below shows changes in the Absolute theta wave before and after inhalation of the perfume composition.

Absolute theta power spectrum (AT) Site Inhalation N Mean SD t-test p Fp1 Before 9 13.5213 5.7076 -2,233 .056 during 9 17.3501 7.4887 Fp2 Before 9 13.1363 6.7460 -2.198 .059 during 9 17.1491 9.0550 F3 Before 9 16.8298 7.4771 -2.051 .074 during 9 21.6864 10.7413 F4 Before 9 15.9689 7.1229 -2.400 .043 during 9 21.2724 11.4785 T3 Before 9 9.0038 5.0530 -1.632 .141 during 9 11.7534 6.6224 T4 Before 9 5.7161 1.9777 -1.167 .277 during 9 7.2424 5.1925 P3 Before 9 12.7876 6.8294 -2.193 .060 during 9 15.3231 8.6971 P4 Before 9 11.8829 7.0162 -1.282 .236 during 9 13.2608 7.9289

Fp1: Left prefrontal, Fp2: Right prefrontal

F3: Left frontal, F4: Right frontal

T3: Left temporal, T4: Right temporal,

P3: Left parietal, P4: Right parietal

These results could be confirmed by the brain map. As shown in FIG. 4, it was confirmed that the color changed from green to red in the prefrontal region of the perfume composition before inhalation and in the right frontal region of the inhalation state. This means that the increase in theta wave induced in the right frontal region (F4) in the inhalation of the perfused perfume of the persimmon leaves leads to relaxation of the awakening state of the brain.

6-2. Relative beta power spectrum value

The relative beta power spectrum (RB) index is the absolute power ratio of the beta band to the absolute power of the whole frequency region in the EEG spectrum, which is the spectrum value obtained by dividing the beta wave region of 13-30 Hz into the entire frequency region (4-50 Hz) do. It is activated when there is a mental activity such as appearing when doing general work, conscious action, or information processing.

(P <0.05) in the left temporal lobe (T3) of the electrode attachment sites (channels). These results indicate that the brain is relaxed by the decrease of beta wave induced in the left temporal lobe (T3) region when sucking perfume fragrance. Table 6 below shows the changes in relative beta waves before and after inhalation of the fragrance composition of the citrus root root combination.

Relative beta power spectrum (RB) Site Inhalation N Mean SD t-test p Fp1 Before 9 .2381 .0611 1.893 .095 during 9 .2102 .0586 Fp2 Before 9 .2174 .0670 1.248 .247 during 9 .2011 .0659 F3 Before 9 .2239 .0617 1.991 .082 during 9 .2026 .0624 F4 Before 9 .2040 .0586 1.176 .273 during 9 .1893 .0673 T3 Before 9 .3094 .1132 2.403 .043 during 9 .2734 .1025 T4 Before 9 .2966 .1105 .256 .804 during 9 .2926 .1151 P3 Before 9 .2702 .0794 1.106 .301 during 9 .2492 .0554 P4 Before 9 .2437 .0778 .202 .845 during 9 .2407 .0577

Fp1: Left prefrontal, Fp2: Right prefrontal

F3: Left frontal, F4: Right frontal

T3: Left temporal, T4: Right temporal,

P3: Left parietal, P4: Right parietal

These results were confirmed by the brain map. As shown in FIG. 5, it was confirmed that the color changes from red to yellow before the inhalation of the perfume composition perfume composition and the left temporal region of the inhalation state. This means that the brain is relaxed by the reduction of the beta wave induced in the left temporal lobe (T3) region when sucking the fragrant perfume.

6-3. Relative high beta power spectrum value

The relative high beta power spectrum (RHB) index is the absolute power ratio of the high beta band to the absolute power of the whole frequency region in the EEG spectrum. The absolute high power ratio is the spectral value divided by the whole frequency region (4-50 Hz) . The high beta wave is a relatively complex reasoning, or a brain wave prevailing in a state of high mental information processing activity, emotional tension, anxiety, and excitement.

(P <0.05) (Table 7). There was no significant difference between the two groups (P <0.05). These results indicate that relaxation of tension, anxiety, and excitement by relaxation of high beta waves induced in the left parietal lobe (P3) region during inhalation of the perfume composition of Rhododendron spp. Table 7 below shows the change in high beta waves before and after inhalation of the fragrance composition of Persimmon root root combination.

Relative high beta power spectrum (RHB) Site Inhalation N Mean SD t-test p Fp1 Before 9 .1196 .05607 1.991 .082 during 9 .1018 .04693 Fp2 Before 9 .1115 .05794 1.872 .098 during 9 .0965 .05253 F3 Before 9 .1024 .04779 1.440 .188 during 9 .0922 .04600 F4 Before 9 .0909 .04235 1.332 .220 during 9 .0812 .04270 T3 Before 9 .1523 .09568 1.950 .087 during 9 .1306 .08256 T4 Before 9 .1403 .07252 .715 .495 during 9 .1360 .07576 P3 Before 9 .0934 .02694 3.025 .016 during 9 .0845 .02767 P4 Before 9 .0890 .02765 2.292 .051 during 9 .0837 .03135

Fp1: Left prefrontal, Fp2: Right prefrontal

F3: Left frontal, F4: Right frontal

T3: Left temporal, T4: Right temporal,

P3: Left parietal, P4: Right parietal

These results could be confirmed by the brain map. As shown in FIG. 6, it was confirmed that the color changed from blue to purple on the left parietal region of the perfume composition before inhalation and inhalation. This suggests that relaxation of tension, anxiety, and excitement by relaxation of the high beta wave induced in the left parietal lobe (P3) area during inhalation of the fragrance composition of Persimmon spp.

[Manufacturing Example]

The fragrance composition as shown in Table 8 below was prepared by blending the fragrance composition having similarity to the fragrance of the fragrant root extract.

A perfume composition comprising a perfume composition recreating the fragrance of persimmon root Combination of fragrance reproduction reproduction 15 wt% Alcohol 80 wt% water 4 wt% Pigment Suitable amount Sunscreen Suitable amount

Claims (7)

The fragrance composition recreating the fragrance of the persimmon tree containing the persimmon extract as an active ingredient. The method according to claim 1,
The fragrance composition recreating the fragrance of the persimmon tree is characterized in that the extract is extracted from a root of persimmon leaves. The method according to claim 1,
The main component of the extract is at least one selected from the group consisting of acetic acid, hexanoic acid, phenylethyl alcohol, vanillin, ethyl palmitate, palmitic acid, stearic acid, oleic acid and linoleic acid. A perfume composition recreating the fragrance of persimmon leaves. The method according to claim 1,
Wherein the perfume composition further comprises a natural oil and a synthetic raw material. 5. The method of claim 4,
Wherein the natural oil is at least one selected from the group consisting of immortelle oil, clove oil, petroleum oil, and carrot seed oil. 5. The method of claim 4,
The synthetic raw material may be at least one selected from the group consisting of acetic acid, hexanoic acid, phenylethyl alcohol, 4-vinyl guaiacol, benzoic acid, 5-hydroxymethyl furfural, vanillin, palmitic acid, stearic acid, oleic acid, Wherein the flavor composition is at least one selected from the group consisting of citric acid, citric acid, citric acid, citric acid, citric acid, citric acid, citric acid, citric acid, citric acid, citric acid, citric acid and citric acid. A composition for external application for skin comprising the perfume composition according to any one of claims 1 to 6.

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