KR101520094B1 - 터릴렌 및 쿼터릴렌 유도체 - Google Patents
터릴렌 및 쿼터릴렌 유도체 Download PDFInfo
- Publication number
- KR101520094B1 KR101520094B1 KR1020077028349A KR20077028349A KR101520094B1 KR 101520094 B1 KR101520094 B1 KR 101520094B1 KR 1020077028349 A KR1020077028349 A KR 1020077028349A KR 20077028349 A KR20077028349 A KR 20077028349A KR 101520094 B1 KR101520094 B1 KR 101520094B1
- Authority
- KR
- South Korea
- Prior art keywords
- general formula
- rylene
- formula
- radicals
- radical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/06—Peri-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
- C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
- C07D493/06—Peri-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/207—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds
- C07C1/2078—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds by a transformation in which at least one -C(=O)-O- moiety is eliminated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D221/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom as the only ring hetero atom, not provided for by groups C07D211/00 - C07D219/00
- C07D221/02—Heterocyclic compounds containing six-membered rings having one nitrogen atom as the only ring hetero atom, not provided for by groups C07D211/00 - C07D219/00 condensed with carbocyclic rings or ring systems
- C07D221/04—Ortho- or peri-condensed ring systems
- C07D221/18—Ring systems of four or more rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/78—Ring systems having three or more relevant rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
- C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
- C07D491/06—Peri-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/025—Boronic and borinic acid compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B3/00—Dyes with an anthracene nucleus condensed with one or more carbocyclic rings
- C09B3/14—Perylene derivatives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B5/00—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings
- C09B5/62—Cyclic imides or amidines of peri-dicarboxylic acids of the anthracene, benzanthrene, or perylene series
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Other In-Based Heterocyclic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pyrane Compounds (AREA)
- Indole Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005021362.6 | 2005-05-04 | ||
| DE102005021362A DE102005021362A1 (de) | 2005-05-04 | 2005-05-04 | Terrylen- und Quaterrylenderivate |
| PCT/EP2006/062015 WO2006117383A1 (de) | 2005-05-04 | 2006-05-03 | Terrylen- und quaterrylenderivate |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020147018151A Division KR20140091075A (ko) | 2005-05-04 | 2006-05-03 | 터릴렌 및 쿼터릴렌 유도체 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20080016601A KR20080016601A (ko) | 2008-02-21 |
| KR101520094B1 true KR101520094B1 (ko) | 2015-05-18 |
Family
ID=36694085
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020077028349A Active KR101520094B1 (ko) | 2005-05-04 | 2006-05-03 | 터릴렌 및 쿼터릴렌 유도체 |
| KR1020147018151A Ceased KR20140091075A (ko) | 2005-05-04 | 2006-05-03 | 터릴렌 및 쿼터릴렌 유도체 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020147018151A Ceased KR20140091075A (ko) | 2005-05-04 | 2006-05-03 | 터릴렌 및 쿼터릴렌 유도체 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US7795431B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP1879847B1 (cg-RX-API-DMAC7.html) |
| JP (2) | JP5594960B2 (cg-RX-API-DMAC7.html) |
| KR (2) | KR101520094B1 (cg-RX-API-DMAC7.html) |
| CN (1) | CN101171222A (cg-RX-API-DMAC7.html) |
| DE (1) | DE102005021362A1 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2395512T3 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2006117383A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005021362A1 (de) * | 2005-05-04 | 2006-11-09 | Basf Ag | Terrylen- und Quaterrylenderivate |
| DE102005032583A1 (de) | 2005-07-11 | 2007-01-25 | Basf Ag | Substituierte Rylenderivate |
| DE102005037115A1 (de) | 2005-08-03 | 2007-02-08 | Basf Ag | Mehrfachchromophore |
| DE102005053995A1 (de) | 2005-11-10 | 2007-05-24 | Basf Ag | Verwendung von Rylenderivaten als Photosensibilisatoren in Solarzellen |
| DE102007004016A1 (de) | 2007-01-26 | 2008-07-31 | Langhals, Heinz, Prof. Dr. | Bichromophore Perylenabkömmlinge für Solarenergiesysteme |
| WO2009013258A1 (de) | 2007-07-23 | 2009-01-29 | Basf Se | Verwendung von rylenderivaten als aktive komponenten in solarzellen und photodetektoren |
| WO2009013282A1 (de) | 2007-07-23 | 2009-01-29 | Basf Se | Photovoltaische tandem-zelle |
| TWI408154B (zh) * | 2008-02-05 | 2013-09-11 | Basf Se | 萘-醯亞胺半導體聚合物 |
| CN104370815A (zh) | 2008-05-23 | 2015-02-25 | 巴斯夫欧洲公司 | 作为ir吸收剂的醌并苯二甲酰亚胺 |
| AR086509A1 (es) * | 2011-05-25 | 2013-12-18 | Sicpa Holding Sa | Tintes de quaterrileno y/o terrileno unidos a polimeros y composiciones que los contienen |
| KR20140099869A (ko) | 2011-11-23 | 2014-08-13 | 시크파 홀딩 에스에이 | S 원자 또는 s(=o)₂ 기를 함유한 폴리시클릭 방향족 화합물 및 염료로서 이들의 용도 |
| DE102012019495A1 (de) | 2012-10-02 | 2014-04-17 | Heinz Langhals | Fluoreszenzstandard für die wäßrige Phase |
| DE102012023247A1 (de) * | 2012-11-27 | 2014-06-26 | Ludwig-Maximilians-Universität München | Terrylen- und Quaterrylenfarbstoffe mit zu den Carbonylgruppen benachbarten Amino-Gruppen und ihre Verwendung in Grätzel-Solarzellen |
| US10319523B2 (en) | 2014-05-12 | 2019-06-11 | Capacitor Sciences Incorporated | Yanli dielectric materials and capacitor thereof |
| US10340082B2 (en) | 2015-05-12 | 2019-07-02 | Capacitor Sciences Incorporated | Capacitor and method of production thereof |
| US10347423B2 (en) | 2014-05-12 | 2019-07-09 | Capacitor Sciences Incorporated | Solid multilayer structure as semiproduct for meta-capacitor |
| US20170301477A1 (en) | 2016-04-04 | 2017-10-19 | Capacitor Sciences Incorporated | Electro-polarizable compound and capacitor |
| CN106575573B (zh) | 2014-05-12 | 2019-03-19 | 柯帕瑟特科学有限责任公司 | 能量储存器件及其制造方法 |
| US9941051B2 (en) | 2015-06-26 | 2018-04-10 | Capactor Sciences Incorporated | Coiled capacitor |
| US10600574B2 (en) | 2015-10-21 | 2020-03-24 | Capacitor Sciences Incorporated | Organic compound, crystal dielectric layer and capacitor |
| US10026553B2 (en) * | 2015-10-21 | 2018-07-17 | Capacitor Sciences Incorporated | Organic compound, crystal dielectric layer and capacitor |
| US10305295B2 (en) | 2016-02-12 | 2019-05-28 | Capacitor Sciences Incorporated | Energy storage cell, capacitive energy storage module, and capacitive energy storage system |
| US20170233528A1 (en) * | 2016-02-12 | 2017-08-17 | Capacitor Sciences Incorporated | Sharp polymer and capacitor |
| US10636575B2 (en) | 2016-02-12 | 2020-04-28 | Capacitor Sciences Incorporated | Furuta and para-Furuta polymer formulations and capacitors |
| US10153087B2 (en) | 2016-04-04 | 2018-12-11 | Capacitor Sciences Incorporated | Electro-polarizable compound and capacitor |
| US9978517B2 (en) | 2016-04-04 | 2018-05-22 | Capacitor Sciences Incorporated | Electro-polarizable compound and capacitor |
| US10566138B2 (en) | 2016-04-04 | 2020-02-18 | Capacitor Sciences Incorporated | Hein electro-polarizable compound and capacitor thereof |
| WO2018065502A1 (en) | 2016-10-06 | 2018-04-12 | Basf Se | 2-phenylphenoxy-substituted perylene bisimide compounds and their use |
| KR102718070B1 (ko) * | 2017-12-19 | 2024-10-17 | 바스프 에스이 | 시아노아릴 치환된 벤즈(오티)오크산텐 화합물 |
| CN109705648B (zh) * | 2018-12-25 | 2021-09-24 | 上海甘田光学材料有限公司 | 一种新型含氟萘酯类成膜助剂在变色涂料中的应用 |
| EP3816238B9 (en) | 2019-11-04 | 2023-06-21 | Textilchemie Dr. Petry Gmbh | Polyparaperylene derivatives and methods for making same |
| JP2022126586A (ja) * | 2021-02-18 | 2022-08-30 | 住友化学株式会社 | 着色樹脂組成物 |
| CN118369312A (zh) * | 2021-12-09 | 2024-07-19 | 巴斯夫欧洲公司 | 三萘嵌二苯二酰亚胺和四萘嵌三苯二酰亚胺着色剂 |
| CN114539019B (zh) * | 2022-03-01 | 2023-11-28 | 苏州大学张家港工业技术研究院 | 一种基于卤盐替代卤素单质的光诱导连续合成卤代化合物的方法 |
| AR132345A1 (es) | 2023-04-13 | 2025-06-18 | Sicpa Holding Sa | Tintas de seguridad y características de seguridad legibles por máquina |
| CN118359635A (zh) * | 2024-04-17 | 2024-07-19 | 天津大学 | 一类基于三萘嵌二苯二酰亚胺结构的小分子化合物、聚合物、制备方法及应用 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11502546A (ja) * | 1995-01-20 | 1999-03-02 | ビーエーエスエフ アクチェンゲゼルシャフト | 置換クァテルリレンテトラカルボン酸ジイミド |
| KR20030075200A (ko) * | 2001-02-20 | 2003-09-22 | 바스프 악티엔게젤샤프트 | 릴렌 유도체 및 염료로서 그것의 용도 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4236885A1 (de) | 1992-10-31 | 1994-05-05 | Basf Ag | Quaterrylentetracarbonsäureimide |
| EP0638613B1 (de) | 1993-08-13 | 1998-12-23 | Ciba SC Holding AG | Perylenamidinimid-Farbstoffe, ein Verfahren zu deren Herstellung und deren Verwendung |
| ATE298754T1 (de) * | 2001-03-23 | 2005-07-15 | Basf Ag | Tert.-alkylphenoxysubstituierte polycyclische verbindungen |
| DE10225595A1 (de) * | 2002-06-07 | 2003-12-18 | Basf Ag | 1,6,9,14-Tetrasubstituierte Terrylentetracarbonsäurediimide |
| DE102005021362A1 (de) * | 2005-05-04 | 2006-11-09 | Basf Ag | Terrylen- und Quaterrylenderivate |
| DE102005032583A1 (de) * | 2005-07-11 | 2007-01-25 | Basf Ag | Substituierte Rylenderivate |
| DE102005053995A1 (de) * | 2005-11-10 | 2007-05-24 | Basf Ag | Verwendung von Rylenderivaten als Photosensibilisatoren in Solarzellen |
-
2005
- 2005-05-04 DE DE102005021362A patent/DE102005021362A1/de not_active Withdrawn
-
2006
- 2006-05-03 KR KR1020077028349A patent/KR101520094B1/ko active Active
- 2006-05-03 CN CNA2006800151556A patent/CN101171222A/zh active Pending
- 2006-05-03 WO PCT/EP2006/062015 patent/WO2006117383A1/de not_active Ceased
- 2006-05-03 JP JP2008509445A patent/JP5594960B2/ja active Active
- 2006-05-03 EP EP06754981A patent/EP1879847B1/de active Active
- 2006-05-03 ES ES06754981T patent/ES2395512T3/es active Active
- 2006-05-03 KR KR1020147018151A patent/KR20140091075A/ko not_active Ceased
- 2006-05-03 US US11/913,333 patent/US7795431B2/en active Active
-
2010
- 2010-08-03 US US12/849,079 patent/US8569500B2/en active Active
-
2013
- 2013-02-12 JP JP2013024995A patent/JP2013136606A/ja not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11502546A (ja) * | 1995-01-20 | 1999-03-02 | ビーエーエスエフ アクチェンゲゼルシャフト | 置換クァテルリレンテトラカルボン酸ジイミド |
| KR20030075200A (ko) * | 2001-02-20 | 2003-09-22 | 바스프 악티엔게젤샤프트 | 릴렌 유도체 및 염료로서 그것의 용도 |
Non-Patent Citations (2)
| Title |
|---|
| Quante H. et al., Angewandte Chemie International Edition, Vol.34(12), pages 1323-1325(1995년 공개). * |
| Quante H. et al., Angewandte Chemie International Edition, Vol.34(12), pages 1323-1325(1995년 공개).* |
Also Published As
| Publication number | Publication date |
|---|---|
| US7795431B2 (en) | 2010-09-14 |
| US8569500B2 (en) | 2013-10-29 |
| EP1879847A1 (de) | 2008-01-23 |
| JP5594960B2 (ja) | 2014-09-24 |
| DE102005021362A1 (de) | 2006-11-09 |
| US20080255357A1 (en) | 2008-10-16 |
| EP1879847B1 (de) | 2012-09-12 |
| ES2395512T3 (es) | 2013-02-13 |
| KR20140091075A (ko) | 2014-07-18 |
| WO2006117383A1 (de) | 2006-11-09 |
| JP2013136606A (ja) | 2013-07-11 |
| KR20080016601A (ko) | 2008-02-21 |
| US20100317876A1 (en) | 2010-12-16 |
| CN101171222A (zh) | 2008-04-30 |
| JP2008540382A (ja) | 2008-11-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101520094B1 (ko) | 터릴렌 및 쿼터릴렌 유도체 | |
| KR101437691B1 (ko) | 헥사릴렌 및 펜타릴렌 테트라카르복실산 디이미드 | |
| US8202994B2 (en) | Pentarylene- and hexarylenetetracarboximides and preparation thereof | |
| JP5511743B2 (ja) | クアテリレン−3,4:13,14−テトラカルボン酸ジイミドの直接合成を介した製造方法 | |
| US8052899B2 (en) | Heptarylene-and octarylenetetracarboximides and preparation thereof | |
| US8501948B2 (en) | Multiple chromophores based on rylene | |
| US20070155968A1 (en) | Method for the production of terylene-3,4:11,12-tetracarboxydiimides by direct synthesis | |
| US8399669B2 (en) | Tri- and tetrasubstituted pentarylenetetracarboximides |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
Patent event date: 20071204 Patent event code: PA01051R01D Comment text: International Patent Application |
|
| PG1501 | Laying open of application | ||
| A201 | Request for examination | ||
| PA0201 | Request for examination |
Patent event code: PA02012R01D Patent event date: 20110503 Comment text: Request for Examination of Application |
|
| E902 | Notification of reason for refusal | ||
| PE0902 | Notice of grounds for rejection |
Comment text: Notification of reason for refusal Patent event date: 20130228 Patent event code: PE09021S01D |
|
| E601 | Decision to refuse application | ||
| PE0601 | Decision on rejection of patent |
Patent event date: 20140227 Comment text: Decision to Refuse Application Patent event code: PE06012S01D Patent event date: 20130228 Comment text: Notification of reason for refusal Patent event code: PE06011S01I |
|
| J201 | Request for trial against refusal decision | ||
| PJ0201 | Trial against decision of rejection |
Patent event date: 20140530 Comment text: Request for Trial against Decision on Refusal Patent event code: PJ02012R01D Patent event date: 20140227 Comment text: Decision to Refuse Application Patent event code: PJ02011S01I Appeal kind category: Appeal against decision to decline refusal Appeal identifier: 2014101003302 Request date: 20140530 |
|
| A107 | Divisional application of patent | ||
| PA0104 | Divisional application for international application |
Comment text: Divisional Application for International Patent Patent event code: PA01041R01D Patent event date: 20140630 |
|
| J301 | Trial decision |
Free format text: TRIAL DECISION FOR APPEAL AGAINST DECISION TO DECLINE REFUSAL REQUESTED 20140530 Effective date: 20150227 |
|
| PJ1301 | Trial decision |
Patent event code: PJ13011S01D Patent event date: 20150227 Comment text: Trial Decision on Objection to Decision on Refusal Appeal kind category: Appeal against decision to decline refusal Request date: 20140530 Decision date: 20150227 Appeal identifier: 2014101003302 |
|
| PS0901 | Examination by remand of revocation | ||
| S901 | Examination by remand of revocation | ||
| GRNO | Decision to grant (after opposition) | ||
| PS0701 | Decision of registration after remand of revocation |
Patent event date: 20150320 Patent event code: PS07012S01D Comment text: Decision to Grant Registration Patent event date: 20150302 Patent event code: PS07011S01I Comment text: Notice of Trial Decision (Remand of Revocation) |
|
| GRNT | Written decision to grant | ||
| PR0701 | Registration of establishment |
Comment text: Registration of Establishment Patent event date: 20150507 Patent event code: PR07011E01D |
|
| PR1002 | Payment of registration fee |
Payment date: 20150507 End annual number: 3 Start annual number: 1 |
|
| PG1601 | Publication of registration | ||
| FPAY | Annual fee payment |
Payment date: 20180418 Year of fee payment: 4 |
|
| PR1001 | Payment of annual fee |
Payment date: 20180418 Start annual number: 4 End annual number: 4 |
|
| FPAY | Annual fee payment |
Payment date: 20190905 Year of fee payment: 5 |
|
| PR1001 | Payment of annual fee |
Payment date: 20190905 Start annual number: 5 End annual number: 5 |
|
| PR1001 | Payment of annual fee |
Payment date: 20200421 Start annual number: 6 End annual number: 6 |
|
| PR1001 | Payment of annual fee |
Payment date: 20210420 Start annual number: 7 End annual number: 7 |
|
| PR1001 | Payment of annual fee |
Payment date: 20240424 Start annual number: 10 End annual number: 10 |