KR101389255B1 - 1,4-사이클로헥산다이메탄올을 함유하는 폴리에스터의 제조방법 - Google Patents
1,4-사이클로헥산다이메탄올을 함유하는 폴리에스터의 제조방법 Download PDFInfo
- Publication number
- KR101389255B1 KR101389255B1 KR1020087026292A KR20087026292A KR101389255B1 KR 101389255 B1 KR101389255 B1 KR 101389255B1 KR 1020087026292 A KR1020087026292 A KR 1020087026292A KR 20087026292 A KR20087026292 A KR 20087026292A KR 101389255 B1 KR101389255 B1 KR 101389255B1
- Authority
- KR
- South Korea
- Prior art keywords
- diol
- component
- diacid
- total
- polyester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/414,466 | 2006-04-28 | ||
| US11/414,466 US7211634B1 (en) | 2006-04-28 | 2006-04-28 | Process for the preparation of polyesters containing 1,4-cyclohexanedimethanol |
| PCT/US2007/009484 WO2007127117A2 (en) | 2006-04-28 | 2007-04-18 | Process for the preparation of polyesters containing 1,4-cyclohexanedimethanol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20080112341A KR20080112341A (ko) | 2008-12-24 |
| KR101389255B1 true KR101389255B1 (ko) | 2014-04-24 |
Family
ID=37991420
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020087026292A Expired - Fee Related KR101389255B1 (ko) | 2006-04-28 | 2007-04-18 | 1,4-사이클로헥산다이메탄올을 함유하는 폴리에스터의 제조방법 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US7211634B1 (https=) |
| EP (1) | EP2013260B1 (https=) |
| JP (1) | JP5689599B2 (https=) |
| KR (1) | KR101389255B1 (https=) |
| CN (1) | CN101466760B (https=) |
| WO (1) | WO2007127117A2 (https=) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8586701B2 (en) | 2005-10-28 | 2013-11-19 | Eastman Chemical Company | Process for the preparation of copolyesters based on 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| JP5635411B2 (ja) | 2007-11-21 | 2014-12-03 | イーストマン ケミカル カンパニー | プラスチック製哺乳瓶、他のブロー成形物品及びそれらの製造方法 |
| KR101837793B1 (ko) * | 2010-10-13 | 2018-03-12 | 데이진 가부시키가이샤 | 전선 피복용 수지 조성물 및 그것을 사용한 절연 전선 |
| US20130029068A1 (en) * | 2011-07-28 | 2013-01-31 | Eastman Chemical Company | Extrusion blow molded articles |
| RU2480486C1 (ru) * | 2011-12-16 | 2013-04-27 | Учреждение Российской академии наук Институт катализа им. Г.К. Борескова Сибирского отделения РАН | Способ получения алифатических и алифатически-ароматических полиэфиров |
| KR20140018468A (ko) * | 2012-07-30 | 2014-02-13 | 삼성정밀화학 주식회사 | 방향족 디카르복실산 화합물의 분할 투입에 의한 생분해성 폴리에스테르 공중합체의 제조방법 |
| US10465335B2 (en) | 2015-09-04 | 2019-11-05 | Dic Corporation | Polyester resin, method for producing polyester resin, resin composition, resin-clad fabric, and method for producing resin-clad fabric |
| IT201600078950A1 (it) * | 2016-07-27 | 2018-01-27 | Versalis Spa | Metodo di sintesi regioselettiva di poliesteri da dioli asimmetrici. |
| WO2020131778A1 (en) * | 2018-12-17 | 2020-06-25 | Eastman Chemical Company | Copolyester from terephthalic acid containing low diethylene glycol |
| JP7697369B2 (ja) * | 2020-04-15 | 2025-06-24 | 東洋紡株式会社 | 共重合ポリエステル樹脂、成形品、熱収縮性フィルム、及び繊維 |
| TWI803384B (zh) * | 2022-07-08 | 2023-05-21 | 南亞塑膠工業股份有限公司 | 透明pet材料及其製造方法以及pet產品 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002037870A (ja) | 2000-07-25 | 2002-02-06 | Toagosei Co Ltd | 共重合ポリエステルの製造方法 |
| JP2004517991A (ja) | 2001-01-22 | 2004-06-17 | イーストマン ケミカル カンパニー | 1,4−シクロヘキサンジメタノール及びイソフタル酸に基づくポリエステルの製造方法 |
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| BE592181A (https=) | 1955-12-22 | |||
| US3070575A (en) | 1958-01-27 | 1962-12-25 | Du Pont | Process for the preparation of polyesters from dicarboxylic acids and bis (hydroxy-alkyl) esters |
| US3271370A (en) | 1961-11-10 | 1966-09-06 | Poly(l,x-cyclohexylenedimethylene ter- ephthalate) process using substantial- ly equal proportions of reactants | |
| AT289391B (de) | 1966-12-30 | 1971-04-26 | Alpine Chemische Ag | Verfahren zur Herstellung von Polyestern und Copolyestern |
| US3487049A (en) | 1967-01-04 | 1969-12-30 | Du Pont | Process for producing polyethylene terephthalate |
| US4020049A (en) | 1967-09-14 | 1977-04-26 | The Goodyear Tire & Rubber Company | Process for preparing polyester resin |
| US3551386A (en) | 1968-06-26 | 1970-12-29 | Monsanto Co | Polyester polymerization process,prepolymer and product |
| US3787370A (en) | 1971-03-19 | 1974-01-22 | Teijin Ltd | Process for the preparation of substan-tially linear polyesters of low free carboxyl group content |
| US3984379A (en) | 1971-12-06 | 1976-10-05 | Teijin Limited | Process for preparation of polyesters |
| JPS49117378A (https=) | 1973-03-13 | 1974-11-09 | ||
| JPS539278B2 (https=) * | 1973-06-07 | 1978-04-04 | ||
| US4205157A (en) | 1979-04-02 | 1980-05-27 | The Goodyear Tire & Rubber Company | Method for production of high molecular weight polyester with low catalyst level and low carboxyl content |
| US4238593B1 (en) | 1979-06-12 | 1994-03-22 | Goodyear Tire & Rubber | Method for production of a high molecular weight polyester prepared from a prepolymer polyester having an optional carboxyl content |
| US4442269A (en) | 1982-12-15 | 1984-04-10 | E. I. Du Pont De Nemours & Company | Staged copolymerization of polyesters |
| US4480086A (en) * | 1983-09-09 | 1984-10-30 | Eastman Kodak Company | Radiation-resistant copolyesters |
| US4578453A (en) * | 1984-11-23 | 1986-03-25 | Eastman Kodak Company | High molecular weight polyesters |
| US5039717A (en) | 1985-07-25 | 1991-08-13 | Amoco Corporation | Copolyesters |
| US5239018A (en) | 1989-09-06 | 1993-08-24 | Exxon Chemical Patents Inc. | Liquid polymer and polyol compositions, and process for preparing phenol-functional polymer |
| US5034263A (en) * | 1989-11-27 | 1991-07-23 | Eastman Kodak Company | Film laminate |
| US4983711A (en) | 1989-12-04 | 1991-01-08 | Eastman Kodak Company | Copolyesters and articles extrusion blow-molded therefrom |
| DE4137841C2 (de) | 1991-11-16 | 2003-08-28 | Zimmer Ag | Diskontinuierliches Verfahren zur Polykondensation von Terephthalsäure und 1,4-Bis-(hydroxymethyl)-cyclohexan |
| DE4137842A1 (de) * | 1991-11-16 | 1993-05-19 | Zimmer Ag | Verfahren zur kontinuierlichen polykondensation von terephthalsaeure und 1,4-bis-(hydroxymethyl)-cyclohexan |
| US5385773A (en) | 1993-04-27 | 1995-01-31 | Eastman Chemical Company | Copolyester of cyclohexanenedimethanol and process for producing such polyester |
| US5340907A (en) | 1993-06-28 | 1994-08-23 | Eastman Chemical Company | Copolyester of cyclohexanedimethanol and process for producing such polyester |
| US5616404A (en) * | 1995-10-10 | 1997-04-01 | Eastman Chemical Company | Orientable, heat setable semi-crystalline copolyesters |
| US5608031A (en) * | 1995-11-30 | 1997-03-04 | Eastman Chemical Company | Polyesters modified with 1,4-cyclohexaned imethanol having high clarity prepared utilizing an antimony containing catalyst/stabilizer system |
| TW381104B (en) | 1996-02-20 | 2000-02-01 | Eastman Chem Co | Process for preparing copolyesters of terephthalic acid, ethylene glycol, and 1,4-cyclohexanedimethanol |
| US5656715A (en) * | 1996-06-26 | 1997-08-12 | Eastman Chemical Company | Copolyesters based on 1,4-cyclohexanedimethanol having improved stability |
| US6103859A (en) * | 1997-04-09 | 2000-08-15 | Eastman Chemical Company | Late addition of supplemental ethylene glycol in the preparation of copolyesters |
| CN1146679C (zh) * | 1997-08-28 | 2004-04-21 | 伊斯曼化学公司 | 改良的共聚物粘合纤维 |
| US5986040A (en) | 1998-09-03 | 1999-11-16 | General Electric Company | Crystalline polyester resins and process for their preparation |
| JP3693831B2 (ja) | 1998-12-18 | 2005-09-14 | 三菱化学株式会社 | ポリシクロヘキサンジメチレンテレフタレートの製造方法 |
| JP3696741B2 (ja) | 1998-12-18 | 2005-09-21 | 三菱化学株式会社 | ポリシクロヘキサンジメチレンテレフタレート |
| IT1304797B1 (it) | 1998-12-23 | 2001-03-29 | Sinco Ricerche Spa | Procedimento per la preparazione di resine poliestere (mg33). |
| US6084055A (en) | 1999-03-30 | 2000-07-04 | General Electric Company | Method for preparing poly(1,4-cyclohexanedicarboxylates) |
| DE60028342T2 (de) | 1999-10-19 | 2007-05-24 | Aies Co., Ltd. | Verfahren zur polymerisation von deionisiertem bis-beta-hydroxyethylterephthalat |
| KR100366483B1 (ko) | 1999-12-17 | 2003-01-14 | 주식회사 이래화학 | 코폴리에스테르 수지 조성물 및 그 제조방법 |
| TWI235754B (en) | 1999-12-27 | 2005-07-11 | Ind Tech Res Inst | Composition and process for preparing a high molecular weight polyester |
| JP3209336B1 (ja) * | 2000-05-17 | 2001-09-17 | エスケー ケミカルズ カンパニー リミテッド | 1,4−シクロヘキサンジメタノールが共重合されたポリエステル樹脂の製造方法 |
| BR0113999A (pt) | 2000-09-21 | 2003-08-12 | Rohm & Haas | Processo para preparar uma dispersão polimérica aquosa nanocompósita de argila, dispersão nanocompósita aquosa, espessador, dispersante, aglutinante, composição de tinta flexográfica, verniz de sobre impressão, modificador de pó de cimento seco, semente polimérica nanocompósita de argila, composição polimérica nanocompósita de argila, e, método para preparar uma pluralidade de partìculas poliméricas nanocompósitas de argila ocas |
| US6458915B1 (en) | 2000-10-13 | 2002-10-01 | Eastman Chemical Company | Process for producing poly(1,4-cyclohexylenedimethylene 1,4-cyclohexanedicarboxylate) and the reactor grade polyester therefrom |
| US6455664B1 (en) | 2000-11-20 | 2002-09-24 | General Electric Company | Crystalline polyester resins and process for their preparation |
| US6740377B2 (en) * | 2001-09-14 | 2004-05-25 | Eastman Chemical Company | Polyester having improved crystallization behavior and extrusion blow molded articles made therefrom |
| ITMI20021293A1 (it) | 2002-06-12 | 2003-12-12 | Gen Electric | Metodo per preparare poli(cicloesan-1,4-dicarbossilato) (i) da acido cicloesan-1,4-bicarbossilico e composizione |
| US6828410B2 (en) | 2002-07-10 | 2004-12-07 | General Electric Company | Method for preparing poly(cyclohexane-1,4-dicarboxylate)s from cyclohexane-1,4-dicarboxylic acid, and composition |
| US6924349B2 (en) * | 2003-06-23 | 2005-08-02 | Sk Chemicals Co., Ltd. | Copolyester resin and articles using the same |
-
2006
- 2006-04-28 US US11/414,466 patent/US7211634B1/en not_active Expired - Lifetime
-
2007
- 2007-02-20 US US11/708,244 patent/US20070255020A1/en not_active Abandoned
- 2007-04-18 EP EP07775690.6A patent/EP2013260B1/en not_active Not-in-force
- 2007-04-18 KR KR1020087026292A patent/KR101389255B1/ko not_active Expired - Fee Related
- 2007-04-18 JP JP2009507729A patent/JP5689599B2/ja not_active Expired - Fee Related
- 2007-04-18 CN CN200780021818XA patent/CN101466760B/zh not_active Expired - Fee Related
- 2007-04-18 WO PCT/US2007/009484 patent/WO2007127117A2/en not_active Ceased
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002037870A (ja) | 2000-07-25 | 2002-02-06 | Toagosei Co Ltd | 共重合ポリエステルの製造方法 |
| JP2004517991A (ja) | 2001-01-22 | 2004-06-17 | イーストマン ケミカル カンパニー | 1,4−シクロヘキサンジメタノール及びイソフタル酸に基づくポリエステルの製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5689599B2 (ja) | 2015-03-25 |
| WO2007127117A3 (en) | 2008-02-07 |
| US7211634B1 (en) | 2007-05-01 |
| EP2013260B1 (en) | 2016-04-06 |
| CN101466760A (zh) | 2009-06-24 |
| JP2009535450A (ja) | 2009-10-01 |
| KR20080112341A (ko) | 2008-12-24 |
| EP2013260A2 (en) | 2009-01-14 |
| WO2007127117A2 (en) | 2007-11-08 |
| US20070255020A1 (en) | 2007-11-01 |
| CN101466760B (zh) | 2012-07-18 |
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