KR101353850B1 - 이산화티타늄 나노입자상 수분산액 제조 방법 및 그방법으로 수득할 수 있는 분산액 - Google Patents
이산화티타늄 나노입자상 수분산액 제조 방법 및 그방법으로 수득할 수 있는 분산액 Download PDFInfo
- Publication number
- KR101353850B1 KR101353850B1 KR1020087019004A KR20087019004A KR101353850B1 KR 101353850 B1 KR101353850 B1 KR 101353850B1 KR 1020087019004 A KR1020087019004 A KR 1020087019004A KR 20087019004 A KR20087019004 A KR 20087019004A KR 101353850 B1 KR101353850 B1 KR 101353850B1
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- South Korea
- Prior art keywords
- titanium
- dispersion
- titanium dioxide
- delete delete
- alkoxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
- C01G23/053—Producing by wet processes, e.g. hydrolysing titanium salts
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/245—Oxides by deposition from the vapour phase
- C03C17/2456—Coating containing TiO2
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/25—Oxides by deposition from the liquid phase
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3669—Treatment with low-molecular organic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
- C01P2002/54—Solid solutions containing elements as dopants one element only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/90—Other properties not specified above
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/212—TiO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/71—Photocatalytic coatings
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nanotechnology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Composite Materials (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Colloid Chemistry (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITFI2006A000030 | 2006-02-01 | ||
| IT000030A ITFI20060030A1 (it) | 2006-02-01 | 2006-02-01 | Processo per la preparazione di dispersioni acquose di ti02 in forma nanoparticelle e dispersioni ottenibili con questo processo |
| PCT/EP2007/050826 WO2007088151A1 (en) | 2006-02-01 | 2007-01-29 | Method for the preparation of aqueous dispersions of tio2 in the form of nanoparticles, and dispersions obtainable with this method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20080094675A KR20080094675A (ko) | 2008-10-23 |
| KR101353850B1 true KR101353850B1 (ko) | 2014-01-20 |
Family
ID=36337463
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020087019004A Active KR101353850B1 (ko) | 2006-02-01 | 2007-01-29 | 이산화티타늄 나노입자상 수분산액 제조 방법 및 그방법으로 수득할 수 있는 분산액 |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US8431621B2 (https=) |
| EP (1) | EP1996515B1 (https=) |
| JP (1) | JP5281415B2 (https=) |
| KR (1) | KR101353850B1 (https=) |
| CN (1) | CN101378993B (https=) |
| AT (1) | ATE490220T1 (https=) |
| AU (1) | AU2007211536B2 (https=) |
| BR (1) | BRPI0707256B1 (https=) |
| CA (1) | CA2640938C (https=) |
| DE (1) | DE602007010908D1 (https=) |
| DK (1) | DK1996515T3 (https=) |
| ES (1) | ES2357369T3 (https=) |
| IT (1) | ITFI20060030A1 (https=) |
| NZ (1) | NZ570356A (https=) |
| PL (1) | PL1996515T3 (https=) |
| PT (1) | PT1996515E (https=) |
| RU (1) | RU2431604C2 (https=) |
| WO (1) | WO2007088151A1 (https=) |
| ZA (1) | ZA200806991B (https=) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITFI20060034A1 (it) | 2006-02-03 | 2007-08-04 | Colorobbia Italiana Spa | Processo per la funzionalizzazione di superfici metalliche in titanio con particelle di titanio nanometriche e prodotti cosi' funzionalizzati |
| KR100921381B1 (ko) | 2008-02-19 | 2009-10-14 | 성균관대학교산학협력단 | 비표면적이 증가된 신규한 이산화티탄 촉매 및 이의제조방법 |
| US20110220855A1 (en) * | 2010-03-12 | 2011-09-15 | Weir John D | Self-Cleaning Coating for Protection Against Hazardous Biopathogens and Toxic Chemical Agents Utilizing Both Super Hydrophobic Effects and Suitable Oxide Interfaces |
| CN101844805A (zh) * | 2010-06-08 | 2010-09-29 | 上海工程技术大学 | 一种制备水性高分散纳米二氧化钛的方法 |
| SI23501A (sl) | 2010-10-25 | 2012-04-30 | CINKARNA Metalurško kemiÄŤna industrija Celje, d.d. | Postopek za pridobivanje nanodelcev anatasa visoke specifične površine in sferične morfologije |
| ITFI20110038A1 (it) | 2011-03-03 | 2012-09-04 | Colorobbia Italiana Spa | Cerameri, loro applicazione ed uso. |
| KR101341250B1 (ko) * | 2011-11-28 | 2013-12-12 | 박홍욱 | 연소 및 광촉매성 세라믹 코팅제 조성물 및 이를 이용한 유해가스 저감 코팅제품 |
| RU2477257C1 (ru) * | 2011-12-26 | 2013-03-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный университет" (СПбГУ) | Композиция на основе нанокристаллического диоксида титана, способ ее изготовления и способ применения композиции для получения фотокаталитического покрытия на стекле |
| US9573126B2 (en) * | 2012-03-20 | 2017-02-21 | Valinge Photocatalytic Ab | Photocatalytic composition |
| KR101397346B1 (ko) * | 2012-06-15 | 2014-05-22 | 경희대학교 산학협력단 | 자외선 차단 및 피부노폐물 흡수 성능을 갖는 화장품용 다기능성 복합체 제조방법 |
| CN103301856B (zh) * | 2013-05-23 | 2014-10-29 | 河北科技大学 | 纳米贵金属/半导体复合光催化剂在有机物卤化反应中的应用 |
| CN103934017A (zh) * | 2014-04-22 | 2014-07-23 | 苏州聚康新材料科技有限公司 | 一种具有高效光催化活性的微乳液的制备方法 |
| CN104190279A (zh) * | 2014-08-27 | 2014-12-10 | 华南师范大学 | 一种纳米二氧化钛分散液的制备方法 |
| CN106219664A (zh) * | 2016-08-10 | 2016-12-14 | 佛山科学技术学院 | 涤/棉一浴法染色的棉基光催化处理染色废水的方法 |
| US11819580B2 (en) | 2016-10-18 | 2023-11-21 | PurWorld Technologies LLC | Method of chemically disinfecting a vehicle |
| IT201700050577A1 (it) * | 2017-05-10 | 2018-11-10 | Colorobbia Consulting S R L | Supporto nanofunzionalizzato e metodo di realizzazione |
| IT201700112570A1 (it) * | 2017-10-06 | 2019-04-06 | Andrea Ferruccio Zoppolato | Apparato automatico per la distribuzione di prodotti |
| CA3097835A1 (en) * | 2018-05-02 | 2019-11-07 | Colorobbia Consulting S.R.L. | Nitrogen-doped tio2 nanoparticles and the use thereof in photocatalysis |
| WO2021053379A1 (en) * | 2019-09-20 | 2021-03-25 | Reair S.R.L. | Sanitization composition and method for sanitization- purification of surfaces and environments |
| IT201900020122A1 (it) | 2019-10-31 | 2021-05-01 | Colorobbia Consulting S R L | Supporto polimerico nanofunzionalizzato con nanoparticelle fotocatalitiche a base di TiO2 e il suo uso nella fotocatalisi |
| IT202000018004A1 (it) | 2020-07-24 | 2022-01-24 | Colorobbia Consulting S R L | Nanoparticelle, substrato nanofunzionalizzato e dispositivo con attività fotocatalitica antibatterica |
| IT202000017995A1 (it) | 2020-07-24 | 2022-01-24 | Colorobbia Consulting S R L | Nanoparticelle, substrato nanofunzionalizzato e dispositivo con attività fotocatalitica antivirale |
| IT202000018007A1 (it) | 2020-07-24 | 2022-01-24 | Colorobbia Consulting S R L | Nanoparticelle, substrato nanofunzionalizzato e dispositivo con attività fotocatalitica antifungina |
| CN114316723B (zh) * | 2022-01-29 | 2022-12-20 | 重庆交通大学 | 光催化成膜组合物及其制备方法和用途 |
| KR102779251B1 (ko) * | 2023-08-09 | 2025-03-11 | 주식회사 젠스 | 환경 개선용 조성물의 제조방법 및 이에 의해 제조되는 조성물 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5718907A (en) | 1994-06-24 | 1998-02-17 | Rhone-Poulenc Chimie | Process for the preparation of organophilic metal oxide particles |
| US20040241427A1 (en) | 2001-07-06 | 2004-12-02 | Huai Zhu | Metal oxide nanoparticles in an exfoliated silicate framework |
| US6905814B1 (en) | 1999-02-17 | 2005-06-14 | Rhodia Chimie | Use of film-forming titanium dioxide dispersions for cleaning and disinfecting surfaces, film-forming titanium dioxide dispersions |
| US20050163924A1 (en) | 2002-09-17 | 2005-07-28 | 3M Innovative Properties Company | Porous surfactant mediated metal oxide films |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0403473A1 (en) * | 1988-03-03 | 1990-12-27 | AlliedSignal Inc. | Process for preparing monodisperse titania spheres |
| US5102853A (en) * | 1989-11-22 | 1992-04-07 | Ford Motor Company | Three-way catalyst for automotive emission control |
| JPH11343118A (ja) * | 1998-06-01 | 1999-12-14 | Minnesota Mining & Mfg Co <3M> | 酸化チタン膜、その製造方法、それをもった物品及びそれを備えた光化学電池 |
| JP2000044242A (ja) * | 1998-07-28 | 2000-02-15 | Teikoku Chem Ind Corp Ltd | 表面被覆組成物 |
| JP2000219515A (ja) * | 1999-01-27 | 2000-08-08 | Jsr Corp | 二酸化チタン前駆体組成物および二酸化チタン |
| JP2000334310A (ja) * | 1999-05-28 | 2000-12-05 | Jsr Corp | 光触媒の製造方法 |
| JP2003232018A (ja) * | 2002-02-08 | 2003-08-19 | Hitachi Chem Co Ltd | 光触媒性路面標示物用材料、光触媒性路面標示物の施工方法及び光触媒性路面標示物 |
| CN1218634C (zh) * | 2002-04-30 | 2005-09-14 | 香港中文大学 | 具有高杀菌光活性介孔二氧化钛薄膜的制备方法 |
| JP4483172B2 (ja) * | 2002-12-05 | 2010-06-16 | 住友化学株式会社 | 酸化チタン分散液 |
| CA2528660A1 (en) * | 2002-12-24 | 2004-07-15 | Oxonica Limited | Sunscreens |
| JP4382607B2 (ja) * | 2004-03-15 | 2009-12-16 | 住友大阪セメント株式会社 | 酸化チタン粒子 |
| EP1828056A1 (en) * | 2004-11-02 | 2007-09-05 | Nanogate AG | Synthesis of titanium dioxide nanoparticles |
| ITFI20040252A1 (it) * | 2004-12-06 | 2005-03-06 | Colorobbia Italiana Spa | Processo per la preparazione di dispersioni di ti02 in forma di nanoparticelle, e dispersioni ottenibili con questo processo |
-
2006
- 2006-02-01 IT IT000030A patent/ITFI20060030A1/it unknown
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2007
- 2007-01-29 CN CN2007800041476A patent/CN101378993B/zh active Active
- 2007-01-29 JP JP2008552790A patent/JP5281415B2/ja active Active
- 2007-01-29 KR KR1020087019004A patent/KR101353850B1/ko active Active
- 2007-01-29 BR BRPI0707256-2A patent/BRPI0707256B1/pt active IP Right Grant
- 2007-01-29 AT AT07726249T patent/ATE490220T1/de active
- 2007-01-29 PL PL07726249T patent/PL1996515T3/pl unknown
- 2007-01-29 RU RU2008135345/05A patent/RU2431604C2/ru active
- 2007-01-29 ES ES07726249T patent/ES2357369T3/es active Active
- 2007-01-29 WO PCT/EP2007/050826 patent/WO2007088151A1/en not_active Ceased
- 2007-01-29 AU AU2007211536A patent/AU2007211536B2/en not_active Ceased
- 2007-01-29 EP EP07726249A patent/EP1996515B1/en active Active
- 2007-01-29 US US12/162,539 patent/US8431621B2/en active Active
- 2007-01-29 DK DK07726249.1T patent/DK1996515T3/da active
- 2007-01-29 DE DE602007010908T patent/DE602007010908D1/de active Active
- 2007-01-29 PT PT07726249T patent/PT1996515E/pt unknown
- 2007-01-29 CA CA2640938A patent/CA2640938C/en active Active
- 2007-01-29 NZ NZ570356A patent/NZ570356A/en unknown
-
2008
- 2008-08-13 ZA ZA200806991A patent/ZA200806991B/xx unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5718907A (en) | 1994-06-24 | 1998-02-17 | Rhone-Poulenc Chimie | Process for the preparation of organophilic metal oxide particles |
| US6905814B1 (en) | 1999-02-17 | 2005-06-14 | Rhodia Chimie | Use of film-forming titanium dioxide dispersions for cleaning and disinfecting surfaces, film-forming titanium dioxide dispersions |
| US20040241427A1 (en) | 2001-07-06 | 2004-12-02 | Huai Zhu | Metal oxide nanoparticles in an exfoliated silicate framework |
| US20050163924A1 (en) | 2002-09-17 | 2005-07-28 | 3M Innovative Properties Company | Porous surfactant mediated metal oxide films |
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0707256A8 (pt) | 2018-01-09 |
| CA2640938C (en) | 2014-10-28 |
| EP1996515B1 (en) | 2010-12-01 |
| US8431621B2 (en) | 2013-04-30 |
| ITFI20060030A1 (it) | 2007-08-02 |
| AU2007211536A1 (en) | 2007-08-09 |
| RU2431604C2 (ru) | 2011-10-20 |
| KR20080094675A (ko) | 2008-10-23 |
| CN101378993B (zh) | 2012-11-07 |
| JP2009525246A (ja) | 2009-07-09 |
| DE602007010908D1 (de) | 2011-01-13 |
| NZ570356A (en) | 2010-09-30 |
| EP1996515A1 (en) | 2008-12-03 |
| US20080317959A1 (en) | 2008-12-25 |
| DK1996515T3 (da) | 2011-03-14 |
| BRPI0707256B1 (pt) | 2018-06-19 |
| ATE490220T1 (de) | 2010-12-15 |
| JP5281415B2 (ja) | 2013-09-04 |
| CA2640938A1 (en) | 2007-08-09 |
| ZA200806991B (en) | 2009-06-24 |
| ES2357369T3 (es) | 2011-04-25 |
| BRPI0707256A2 (pt) | 2011-04-26 |
| RU2008135345A (ru) | 2010-03-10 |
| AU2007211536B2 (en) | 2012-10-04 |
| WO2007088151A1 (en) | 2007-08-09 |
| PL1996515T3 (pl) | 2011-05-31 |
| PT1996515E (pt) | 2011-03-09 |
| CN101378993A (zh) | 2009-03-04 |
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