KR101265735B1 - 셧다운 기능을 갖는 초극세 섬유상 다공성 분리막 및 그 제조방법과 제조장치 - Google Patents
셧다운 기능을 갖는 초극세 섬유상 다공성 분리막 및 그 제조방법과 제조장치 Download PDFInfo
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- KR101265735B1 KR101265735B1 KR1020110024560A KR20110024560A KR101265735B1 KR 101265735 B1 KR101265735 B1 KR 101265735B1 KR 1020110024560 A KR1020110024560 A KR 1020110024560A KR 20110024560 A KR20110024560 A KR 20110024560A KR 101265735 B1 KR101265735 B1 KR 101265735B1
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- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0246—Acrylic resin fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0292—Polyurethane fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/14—Mixture of at least two fibres made of different materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/308—Heat stability
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/732—Dimensional properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
- H01M50/494—Tensile strength
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
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- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Textile Engineering (AREA)
- Materials Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Cell Separators (AREA)
- Laminated Bodies (AREA)
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KR20100024442 | 2010-03-18 | ||
KR1020100024442 | 2010-03-18 |
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KR101291090B1 (ko) * | 2011-10-04 | 2013-08-01 | 천석원 | 스피커 진동판 |
WO2013066022A1 (fr) * | 2011-10-31 | 2013-05-10 | 주식회사 아모텍 | Film de nanofibres stratifiés et procédés pour sa production et composite de nanofibres les utilisant |
KR101366022B1 (ko) * | 2011-12-21 | 2014-02-24 | 주식회사 아모그린텍 | 전극 조립체 |
RU2482570C1 (ru) * | 2012-03-19 | 2013-05-20 | Открытое акционерное общество "Тюменский аккумуляторный завод" | Способ обработки пористого материала |
KR101470696B1 (ko) * | 2012-10-10 | 2014-12-08 | 한국생산기술연구원 | 리튬이차전지용 분리막의 제조방법 및 이에 따라 제조된 분리막 및 이를 구비하는 리튬이차전지 |
KR101371061B1 (ko) * | 2013-03-14 | 2014-03-10 | (주)에프티이앤이 | 내열성이 향상된 이차전지용 2층 분리막 및 이의 제조방법 |
WO2014142450A1 (fr) * | 2013-03-14 | 2014-09-18 | (주)에프티이앤이 | Procédé de préparation de membrane de séparation poreuse pour batterie secondaire et membrane de séparation poreuse pour batterie secondaire préparée ainsi |
KR101375226B1 (ko) * | 2013-03-14 | 2014-03-17 | (주)에프티이앤이 | 내열성이 향상된 이차전지용 3층 분리막의 제조방법 및 그에 따라 제조된 분리막 |
KR101419772B1 (ko) * | 2013-03-14 | 2014-07-17 | (주)에프티이앤이 | 내열성이 향상된 이차전지용 내열성/무기 고분자 2층 분리막 및 이의 제조방법 |
KR101447566B1 (ko) * | 2013-03-14 | 2014-10-07 | (주)에프티이앤이 | 이차전지용 다층 분리막의 제조방법 및 그에 따라 제조된 다층 분리막 |
KR101479748B1 (ko) * | 2013-03-14 | 2015-01-07 | (주)에프티이앤이 | 이차전지용 무기 고분자 분리막 및 이의 제조방법 |
KR101447564B1 (ko) * | 2013-03-14 | 2014-10-07 | (주)에프티이앤이 | 상향식 전기방사를 이용한 이차전지용 분리막의 제조방법 및 그에 따라 제조된 분리막 |
WO2014142449A1 (fr) * | 2013-03-14 | 2014-09-18 | (주)에프티이앤이 | Procédé de fabrication de film de séparation multicouche pour batterie secondaire ayant une résistance thermique améliorée, et film de séparation multicouche fabriqué ainsi |
CN104377328B (zh) | 2013-08-14 | 2019-09-13 | 三星Sdi株式会社 | 可再充电锂电池 |
KR101724009B1 (ko) * | 2013-08-14 | 2017-04-06 | 삼성에스디아이 주식회사 | 리튬 이차 전지 |
US9419265B2 (en) | 2013-10-31 | 2016-08-16 | Lg Chem, Ltd. | High-strength electrospun microfiber non-woven web for a separator of a secondary battery, a separator comprising the same and a method for manufacturing the same |
CN107731532A (zh) * | 2017-11-18 | 2018-02-23 | 陈馨雅 | 一种电解电容器用隔膜纸 |
TWI788616B (zh) * | 2019-05-30 | 2023-01-01 | 財團法人工業技術研究院 | 複合膜及其製作方法與應用 |
WO2024192602A1 (fr) * | 2023-03-17 | 2024-09-26 | 宁德时代新能源科技股份有限公司 | Séparateur et son procédé de préparation, accumulateur, et dispositif électrique |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100820162B1 (ko) | 2006-08-07 | 2008-04-10 | 한국과학기술연구원 | 내열성 초극세 섬유상 분리막 및 그 제조 방법과, 이를 이용한 이차전지 |
KR100845239B1 (ko) | 2006-08-07 | 2008-07-10 | 한국과학기술연구원 | 내열성 초극세 섬유층을 지닌 분리막 및 이를 이용한이차전지 |
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JP4226792B2 (ja) * | 2001-02-09 | 2009-02-18 | 株式会社東芝 | 非水電解質二次電池 |
KR101093590B1 (ko) * | 2004-11-30 | 2011-12-15 | 에스케이이노베이션 주식회사 | 다층형 고분자 막을 이용한 리튬 고분자 전지 및 그의제조방법 |
JP5196752B2 (ja) * | 2005-09-16 | 2013-05-15 | 東レバッテリーセパレータフィルム株式会社 | ポリエチレン微多孔膜及びその製造方法、並びに電池用セパレータ |
JP5122239B2 (ja) * | 2007-10-22 | 2013-01-16 | 旭化成イーマテリアルズ株式会社 | 多層多孔膜 |
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KR100820162B1 (ko) | 2006-08-07 | 2008-04-10 | 한국과학기술연구원 | 내열성 초극세 섬유상 분리막 및 그 제조 방법과, 이를 이용한 이차전지 |
KR100845239B1 (ko) | 2006-08-07 | 2008-07-10 | 한국과학기술연구원 | 내열성 초극세 섬유층을 지닌 분리막 및 이를 이용한이차전지 |
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