KR101165454B1 - 촉매 조성물, 그의 제조 방법 및 에틸렌계 불포화단량체로부터 중합체를 제조하기 위한 그의 용도 - Google Patents

촉매 조성물, 그의 제조 방법 및 에틸렌계 불포화단량체로부터 중합체를 제조하기 위한 그의 용도 Download PDF

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KR101165454B1
KR101165454B1 KR1020050050316A KR20050050316A KR101165454B1 KR 101165454 B1 KR101165454 B1 KR 101165454B1 KR 1020050050316 A KR1020050050316 A KR 1020050050316A KR 20050050316 A KR20050050316 A KR 20050050316A KR 101165454 B1 KR101165454 B1 KR 101165454B1
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metal
pair
ligand
branched
linear
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KR20060049579A (ko
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브라이언 레슬리 구덜
제니퍼 린 페토프
한 셴
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롬 앤드 하아스 컴패니
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Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7208541B2 (en) * 2003-08-22 2007-04-24 National Starch And Chemical Investment Holding Corporation Hot melt adhesive
US7435701B2 (en) 2005-05-27 2008-10-14 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
CA2756511C (en) 2009-03-24 2018-09-18 Chemgreen Innovation Inc. Process for the production of polystyrene in an ionic liquid and novel polymers thereof
US20100317463A1 (en) * 2009-06-12 2010-12-16 Sullivan Michael J Golf balls having layers made from functionalized ethylene copolymers
JP5675162B2 (ja) * 2010-04-30 2015-02-25 三井化学株式会社 非極性−極性オレフィン共重合体の製造方法
WO2012164574A1 (en) 2011-05-09 2012-12-06 Reliance Industries Limited Nitrogen containing external donor system for propylene polymerization
CN110368987B (zh) * 2019-07-23 2021-12-31 华侨大学 一种树状丝瓜络固载离子液体型催化剂的制备方法及其应用
CN111715299B (zh) * 2020-07-25 2023-03-24 万华化学集团股份有限公司 一种硼盐络合催化剂、制备方法及其在乙烯齐聚中的应用
CN116410379A (zh) * 2021-12-31 2023-07-11 中国石油天然气股份有限公司 一种用于乙烯和甲基丙烯酸甲酯共聚的催化剂及其应用
CN114933668B (zh) * 2022-05-23 2023-07-14 万华化学集团股份有限公司 一种含氧环烯烃加成聚合物及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040063574A1 (en) 1998-02-12 2004-04-01 Theopold Klaus H. Catalyst compounds with beta-diiminate anionic ligands and processes for polymerizing olefins

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU432769A1 (ru) * 1970-07-13 1974-12-15 Способ получения линейных полимеров
DE69325757T2 (de) 1992-09-21 1999-12-30 Montell Technology Co. B.V., Hoofddorp Polymerisationsverfahren
US5372980A (en) * 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
US6232417B1 (en) * 1996-03-07 2001-05-15 The B. F. Goodrich Company Photoresist compositions comprising polycyclic polymers with acid labile pendant groups
EP0988331B1 (en) * 1997-06-09 2004-09-01 Promerus LLC Method for the preparation of copolymers of ethylene/norbornene-type monomers with cationic palladium catalysts
US5929181A (en) * 1997-06-09 1999-07-27 The B.F.Goodrich Co. Method for preparation of copolymers of ethylene/norbornene-type monomers with nickel catalysts
US6111041A (en) * 1997-06-18 2000-08-29 The Penn State Research Foundation Palladium (II) catalyized polymerization of norbornene and acrylates
US7087691B2 (en) * 1997-06-18 2006-08-08 Promerus Llc Photo-imageable compositions of norbornene and acrylate copolymers and use thereof
US6593440B2 (en) * 1997-06-18 2003-07-15 Penn State Research Foundation Palladium (II) catalyzed polymerization of norbornene and acrylates
US6037297A (en) * 1997-12-16 2000-03-14 Exxon Research And Engineering Co. Catalyst complexes and polymers therefrom
US6417303B1 (en) * 1997-12-16 2002-07-09 Exxonmobil Research And Engineering Company Substantially linear copolymers
JP2002519487A (ja) * 1998-07-01 2002-07-02 ザ ビー．エフ．グッドリッチ カンパニー 多環式共重合体組成物
KR20000011466A (ko) * 1998-07-08 2000-02-25 고사이 아끼오 전이금속화합물,올레핀중합촉매성분,올레핀중합촉매및올레핀폴리머의제조방법
JP2002521534A (ja) 1998-07-27 2002-07-16 バセル テクノロジー カンパニー ビー．ブイ． 重合方法
CN1249105C (zh) * 1998-10-05 2006-04-05 普罗米鲁斯有限责任公司 环烯烃聚合催化剂及聚合方法
KR100739482B1 (ko) * 1998-12-09 2007-07-13 스미토모 베이클라이트 가부시키가이샤 제 10족 금속 착물을 사용하는 노르보르넨형 단량체의 몰드내 첨가 중합반응
US6544919B1 (en) * 1999-10-06 2003-04-08 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions
CN100369940C (zh) 2000-05-31 2008-02-20 纳幕尔杜邦公司 烯烃聚合催化剂
KR20030005432A (ko) * 2000-05-31 2003-01-17 이 아이 듀폰 디 네모아 앤드 캄파니 올레핀의 중합
US20030144441A1 (en) * 2001-11-13 2003-07-31 Ayusman Sen Controlled copolymerization of methyl acrylate with olefins under mild conditions
US6730757B2 (en) * 2002-03-08 2004-05-04 Exxonmobil Research And Engineering Company Sulfur-containing and sulfur-nitrogen-containing catalysts for polymerization of olefins and polar monomers
AU2003241078A1 (en) 2002-06-04 2003-12-19 Thales Technologies, Ag Polymerization catalysts
KR100576971B1 (ko) * 2002-09-13 2006-05-10 금호석유화학 주식회사 올레핀 중합용 이핵 전이금속 화합물의 제조 방법
US6677419B1 (en) * 2002-11-13 2004-01-13 International Business Machines Corporation Preparation of copolymers
US7087687B2 (en) 2003-08-21 2006-08-08 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040063574A1 (en) 1998-02-12 2004-04-01 Theopold Klaus H. Catalyst compounds with beta-diiminate anionic ligands and processes for polymerizing olefins

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