JP2006028489A - 触媒組成物およびその調製ならびにエチレン性不飽和モノマーからポリマーを調製するための使用 - Google Patents

触媒組成物およびその調製ならびにエチレン性不飽和モノマーからポリマーを調製するための使用 Download PDF

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JP2006028489A
JP2006028489A JP2005171881A JP2005171881A JP2006028489A JP 2006028489 A JP2006028489 A JP 2006028489A JP 2005171881 A JP2005171881 A JP 2005171881A JP 2005171881 A JP2005171881 A JP 2005171881A JP 2006028489 A JP2006028489 A JP 2006028489A
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metal
pair
metal atom
complex
precursor complex
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JP2006028489A5 (enExample
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Brian Leslie Goodall
ブライアン・レスリー・グッダル
Jennifer Lynn Petoff
ジェニファー・リン・ペトフ
Han Shen
ハン・シェン
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Rohm and Haas Co
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Rohm and Haas Co
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009203479A (ja) * 2005-05-27 2009-09-10 Rohm & Haas Co 触媒組成物およびその製造ならびにエチレン性不飽和モノマーからポリマーを製造するための使用

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7208541B2 (en) * 2003-08-22 2007-04-24 National Starch And Chemical Investment Holding Corporation Hot melt adhesive
CA2756511C (en) 2009-03-24 2018-09-18 Chemgreen Innovation Inc. Process for the production of polystyrene in an ionic liquid and novel polymers thereof
US20100317463A1 (en) * 2009-06-12 2010-12-16 Sullivan Michael J Golf balls having layers made from functionalized ethylene copolymers
JP5675162B2 (ja) * 2010-04-30 2015-02-25 三井化学株式会社 非極性−極性オレフィン共重合体の製造方法
US8809221B2 (en) 2011-05-09 2014-08-19 Reliance Industries Limited Nitrogen containing external donor system for propylene polymerization
CN110368987B (zh) * 2019-07-23 2021-12-31 华侨大学 一种树状丝瓜络固载离子液体型催化剂的制备方法及其应用
CN111715299B (zh) * 2020-07-25 2023-03-24 万华化学集团股份有限公司 一种硼盐络合催化剂、制备方法及其在乙烯齐聚中的应用
CN116410379A (zh) * 2021-12-31 2023-07-11 中国石油天然气股份有限公司 一种用于乙烯和甲基丙烯酸甲酯共聚的催化剂及其应用
CN114933668B (zh) * 2022-05-23 2023-07-14 万华化学集团股份有限公司 一种含氧环烯烃加成聚合物及其制备方法

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU432769A1 (ru) 1970-07-13 1974-12-15 Способ получения линейных полимеров
EP0589527B1 (en) 1992-09-21 1999-07-28 Montell Technology Company bv Polymerization process
US5372980A (en) 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
US6232417B1 (en) 1996-03-07 2001-05-15 The B. F. Goodrich Company Photoresist compositions comprising polycyclic polymers with acid labile pendant groups
US5929181A (en) 1997-06-09 1999-07-27 The B.F.Goodrich Co. Method for preparation of copolymers of ethylene/norbornene-type monomers with nickel catalysts
EP0988331B1 (en) 1997-06-09 2004-09-01 Promerus LLC Method for the preparation of copolymers of ethylene/norbornene-type monomers with cationic palladium catalysts
US6111041A (en) 1997-06-18 2000-08-29 The Penn State Research Foundation Palladium (II) catalyized polymerization of norbornene and acrylates
US6593440B2 (en) 1997-06-18 2003-07-15 Penn State Research Foundation Palladium (II) catalyzed polymerization of norbornene and acrylates
US7087691B2 (en) 1997-06-18 2006-08-08 Promerus Llc Photo-imageable compositions of norbornene and acrylate copolymers and use thereof
US6417303B1 (en) 1997-12-16 2002-07-09 Exxonmobil Research And Engineering Company Substantially linear copolymers
US6037297A (en) 1997-12-16 2000-03-14 Exxon Research And Engineering Co. Catalyst complexes and polymers therefrom
US6511936B1 (en) 1998-02-12 2003-01-28 University Of Delaware Catalyst compounds with β-diminate anionic ligands and processes for polymerizing olefins
CN1307603A (zh) 1998-07-01 2001-08-08 B·F·谷德里奇公司 多环共聚物组合物
SG72966A1 (en) 1998-07-08 2000-05-23 Sumitomo Chemical Co Transition metal compound olefin polymerization catalyst component olefin polymerization catalyst and process for producing olefin polymer
CA2338847A1 (en) 1998-07-27 2000-02-10 Basell Technology Company B.V. A polymerization process
AU6291999A (en) 1998-10-05 2000-04-26 B.F. Goodrich Company, The Catalyst and methods for polymerizing cycloolefins
KR100739482B1 (ko) * 1998-12-09 2007-07-13 스미토모 베이클라이트 가부시키가이샤 제 10족 금속 착물을 사용하는 노르보르넨형 단량체의 몰드내 첨가 중합반응
US6544919B1 (en) 1999-10-06 2003-04-08 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions
US20020028897A1 (en) 2000-05-31 2002-03-07 Johnson Lynda Kaye Copolymers of ethylene and selected acrylate esters
WO2001092348A2 (en) 2000-05-31 2001-12-06 E.I. Du Pont De Nemours And Company Polymerization of olefins
US20030144441A1 (en) 2001-11-13 2003-07-31 Ayusman Sen Controlled copolymerization of methyl acrylate with olefins under mild conditions
US6730757B2 (en) 2002-03-08 2004-05-04 Exxonmobil Research And Engineering Company Sulfur-containing and sulfur-nitrogen-containing catalysts for polymerization of olefins and polar monomers
AU2003241078A1 (en) 2002-06-04 2003-12-19 Thales Technologies, Ag Polymerization catalysts
KR100576971B1 (ko) 2002-09-13 2006-05-10 금호석유화학 주식회사 올레핀 중합용 이핵 전이금속 화합물의 제조 방법
US6677419B1 (en) 2002-11-13 2004-01-13 International Business Machines Corporation Preparation of copolymers
US7087687B2 (en) 2003-08-21 2006-08-08 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009203479A (ja) * 2005-05-27 2009-09-10 Rohm & Haas Co 触媒組成物およびその製造ならびにエチレン性不飽和モノマーからポリマーを製造するための使用

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