TWI318986B - A catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers - Google Patents

A catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers

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Publication number
TWI318986B
TWI318986B TW094118117A TW94118117A TWI318986B TW I318986 B TWI318986 B TW I318986B TW 094118117 A TW094118117 A TW 094118117A TW 94118117 A TW94118117 A TW 94118117A TW I318986 B TWI318986 B TW I318986B
Authority
TW
Taiwan
Prior art keywords
preparation
ethylenically unsaturated
unsaturated monomers
catalytic composition
preparing polymers
Prior art date
Application number
TW094118117A
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English (en)
Chinese (zh)
Other versions
TW200613345A (en
Inventor
Brian Leslie Goodall
Jennifer Lynn Petoff
Han Shen
Original Assignee
Rohm & Haas
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Publication date
Application filed by Rohm & Haas filed Critical Rohm & Haas
Publication of TW200613345A publication Critical patent/TW200613345A/zh
Application granted granted Critical
Publication of TWI318986B publication Critical patent/TWI318986B/zh

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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
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    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
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    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
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    • B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
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TW094118117A 2004-06-14 2005-06-02 A catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers TWI318986B (en)

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Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7208541B2 (en) * 2003-08-22 2007-04-24 National Starch And Chemical Investment Holding Corporation Hot melt adhesive
US7435701B2 (en) 2005-05-27 2008-10-14 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
CA2756511C (en) 2009-03-24 2018-09-18 Chemgreen Innovation Inc. Process for the production of polystyrene in an ionic liquid and novel polymers thereof
US20100317463A1 (en) * 2009-06-12 2010-12-16 Sullivan Michael J Golf balls having layers made from functionalized ethylene copolymers
JP5675162B2 (ja) * 2010-04-30 2015-02-25 三井化学株式会社 非極性−極性オレフィン共重合体の製造方法
WO2012164574A1 (en) 2011-05-09 2012-12-06 Reliance Industries Limited Nitrogen containing external donor system for propylene polymerization
CN110368987B (zh) * 2019-07-23 2021-12-31 华侨大学 一种树状丝瓜络固载离子液体型催化剂的制备方法及其应用
CN111715299B (zh) * 2020-07-25 2023-03-24 万华化学集团股份有限公司 一种硼盐络合催化剂、制备方法及其在乙烯齐聚中的应用
CN116410379A (zh) * 2021-12-31 2023-07-11 中国石油天然气股份有限公司 一种用于乙烯和甲基丙烯酸甲酯共聚的催化剂及其应用
CN114933668B (zh) * 2022-05-23 2023-07-14 万华化学集团股份有限公司 一种含氧环烯烃加成聚合物及其制备方法

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU432769A1 (ru) * 1970-07-13 1974-12-15 Способ получения линейных полимеров
DE69325757T2 (de) 1992-09-21 1999-12-30 Montell Technology Co. B.V., Hoofddorp Polymerisationsverfahren
US5372980A (en) * 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
US6232417B1 (en) * 1996-03-07 2001-05-15 The B. F. Goodrich Company Photoresist compositions comprising polycyclic polymers with acid labile pendant groups
EP0988331B1 (en) * 1997-06-09 2004-09-01 Promerus LLC Method for the preparation of copolymers of ethylene/norbornene-type monomers with cationic palladium catalysts
US5929181A (en) * 1997-06-09 1999-07-27 The B.F.Goodrich Co. Method for preparation of copolymers of ethylene/norbornene-type monomers with nickel catalysts
US6111041A (en) * 1997-06-18 2000-08-29 The Penn State Research Foundation Palladium (II) catalyized polymerization of norbornene and acrylates
US7087691B2 (en) * 1997-06-18 2006-08-08 Promerus Llc Photo-imageable compositions of norbornene and acrylate copolymers and use thereof
US6593440B2 (en) * 1997-06-18 2003-07-15 Penn State Research Foundation Palladium (II) catalyzed polymerization of norbornene and acrylates
US6037297A (en) * 1997-12-16 2000-03-14 Exxon Research And Engineering Co. Catalyst complexes and polymers therefrom
US6417303B1 (en) * 1997-12-16 2002-07-09 Exxonmobil Research And Engineering Company Substantially linear copolymers
US6511936B1 (en) 1998-02-12 2003-01-28 University Of Delaware Catalyst compounds with β-diminate anionic ligands and processes for polymerizing olefins
JP2002519487A (ja) * 1998-07-01 2002-07-02 ザ ビー．エフ．グッドリッチ カンパニー 多環式共重合体組成物
KR20000011466A (ko) * 1998-07-08 2000-02-25 고사이 아끼오 전이금속화합물,올레핀중합촉매성분,올레핀중합촉매및올레핀폴리머의제조방법
JP2002521534A (ja) 1998-07-27 2002-07-16 バセル テクノロジー カンパニー ビー．ブイ． 重合方法
CN1249105C (zh) * 1998-10-05 2006-04-05 普罗米鲁斯有限责任公司 环烯烃聚合催化剂及聚合方法
KR100739482B1 (ko) * 1998-12-09 2007-07-13 스미토모 베이클라이트 가부시키가이샤 제 10족 금속 착물을 사용하는 노르보르넨형 단량체의 몰드내 첨가 중합반응
US6544919B1 (en) * 1999-10-06 2003-04-08 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions
CN100369940C (zh) 2000-05-31 2008-02-20 纳幕尔杜邦公司 烯烃聚合催化剂
KR20030005432A (ko) * 2000-05-31 2003-01-17 이 아이 듀폰 디 네모아 앤드 캄파니 올레핀의 중합
US20030144441A1 (en) * 2001-11-13 2003-07-31 Ayusman Sen Controlled copolymerization of methyl acrylate with olefins under mild conditions
US6730757B2 (en) * 2002-03-08 2004-05-04 Exxonmobil Research And Engineering Company Sulfur-containing and sulfur-nitrogen-containing catalysts for polymerization of olefins and polar monomers
AU2003241078A1 (en) 2002-06-04 2003-12-19 Thales Technologies, Ag Polymerization catalysts
KR100576971B1 (ko) * 2002-09-13 2006-05-10 금호석유화학 주식회사 올레핀 중합용 이핵 전이금속 화합물의 제조 방법
US6677419B1 (en) * 2002-11-13 2004-01-13 International Business Machines Corporation Preparation of copolymers
US7087687B2 (en) 2003-08-21 2006-08-08 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers

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TW200613345A (en) 2006-05-01
CN1331898C (zh) 2007-08-15
JP2006028489A (ja) 2006-02-02
KR20060049579A (ko) 2006-05-19
CN1737015A (zh) 2006-02-22
US20050277749A1 (en) 2005-12-15
US7199074B2 (en) 2007-04-03
KR101165454B1 (ko) 2012-07-12
CA2509073C (en) 2008-12-02
JP2009108329A (ja) 2009-05-21
CA2509073A1 (en) 2005-12-14
EP1607414A1 (en) 2005-12-21

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