KR100814597B1 - 메틸 4-포밀벤조에이트와 디메틸테레프탈레이트의 분리방법 - Google Patents

메틸 4-포밀벤조에이트와 디메틸테레프탈레이트의 분리방법 Download PDF

Info

Publication number
KR100814597B1
KR100814597B1 KR1020060099881A KR20060099881A KR100814597B1 KR 100814597 B1 KR100814597 B1 KR 100814597B1 KR 1020060099881 A KR1020060099881 A KR 1020060099881A KR 20060099881 A KR20060099881 A KR 20060099881A KR 100814597 B1 KR100814597 B1 KR 100814597B1
Authority
KR
South Korea
Prior art keywords
mfb
methyl
dmt
weight
formylbenzoate
Prior art date
Application number
KR1020060099881A
Other languages
English (en)
Korean (ko)
Inventor
고재석
김우선
유영갑
Original Assignee
에스케이에너지 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 에스케이에너지 주식회사 filed Critical 에스케이에너지 주식회사
Priority to KR1020060099881A priority Critical patent/KR100814597B1/ko
Priority to CN2007800379834A priority patent/CN101522605B/zh
Priority to JP2009532300A priority patent/JP5246516B2/ja
Priority to PCT/KR2007/005005 priority patent/WO2008044895A1/en
Application granted granted Critical
Publication of KR100814597B1 publication Critical patent/KR100814597B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/60—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C07C69/80—Phthalic acid esters
    • C07C69/82—Terephthalic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020060099881A 2006-10-13 2006-10-13 메틸 4-포밀벤조에이트와 디메틸테레프탈레이트의 분리방법 KR100814597B1 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
KR1020060099881A KR100814597B1 (ko) 2006-10-13 2006-10-13 메틸 4-포밀벤조에이트와 디메틸테레프탈레이트의 분리방법
CN2007800379834A CN101522605B (zh) 2006-10-13 2007-10-12 分离4-甲酰基苯甲酸甲酯和对苯二甲酸二甲酯的方法
JP2009532300A JP5246516B2 (ja) 2006-10-13 2007-10-12 メチル−４−ホルミルベンゾエートとジメチルテレフタレートの単離方法
PCT/KR2007/005005 WO2008044895A1 (en) 2006-10-13 2007-10-12 The process of isolating methyl-4-formylbenzoate and dimethylterephtalate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020060099881A KR100814597B1 (ko) 2006-10-13 2006-10-13 메틸 4-포밀벤조에이트와 디메틸테레프탈레이트의 분리방법

Publications (1)

Publication Number Publication Date
KR100814597B1 true KR100814597B1 (ko) 2008-03-17

Family

ID=39283050

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020060099881A KR100814597B1 (ko) 2006-10-13 2006-10-13 메틸 4-포밀벤조에이트와 디메틸테레프탈레이트의 분리방법

Country Status (4)

Country Link
JP (1) JP5246516B2 (zh)
KR (1) KR100814597B1 (zh)
CN (1) CN101522605B (zh)
WO (1) WO2008044895A1 (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011087211A2 (ko) 2010-01-14 2011-07-21 주식회사 네이퓨 4-아미노메틸벤조산의 제조방법
KR101263405B1 (ko) 2011-01-13 2013-05-10 한국화학연구원 디메틸 테레프탈레이트 제조 공정으로부터 발생하는 부산물로부터 고순도의 메틸-4-포밀벤조에이트의 정제방법
KR101341449B1 (ko) 2011-01-25 2013-12-13 주식회사 네이퓨 디메틸 테레프탈레이트 제조공정의 부산물로부터 ｐ-클로로메틸벤조산 및 벤조산의 제조방법
KR101521607B1 (ko) * 2013-08-13 2015-05-20 주식회사 네이퓨 메틸 4-포밀벤조에이트와 디메틸테레프탈레이트를 고수율로 분리회수하는 방법

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005002507A2 (en) 2003-06-03 2005-01-13 Isis Pharmaceuticals, Inc. Modulation of survivin expression

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4760165A (en) 1985-11-13 1988-07-26 Teijin Petrochemical Industries, Ltd. Recovering useful components at least containing dimethyl terephthalate from high-boiling byproducts occurring in the production of dimethyl terephthalate
KR19980082548A (ko) * 1997-05-07 1998-12-05 조민호 디메틸 테레프탈레이트 제조공정 중 발생하는 메틸 파라포밀벤조에이트의 재활용 방법
KR20050087544A (ko) * 2004-02-27 2005-08-31 에스케이 주식회사 디메틸 테레프탈레이트 제조공정의 부산물로부터메틸-4-포밀벤조에이트와 디메틸 테레프탈레이트의분리회수방법

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2427875C3 (de) * 1974-06-10 1980-03-20 Dynamit Nobel Ag, 5210 Troisdorf Verfahren zur Gewinnung von Dimethylterephthalat und von Zwischenprodukten der Dimethylterephthalat-Herstellung
JPS6039066B2 (ja) * 1976-03-01 1985-09-04 帝人株式会社 Ｐ−ホルミル安息香酸メチルの分離法
JPS5463038A (en) * 1977-10-27 1979-05-21 Teijin Hercules Chem Co Ltd Method of recovering useful components

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4760165A (en) 1985-11-13 1988-07-26 Teijin Petrochemical Industries, Ltd. Recovering useful components at least containing dimethyl terephthalate from high-boiling byproducts occurring in the production of dimethyl terephthalate
KR19980082548A (ko) * 1997-05-07 1998-12-05 조민호 디메틸 테레프탈레이트 제조공정 중 발생하는 메틸 파라포밀벤조에이트의 재활용 방법
KR20050087544A (ko) * 2004-02-27 2005-08-31 에스케이 주식회사 디메틸 테레프탈레이트 제조공정의 부산물로부터메틸-4-포밀벤조에이트와 디메틸 테레프탈레이트의분리회수방법

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011087211A2 (ko) 2010-01-14 2011-07-21 주식회사 네이퓨 4-아미노메틸벤조산의 제조방법
US8907127B2 (en) 2010-01-14 2014-12-09 Naf Co Ltd Preparation method of 4-aminomethylbenzoic acid
KR101263405B1 (ko) 2011-01-13 2013-05-10 한국화학연구원 디메틸 테레프탈레이트 제조 공정으로부터 발생하는 부산물로부터 고순도의 메틸-4-포밀벤조에이트의 정제방법
KR101341449B1 (ko) 2011-01-25 2013-12-13 주식회사 네이퓨 디메틸 테레프탈레이트 제조공정의 부산물로부터 ｐ-클로로메틸벤조산 및 벤조산의 제조방법
KR101521607B1 (ko) * 2013-08-13 2015-05-20 주식회사 네이퓨 메틸 4-포밀벤조에이트와 디메틸테레프탈레이트를 고수율로 분리회수하는 방법

Also Published As

Publication number Publication date
WO2008044895A1 (en) 2008-04-17
JP5246516B2 (ja) 2013-07-24
JP2010505945A (ja) 2010-02-25
CN101522605B (zh) 2013-03-27
CN101522605A (zh) 2009-09-02

Similar Documents

Publication Publication Date Title
KR100814597B1 (ko) 메틸 4-포밀벤조에이트와 디메틸테레프탈레이트의 분리방법
JP4782436B2 (ja) ２−ヒドロキシエステル類の製造方法
CN111269149A (zh) 一种5-(3,3-二甲基胍基)-2-氧代戊酸的生产工艺
JP5188475B2 (ja) ２−（３−ニトロベンジリデン）アセト酢酸イソプロピルの製造方法
KR100789557B1 (ko) 디메틸 테레프탈레이트 제조공정의 부산물로부터메틸-4-포밀벤조에이트와 디메틸 테레프탈레이트의분리회수방법
KR101341449B1 (ko) 디메틸 테레프탈레이트 제조공정의 부산물로부터 ｐ-클로로메틸벤조산 및 벤조산의 제조방법
JP2000072719A (ja) ２−ヒドロキシイソ酪酸アリルの製造方法
KR101521607B1 (ko) 메틸 4-포밀벤조에이트와 디메틸테레프탈레이트를 고수율로 분리회수하는 방법
JP3291987B2 (ja) Ｏ，ｓ−ジメチル−ｎ−アセチルホスホルアミドチオエートの精製法
KR100403143B1 (ko) 1-브로모에틸 아세테이트의 제조방법
JP3640319B2 (ja) ベンズアミド誘導体の製造方法
RU2483055C1 (ru) Способ получения 1,5-бис(2-гидроксифенокси)-3-оксапентана моногидрата
KR100228736B1 (ko) 말론산에스터 폐액으로부터 말론산디알킬에스터의 제조방법
KR100877134B1 (ko) 아캄프로세이트 칼슘의 제조방법
JPH0616585A (ja) ジペンタエリスリトールの製造方法
JP4508670B2 (ja) 高純度アダマンタントリオール類の製造方法
JP2004149440A (ja) ベンジルカルバゼート化合物の製造法
JP4085199B2 (ja) Ｏ，Ｏ−ジメチル−Ｏ−（ｐ−シアノフェニル）ホスホロチオエートの製造方法
JP3962467B2 (ja) １，４−ジヒドロキシ−２−ナフトエ酸アリールエステル類の製造方法
JP4827364B2 (ja) ｐ−シアノフェノールの精製方法
JP2002047234A (ja) ジトリメチロールプロパンの回収方法
JP4505936B2 (ja) プロピオール酸エステルの製造方法
JP2006199599A (ja) ビス含フッ素フタロニトリル化合物の製造方法
WO1985003301A1 (fr) Procede de preparation d'aspartyl peptides et nouveaux derives de l'acide aspartique utilisables dans leurs synthese
JP2007223964A (ja) ４−（ｎ−エチル−ｎ−イソプロピルアミノ）アニリンの精製方法

Legal Events

Date Code Title Description
A201 Request for examination
N231 Notification of change of applicant
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20121122

Year of fee payment: 6

FPAY Annual fee payment

Payment date: 20131212

Year of fee payment: 7

FPAY Annual fee payment

Payment date: 20141215

Year of fee payment: 8

LAPS Lapse due to unpaid annual fee