KR100583931B1 - 메탈로센 및 올레핀 중합용 촉매 - Google Patents

메탈로센 및 올레핀 중합용 촉매 Download PDF

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Publication number
KR100583931B1
KR100583931B1 KR1019997006194A KR19997006194A KR100583931B1 KR 100583931 B1 KR100583931 B1 KR 100583931B1 KR 1019997006194 A KR1019997006194 A KR 1019997006194A KR 19997006194 A KR19997006194 A KR 19997006194A KR 100583931 B1 KR100583931 B1 KR 100583931B1
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Prior art keywords
dihydroindeno
methyl
formula
indol
indole
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Expired - Fee Related
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Korean (ko)
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KR20000069979A (ko
Inventor
니판테브일야이.
바그로브블라디미르브이.
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바셀 테크놀로지 캄파니 비이브이
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/56—Ring systems containing three or more rings
    • C07D209/58—[b]- or [c]-condensed
    • C07D209/70—[b]- or [c]-condensed containing carbocyclic rings other than six-membered
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Indole Compounds (AREA)
KR1019997006194A 1997-11-12 1998-11-04 메탈로센 및 올레핀 중합용 촉매 Expired - Fee Related KR100583931B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP97119778 1997-11-12
EP97119778.5 1997-11-12
PCT/EP1998/007034 WO1999024446A1 (en) 1997-11-12 1998-11-04 Metallocenes and catalysts for olefin-polymerisation

Publications (2)

Publication Number Publication Date
KR20000069979A KR20000069979A (ko) 2000-11-25
KR100583931B1 true KR100583931B1 (ko) 2006-05-26

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Family Applications (1)

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KR1019997006194A Expired - Fee Related KR100583931B1 (ko) 1997-11-12 1998-11-04 메탈로센 및 올레핀 중합용 촉매

Country Status (20)

Country Link
US (2) US6451724B1 (enExample)
EP (1) EP0952978B1 (enExample)
JP (1) JP4540755B2 (enExample)
KR (1) KR100583931B1 (enExample)
CN (1) CN1231487C (enExample)
AR (1) AR016150A1 (enExample)
AU (1) AU1870999A (enExample)
BR (1) BR9807103A (enExample)
CA (1) CA2277127A1 (enExample)
DE (1) DE69810894T2 (enExample)
ES (1) ES2190131T3 (enExample)
HU (1) HUP0001331A2 (enExample)
ID (1) ID22914A (enExample)
IL (1) IL130713A0 (enExample)
MY (1) MY132919A (enExample)
NO (1) NO993398L (enExample)
PL (1) PL334470A1 (enExample)
TR (1) TR199901908T1 (enExample)
WO (1) WO1999024446A1 (enExample)
ZA (1) ZA9810179B (enExample)

Families Citing this family (115)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
HUP0001331A2 (hu) * 1997-11-12 2000-08-28 Montell Technology Company B.V. Metallocének, áthidalt ligandumok, olefinpolimerizációs katalizátorok és eljárás olefinek polimerizálására
DE19903306A1 (de) * 1999-01-28 2000-08-03 Targor Gmbh Organometallverbindung, Katalysatorsystem enthaltend diese Organometallverbindung und seine Verwendung
ES2202169T3 (es) 1999-09-22 2004-04-01 Basell Polyolefine Gmbh Sistema catalitico y procedimiento para la polimerizacion de olefinas.
US6232260B1 (en) * 1999-10-14 2001-05-15 Equistar Chemicals, L.P. Single-site catalysts for olefin polymerization
US6444833B1 (en) * 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
AU3729501A (en) 2000-01-18 2001-07-31 Basell Technology Company B.V. Process for producing substantially amorphous propylene-based polymers
CA2370799A1 (en) 2000-02-24 2001-08-30 Basell Technology Company Bv Organometallic compound useful as cocatalyst for polymerizing olefins
US6476165B1 (en) 2000-03-08 2002-11-05 Equistar Chemicals, Lp Olefin polymerization process using fatty amine additives and boron-modified supported catalyst
US6703458B2 (en) 2000-12-22 2004-03-09 Basell Polyolefine Gmbh Catalyst components for the polymerization of olefins
EP1355958A2 (en) 2000-12-22 2003-10-29 Basell Poliolefine Italia S.p.A. Process for the preparation of porous polymers and polymers obtainable thereof
US6414162B1 (en) * 2001-04-05 2002-07-02 Equistar Chemicals, Lp Bimetallic catalysts for olefin polymerization
US6579957B2 (en) 2001-04-11 2003-06-17 Equistar Chemicals, Lp Single-site catalysts based on anionic thiopyran dioxide ligands
US7253292B2 (en) 2001-05-15 2007-08-07 Basell Polyolefine Gmbh Synthesis of cyclopentadiene derivatives
US6541583B2 (en) * 2001-05-17 2003-04-01 Equistar Chemicals, Lp Polypropylene preparation
DE60202524T2 (de) 2001-05-21 2005-06-30 Basell Polyolefine Gmbh Katalysatorsystem für die polymerisierung von olefinen
US6759361B2 (en) 2001-06-04 2004-07-06 Equistar Chemicals, Lp Aluminoboronate activators for single-site olefin polymerization catalysts
US6583242B2 (en) 2001-08-02 2003-06-24 Equistar Chemicals, Lp Supported olefin polymerization catalysts
US6440889B1 (en) * 2001-08-15 2002-08-27 Equistar Chemicals, Lp Amine elimination process for making single-site catalysts
ATE412016T1 (de) 2001-09-14 2008-11-15 Basell Polyolefine Gmbh Verfahren zur polymerisation von olefinen
DE10145453A1 (de) * 2001-09-14 2003-06-05 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus
US7022793B2 (en) 2001-11-27 2006-04-04 Basell Polyolefine Gmbh Process for the treatment of polymer compositions
JP4062929B2 (ja) 2002-02-08 2008-03-19 住友化学株式会社 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法
US6908972B2 (en) 2002-04-16 2005-06-21 Equistar Chemicals, Lp Method for making polyolefins
US6756455B2 (en) 2002-05-31 2004-06-29 Equistar Chemicals, Lp High-temperature solution process for polyolefin manufacture
US6630547B1 (en) 2002-06-11 2003-10-07 Equistar Chemicals, Lp Use of silanes to control molecular weight in olefin polymerizations
CA2487512A1 (en) 2002-06-26 2004-01-08 Basell Poliolefine Italia S.P.A. Impact-resistant polyolefin compositions
AU2003242663A1 (en) * 2002-06-26 2004-01-19 Basell Poliolefine Italia S.P.A. Impact-resistant polyolefin compositions
US6737487B2 (en) * 2002-07-30 2004-05-18 Equistar Chemicals, Lp Polyolefin block copolymers
MXPA05001075A (es) 2002-08-02 2005-06-06 Equistar Chem Lp Catalizadores y proceso para elaborar poliolefinas.
US6559251B1 (en) 2002-08-02 2003-05-06 Equistar Chemicals, Lp Process for making low-density polyolefins
US6765074B2 (en) * 2002-09-27 2004-07-20 Equistar Chemicals, Lp Olefin polymerization process
US6841500B2 (en) * 2002-12-03 2005-01-11 Equistar Chemicals, Lp Bimetallic indenoindolyl catalysts
US6683150B1 (en) * 2002-12-19 2004-01-27 Equistar Chemicals, Lp High molecular weight polypropylene process
US20040176241A1 (en) * 2003-03-04 2004-09-09 Sandor Nagy Benzoindenoindolyl metal catalysts for olefin polymerization
US6693155B1 (en) 2003-03-05 2004-02-17 Equistar Chemicals, Lp Propylene polymerization process
BRPI0409738B1 (pt) 2003-04-17 2014-01-21 Processo contínuo para a polimerização de olefinas em um reator de leito fluidizado
US6794468B1 (en) 2003-05-12 2004-09-21 Equistar Chemicals, Lp Olefin polymerization process
US6995216B2 (en) 2003-06-16 2006-02-07 Equistar Chemicals, Lp Process for manufacturing single-site polyolefins
US6998451B2 (en) 2003-07-01 2006-02-14 Equistar Chemicals, Lp Olefin polymerization process
US7122606B2 (en) 2003-07-04 2006-10-17 Basell Polyolefine Gmbh Olefin polymerization process
US6933353B2 (en) * 2003-07-07 2005-08-23 Equistar Chemicals, Lp Olefin polymerization process
US6818713B1 (en) 2003-08-11 2004-11-16 Equistar Chemicals, Lp Process for making polyethylene
US6939930B2 (en) 2003-09-09 2005-09-06 Equistar Chemicals, Lp Hydrosilane additives for increased polyolefin molecular weight
US6958377B2 (en) * 2003-10-15 2005-10-25 Equistar Chemicals, Lp Olefin polymerization process
US7741417B2 (en) * 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
US7220695B2 (en) * 2004-01-07 2007-05-22 Exxonmobil Chemical Patents Inc. Supported activator
EP1564226A1 (en) 2004-02-16 2005-08-17 Stichting Dutch Polymer Institute Titanocene-based catalyst system
ATE482983T1 (de) 2004-03-12 2010-10-15 Basell Polyolefine Gmbh Verfahren zur polymerisation von 1-hexen oder höheren alpha-olefinen
EP1723184A1 (en) 2004-03-12 2006-11-22 Basell Polyolefine GmbH Process for polymerizing 1-hexene or higher alpha-olefins
WO2005095468A2 (en) 2004-03-12 2005-10-13 Basell Polyolefine Gmbh Catalyst system for the polymerization of olefin
US6995220B2 (en) 2004-04-29 2006-02-07 Equistar Chemicals, Lp Ethylene polymerization process
DE102004027332A1 (de) * 2004-06-04 2005-12-22 Basell Polyolefine Gmbh Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
JP5006783B2 (ja) * 2004-07-13 2012-08-22 バーゼル・ポリオレフィン・ゲーエムベーハー メタロセン化合物、それらの調製で使用される配位子、１−ブテンポリマーの調製法、およびその方法から得られる１−ブテンポリマー
US6967231B1 (en) 2004-09-23 2005-11-22 Equistar Chemicals, Lp Olefin polymerization process
EP1655314A1 (en) * 2004-11-09 2006-05-10 Basell Polyolefine GmbH Process for the preparation of 1-butene/propylene copolymers
CN101061142B (zh) * 2004-11-22 2012-04-18 巴塞尔聚烯烃股份有限公司 基于丙烯的三元共聚物
US20080160862A1 (en) * 2004-12-13 2008-07-03 Basell Poliolefine Italia S.R.L. Polyolefin Composition, Fibres and Nonwoven Fabrics
WO2006067214A1 (en) * 2004-12-23 2006-06-29 Basell Poliolefine Italia S.R.L. Fibres having elastic properties
US7196147B2 (en) 2005-07-01 2007-03-27 Equistar Chemicals, Lp Olefin polymerization process with improved operability and polymer properties
US7230056B2 (en) 2005-07-01 2007-06-12 Equistar Chemicals, Lp Catalyst preparation method
US7538173B2 (en) 2005-11-21 2009-05-26 Equistar Chemicals Lp Polyolefin compositions
DE102005061326A1 (de) * 2005-12-20 2007-06-21 Basell Polyolefine Gmbh Verfahren zur Herstellung von Metallocenen aus recycelten, substituierten Cyclopentadienylderivaten
US7423098B2 (en) 2006-01-17 2008-09-09 Equistar Chemicals, Lp Polyethylene process
US8003739B2 (en) * 2007-10-17 2011-08-23 Fina Technology, Inc. Multi-component catalyst systems and polymerization processes for forming in-situ heterophasic copolymers and/or varying the xylene solubles content of polyolefins
US7638584B2 (en) 2006-06-20 2009-12-29 Equistar Chemicals, Lp Olefin polymerization process
US7638586B2 (en) 2006-09-26 2009-12-29 Equistar Chemicals, Lp Olefin polymerization process
US8475898B2 (en) 2007-08-29 2013-07-02 Equistar Chemicals, Lp Polyolefin resin blends for crack-resistant pipe
US7655740B2 (en) * 2007-09-04 2010-02-02 Equistar Chemicals, Lp Olefin polymerization process
US7781549B2 (en) * 2007-09-04 2010-08-24 Equistar Chemicals, Lp Olefin polymerization process
US7723451B2 (en) * 2007-09-04 2010-05-25 Equistar Chemicals, Lp Olefin polymerization process
US7666961B2 (en) * 2007-09-04 2010-02-23 Equistar Chemicals, Lp Olefin polymerization process
US8022005B2 (en) 2007-11-08 2011-09-20 Exxonmobil Chemical Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
ATE519788T1 (de) 2007-12-18 2011-08-15 Basell Polyolefine Gmbh Gasphasenverfahren zur polymerisation von alpha- olefinen
BRPI0908411B1 (pt) * 2008-02-29 2018-10-30 Basell Poliolefine Italia Srl composições de poliolefinas
US7776974B2 (en) * 2008-04-30 2010-08-17 Equistar Chemicals, Lp Olefin polymerization process
US7671151B2 (en) * 2008-05-21 2010-03-02 Equistar Chemicals, Lp Olefin polymerization process
US7816478B2 (en) 2008-09-03 2010-10-19 Equistar Chemicals, Lp Polyethylene thick film and process for preparing polyethylene
US20100129924A1 (en) * 2008-11-21 2010-05-27 Sandor Nagy Quality assurance method for olefin polymerization catalysts
DE102010033548A1 (de) 2010-08-05 2012-02-09 Merck Patent Gmbh Materialien für elektronische Vorrichtungen
KR101623485B1 (ko) * 2013-08-01 2016-05-23 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하는 올레핀계 중합체의 제조방법
CN104558058B (zh) * 2013-10-12 2017-08-08 中国科学院长春应用化学研究所 茂金属配合物及其制备方法、催化剂组合物
KR101644113B1 (ko) 2013-10-18 2016-07-29 주식회사 엘지화학 혼성 담지 메탈로센 촉매
US9321854B2 (en) 2013-10-29 2016-04-26 Exxonmobil Chemical Patents Inc. Aluminum alkyl with C5 cyclic and pendent olefin polymerization catalyst
KR20150058083A (ko) * 2013-11-20 2015-05-28 주식회사 동진쎄미켐 신규한 발광 화합물 및 이를 포함하는 유기발광소자
KR101705340B1 (ko) 2014-06-03 2017-02-09 주식회사 엘지화학 폴리올레핀의 제조 방법 및 이로부터 제조된 폴리올레핀
WO2016024818A1 (ko) * 2014-08-12 2016-02-18 주식회사 엘지화학 메탈로센 화합물， 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조방법
KR101703274B1 (ko) * 2014-08-12 2017-02-22 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조방법
KR101784463B1 (ko) 2014-10-06 2017-10-11 주식회사 엘지화학 리간드 화합물, 메탈로센 화합물 및 이를 이용하는 올레핀계 중합체의 제조방법
EP3056524B1 (en) 2014-10-13 2021-09-22 LG Chem, Ltd. Ethylene/1-butene copolymer having excellent processibility and environmental stress cracking resistance
US9796795B2 (en) 2015-01-14 2017-10-24 Exxonmobil Chemical Patents Inc. Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof
WO2016171808A1 (en) 2015-04-20 2016-10-27 Exxonmobil Chemical Patents Inc. Catalyst composition comprising fluorided support and processes for use thereof
WO2016122018A1 (ko) 2015-01-28 2016-08-04 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용하는 폴리올레핀의 제조방법
EP3138846B1 (en) * 2015-01-28 2019-03-06 LG Chem, Ltd. Metallocene compound, catalyst composition comprising same, and method for preparing olefin-based polymer using same
WO2016124157A1 (zh) * 2015-02-06 2016-08-11 中国石油天然气股份有限公司 含杂原子的π-配体的茂金属络合物及其制备方法、其催化剂体系和催化剂体系的应用
CN105985383B (zh) * 2015-02-06 2019-09-03 中国石油天然气股份有限公司 含杂原子的π-配体的茂金属络合物及其制备方法、其催化剂体系和催化剂体系的应用
CN105985368B (zh) * 2015-02-06 2020-03-10 中国石油天然气股份有限公司 含杂原子的π-配体的茂金属络合物及其制备方法、其催化剂体系和催化剂体系的应用
CN107636029B (zh) 2015-04-20 2020-05-22 埃克森美孚化学专利公司 包含氟化载体的催化剂组合物及其使用方法
US10351647B2 (en) 2015-05-29 2019-07-16 Exxonmobil Chemical Patents Inc. Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports
EP3344385A4 (en) 2015-08-31 2019-08-14 ExxonMobil Chemical Patents Inc. ALUMINUM ALKYLE WITH HANGING OLEFINS ON SOUND
EP3344665A4 (en) 2015-08-31 2019-08-14 ExxonMobil Chemical Patents Inc. ALUMINUM ALKYLE WITH HANGING OLEFINS FOR POLYOLEFINREACTIONS
US10618988B2 (en) 2015-08-31 2020-04-14 Exxonmobil Chemical Patents Inc. Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof
US10059788B2 (en) 2016-04-29 2018-08-28 Exxonmobil Chemical Patents Inc. Organoaluminum activators on clays
US9803037B1 (en) 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
US10562987B2 (en) 2016-06-30 2020-02-18 Exxonmobil Chemical Patents Inc. Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents
KR102072697B1 (ko) 2016-12-09 2020-02-03 주식회사 엘지화학 가공성 및 기계적 물성이 우수한 에틸렌/1-헥센 공중합체
US10626200B2 (en) 2017-02-28 2020-04-21 Exxonmobil Chemical Patents Inc. Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof
WO2018160278A1 (en) 2017-03-01 2018-09-07 Exxonmobil Chemical Patents Inc. Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof
CN107325034A (zh) * 2017-06-23 2017-11-07 浙江华海药业股份有限公司 一种制备罗匹尼罗二聚物的方法
EP3694811B1 (en) 2017-10-11 2024-04-03 Basell Polyolefine GmbH Supported catalyst system
US10703838B2 (en) 2017-10-31 2020-07-07 Exxonmobil Chemical Patents Inc. Mixed catalyst systems with four metallocenes on a single support
WO2019203676A1 (en) 2018-04-16 2019-10-24 Arlanxeo Netherlands B.V. Metal complex comprising amidine and indole fused cyclopentadienyl ligands
US12448471B2 (en) 2020-09-29 2025-10-21 Lg Chem, Ltd. Ethylene/1-hexene copolymer having improved flexibility and processibility
CN116425774A (zh) * 2021-12-30 2023-07-14 中国石油天然气股份有限公司 一种稀土金属配合物及其制备方法和应用
CN115400797B (zh) * 2022-08-19 2024-09-27 中国科学院山西煤炭化学研究所 含杂原子的茂金属催化剂体系及催化α-烯烃齐聚的方法
CN119431465B (zh) * 2023-08-01 2025-12-02 中国石油化工股份有限公司 茂金属化合物、催化剂组合物、烯烃聚合方法和应用

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3714148A (en) * 1968-10-15 1973-01-30 Sumitomo Chemical Co Process for preparing dibenzazocine derivatives and salts thereof
DE3007725A1 (de) 1980-02-29 1981-09-17 Hansjörg Prof. Dr. 2000 Hamburg Sinn Verfahren zur herstellung von polyethylen, polypropylen und copolymeren
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
IT1256259B (it) 1992-12-30 1995-11-29 Montecatini Tecnologie Srl Composti mettallocenici aventi leganti di tipo fluorenilico
IT1273420B (it) 1994-04-06 1997-07-08 Spherilene Srl Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
ZA9710211B (en) 1996-11-15 1998-06-03 Montell Technology Company Bv Heterocyclic metallocenes and polymerization catalysts.
US6451938B1 (en) 1997-02-25 2002-09-17 Exxon Mobil Chemical Patents Inc. Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands
HUP0001331A2 (hu) * 1997-11-12 2000-08-28 Montell Technology Company B.V. Metallocének, áthidalt ligandumok, olefinpolimerizációs katalizátorok és eljárás olefinek polimerizálására
US6232260B1 (en) * 1999-10-14 2001-05-15 Equistar Chemicals, L.P. Single-site catalysts for olefin polymerization

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IL130713A0 (en) 2000-06-01
TR199901908T1 (xx) 2000-02-21
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WO1999024446A1 (en) 1999-05-20
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CN1231487C (zh) 2005-12-14
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PL334470A1 (en) 2000-02-28
HUP0001331A2 (hu) 2000-08-28
US20030148877A1 (en) 2003-08-07
NO993398L (no) 1999-09-09
US6451724B1 (en) 2002-09-17
JP2001508083A (ja) 2001-06-19
DE69810894D1 (de) 2003-02-27

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