KR100582313B1 - 폴리에틸렌의 제조 방법 - Google Patents

폴리에틸렌의 제조 방법 Download PDF

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Publication number
KR100582313B1
KR100582313B1 KR1020017011101A KR20017011101A KR100582313B1 KR 100582313 B1 KR100582313 B1 KR 100582313B1 KR 1020017011101 A KR1020017011101 A KR 1020017011101A KR 20017011101 A KR20017011101 A KR 20017011101A KR 100582313 B1 KR100582313 B1 KR 100582313B1
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South Korea
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ether
ziegler
methyl
electron donor
groups
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KR1020017011101A
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Korean (ko)
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KR20010108287A (ko
Inventor
포드랜들레이
에임즈윌리엄앨버트
둘레이케네쓰앨런
밴더빌트제프리제임스
원더스앨런조지
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이스트만 케미칼 캄파니
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/18Suspension polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/602Component covered by group C08F4/60 with an organo-aluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/607Catalysts containing a specific non-metal or metal-free compound
    • C08F4/609Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6094Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/61Pretreating the metal or compound covered by group C08F4/60 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/612Pretreating with metals or metal-containing compounds
    • C08F4/614Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6143Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Emergency Medicine (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
KR1020017011101A 1999-03-03 1999-03-03 폴리에틸렌의 제조 방법 Expired - Lifetime KR100582313B1 (ko)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1999/004766 WO2000052068A1 (en) 1999-03-03 1999-03-03 Process for producing polyethylene

Publications (2)

Publication Number Publication Date
KR20010108287A KR20010108287A (ko) 2001-12-07
KR100582313B1 true KR100582313B1 (ko) 2006-05-22

Family

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KR1020017011101A Expired - Lifetime KR100582313B1 (ko) 1999-03-03 1999-03-03 폴리에틸렌의 제조 방법

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EP (1) EP1159315B1 (enExample)
JP (1) JP2002538244A (enExample)
KR (1) KR100582313B1 (enExample)
CN (1) CN1168748C (enExample)
DE (1) DE69933139T2 (enExample)
WO (1) WO2000052068A1 (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4571314B2 (ja) * 1999-03-03 2010-10-27 ウエストレイク ロングビュー コーポレイション ポリエチレンの製造方法
JP5283808B2 (ja) * 2000-03-30 2013-09-04 住友化学株式会社 エチレン重合用触媒およびエチレン重合体の製造方法
CN1194993C (zh) * 2002-06-06 2005-03-30 中国石油化工股份有限公司 用于乙烯聚合的固体催化剂组分及其催化剂
US7427653B2 (en) * 2002-12-18 2008-09-23 Basell Poliolefine Italia S.P.A Catalyst components for the polymerization of olefins
RU2006139061A (ru) * 2004-04-07 2008-05-20 Юнион Карбайд Кемикалз энд Пластикс Текнолоджи Корпорейшн (US) Композиции прокатализаторов для полимеризации олефинов и способ получения
US9796796B2 (en) 2007-08-24 2017-10-24 W. R. Grace & Co.-Conn. Self-limiting catalyst composition with No silane
CN101671410B (zh) * 2008-09-11 2011-12-28 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其催化剂
US8835578B2 (en) 2010-03-04 2014-09-16 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins
WO2011107371A1 (en) * 2010-03-04 2011-09-09 Basell Poliolefine Italia Srl Catalyst components for the polymerization of olefins
CN102286118B (zh) * 2010-06-18 2013-02-27 中国石油化工股份有限公司 一种用于烯烃聚合的含钛的固体催化剂组分及催化剂
CN105622801B (zh) * 2014-11-06 2018-08-17 中国石油化工股份有限公司 一种用于乙烯聚合的催化剂组分、催化剂及其制备方法
CN107778392A (zh) * 2016-08-31 2018-03-09 中国石油化工股份有限公司 一种用于乙烯聚合的催化剂组分及其制备方法和催化剂
RU2692246C1 (ru) * 2017-06-15 2019-06-24 Индийская Нефтяная Корпорация Лимитэд Внешний донор для полимеризации олефинов

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS617306A (ja) * 1984-06-22 1986-01-14 Tokuyama Soda Co Ltd ポリオレフインの製造方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3682928D1 (de) * 1985-03-08 1992-01-30 Mitsubishi Petrochemical Co Verfahren zum polymerisieren von aethylen.
JPS63146905A (ja) * 1986-12-11 1988-06-18 Idemitsu Petrochem Co Ltd オレフイン重合体の製造方法
FR2640273B1 (fr) * 1988-12-14 1992-09-04 Atochem Procede de polymerisation en phase gazeuse de l'ethylene permettant la fabrication de polyethylene lineaire de distribution etroite de masse moleculaire
JPH044206A (ja) * 1990-04-23 1992-01-08 Mitsubishi Petrochem Co Ltd オレフィン重合体の製造法
IT1271344B (it) * 1994-12-29 1997-05-27 Spherilene Srl Catalizzatori per la (co) polimerizzazione dell'etilene

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS617306A (ja) * 1984-06-22 1986-01-14 Tokuyama Soda Co Ltd ポリオレフインの製造方法

Also Published As

Publication number Publication date
CN1168748C (zh) 2004-09-29
DE69933139D1 (de) 2006-10-19
EP1159315A1 (en) 2001-12-05
WO2000052068A1 (en) 2000-09-08
KR20010108287A (ko) 2001-12-07
DE69933139T2 (de) 2007-09-13
CN1348472A (zh) 2002-05-08
EP1159315B1 (en) 2006-09-06
JP2002538244A (ja) 2002-11-12

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