CN1168748C - 制备聚乙烯的方法 - Google Patents

制备聚乙烯的方法 Download PDF

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Publication number
CN1168748C
CN1168748C CNB998166065A CN99816606A CN1168748C CN 1168748 C CN1168748 C CN 1168748C CN B998166065 A CNB998166065 A CN B998166065A CN 99816606 A CN99816606 A CN 99816606A CN 1168748 C CN1168748 C CN 1168748C
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CN
China
Prior art keywords
ether
ziegler
methyl
elements
electron donor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CNB998166065A
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English (en)
Chinese (zh)
Other versions
CN1348472A (zh
Inventor
R・R・福德
R·R·福德
阿梅斯
W·A·阿梅斯
多利
K·A·多利
范德比尔特
J·J·范德比尔特
万德斯
A·G·万德斯
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Westlake Longview Corp
Original Assignee
Eastman Chemical Co
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Publication of CN1348472A publication Critical patent/CN1348472A/zh
Application granted granted Critical
Publication of CN1168748C publication Critical patent/CN1168748C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/602—Component covered by group C08F4/60 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/607—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/609—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6094—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/61—Pretreating the metal or compound covered by group C08F4/60 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/612—Pretreating with metals or metal-containing compounds
    • C08F4/614—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6143—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Emergency Medicine (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
CNB998166065A 1999-03-03 1999-03-03 制备聚乙烯的方法 Expired - Lifetime CN1168748C (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1999/004766 WO2000052068A1 (en) 1999-03-03 1999-03-03 Process for producing polyethylene

Publications (2)

Publication Number Publication Date
CN1348472A CN1348472A (zh) 2002-05-08
CN1168748C true CN1168748C (zh) 2004-09-29

Family

ID=22272301

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB998166065A Expired - Lifetime CN1168748C (zh) 1999-03-03 1999-03-03 制备聚乙烯的方法

Country Status (6)

Country Link
EP (1) EP1159315B1 (enExample)
JP (1) JP2002538244A (enExample)
KR (1) KR100582313B1 (enExample)
CN (1) CN1168748C (enExample)
DE (1) DE69933139T2 (enExample)
WO (1) WO2000052068A1 (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4571314B2 (ja) * 1999-03-03 2010-10-27 ウエストレイク ロングビュー コーポレイション ポリエチレンの製造方法
JP5283808B2 (ja) * 2000-03-30 2013-09-04 住友化学株式会社 エチレン重合用触媒およびエチレン重合体の製造方法
CN1194993C (zh) * 2002-06-06 2005-03-30 中国石油化工股份有限公司 用于乙烯聚合的固体催化剂组分及其催化剂
US7427653B2 (en) * 2002-12-18 2008-09-23 Basell Poliolefine Italia S.P.A Catalyst components for the polymerization of olefins
RU2006139061A (ru) * 2004-04-07 2008-05-20 Юнион Карбайд Кемикалз энд Пластикс Текнолоджи Корпорейшн (US) Композиции прокатализаторов для полимеризации олефинов и способ получения
US9796796B2 (en) 2007-08-24 2017-10-24 W. R. Grace & Co.-Conn. Self-limiting catalyst composition with No silane
CN101671410B (zh) * 2008-09-11 2011-12-28 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其催化剂
US8835578B2 (en) 2010-03-04 2014-09-16 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins
WO2011107371A1 (en) * 2010-03-04 2011-09-09 Basell Poliolefine Italia Srl Catalyst components for the polymerization of olefins
CN102286118B (zh) * 2010-06-18 2013-02-27 中国石油化工股份有限公司 一种用于烯烃聚合的含钛的固体催化剂组分及催化剂
CN105622801B (zh) * 2014-11-06 2018-08-17 中国石油化工股份有限公司 一种用于乙烯聚合的催化剂组分、催化剂及其制备方法
CN107778392A (zh) * 2016-08-31 2018-03-09 中国石油化工股份有限公司 一种用于乙烯聚合的催化剂组分及其制备方法和催化剂
RU2692246C1 (ru) * 2017-06-15 2019-06-24 Индийская Нефтяная Корпорация Лимитэд Внешний донор для полимеризации олефинов

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS617306A (ja) * 1984-06-22 1986-01-14 Tokuyama Soda Co Ltd ポリオレフインの製造方法
DE3682928D1 (de) * 1985-03-08 1992-01-30 Mitsubishi Petrochemical Co Verfahren zum polymerisieren von aethylen.
JPS63146905A (ja) * 1986-12-11 1988-06-18 Idemitsu Petrochem Co Ltd オレフイン重合体の製造方法
FR2640273B1 (fr) * 1988-12-14 1992-09-04 Atochem Procede de polymerisation en phase gazeuse de l'ethylene permettant la fabrication de polyethylene lineaire de distribution etroite de masse moleculaire
JPH044206A (ja) * 1990-04-23 1992-01-08 Mitsubishi Petrochem Co Ltd オレフィン重合体の製造法
IT1271344B (it) * 1994-12-29 1997-05-27 Spherilene Srl Catalizzatori per la (co) polimerizzazione dell'etilene

Also Published As

Publication number Publication date
DE69933139D1 (de) 2006-10-19
EP1159315A1 (en) 2001-12-05
WO2000052068A1 (en) 2000-09-08
KR20010108287A (ko) 2001-12-07
DE69933139T2 (de) 2007-09-13
CN1348472A (zh) 2002-05-08
EP1159315B1 (en) 2006-09-06
KR100582313B1 (ko) 2006-05-22
JP2002538244A (ja) 2002-11-12

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C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: WESTLAKE LONGVIEW CORPORATION

Free format text: FORMER OWNER: YISIMAN CHEMICAL COMPANY

Effective date: 20070511

C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20070511

Address after: The United States. Texas

Patentee after: Westlake Longview Corp.

Address before: Tennessee

Patentee before: Eastman Chem Co.

CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20040929