KR100570638B1 - 리튬 이차 전지용 양극 활물질 및 그의 제조 방법 - Google Patents
리튬 이차 전지용 양극 활물질 및 그의 제조 방법 Download PDFInfo
- Publication number
- KR100570638B1 KR100570638B1 KR1020040010262A KR20040010262A KR100570638B1 KR 100570638 B1 KR100570638 B1 KR 100570638B1 KR 1020040010262 A KR1020040010262 A KR 1020040010262A KR 20040010262 A KR20040010262 A KR 20040010262A KR 100570638 B1 KR100570638 B1 KR 100570638B1
- Authority
- KR
- South Korea
- Prior art keywords
- active material
- diffraction
- formula
- positive electrode
- electrode active
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 29
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 239000006182 cathode active material Substances 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 239000007774 positive electrode material Substances 0.000 claims abstract description 52
- 238000002441 X-ray diffraction Methods 0.000 claims abstract description 19
- 229910018871 CoO 2 Inorganic materials 0.000 claims abstract description 13
- 239000010941 cobalt Substances 0.000 claims abstract description 10
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 10
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000010304 firing Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 6
- 230000000704 physical effect Effects 0.000 abstract description 8
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 21
- 239000002245 particle Substances 0.000 description 9
- 229910020599 Co 3 O 4 Inorganic materials 0.000 description 5
- 238000005259 measurement Methods 0.000 description 4
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 229910001416 lithium ion Inorganic materials 0.000 description 3
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 2
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 1
- 229910014689 LiMnO Inorganic materials 0.000 description 1
- 229910013716 LiNi Inorganic materials 0.000 description 1
- 229910013290 LiNiO 2 Inorganic materials 0.000 description 1
- JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- -1 chalcogenide compound Chemical class 0.000 description 1
- 229910021446 cobalt carbonate Inorganic materials 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 210000001787 dendrite Anatomy 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 239000005486 organic electrolyte Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04G—SCAFFOLDING; FORMS; SHUTTERING; BUILDING IMPLEMENTS OR AIDS, OR THEIR USE; HANDLING BUILDING MATERIALS ON THE SITE; REPAIRING, BREAKING-UP OR OTHER WORK ON EXISTING BUILDINGS
- E04G17/00—Connecting or other auxiliary members for forms, falsework structures, or shutterings
- E04G17/16—Members, e.g. consoles, for attachment to the wall to support girders, beams, or the like carrying forms or moulds for floors, lintels, or transoms
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
- C01G51/40—Complex oxides containing cobalt and at least one other metal element
- C01G51/42—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
- C01P2002/54—Solid solutions containing elements as dopants one element only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
- H01M4/1315—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Architecture (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020040010262A KR100570638B1 (ko) | 2004-02-17 | 2004-02-17 | 리튬 이차 전지용 양극 활물질 및 그의 제조 방법 |
| JP2005038169A JP2005235764A (ja) | 2004-02-17 | 2005-02-15 | リチウム二次電池用正極活物質及びその製造方法 |
| US11/061,969 US7674553B2 (en) | 2004-02-17 | 2005-02-16 | Positive active material for lithium secondary battery and method of preparing same |
| CNB2005100542078A CN100377394C (zh) | 2004-02-17 | 2005-02-17 | 用于锂二次电池的正极活性物质及其制备方法 |
| US12/354,528 US7695869B2 (en) | 2004-02-17 | 2009-01-15 | Positive active material for lithium secondary battery and method of preparing same |
| JP2009147872A JP2009218227A (ja) | 2004-02-17 | 2009-06-22 | リチウム二次電池用正極活物質及びその製造方法 |
| US12/714,341 US7790318B2 (en) | 2004-02-17 | 2010-02-26 | Positive active material for lithium secondary battery and method of preparing same |
| JP2013000051A JP2013093332A (ja) | 2004-02-17 | 2013-01-04 | リチウム二次電池用正極活物質及びその製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020040010262A KR100570638B1 (ko) | 2004-02-17 | 2004-02-17 | 리튬 이차 전지용 양극 활물질 및 그의 제조 방법 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20050081949A KR20050081949A (ko) | 2005-08-22 |
| KR100570638B1 true KR100570638B1 (ko) | 2006-04-12 |
Family
ID=34836787
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020040010262A Expired - Lifetime KR100570638B1 (ko) | 2004-02-17 | 2004-02-17 | 리튬 이차 전지용 양극 활물질 및 그의 제조 방법 |
Country Status (4)
| Country | Link |
|---|---|
| US (3) | US7674553B2 (enExample) |
| JP (3) | JP2005235764A (enExample) |
| KR (1) | KR100570638B1 (enExample) |
| CN (1) | CN100377394C (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5657970B2 (ja) * | 2005-09-27 | 2015-01-21 | 石原産業株式会社 | リチウム・遷移金属複合酸化物及びそれを用いてなるリチウム電池 |
| JP4768562B2 (ja) * | 2005-09-27 | 2011-09-07 | 石原産業株式会社 | リチウム・遷移金属複合酸化物及びその製造方法並びにそれを用いてなるリチウム電池 |
| JP2007200827A (ja) * | 2006-01-30 | 2007-08-09 | Sanyo Electric Co Ltd | 非水電解質二次電池 |
| JP2009087543A (ja) * | 2007-09-27 | 2009-04-23 | Toshiba Corp | 燃料電池 |
| JP5128018B1 (ja) * | 2011-03-11 | 2013-01-23 | 三洋電機株式会社 | 非水電解質二次電池 |
| CN102259935B (zh) * | 2011-06-27 | 2013-01-16 | 北京工业大学 | 一种制备鸟巢形Co3O4的表面活性剂辅助的水热方法 |
| KR101375701B1 (ko) * | 2011-11-11 | 2014-03-20 | 에스케이씨 주식회사 | 플루오르화 포스페이트 함유 리튬이차전지용 양극활물질 및 이의 제조방법 |
| JP6990854B6 (ja) | 2017-04-24 | 2023-12-14 | パナソニックIpマネジメント株式会社 | 正極活物質、および、電池 |
| WO2018220882A1 (ja) | 2017-05-29 | 2018-12-06 | パナソニックIpマネジメント株式会社 | 正極活物質、および、電池 |
| WO2019064816A1 (ja) * | 2017-09-27 | 2019-04-04 | パナソニックIpマネジメント株式会社 | 正極活物質、および、電池 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3019421B2 (ja) * | 1990-12-28 | 2000-03-13 | ソニー株式会社 | 非水電解質二次電池 |
| JP3030141B2 (ja) | 1991-11-01 | 2000-04-10 | 三洋電機株式会社 | 非水系電池 |
| JP3252433B2 (ja) * | 1992-03-23 | 2002-02-04 | 松下電器産業株式会社 | 正極活物質の製造法およびこれを用いた非水電解液二次電池 |
| JPH06243897A (ja) | 1992-12-24 | 1994-09-02 | Fuji Photo Film Co Ltd | 非水二次電池 |
| US5591548A (en) * | 1995-06-05 | 1997-01-07 | Motorola, Inc. | Electrode materials for rechargeable electrochemical cells and method of making same |
| JP3130813B2 (ja) * | 1995-11-24 | 2001-01-31 | 富士化学工業株式会社 | リチウムニッケル複合酸化物、その製造方法および二次電池用正極活物質 |
| JPH09283144A (ja) * | 1996-04-16 | 1997-10-31 | Matsushita Electric Ind Co Ltd | 非水電解液二次電池およびその正極活物質 |
| US6083646A (en) * | 1996-08-29 | 2000-07-04 | Sony Corporation | Non-aqueous electrolyte secondary battery and method for producing cathode material |
| JPH11154509A (ja) * | 1997-11-21 | 1999-06-08 | Japan Storage Battery Co Ltd | 非水電解質二次電池 |
| JPH11273678A (ja) | 1998-03-23 | 1999-10-08 | Sumitomo Metal Mining Co Ltd | 非水系電解質二次電池用正極活物質およびその製造方法ならびに該正極活物質を用いた非水系電解質二次電池 |
| JP4482987B2 (ja) | 1999-12-07 | 2010-06-16 | 株式会社豊田中央研究所 | リチウム二次電池正極活物質用リチウム遷移金属複合酸化物およびその製造方法 |
| JP2001297761A (ja) | 2000-04-12 | 2001-10-26 | Sumitomo Metal Mining Co Ltd | 非水系電解質二次電池用正極活物質 |
| JP2003142093A (ja) * | 2001-11-02 | 2003-05-16 | Japan Storage Battery Co Ltd | 非水電解質二次電池 |
| JP4467951B2 (ja) | 2002-11-06 | 2010-05-26 | 株式会社東芝 | 非水電解質二次電池 |
| WO2004042860A1 (ja) | 2002-11-06 | 2004-05-21 | Kabushiki Kaisha Toshiba | 非水電解質二次電池 |
| JP4169615B2 (ja) * | 2003-03-19 | 2008-10-22 | 三洋電機株式会社 | リチウム二次電池 |
-
2004
- 2004-02-17 KR KR1020040010262A patent/KR100570638B1/ko not_active Expired - Lifetime
-
2005
- 2005-02-15 JP JP2005038169A patent/JP2005235764A/ja active Pending
- 2005-02-16 US US11/061,969 patent/US7674553B2/en active Active
- 2005-02-17 CN CNB2005100542078A patent/CN100377394C/zh not_active Expired - Lifetime
-
2009
- 2009-01-15 US US12/354,528 patent/US7695869B2/en not_active Expired - Lifetime
- 2009-06-22 JP JP2009147872A patent/JP2009218227A/ja active Pending
-
2010
- 2010-02-26 US US12/714,341 patent/US7790318B2/en not_active Expired - Lifetime
-
2013
- 2013-01-04 JP JP2013000051A patent/JP2013093332A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CN1658416A (zh) | 2005-08-24 |
| JP2013093332A (ja) | 2013-05-16 |
| JP2005235764A (ja) | 2005-09-02 |
| KR20050081949A (ko) | 2005-08-22 |
| US7674553B2 (en) | 2010-03-09 |
| US20090127504A1 (en) | 2009-05-21 |
| CN100377394C (zh) | 2008-03-26 |
| JP2009218227A (ja) | 2009-09-24 |
| US20100151121A1 (en) | 2010-06-17 |
| US7695869B2 (en) | 2010-04-13 |
| US7790318B2 (en) | 2010-09-07 |
| US20050181281A1 (en) | 2005-08-18 |
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