KR100544749B1 - 금속소재에 대한 밀착성이 우수한 주석도금강판 처리용크롬-무함유 유화중합수지 조성물 - Google Patents
금속소재에 대한 밀착성이 우수한 주석도금강판 처리용크롬-무함유 유화중합수지 조성물 Download PDFInfo
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- KR100544749B1 KR100544749B1 KR1020010082266A KR20010082266A KR100544749B1 KR 100544749 B1 KR100544749 B1 KR 100544749B1 KR 1020010082266 A KR1020010082266 A KR 1020010082266A KR 20010082266 A KR20010082266 A KR 20010082266A KR 100544749 B1 KR100544749 B1 KR 100544749B1
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- plated steel
- steel sheet
- tin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/02—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using non-aqueous solutions
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
- C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Paints Or Removers (AREA)
Abstract
Description
시편 | 단량체 조성 (중량부) | 도막성 | 유화안정성 | 밀착성 | Tg | TDT | |||||
AA | BA | HEMA | St | MMA | GMA | ||||||
비교예1 | 10 | 40 | 10 | 20 | 20 | 0 | ○ | ○ | 19 | 1.32 | 348.8 |
발명예2 | 10 | 40 | 10 | 19.5 | 20 | 0.5 | ○ | ○ | 4 | 0.94 | 348.3 |
발명예3 | 10 | 40 | 10 | 19 | 20 | 1 | ○ | ○ | 0 | 1.64 | 351.2 |
발명예4 | 10 | 40 | 10 | 17 | 20 | 3 | ○ | △ | 0 | 3.72 | 354.9 |
비교예2 | 10 | 40 | 10 | 15 | 20 | 5 | - | × | - | - | - |
Claims (3)
- 아크릴산 2-10 중량부, 부틸아크릴레이트 30-50 중량부, 하이드록시 에틸 메타크릴레이트 5-10중량부, 스티렌 0-25 중량부, 메틸 메타크릴레이트 10-15 중량부 및 글리시딜 메타크릴레이트 0.5-3중량부로된 금속소재에 대한 밀착성이 우수한 주석도금강판 처리용 유화 중합수지 조성물
- 제 1항에 있어서, 상기 유화중합 수지 조성물은 유화중합시 옥틸페놀 에틸렌 옥사이드 및 노닐페놀 에틸렌 옥사이드로 구성되는 그룹으로 부터 선택된 최소 일종의 비이온계 유화제를 5-7중량부로 사용하여 제조됨을 특징으로 하는 유화중합 수지 조성물.
- 제 1항에 있어서, 상기 유화중합 수지 조성물은 프리-에멀션(pre-emulsion)중합법으로 중합됨을 특징으로 하는 유화중합 수지 조성물.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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KR1020010082266A KR100544749B1 (ko) | 2001-12-21 | 2001-12-21 | 금속소재에 대한 밀착성이 우수한 주석도금강판 처리용크롬-무함유 유화중합수지 조성물 |
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KR1020010082266A KR100544749B1 (ko) | 2001-12-21 | 2001-12-21 | 금속소재에 대한 밀착성이 우수한 주석도금강판 처리용크롬-무함유 유화중합수지 조성물 |
Publications (2)
Publication Number | Publication Date |
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KR20030052371A KR20030052371A (ko) | 2003-06-27 |
KR100544749B1 true KR100544749B1 (ko) | 2006-01-24 |
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KR1020010082266A KR100544749B1 (ko) | 2001-12-21 | 2001-12-21 | 금속소재에 대한 밀착성이 우수한 주석도금강판 처리용크롬-무함유 유화중합수지 조성물 |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5160600A (en) * | 1990-03-05 | 1992-11-03 | Patel Gordhanbai N | Chromic acid free etching of polymers for electroless plating |
US5646211A (en) * | 1992-01-31 | 1997-07-08 | Henkel Corporation | Autodeposition coating composition |
US6040054A (en) * | 1996-02-01 | 2000-03-21 | Toyo Boseki Kabushiki Kaisha | Chromium-free, metal surface-treating composition and surface-treated metal sheet |
-
2001
- 2001-12-21 KR KR1020010082266A patent/KR100544749B1/ko active IP Right Grant
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5160600A (en) * | 1990-03-05 | 1992-11-03 | Patel Gordhanbai N | Chromic acid free etching of polymers for electroless plating |
US5646211A (en) * | 1992-01-31 | 1997-07-08 | Henkel Corporation | Autodeposition coating composition |
US6040054A (en) * | 1996-02-01 | 2000-03-21 | Toyo Boseki Kabushiki Kaisha | Chromium-free, metal surface-treating composition and surface-treated metal sheet |
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Publication number | Publication date |
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KR20030052371A (ko) | 2003-06-27 |
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