KR100513077B1 - 이소시아네이트조성물,그의사용방법,코팅을제조하기위한그의사용및생성된코팅 - Google Patents
이소시아네이트조성물,그의사용방법,코팅을제조하기위한그의사용및생성된코팅 Download PDFInfo
- Publication number
- KR100513077B1 KR100513077B1 KR1019980706749A KR19980706749A KR100513077B1 KR 100513077 B1 KR100513077 B1 KR 100513077B1 KR 1019980706749 A KR1019980706749 A KR 1019980706749A KR 19980706749 A KR19980706749 A KR 19980706749A KR 100513077 B1 KR100513077 B1 KR 100513077B1
- Authority
- KR
- South Korea
- Prior art keywords
- isocyanate
- advantageously
- composition
- compound
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
- C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
- C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/18—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C265/00—Derivatives of isocyanic acid
- C07C265/14—Derivatives of isocyanic acid containing at least two isocyanate groups bound to the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3878—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus
- C08G18/3882—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus having phosphorus bound to oxygen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
- C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- General Preparation And Processing Of Foods (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9602710A FR2745577B1 (fr) | 1996-02-29 | 1996-02-29 | Compositions a base d'isocyanate, leur procede d'utilisation leur utilisation pour realiser des revetements et revetement ainsi obtenu |
| FR96/02710 | 1996-02-29 | ||
| PCT/FR1997/000359 WO1997031960A1 (fr) | 1996-02-29 | 1997-02-28 | Compositions a base d'isocyanate, leur procede d'utilisation, leur utilisation pour realiser des revetements et revetements ainsi obtenus |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR19990087340A KR19990087340A (ko) | 1999-12-27 |
| KR100513077B1 true KR100513077B1 (ko) | 2006-02-28 |
Family
ID=9489839
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019980706749A Expired - Lifetime KR100513077B1 (ko) | 1996-02-29 | 1997-02-28 | 이소시아네이트조성물,그의사용방법,코팅을제조하기위한그의사용및생성된코팅 |
Country Status (15)
| Country | Link |
|---|---|
| EP (2) | EP1524281A2 (https=) |
| JP (2) | JP4138879B2 (https=) |
| KR (1) | KR100513077B1 (https=) |
| CN (2) | CN1273445C (https=) |
| AT (1) | ATE294826T1 (https=) |
| AU (1) | AU1930397A (https=) |
| BR (1) | BR9707712A (https=) |
| CA (1) | CA2247182A1 (https=) |
| DE (2) | DE69733171T2 (https=) |
| ES (1) | ES2140361T3 (https=) |
| FR (1) | FR2745577B1 (https=) |
| HU (1) | HUP9900936A3 (https=) |
| MX (1) | MX229227B (https=) |
| WO (1) | WO1997031960A1 (https=) |
| ZA (1) | ZA971768B (https=) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0963391B1 (fr) | 1997-02-28 | 2004-10-06 | Rodhia Chimie | Revetement pour exterieur, composition utile pour ces revetements et procede d'obtention de ces revetements |
| FR2760242A1 (fr) * | 1997-02-28 | 1998-09-04 | Rhodia Chimie Sa | Revetement pour exterieur, composition utile pour ces revetements et procede d'obtention de ces revetements |
| DE19724199A1 (de) * | 1997-06-09 | 1998-12-10 | Basf Ag | Emulgatoren |
| FR2767836B1 (fr) * | 1997-08-27 | 1999-12-17 | Rhodia Chimie Sa | Utilisation de tensioactif anionique pour la synthese en emulsion de(poly)isocyanates masques, emulsion ainsi obtenue, utilisation des emulsions dans des compositions pour revetement et revetement ainsi obtenu |
| ES2205540T3 (es) * | 1997-08-27 | 2004-05-01 | Rhodia Chimie | Procedimiento de enmascaramiento en emulsion de poliisocianatos. |
| FR2775482A1 (fr) * | 1998-03-02 | 1999-09-03 | Rhodia Chimie Sa | Revetement a deux polyols, composition utile pour ces revetements et procede d'obtention de ces revetements |
| DE19858733A1 (de) | 1998-12-18 | 2000-06-21 | Bayer Ag | Wäßrige 2 K-PUR-Systeme mit erhöhter Schlagzähigkeit und guten Beständigkeitseigenschaften, ein Verfahren zu deren Herstellung und deren Verwendung |
| FR2814171B1 (fr) * | 2000-09-18 | 2003-08-29 | Rhodia Chimie Sa | Procede pour conferer a des substrats en bois une resistance elevee a l'attaque des produits chimiques |
| FR2853662B1 (fr) * | 2003-04-08 | 2008-07-04 | Rhodia Chimie Sa | Compositions a base d'isocyanate, leur procede d'utilisation pour realiser des adhesifs et joints de colle aromatique ainsi obtenus |
| FR2853661B1 (fr) * | 2003-04-08 | 2008-07-04 | Rhodia Chimie Sa | Compositions a base d'isocyanate, leur utilisation pour realiser des adhesifs et joints de colle aliphatique ainsi obtenus |
| FR2855768B1 (fr) * | 2003-05-21 | 2006-06-16 | Rhodia Chimie Sa | Compositions a base d'isocyanate, leur procede d'utilisation pour realiser des vetements et revetements ainsi obtenus |
| EP1627004B1 (fr) * | 2003-05-21 | 2012-02-22 | Perstorp France | Compositions a base d'isocyanate, leur procede d'utilisation, leur utilisation pour realiser des revetements a adherence directe et revetements ainsi obtenus |
| FR2870253B1 (fr) * | 2004-05-11 | 2008-08-08 | Rhodia Chimie Sa | Compositions a base d'isocyanate, leur procede d'utilisation, leur utilisation pour realiser des revetements a adherence directe et revetements ainsi obtenus |
| DE10350242A1 (de) * | 2003-10-27 | 2005-05-19 | Basf Ag | Wasseremulgierbare Isocyanate mit verbesserten Eigenschaften |
| FR2879616B1 (fr) * | 2004-12-21 | 2007-05-25 | Rhodia Chimie Sa | Composition polyisacyanate a proprietes anti-chocs ameliorees |
| FR2880021B1 (fr) * | 2004-12-23 | 2007-02-09 | Rhodia Chimie Sa | Compositions isocyanates presentant de bonnes proprietes de melange et utilisation de derives silyles comme adjuvants de compositions isocyanates, notamment de melange |
| JP2007084801A (ja) * | 2005-08-22 | 2007-04-05 | Kansai Paint Co Ltd | 水性2液型クリヤ塗料組成物及び複層塗膜形成方法 |
| WO2007110425A1 (fr) * | 2006-03-29 | 2007-10-04 | Rhodia Operations | Melange a base de polyisocyanate et d'un solvant de type acetal, emulsion aqueuse obtenue a partir de ce melange et utilisation de cette emulsion pour la fabrication de revetements et d'adhesifs |
| JP5424643B2 (ja) * | 2006-10-23 | 2014-02-26 | 関西ペイント株式会社 | 水性2液型クリヤ塗料組成物及び上塗り複層塗膜形成方法 |
| FR2915750B1 (fr) * | 2007-05-03 | 2011-05-06 | Rhodia Recherches & Tech | Melange a base de polyisocyanate et d'un solvant de type ether ester, emulsion aqueuse obtenue a partir de ce melange et utilisation de cette emulsion pour la fabrication de revetements et d'adhesifs |
| FR2923835B1 (fr) * | 2007-11-20 | 2009-12-11 | Rhodia Operations | Nouvelles compositions polyisocyanates hydrophiles a base d'esters de phosphate. |
| EP2154206A1 (de) | 2008-07-26 | 2010-02-17 | Bayer MaterialScience AG | Stabilisierte Nanopartikeldispersionen |
| EP2236532A1 (de) * | 2009-03-31 | 2010-10-06 | Bayer MaterialScience AG | Nanopartikelmodifizierte hydrophile Polyisocyanate |
| EP2236531A1 (de) | 2009-03-31 | 2010-10-06 | Bayer MaterialScience AG | Neue wäßrige 2K PUR-Beschichtungssysteme für verbesserten Korrosionsschutz |
| ES2715851T3 (es) | 2014-08-29 | 2019-06-06 | Covestro Deutschland Ag | Esteres de poli(ácido aspártico) hidrófilos |
| US10639672B2 (en) | 2015-01-29 | 2020-05-05 | Kansai Paint Co., Ltd. | Method for forming multilayer coating film |
| US10508212B2 (en) | 2015-01-30 | 2019-12-17 | Kansai Paint Co., Ltd. | Method for forming multilayer coating film |
| EP3271412B1 (de) | 2015-03-16 | 2020-02-05 | Covestro Deutschland AG | Hydrophile polyisocyanate auf basis von 1,5-diisocyanatopentan |
| EP3085720A1 (de) * | 2015-04-21 | 2016-10-26 | Covestro Deutschland AG | Hydrophil modifizierter polyisocyanuratkunststoff und verfahren zu dessen herstellung |
| KR102555281B1 (ko) | 2015-09-09 | 2023-07-14 | 코베스트로 도이칠란트 아게 | 스크래치-내성 2-성분 폴리우레탄 코팅 |
| EP3347392B1 (en) | 2015-09-09 | 2021-03-10 | Covestro Intellectual Property GmbH & Co. KG | Scratch-resistant aqueous 2k pu coatings |
| EP3824009B1 (en) | 2018-07-20 | 2022-03-09 | Covestro Intellectual Property GmbH & Co. KG | Ionically hydrophilized polyisocyanates with improved drying |
| EP3599255A1 (en) | 2018-07-23 | 2020-01-29 | Covestro Deutschland AG | Ionically hydrophilized polyisocyanates with improved drying |
| US20230080775A1 (en) | 2020-02-17 | 2023-03-16 | Covestro Deutschland Ag | Polyisocyanate preparations |
| EP4116349A1 (de) | 2021-07-07 | 2023-01-11 | Covestro Deutschland AG | Hydrophil-modifizierte silan- und thioallophanatstrukturen aufweisende polyisocyanate |
| EP4116347A1 (de) | 2021-07-07 | 2023-01-11 | Covestro Deutschland AG | Zweikomponentige polyurethandispersionsklebstoffe |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0367667A2 (en) * | 1988-10-28 | 1990-05-09 | Kyowa Hakko Kogyo Co., Ltd. | A new polyurethane resin containing at least one phosphoric acid group and its use in a magnetic coating formulation and a magnetic recording medium |
| US5473011A (en) * | 1991-04-23 | 1995-12-05 | Bayer Aktiengesellschaft | Polyisocyanate mixtures, a process for their preparation and their use as cross-linking agents in coating compositions |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1278286A (fr) * | 1959-12-17 | 1961-12-08 | Hoechst Ag | Nouveaux carbamylphosphates et leur préparation |
| DE2816815A1 (de) * | 1978-04-18 | 1979-10-31 | Bayer Ag | In wasser dispergierbare oder loesliche polyurethane, sowie ein verfahren zu ihrer herstellung |
| IN152487B (https=) * | 1978-09-29 | 1984-01-28 | Upjohn Co | |
| DE3108537A1 (de) * | 1981-03-06 | 1982-11-04 | Bayer Ag, 5090 Leverkusen | Waessrige isocyanat-emulsionen sowie deren verwendung als bindemittel in einem verfahren zur herstellung von formkoerpern |
| ES2172532T3 (es) * | 1993-03-31 | 2002-10-01 | Rhodia Chimie Sa | Procedimiento de preparacion de emulsiones acuosas de aceites y/o de gomas y/o resinas (poli)isocianatos ventajosamente encubiertos y emulsiones obtenidas. |
-
1996
- 1996-02-29 FR FR9602710A patent/FR2745577B1/fr not_active Expired - Fee Related
-
1997
- 1997-02-28 DE DE69733171T patent/DE69733171T2/de not_active Expired - Lifetime
- 1997-02-28 EP EP05001315A patent/EP1524281A2/fr not_active Withdrawn
- 1997-02-28 EP EP97907149A patent/EP0815153B1/fr not_active Expired - Lifetime
- 1997-02-28 AT AT97907149T patent/ATE294826T1/de not_active IP Right Cessation
- 1997-02-28 ZA ZA971768A patent/ZA971768B/xx unknown
- 1997-02-28 ES ES97907149T patent/ES2140361T3/es not_active Expired - Lifetime
- 1997-02-28 JP JP53067697A patent/JP4138879B2/ja not_active Expired - Lifetime
- 1997-02-28 AU AU19303/97A patent/AU1930397A/en not_active Abandoned
- 1997-02-28 CN CNB031041051A patent/CN1273445C/zh not_active Expired - Lifetime
- 1997-02-28 HU HU9900936A patent/HUP9900936A3/hu unknown
- 1997-02-28 BR BR9707712A patent/BR9707712A/pt not_active IP Right Cessation
- 1997-02-28 DE DE0815153T patent/DE815153T1/de active Pending
- 1997-02-28 CA CA002247182A patent/CA2247182A1/fr not_active Abandoned
- 1997-02-28 KR KR1019980706749A patent/KR100513077B1/ko not_active Expired - Lifetime
- 1997-02-28 CN CNB971935599A patent/CN1152073C/zh not_active Expired - Lifetime
- 1997-02-28 WO PCT/FR1997/000359 patent/WO1997031960A1/fr not_active Ceased
-
1998
- 1998-08-27 MX MX9806970A patent/MX229227B/es active IP Right Grant
-
2006
- 2006-09-14 JP JP2006249975A patent/JP2007016047A/ja active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0367667A2 (en) * | 1988-10-28 | 1990-05-09 | Kyowa Hakko Kogyo Co., Ltd. | A new polyurethane resin containing at least one phosphoric acid group and its use in a magnetic coating formulation and a magnetic recording medium |
| US5473011A (en) * | 1991-04-23 | 1995-12-05 | Bayer Aktiengesellschaft | Polyisocyanate mixtures, a process for their preparation and their use as cross-linking agents in coating compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1152073C (zh) | 2004-06-02 |
| ES2140361T3 (es) | 2005-11-01 |
| HUP9900936A1 (hu) | 1999-07-28 |
| MX229227B (es) | 2005-07-19 |
| HUP9900936A3 (en) | 1999-11-29 |
| CN1273445C (zh) | 2006-09-06 |
| JP4138879B2 (ja) | 2008-08-27 |
| EP0815153B1 (fr) | 2005-05-04 |
| DE69733171T2 (de) | 2006-02-16 |
| JP2007016047A (ja) | 2007-01-25 |
| CN1215415A (zh) | 1999-04-28 |
| WO1997031960A1 (fr) | 1997-09-04 |
| DE815153T1 (de) | 2000-04-06 |
| ZA971768B (en) | 1998-08-28 |
| EP1524281A2 (fr) | 2005-04-20 |
| AU1930397A (en) | 1997-09-16 |
| KR19990087340A (ko) | 1999-12-27 |
| DE69733171D1 (de) | 2005-06-09 |
| FR2745577B1 (fr) | 2004-09-24 |
| EP0815153A1 (fr) | 1998-01-07 |
| JP2000506195A (ja) | 2000-05-23 |
| FR2745577A1 (fr) | 1997-09-05 |
| BR9707712A (pt) | 1999-04-06 |
| CN1515638A (zh) | 2004-07-28 |
| ES2140361T1 (es) | 2000-03-01 |
| ATE294826T1 (de) | 2005-05-15 |
| CA2247182A1 (fr) | 1997-09-04 |
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