KR100508715B1 - 고성능 이오노머 블렌드 - Google Patents
고성능 이오노머 블렌드 Download PDFInfo
- Publication number
- KR100508715B1 KR100508715B1 KR10-1999-7001549A KR19997001549A KR100508715B1 KR 100508715 B1 KR100508715 B1 KR 100508715B1 KR 19997001549 A KR19997001549 A KR 19997001549A KR 100508715 B1 KR100508715 B1 KR 100508715B1
- Authority
- KR
- South Korea
- Prior art keywords
- polyamide
- ionomer
- weight
- blend
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 229920000554 ionomer Polymers 0.000 title claims abstract description 109
- 239000000203 mixture Substances 0.000 title claims abstract description 75
- 229920002647 polyamide Polymers 0.000 claims abstract description 87
- 239000004952 Polyamide Substances 0.000 claims abstract description 86
- 229920001577 copolymer Polymers 0.000 claims abstract description 59
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000005977 Ethylene Substances 0.000 claims abstract description 31
- 239000002253 acid Substances 0.000 claims description 75
- 238000006386 neutralization reaction Methods 0.000 claims description 65
- 238000002156 mixing Methods 0.000 claims description 49
- 229920002292 Nylon 6 Polymers 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 23
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 17
- 150000001768 cations Chemical class 0.000 claims description 17
- 229910052725 zinc Inorganic materials 0.000 claims description 17
- 239000011701 zinc Substances 0.000 claims description 17
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- -1 alkyl methacrylates Chemical class 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 11
- 229920006020 amorphous polyamide Polymers 0.000 claims description 11
- 229920006114 semi-crystalline semi-aromatic polyamide Polymers 0.000 claims description 11
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 10
- 239000012963 UV stabilizer Substances 0.000 claims description 8
- 210000003195 fascia Anatomy 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 5
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 claims description 4
- 229920001897 terpolymer Polymers 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 3
- JAWQFSAXQNAIJO-UHFFFAOYSA-N benzene-1,3-dicarboxamide;hexane-1,6-diamine Chemical compound NCCCCCCN.NC(=O)C1=CC=CC(C(N)=O)=C1 JAWQFSAXQNAIJO-UHFFFAOYSA-N 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 239000012798 spherical particle Substances 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000006750 UV protection Effects 0.000 abstract description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 58
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- 239000004677 Nylon Substances 0.000 description 34
- 229920001778 nylon Polymers 0.000 description 34
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- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 238000001125 extrusion Methods 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
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- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 7
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- 229920002302 Nylon 6,6 Polymers 0.000 description 6
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 6
- 239000000395 magnesium oxide Substances 0.000 description 6
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- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- 239000006057 Non-nutritive feed additive Substances 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
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- 150000001735 carboxylic acids Chemical class 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000000113 differential scanning calorimetry Methods 0.000 description 4
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
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- 239000011777 magnesium Substances 0.000 description 4
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- 229920000573 polyethylene Polymers 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229920005657 Surlyn® 9320 Polymers 0.000 description 3
- 229920006097 Ultramide® Polymers 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 2
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 229920000299 Nylon 12 Polymers 0.000 description 2
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- 229920000577 Nylon 6/66 Polymers 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229920003365 Selar® Polymers 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- TZYHIGCKINZLPD-UHFFFAOYSA-N azepan-2-one;hexane-1,6-diamine;hexanedioic acid Chemical compound NCCCCCCN.O=C1CCCCCN1.OC(=O)CCCCC(O)=O TZYHIGCKINZLPD-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical group CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 2
- 239000004715 ethylene vinyl alcohol Substances 0.000 description 2
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- 239000002667 nucleating agent Substances 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
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- QQVIHTHCMHWDBS-UHFFFAOYSA-N perisophthalic acid Natural products OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
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- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
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- SGPDKAGVCMVLGQ-UHFFFAOYSA-N (2-dodecoxy-3-hydroxyphenyl)-phenylmethanone Chemical compound CCCCCCCCCCCCOC1=C(O)C=CC=C1C(=O)C1=CC=CC=C1 SGPDKAGVCMVLGQ-UHFFFAOYSA-N 0.000 description 1
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
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- OLFNXLXEGXRUOI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-phenylpropan-2-yl)phenol Chemical compound C=1C(N2N=C3C=CC=CC3=N2)=C(O)C(C(C)(C)C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=CC=C1 OLFNXLXEGXRUOI-UHFFFAOYSA-N 0.000 description 1
- IYAZLDLPUNDVAG-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 IYAZLDLPUNDVAG-UHFFFAOYSA-N 0.000 description 1
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- ZVVFVKJZNVSANF-UHFFFAOYSA-N 6-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]hexyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCCCCCCOC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 ZVVFVKJZNVSANF-UHFFFAOYSA-N 0.000 description 1
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- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- ZMUCVNSKULGPQG-UHFFFAOYSA-N dodecanedioic acid;hexane-1,6-diamine Chemical compound NCCCCCCN.OC(=O)CCCCCCCCCCC(O)=O ZMUCVNSKULGPQG-UHFFFAOYSA-N 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical group C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- HYONQIJZVYCWOP-UHFFFAOYSA-N n',n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine Chemical compound C1C(C)(C)NC(C)(C)CC1N(CCCCCCN)C1CC(C)(C)NC(C)(C)C1 HYONQIJZVYCWOP-UHFFFAOYSA-N 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- IGEIPFLJVCPEKU-UHFFFAOYSA-N pentan-2-amine Chemical compound CCCC(C)N IGEIPFLJVCPEKU-UHFFFAOYSA-N 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000012899 standard injection Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
- C08L23/0876—Salts thereof, i.e. ionomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8/703,294 | 1996-08-26 | ||
| US08/703,294 US5866658A (en) | 1996-08-26 | 1996-08-26 | High performance ionomer blends |
| US08/703,294 | 1996-08-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20000035855A KR20000035855A (ko) | 2000-06-26 |
| KR100508715B1 true KR100508715B1 (ko) | 2005-08-17 |
Family
ID=24824823
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR10-1999-7001549A Expired - Lifetime KR100508715B1 (ko) | 1996-08-26 | 1997-08-25 | 고성능 이오노머 블렌드 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5866658A (enExample) |
| EP (1) | EP0920476B1 (enExample) |
| JP (1) | JP4302774B2 (enExample) |
| KR (1) | KR100508715B1 (enExample) |
| BR (1) | BR9711199A (enExample) |
| CA (1) | CA2263543C (enExample) |
| DE (1) | DE69714049T2 (enExample) |
| WO (1) | WO1998008901A1 (enExample) |
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|---|---|---|---|---|
| ZA964731B (en) | 1995-06-07 | 1997-01-07 | Avery Dennison Corp A Legal Bo | Extrusion coating process for making protective and decorative films |
| WO2000076834A1 (en) * | 1999-06-10 | 2000-12-21 | Plastech Engineered Products, Inc. | Exterior vehicle component with moldable thermoplastic composition and ultraviolet stabilized color concentrate |
| WO2001021712A1 (en) * | 1999-09-23 | 2001-03-29 | E.I. Du Pont De Nemours And Company | Toughened nylon compositions with improved flow and processes for their preparation |
| US20030018135A1 (en) * | 1999-09-23 | 2003-01-23 | Pagilagan Rolando Umali | Toughened nylon compositions with improved flow and processes for their preparation |
| ATE299096T1 (de) * | 2000-04-14 | 2005-07-15 | Du Pont | Mehrschichtige, koextrudierte dekoroberfläche aus ionomer |
| US6552787B1 (en) | 2000-09-29 | 2003-04-22 | General Electric Company | Rapid non-destructive screening methods for polymeric coatings and materials |
| US6998084B2 (en) * | 2001-02-16 | 2006-02-14 | Daimlerchrysler Corporation | Co-extruded pigmented/clear coated polymeric coating for an article such as automotive exterior body panels |
| US20040161623A1 (en) * | 2001-03-29 | 2004-08-19 | Domine Joseph D | Ionomer laminates and articles formed from ionomer laminates |
| WO2002078953A1 (en) * | 2001-03-29 | 2002-10-10 | Exxonmobil Chemical Patents Inc. | Ionomer laminates and articles formed from ionomer laminates |
| US7402629B2 (en) * | 2001-06-26 | 2008-07-22 | Acushnet Company | Highly-neutralized acid polymers and their use in golf balls |
| JP2005509712A (ja) * | 2001-11-19 | 2005-04-14 | エクソンモービル・ケミカル・パテンツ・インク | 耐衝撃性組成物 |
| US6569947B1 (en) | 2002-01-25 | 2003-05-27 | E. I. Du Pont De Nemours And Company | Ionomer/high density polyethylene blends with improved impact |
| US6756443B2 (en) | 2002-01-25 | 2004-06-29 | E. I. Du Pont De Nemours And Company | Ionomer/polyamide blends with improved flow and impact properties |
| US20040144415A1 (en) * | 2002-12-03 | 2004-07-29 | Arhart Richard J. | Ionomer/nylon films for use as backing layer for photovoltaic cells |
| WO2005035244A1 (en) * | 2003-10-07 | 2005-04-21 | E.I. Dupont De Nemours And Company | Multi-layer ionomer sheet having improved weathering |
| US20060057392A1 (en) * | 2003-10-07 | 2006-03-16 | Smillie Benjamin A | Multi-layer sheet having a weatherable surface layer |
| KR20060134922A (ko) * | 2003-10-07 | 2006-12-28 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 내후성 표층을 갖는 다층 시트 |
| KR20060134920A (ko) * | 2003-10-07 | 2006-12-28 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 이오노머 층을 포함하는 다층 시트 |
| CA2545529A1 (en) * | 2003-11-26 | 2005-06-16 | E.I. Du Pont De Nemours And Company | High flow, toughened, weatherable polyamide compositions containing a blend of stabilizers |
| US20050136272A1 (en) * | 2003-12-23 | 2005-06-23 | Vanrheenen Paul | Gloss reducing polymer composition |
| PL1756225T3 (pl) * | 2004-06-08 | 2009-04-30 | Lanxess Deutschland Gmbh | Masy do formowania z poliamidów o polepszonej zdolności płynięcia |
| DE102005050958A1 (de) * | 2005-10-25 | 2007-04-26 | Lanxess Deutschland Gmbh | Polyamid-Formmassen mit verbesserter Fließfähigkeit |
| US20070100076A1 (en) * | 2005-10-28 | 2007-05-03 | Hayes Richard A | High modulus ionomers for packaging |
| US7445683B2 (en) * | 2005-11-30 | 2008-11-04 | E. I. Du Pont De Nemours And Company | Thermoplastic resin compositions suitable for use in laminated safety glass |
| US7144938B1 (en) | 2005-12-02 | 2006-12-05 | E. I. Du Pont De Nemours And Company | Composition comprising ionomer and polyamide |
| US8198355B2 (en) * | 2006-06-15 | 2012-06-12 | E. I. Du Pont De Nemours And Company | Nanocomposite compositions of polyamides and sepiolite-type clays |
| US7592056B2 (en) * | 2006-10-24 | 2009-09-22 | E.I. Du Pont De Nemours And Company | Composition comprising ionomer and polyamide |
| US8372518B1 (en) | 2006-11-30 | 2013-02-12 | E I Du Pont De Nemours And Company | Antistatic styrenic polymer compositions and articles therefrom |
| US7544742B2 (en) * | 2006-11-30 | 2009-06-09 | E.I. Du Pont De Nemours And Company | Antistatic polyamide composition and articles therewith |
| US20080132628A1 (en) * | 2006-11-30 | 2008-06-05 | Karlheinz Hausmann | Antistatic styrenic polymer compositions and articles therefrom |
| US8802778B2 (en) * | 2008-04-03 | 2014-08-12 | Bridgestone Sports Co., Ltd. | Golf ball material, golf ball and method for preparing golf ball material |
| US20100166991A1 (en) * | 2008-12-30 | 2010-07-01 | E.I. Du Pont De Nemours And Company | High-clarity blended ionomer compositions and articles comprising the same |
| ATE522564T1 (de) * | 2009-06-18 | 2011-09-15 | Ems Patent Ag | Photovoltaikmodul-monorückfolie, verfahren zu deren herstellung sowie deren verwendung bei der produktion photovoltaischer module |
| US8895138B2 (en) * | 2009-11-17 | 2014-11-25 | E I Du Pont De Nemours And Company | Impact resistant composite article |
| CA2799593C (en) * | 2010-06-11 | 2018-10-30 | E. I. Du Pont De Nemours And Company | Polymeric blends useful in ballistic applications |
| BR112012028590A2 (pt) | 2010-06-11 | 2016-08-02 | Du Pont | composição termoplástica, uso de uma composição termoplástica, equipamento de proteção pessoal e tecido balístico reforçado |
| US8586663B2 (en) | 2011-02-08 | 2013-11-19 | E I Du Pont De Nemours And Company | Polymer composition comprising polyamide and ionomer |
| US8921460B2 (en) * | 2011-06-21 | 2014-12-30 | E. I. Du Pont De Nemours And Company | Heat-stabilized acrylate elastomer composition and process for its production |
| US8791180B2 (en) | 2011-06-21 | 2014-07-29 | E I Du Pont De Nemours And Company | Process for production of a heat-stabilized acrylate polymer |
| US20130171394A1 (en) | 2011-12-30 | 2013-07-04 | E. I. Du Pont De Nemours And Company | Polyamide Composition Containing Ionomer |
| US8906479B2 (en) | 2011-12-30 | 2014-12-09 | E I Du Pont De Nemours And Company | Compositions of polyamide and ionomer |
| US20130172470A1 (en) * | 2011-12-30 | 2013-07-04 | E I Du Pont De Nemours And Company | Optionally reinforced polyamide composition containing ionomer |
| US10406402B2 (en) | 2012-02-29 | 2019-09-10 | Acushnet Company | Golf balls containing layers made from transparent polyamide and plasticizer compositions |
| US8987360B2 (en) | 2012-02-29 | 2015-03-24 | Acushnet Company | Golf balls having layers based on polyamide and fatty acid amide blends |
| US9522304B2 (en) | 2012-02-29 | 2016-12-20 | Acushnet Company | Golf balls having layers based on polyamide, ionomer, and fatty acid amide blends |
| US8905862B2 (en) | 2012-02-29 | 2014-12-09 | Acushnet Company | Golf balls containing layers based on polyamide and fatty acid salt blends |
| US9975006B2 (en) | 2012-02-29 | 2018-05-22 | Acushnet Company | Golf balls containing layers made from transparent polyamide and plasticizer compositions |
| EP2690127A1 (de) * | 2012-07-27 | 2014-01-29 | nolax AG | Verfahren zur Herstellung einer Polymer-Dispersion und deren Verwendung |
| US20150135937A1 (en) | 2013-11-18 | 2015-05-21 | E I Du Pont De Nemours And Company | Method to produce ballistic and stab resistant structures for garments and structures produced by the method |
| US20160347929A1 (en) | 2014-02-24 | 2016-12-01 | E.I. Du Pont De Nemours And Company | Plasticized polyamide compositions |
| CN106232724A (zh) | 2014-04-29 | 2016-12-14 | 纳幕尔杜邦公司 | 具有改善的背板的太阳能电池模块 |
| WO2015168075A1 (en) | 2014-04-29 | 2015-11-05 | E. I. Du Pont De Nemours And Company | Photovoltaic cells with improved backsheet |
| CN106457789A (zh) | 2014-04-29 | 2017-02-22 | 纳幕尔杜邦公司 | 具有改善的多层背板的光伏电池 |
| US10323908B2 (en) | 2015-05-08 | 2019-06-18 | E I Du Pont De Nemours And Company | Ballistic and stab resistant composite |
| EP3120722B1 (en) * | 2015-07-24 | 2020-05-20 | Performance Materials NA, Inc. | Thermoformable polyamide ionomer material for heel counter and toe puff |
| US11353640B2 (en) | 2015-09-11 | 2022-06-07 | 3M Innovative Properties Company | Durable retroreflective elements with an ionic copolymer core |
| WO2018123804A1 (ja) | 2016-12-27 | 2018-07-05 | 三井・デュポンポリケミカル株式会社 | ダイシングフィルム基材およびダイシングフィルム |
| CN108546406A (zh) * | 2018-03-29 | 2018-09-18 | 东莞市树林自动化科技有限公司 | 一种超强度超韧性去毛边喷砂及其制备方法 |
| US11919979B2 (en) | 2018-07-31 | 2024-03-05 | Dow Global Technologies, Llc | Ionomers of ethylene acid copolymers with enhanced creep resistance |
| WO2020028245A1 (en) | 2018-07-31 | 2020-02-06 | E. I. Du Pont De Nemours And Company | Ionomers of ethylene acid copolymers with enhanced creep resistance |
| EP3950737B1 (en) * | 2019-04-02 | 2025-12-17 | Japan Polyethylene Corporation | Polyamide resin composition comprising a specific ionomer |
| EP4074759A4 (en) * | 2019-12-11 | 2024-02-21 | Dow-Mitsui Polychemicals Co., Ltd. | METHOD FOR PRODUCING A RESIN COMPOSITION AND METHOD FOR PRODUCING A MOLDED ARTICLE |
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| US5112908A (en) * | 1986-12-23 | 1992-05-12 | E. I. Du Pont De Nemours And Company | Tough polyamide compositions having high melt flow for complex moldings |
| US4885340A (en) * | 1988-03-28 | 1989-12-05 | Asahi Kasei Kogyo Kabushiki Kaisha | High impact polyamide composition |
| JP2599794B2 (ja) * | 1989-08-01 | 1997-04-16 | 三井・デュポンポリケミカル株式会社 | アイオノマー組成物 |
| JP2521820B2 (ja) * | 1989-09-21 | 1996-08-07 | 三井・デュポンポリケミカル株式会社 | アイオノマ―組成物 |
| DE69212995T2 (de) * | 1991-03-05 | 1997-01-16 | Allied Signal Inc | Flexible nylon-enthaltende, thermoplastische zusammensetzungen |
-
1996
- 1996-08-26 US US08/703,294 patent/US5866658A/en not_active Expired - Lifetime
-
1997
- 1997-08-25 KR KR10-1999-7001549A patent/KR100508715B1/ko not_active Expired - Lifetime
- 1997-08-25 JP JP51175198A patent/JP4302774B2/ja not_active Expired - Lifetime
- 1997-08-25 WO PCT/US1997/014799 patent/WO1998008901A1/en not_active Ceased
- 1997-08-25 EP EP97939503A patent/EP0920476B1/en not_active Expired - Lifetime
- 1997-08-25 DE DE69714049T patent/DE69714049T2/de not_active Expired - Lifetime
- 1997-08-25 CA CA002263543A patent/CA2263543C/en not_active Expired - Lifetime
- 1997-08-25 BR BR9711199A patent/BR9711199A/pt not_active IP Right Cessation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63193946A (ja) * | 1987-01-27 | 1988-08-11 | イー・アイ・デユポン・デ・ニモアス・アンド・カンパニー | 熱可塑性成形組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69714049T2 (de) | 2003-04-10 |
| JP2000516984A (ja) | 2000-12-19 |
| US5866658A (en) | 1999-02-02 |
| CA2263543A1 (en) | 1998-03-05 |
| JP4302774B2 (ja) | 2009-07-29 |
| CA2263543C (en) | 2008-06-17 |
| KR20000035855A (ko) | 2000-06-26 |
| BR9711199A (pt) | 1999-08-17 |
| EP0920476B1 (en) | 2002-07-17 |
| WO1998008901A1 (en) | 1998-03-05 |
| DE69714049D1 (de) | 2002-08-22 |
| EP0920476A1 (en) | 1999-06-09 |
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