KR100209982B1 - 고순도 수소의 제조 방법 - Google Patents
고순도 수소의 제조 방법 Download PDFInfo
- Publication number
- KR100209982B1 KR100209982B1 KR1019910020454A KR910020454A KR100209982B1 KR 100209982 B1 KR100209982 B1 KR 100209982B1 KR 1019910020454 A KR1019910020454 A KR 1019910020454A KR 910020454 A KR910020454 A KR 910020454A KR 100209982 B1 KR100209982 B1 KR 100209982B1
- Authority
- KR
- South Korea
- Prior art keywords
- hydrogen
- gas
- gas mixture
- mixture
- carbon monoxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
- C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
- C01B2203/0288—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing two CO-shift steps
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
- C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0435—Catalytic purification
- C01B2203/045—Purification by catalytic desulfurisation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0495—Composition of the impurity the impurity being water
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
- C01B2203/0816—Heating by flames
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
- C01B2203/0822—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel the fuel containing hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0833—Heating by indirect heat exchange with hot fluids, other than combustion gases, product gases or non-combustive exothermic reaction product gases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0872—Methods of cooling
- C01B2203/0877—Methods of cooling by direct injection of fluid
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0872—Methods of cooling
- C01B2203/0883—Methods of cooling by indirect heat exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0872—Methods of cooling
- C01B2203/0888—Methods of cooling by evaporation of a fluid
- C01B2203/0894—Generation of steam
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/146—At least two purification steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Industrial Gases (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/614,335 US5152976A (en) | 1990-11-16 | 1990-11-16 | Process for producing high purity hydrogen |
| US614,335 | 1991-03-15 | ||
| US07/669,796 US5152975A (en) | 1991-03-15 | 1991-03-15 | Process for producing high purity hydrogen |
| US669,796 | 1996-06-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR920009687A KR920009687A (ko) | 1992-06-25 |
| KR100209982B1 true KR100209982B1 (ko) | 1999-07-15 |
Family
ID=27087214
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019910020454A Expired - Lifetime KR100209982B1 (ko) | 1990-11-16 | 1991-11-14 | 고순도 수소의 제조 방법 |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0486174B1 (enExample) |
| JP (1) | JP3638618B2 (enExample) |
| KR (1) | KR100209982B1 (enExample) |
| CN (1) | CN1025844C (enExample) |
| AU (1) | AU645628B2 (enExample) |
| DE (1) | DE69104461T2 (enExample) |
| ES (1) | ES2061189T3 (enExample) |
| MX (1) | MX9101972A (enExample) |
| TW (1) | TW197997B (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100884701B1 (ko) | 2007-08-22 | 2009-02-19 | 한국에너지기술연구원 | 연료개질 장치에서 압력구동을 이용한 이산화탄소 흡착제재생방법 |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5458808A (en) * | 1994-01-07 | 1995-10-17 | Texaco Inc. | Process for continuously controlling the heat content of a partial oxidation unit feed-gas stream |
| CN1067348C (zh) * | 1996-12-19 | 2001-06-20 | 中国石化茂名石油化工公司 | 氢气保温保压循环方法 |
| DE19902926C2 (de) * | 1999-01-26 | 2001-01-04 | Daimler Chrysler Ag | Reaktoranlage und Betriebsverfahren hierfür |
| AU2001268019A1 (en) * | 2000-07-07 | 2002-01-21 | National University Of Singapore | Method for hydrogen production |
| JP4568448B2 (ja) * | 2001-03-30 | 2010-10-27 | 出光興産株式会社 | 水素製造プラントおよび水素製造方法 |
| DE10334590B4 (de) * | 2003-07-28 | 2006-10-26 | Uhde Gmbh | Verfahren zur Gewinnung von Wasserstoff aus einem methanhaltigen Gas, insbesondere Erdgas und Anlage zur Durchführung des Verfahrens |
| DE102006045379B4 (de) * | 2006-09-26 | 2008-07-31 | Lurgi Ag | Verfahren zur Herstellung von Wasserstoff |
| JP5288840B2 (ja) * | 2008-03-17 | 2013-09-11 | Jx日鉱日石エネルギー株式会社 | 水素製造システム |
| US7909913B2 (en) | 2008-07-17 | 2011-03-22 | Air Products And Chemicals, Inc. | Gas purification by adsorption of hydrogen sulfide |
| JP2012521955A (ja) * | 2009-03-30 | 2012-09-20 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 精製合成ガス流を生成する方法 |
| EP2414074A1 (en) * | 2009-03-30 | 2012-02-08 | Shell Internationale Research Maatschappij B.V. | Process for producing purified synthesis gas |
| US8808654B2 (en) | 2009-09-29 | 2014-08-19 | Praxair Technology, Inc. | Process for sulfur removal from refinery off gas |
| CN101773765B (zh) * | 2010-01-14 | 2012-07-25 | 党延斋 | 炼厂干气中氢气的回收方法 |
| US8518356B2 (en) * | 2010-07-27 | 2013-08-27 | Air Products And Chemicals, Inc. | Method and apparatus for adjustably treating a sour gas |
| US8206669B2 (en) * | 2010-07-27 | 2012-06-26 | Air Products And Chemicals, Inc. | Method and apparatus for treating a sour gas |
| CN102614764B (zh) * | 2011-01-27 | 2014-03-26 | 中科合成油工程有限公司 | 一种费托合成尾气处理的工艺 |
| CN103922280B (zh) * | 2014-04-18 | 2017-10-20 | 四川省达科特能源科技股份有限公司 | 一种灵活焦化气化气制氢工艺方法 |
| WO2016059566A1 (en) * | 2014-10-15 | 2016-04-21 | Sabic Global Technologies B.V. | Integrated syngas-based production of dimethyl carbonate |
| PL3448576T3 (pl) * | 2016-04-26 | 2024-09-16 | Newcastle Innovation Limited | Urządzenie podające do separatora cząstek stałych, separator cząstek stałych i sposób separacji cząstek |
| US10622656B2 (en) * | 2017-10-11 | 2020-04-14 | Saudi Arabian Oil Company | Method and system for capturing high-purity CO2 in a hydrocarbon facility |
| CN110937573B (zh) * | 2019-10-28 | 2023-08-22 | 中科液态阳光(苏州)氢能科技发展有限公司 | 氢气混合余气重整方法 |
| CN112626560B (zh) * | 2020-12-14 | 2022-04-08 | 阳光电源股份有限公司 | 电解槽设备及其气体回收装置、电解气体回收方法 |
| US11772966B2 (en) * | 2021-03-29 | 2023-10-03 | Uop Llc | Integrated hydrogen production and bio-renewable conversion process |
| CN114348962A (zh) * | 2021-12-23 | 2022-04-15 | 甘肃银光聚银化工有限公司 | 一种基于排放火炬废气回收提氢方法 |
| CN117620915A (zh) * | 2023-12-19 | 2024-03-01 | 青岛理工大学 | 一种仿生澳洲棘蜥磨削砂轮、磨削装置及制备工艺 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR6899414D0 (pt) * | 1963-06-06 | 1973-01-02 | Texaco Development Corp | Processo para producao de hidrogenio |
| US4533981A (en) * | 1982-08-16 | 1985-08-06 | Ready Metal Manufacturing Company | Light cornice |
| GB8519821D0 (en) * | 1985-08-07 | 1985-09-11 | Ici Plc | Hydrogen streams |
| DE3667180D1 (de) * | 1985-06-27 | 1990-01-04 | Texaco Development Corp | Verfahren zur teiloxydation. |
| DE3605811A1 (de) * | 1986-02-22 | 1987-08-27 | Uhde Gmbh | Vorrichtung zum einsetzen in einem verfahren zur erzeugung von produktgas mit wasserstoff- und kohlenoxidgehalten |
-
1991
- 1991-10-24 ES ES91309837T patent/ES2061189T3/es not_active Expired - Lifetime
- 1991-10-24 EP EP91309837A patent/EP0486174B1/en not_active Revoked
- 1991-10-24 DE DE69104461T patent/DE69104461T2/de not_active Revoked
- 1991-11-08 MX MX9101972A patent/MX9101972A/es unknown
- 1991-11-13 TW TW080108901A patent/TW197997B/zh active
- 1991-11-14 AU AU87876/91A patent/AU645628B2/en not_active Expired
- 1991-11-14 KR KR1019910020454A patent/KR100209982B1/ko not_active Expired - Lifetime
- 1991-11-15 CN CN91110738A patent/CN1025844C/zh not_active Expired - Lifetime
- 1991-11-15 JP JP32680491A patent/JP3638618B2/ja not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100884701B1 (ko) | 2007-08-22 | 2009-02-19 | 한국에너지기술연구원 | 연료개질 장치에서 압력구동을 이용한 이산화탄소 흡착제재생방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| TW197997B (enExample) | 1993-01-11 |
| JP3638618B2 (ja) | 2005-04-13 |
| DE69104461T2 (de) | 1995-02-09 |
| CN1061386A (zh) | 1992-05-27 |
| KR920009687A (ko) | 1992-06-25 |
| MX9101972A (es) | 1992-07-08 |
| DE69104461D1 (de) | 1994-11-10 |
| AU645628B2 (en) | 1994-01-20 |
| EP0486174B1 (en) | 1994-10-05 |
| CN1025844C (zh) | 1994-09-07 |
| ES2061189T3 (es) | 1994-12-01 |
| JPH0624703A (ja) | 1994-02-01 |
| EP0486174A1 (en) | 1992-05-20 |
| AU8787691A (en) | 1992-05-21 |
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