JPWO2015098714A1 - 光学積層体および面光源装置 - Google Patents
光学積層体および面光源装置 Download PDFInfo
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- JPWO2015098714A1 JPWO2015098714A1 JP2015554811A JP2015554811A JPWO2015098714A1 JP WO2015098714 A1 JPWO2015098714 A1 JP WO2015098714A1 JP 2015554811 A JP2015554811 A JP 2015554811A JP 2015554811 A JP2015554811 A JP 2015554811A JP WO2015098714 A1 JPWO2015098714 A1 JP WO2015098714A1
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- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
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- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
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- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
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- SOLUNJPVPZJLOM-UHFFFAOYSA-N trizinc;distiborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-][Sb]([O-])([O-])=O.[O-][Sb]([O-])([O-])=O SOLUNJPVPZJLOM-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
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Abstract
Description
<2>前記アクリル系粘着剤組成物は、無機酸化物(B)を含有する、<1>に記載の光学積層体。
<3>前記無機酸化物(B)は、その体積平均粒子径が5nm〜50nmの粒子であり、かつ前記アクリル系粘着剤組成物は前記アクリル系樹脂100重量部に対して前記無機酸化物(B)を80〜130重量部含有する、<2>に記載の光学積層体。
<4>前記アクリル系粘着剤組成物は、架橋剤(C)を含有する、<1>〜<3>のいずれか1項に記載の光学積層体。
<5>前記アクリル系粘着剤組成物は、可塑剤(D)を含有する、<1>〜<4>のいずれか1項に記載の光学積層体。
<6>前記アクリル系粘着剤組成物は、前記可塑剤(D)を、前記アクリル系樹脂(A)100重量部に対して5〜20重量部含有する<5>に記載の光学積層体。
<7>前記可塑剤(D)は、その融点が0℃以下である、<5>又は<6>に記載の光学積層体。
<8>前記可塑剤(D)は、エステル系可塑剤からなる群から選択される、<5>〜<7>のいずれか1項に記載の光学積層体。
<9>前記可塑剤(D)は、安息香酸エステルである、<8>に記載の光学積層体。
<10>前記基材の屈折率n3と前記粘着層の屈折率n2との差(n3−n2)が0.02以下である、<1>〜<9>のいずれか1項に記載の光学積層体。
<11>前記粘着層の屈折率n2と前記ガラスの屈折率n1との差(n2−n1)が0.02以下である、<1>〜<10>のいずれか1項に記載の光学積層体。
<12>前記粘着層の屈折率n2が1.53以上である、<1>〜<11>のいずれか1項に記載の光学積層体。
<13>前記基材上に形成される凹凸構造層をさらに備える、<1>〜<12>のいずれか1項に記載の光学積層体。
<14>ガラス製の発光面を有する面発光体と、<1>〜<13>のいずれか1項に記載の光学積層体と、を備え、前記発光面に前記粘着層が貼付されている、面光源装置。
なお、本願において、「溶媒」の文言は、記述の便宜上、その中に溶質が溶解される、溶液を構成する媒体のみならず、その中に分散物が分散される、懸濁液(スラリーを含む)を構成する媒体をも含むものとして用いられる。本願において、ある物質と他のある物質との「相溶性」とは、それらの物質と、必要に応じて溶媒とを混合して溶液又は懸濁液とした際に、これらがゲル化又は分離を起こさず均質な状態を保つ性質をいう。また、本発明において、(メタ)アクリルとは、アクリルおよびメタクリルを包含する用語であり、(メタ)アクリロイルとはアクリロイルおよびメタクリロイルを包含する用語であり、(メタ)アクリレートとは、アクリレートおよびメタクリレートを包含する用語であり、アクリル系樹脂とは、(メタ)アクリル系モノマーを少なくとも1種含有するモノマー成分を重合して得られる樹脂を意味する。
本発明の光学積層体は、基材と、基材上に形成される粘着層とを備える。光学積層体は、シートまたはフィルム状に形成されている。
基材を構成する材料としては、特に限定されないが、有機EL素子を含む面発光体のガラス製の発光面上に積層して用いられるため、透明性を有する必要があり、通常、透明樹脂を含む樹脂組成物を用いることができる。透明樹脂が「透明」であるとは、光学部材として用いるのに適した程度の光線透過率を有する意味である。本実施形態において、光学積層体を構成する粘着層や基板、後述するその他の層は、光学積層体全体として80%以上の全光線透過率を有するように適宜構成することができる。「ガラス製の発光面」とは、発光する最外層としてガラス製の層を有する面発光体の発光面である。
また、基材の屈折率n3は、通常1.53以上であり、好ましくは1.60以上である。
基材の屈折率n3は、面発光体の発光面となるガラスの屈折率をn1とし、粘着層の屈折率をn2とした際に、n3≧n2≧n1の関係を満たす。この中でも、基材の屈折率n3と粘着層の屈折率n2との差(n3−n2)が0.05以下であることが好ましく、0.02以下であることがより好ましい。屈折率の差を前記範囲とすることにより、界面でのロスを減らすことができ、光の取り出し効率をより一層高めることができる。なお、基材は、単層体として又は2種以上が積層された複層体として用いることができる。
粘着層は、アクリル系樹脂(A)を含むアクリル系粘着剤組成物により構成される。
アクリル系樹脂(A)は、芳香環含有モノマー(a1)40〜93重量%、水酸基含有モノマー(a2)7〜60重量%を必須成分として含有する共重合成分[I]を共重合してなるものであり、共重合成分[I]は、必要に応じて(メタ)アクリル酸アルキルエステル系モノマー(a3)、その他の共重合性モノマー(a4)を含むものであってもよい。
なお、分散度の下限は、製造の限界の点から、通常1.1である。
1/Tg=Wa/Tga+Wb/Tgb+・・・Wn/Tgn
Tg:共重合体のガラス転移温度(K)
Tga:モノマーAのホモポリマーのガラス転移温度(K)
Wa:モノマーAの重量分率
Tgb:モノマーBのホモポリマーのガラス転移温度(K)
Wb:モノマーBの重量分率
Tgn:モノマーNのホモポリマーのガラス転移温度(K)
Wn:モノマーNの重量分率
(Wa+Wb+・・・+Wn=1)
無機酸化物(B)は、比較的屈折率が高いため、粘着層の高屈折率化を図る目的で、粘着力を損なわない範囲で添加することが好ましい。無機酸化物(B)としては、特に制限はないが、金属酸化物が好ましい。その中でも、金属酸化物と、その表面を修飾する、反応性官能基を有する有機物とを含む粒子、より具体的には、金属酸化物の粒子と当該粒子の表面を修飾する、反応性官能基を有する有機物とを含む被覆粒子(以下、反応性修飾金属酸化物粒子ともいう)が好ましい。反応性官能基は、金属酸化物と、水素結合等の相互作用を有した状態にあってもよいし、そのような状態になく別物質と相互作用できる状態にあってもよい。前記無機酸化物(B)は、微粒子状態である無機酸化物微粒子であることが好ましく、さらに無機酸化物微粒子の態様としては、たとえば、微粒子粉体、ペーストまたはゾルを挙げることができるが、好ましくはゾルである。
可塑剤(D)は、アクリル系粘着剤組成物の粘度を下げ、粘着性を保持するために用いうる。即ち、アクリル系粘着剤組成物は、粒子、特に反応性修飾金属酸化物粒子を含有することにより粘度が高くなり、その結果粘着性が低下しうるが、この場合可塑剤(D)を添加することにより、粘着性を保持することができる。その結果、高い屈折率と高い粘着性とを両立することが可能となる。前記可塑剤(D)は、融点が0℃以下であることが好ましく、−10℃以下であることがより好ましい。融点の下限は、−70℃以上であることが好ましく、−60℃以上であることがより好ましい。可塑剤(D)の融点が、この範囲内であると、相溶性に優れ、かつ被着体への糊残りもなく、また適度の粘着性を有するという利点がある。
前記アクリル系粘着剤組成物は、必要に応じて任意の成分を含有しうる。かかる任意の成分の例としては、シランカップリング剤、光拡散粒子、及び溶媒を挙げることができる。
光拡散層は、構成する材料に光拡散性のある材料を配合することにより実現できる。光拡散層を透過する光を拡散させ、光の光路を変化させることができ、光路長を長くすることにより、光の取り出し効率をより高めることができる。
本発明の面光源装置は、ガラス製の発光面を有する面発光体と、前記光学積層体とを備え、前記発光面上に前記粘着層が貼付された構成である。面発光体としては、有機EL素子を含んでなる面発光体を用いることができる。前記積層体を構成する粘着層は、透明性が高いことにより、特に有機EL素子の電極を透明にすることで、面発光体の向こう側が見渡せるシースルータイプの面光源装置において好適に使用できる。
<アクリル系樹脂(A−1)の製造>
温度計、攪拌機、滴下ロート及び還流冷却器を備えた反応器内にメチルエチルケトン28部、トルエン8部を仕込み、攪拌しながら昇温し、90℃になった後フェノキシエチルアクリレート(a1)70部、2−ヒドロキシエチルアクリレート(a2)15部、ブチルアクリレート(a3)15部に、重合開始剤としてアゾビスイソブチロニトリル(AIBN))0.16部を溶解させた混合物を2時間にわたって滴下した。さらに重合途中に、酢酸エチル2部にAIBN0.06部を溶解させた重合触媒液を逐次追加しながら7時間重合させ、アクリル系樹脂(A−1)溶液(固形分濃度65.0%、粘度1100mPa・s(25℃)、重量平均分子量108,200、数平均分子量41,700、分散度2.59、ガラス転移温度−26.6℃)を得た。
<アクリル系樹脂(A−2)の製造>
温度計、攪拌機、滴下ロート及び還流冷却器を備えた反応器内にメチルエチルケトン28部、トルエン8部を仕込み、攪拌しながら昇温し、90℃になった後フェノキシエチルアクリレート(a1)70部、2−ヒドロキシエチルアクリレート(a2)28部、ブチルアクリレート(a3)2部に、重合開始剤としてアゾビスイソブチロニトリル(AIBN))0.16部を溶解させた混合物を2時間にわたって滴下した。さらに重合途中に、酢酸エチル2部にAIBN0.06部を溶解させた重合触媒液を逐次追加しながら7時間重合させ、アクリル系樹脂(A−2)溶液(固形分濃度65.1%、粘度2,500mPa・s(25℃)、重量平均分子量126,000、数平均分子量48,000、分散度2.63、ガラス転移温度−20.8℃)を得た。
<アクリル系樹脂(A−3)の製造>
温度計、攪拌機、滴下ロート及び還流冷却器を備えた反応器内にメチルエチルケトン28部、トルエン8部を仕込み、攪拌しながら昇温し、90℃になった後、ベンジルアクリレート(a1)70部、2−ヒドロキシエチルアクリレート(a2)15部、ブチルアクリレート(a3)15部に、重合開始剤としてアゾビスイソブチロニトリル(AIBN))0.16部を溶解させた混合物を2時間にわたって滴下した。さらに重合途中に、酢酸エチル2部にAIBN0.06部を溶解させた重合触媒液を逐次追加しながら7時間重合させ、アクリル系樹脂(A−3)溶液(固形分濃度65.1%、粘度1300mPa・s(25℃)、重量平均分子量105,000、数平均分子量36,000、分散度2.92、ガラス転移温度−8.3℃)を得た。
<アクリル系樹脂(A−4)の製造>
温度計、攪拌機、滴下ロート及び還流冷却器を備えた反応器内にメチルエチルケトン28部、トルエン8部を仕込み、攪拌しながら昇温し、90℃になった後フェノキシエチルアクリレート(a1)70部、2−ヒドロキシエチルアクリレート(a2)15部、ブチルアクリレート(a3)14.8部、アクリル酸(a)0.2部に、重合開始剤としてアゾビスイソブチロニトリル(AIBN))0.16部を溶解させた混合物を2時間にわたって滴下した。さらに重合途中に、酢酸エチル2部にAIBN0.06部を溶解させた重合触媒液を逐次追加しながら7時間重合させ、アクリル系樹脂(A−4)溶液(固形分濃度65%、粘度3,000mPa・s(25℃)、重量平均分子量99,500、数平均分子量36,800、分散度2.70、ガラス転移温度−26.4℃)を得た。
(評価基準)
A・・・配合後すぐに相溶し、かつ室温で10日放置した時点でも相溶していた
B・・・配合後一旦は相溶したが、室温に放置で10日以内に相溶しなくなった(分離した、ゲル化した)
C・・・相溶しなかった(ゲル化した)
以上の測定結果を表1に示す。
製造例1〜4で得られたアクリル系樹脂(A−1)、(A−2)、(A−3)及び(A−4)を用いて得られた、粘着層付きPETフィルムから、離型シートを剥離し、(粘着層)/(PETフィルム)の層構成を有する複層物(光学積層体)とした。この複層物の粘着層側の面を、面発光体を形成するためのガラス基板(屈折率n1=1.53)に貼付して、積層体01〜04を得た。
実施例1((A−1)を用いた例)においては、ガラスの屈折率n1、粘着層の屈折率n2、およびPETフィルム(基材)の屈折率n3は、n3=1.65、n2=1.53、及びn1=1.53であり、n3≧n2≧n1の関係を満たしていた。
アクリル系粘着剤(サイデン化学株式会社製、商品名「X−311033S」、固形分35%)のアクリル系樹脂100部に対して、トリメチロールプロパンのトリレンジイソシアネート付加物の55%酢酸エチル溶液(日本ポリウレタン社製、「コロネートL−55E」)0.5部を配合し、粘着剤組成物とした。この粘着剤組成物の相溶性を、製造例1〜4の組成物の評価と同様に評価した。結果を表1に示す。
この粘着剤組成物を、ポリエステル系離型シートに、乾燥後の厚みが40μmとなるように塗布し、80℃で5分乾燥し、粘着層を形成した。これにより、(離型シート)/(粘着層)の層構成を有する2層の複層物を得た。その後、この複層物の粘着層側の面に、ポリエステル系離型シートを貼り合わせ、(離型シート)/(粘着層)/(離型シート)の層構成を有する、3層の複層物を得た。これを、40℃の条件下で10日間エージングさせて両面粘着シートを得た。この粘着シートを用いて、粘着層の屈折率を測定したところ、n=1.48であった。また、この粘着層の剥離強度を、製造例1〜4の組成物で得た粘着層の評価と同様に評価した。結果を表1に示す。
次に、前記両面粘着シートの粘着層から一方の面の離型シートを剥がし、(離型シート)/(粘着層)の層構成を有する、2層の複層物とした。この複層物の粘着層側の面を、100μmポリエチレンテレフタレート(PET)フィルムに押圧した。これにより、(離型シート)/(粘着層)/(PETフィルム)の層構成を有する、粘着層付きPETフィルムを得た。得られた粘着層付きPETフィルムから、離型シートを剥離し、(粘着層)/(PETフィルム)の層構成を有する複層物(光学積層体)とした。この複層物の粘着層側の面を、面発光体を形成するためのガラス基板(n=1.53)に貼付して、積層体05を得た。ガラスの屈折率n1、粘着層の屈折率n2、およびPETフィルム(基材)の屈折率n3は、n1=1.63、n2=1.48及びn3=1.53であり、従ってn3≧n1≧n2の関係を有しており、n3≧n2≧n1の関係を満たしていなかった。
実施例1〜4並びに比較例1で得られた積層体01〜05を備える、面光源装置01〜05をモデル化したものについて、プログラム(プログラム名:ASAP、breault Reserch社製)を用いた光学シミュレーションで、光取り出し量を求めた。
モデル化した積層構造は、装置出光面側から、フィルム(厚み100μm)、粘着層(厚み10μm)、ガラス基板(厚み0.7mm、屈折率1.63)、透明電極(厚み100nm、屈折率1.9)、発光層(厚み20nm、屈折率1.7)、反射電極(厚み100nm、屈折率1.5、反射率85%)、封止基板(厚み0.7mm、屈折率1.52)とした。
フィルム及び粘着層の屈折率は、各実施例及び比較例に応じて設定し、透明電極の装置出光面側の面を発光面とし、発光面の光度は1ルーメンとした。
(5−1.アクリル系粘着剤組成物)
製造例1で得られたアクリル系樹脂(A−1)溶液の100部(固形分相当量)と、無機粒子として、酸化ジルコニウム粒子分散液(ソーラー社製NANON5 ZR−010 体積平均粒子径15nm)122部(固形分相当量)と、可塑剤(BENZOFLEX 9−88SG」(イーストマン社製))融点−30℃)14部と、光拡散粒子(体積平均粒子径を0.7μmとしたシリコーン粒子、モメンティブ・パフォーマンス・マテリアル社製、商品名「XC−99」8.47部とを加え15分攪拌し、アクリル系粘着剤組成物を得た。得られた組成物の相溶性を目視で確認したところ、相溶性は問題なく(分離及びゲル化が観察されず)、良好であった。
得られたアクリル系粘着剤組成物のアクリル系樹脂100部に対して、トリメチロールプロパンのトリレンジイソシアネート付加物の55%酢酸エチル溶液(日本ポリウレタン社製、「コロネートL−55E」)0.5部を配合し、混合物とした。この混合物を、基材としての100μm厚みのポリエチレンテレフタレートフィルム(東レ製、商品名「U34」)の片面に、乾燥後の厚みが40μmとなるように塗布し、80℃で5分乾燥し、粘着層を形成した。これにより、(粘着層)/(基材)の層構成を有する2層の複層物を得た。その後、この複層物の粘着層側の面に、ポリエステル系離型シートを貼り合わせ、(離型シート)/(粘着層)/(基材)の層構成を有する、3層の複層物を得た。これを、40℃の条件下で10日間エージングさせて粘着層および基材を有する光学積層体を得た。
(5−2)で得られた光学積層体を幅25mm、長さ100mmに切り出し、離型シートを剥離し、ローラーを用いてガラス板に貼合し、(基材)/(粘着層)/(ガラス板)の層構成を有する複層物を得た。貼合から24時間経過後、ピール試験機を用いて、速度20mm/分、90°の条件で、基材をガラス板から剥離し、長さ方向のピール強度を測定した。結果を表2に示す。
(5−1)で得られたアクリル系粘着剤組成物を、ガラス板の片面に、乾燥後の厚みが20μmとなるように塗布し、80℃で5分乾燥させて、屈折率測定用の粘着層を形成した。この粘着層の屈折率を、エリプソメーター(ジェー・エー・ウーラム・ジャパン株式会社製 M−2000)にて測定した。結果を表2に示す。
アクリル系樹脂(A−1)溶液をアクリル系樹脂(A−2)溶液に変更した以外は、実施例1と同様にして光学積層体を得て評価した。結果を表2に示す。
アクリル系樹脂(A−1)溶液をアクリル系樹脂(A−3)溶液に変更した以外は、実施例1と同様にして光学積層体を得て評価した。結果を表2に示す。
アクリル系樹脂(A−1)溶液をアクリル系樹脂(A−4)溶液に変更した以外は、実施例1と同様にして光学積層体を得て評価した。結果を表2に示す。
Claims (14)
- 基材と、この基材上に形成される粘着層と、を備え、ガラス製の発光面上に前記粘着層側を貼付して用いられる光学積層体であって、
前記発光面を構成するガラスの屈折率をn1とし、前記粘着層の屈折率をn2とし、前記基材の屈折率をn3として、n3≧n2≧n1の関係を満たし、
前記粘着層は、アクリル系樹脂(A)を含むアクリル系粘着剤組成物により構成され、
前記アクリル系樹脂(A)は、芳香環含有モノマー(a1)40〜93重量%と、水酸基含有モノマー(a2)7〜60重量%とを含む共重合成分[I]の共重合体であって、かつその重量平均分子量が20万以下である、光学積層体。 - 前記アクリル系粘着剤組成物は、無機酸化物(B)を含有する、請求項1に記載の光学積層体。
- 前記無機酸化物(B)は、その体積平均粒子径が5nm〜50nmの粒子であり、かつ前記アクリル系粘着剤組成物は前記アクリル系樹脂100重量部に対して前記無機酸化物(B)を80〜130重量部含有する、請求項2に記載の光学積層体。
- 前記アクリル系粘着剤組成物は、架橋剤(C)を含有する、請求項1〜3のいずれか1項に記載の光学積層体。
- 前記アクリル系粘着剤組成物は、可塑剤(D)を含有する、請求項1〜4のいずれか1項に記載の光学積層体。
- 前記アクリル系粘着剤組成物は、前記可塑剤(D)を、前記アクリル系樹脂(A)100重量部に対して5〜20重量部含有する、請求項5に記載の光学積層体。
- 前記可塑剤(D)は、その融点が0℃以下である、請求項5または6に記載の光学積層体。
- 前記可塑剤(D)は、エステル系可塑剤からなる群から選択される、請求項5〜7のいずれか1項に記載の光学積層体。
- 前記可塑剤(D)は、安息香酸エステルである、請求項8に記載の光学積層体。
- 前記基材の屈折率n3と前記粘着層の屈折率n2との差(n3−n2)が0.02以下である、請求項1〜9のいずれか1項に記載の光学積層体。
- 前記粘着層の屈折率n2と前記ガラスの屈折率n1との差(n2−n1)が0.02以下である、請求項1〜10のいずれか1項に記載の光学積層体。
- 前記粘着層の屈折率n2が1.53以上である、請求項1〜11のいずれか1項に記載の光学積層体。
- 前記基材上に形成される凹凸構造層をさらに備える、請求項1〜12のいずれか1項に記載の光学積層体。
- ガラス製の発光面を有する面発光体と、請求項1〜13のいずれか1項に記載の光学積層体と、を備え、前記発光面に前記粘着層が貼付されている、面光源装置。
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JP6676881B2 (ja) * | 2015-03-30 | 2020-04-08 | 三菱ケミカル株式会社 | 可塑剤含有部材用アクリル系粘着剤、並びに粘着テープ |
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JP7010832B2 (ja) * | 2016-10-14 | 2022-02-10 | 株式会社クラレ | ガラス積層体 |
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US20190054527A1 (en) * | 2017-08-18 | 2019-02-21 | General Electric Company | Thermoplastic binders for use in binder jetting additive manufacturing |
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