JPWO2012026393A1 - 太陽電池用封止材および合わせガラス用中間膜 - Google Patents
太陽電池用封止材および合わせガラス用中間膜 Download PDFInfo
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- JPWO2012026393A1 JPWO2012026393A1 JP2012530644A JP2012530644A JPWO2012026393A1 JP WO2012026393 A1 JPWO2012026393 A1 JP WO2012026393A1 JP 2012530644 A JP2012530644 A JP 2012530644A JP 2012530644 A JP2012530644 A JP 2012530644A JP WO2012026393 A1 JPWO2012026393 A1 JP WO2012026393A1
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- Prior art keywords
- laminated glass
- glass
- solar cell
- sealing material
- mass
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- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
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- 239000011734 sodium Substances 0.000 description 1
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- 238000003756 stirring Methods 0.000 description 1
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- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- XUHUMYVYHLHMCD-UHFFFAOYSA-N tris(2-cyclohexylphenyl) phosphite Chemical compound C1CCCCC1C1=CC=CC=C1OP(OC=1C(=CC=CC=1)C1CCCCC1)OC1=CC=CC=C1C1CCCCC1 XUHUMYVYHLHMCD-UHFFFAOYSA-N 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
- WRSPWQHUHVRNFV-UHFFFAOYSA-N tris[3,5-di(nonyl)phenyl] phosphite Chemical compound CCCCCCCCCC1=CC(CCCCCCCCC)=CC(OP(OC=2C=C(CCCCCCCCC)C=C(CCCCCCCCC)C=2)OC=2C=C(CCCCCCCCC)C=C(CCCCCCCCC)C=2)=C1 WRSPWQHUHVRNFV-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10678—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer comprising UV absorbers or stabilizers, e.g. antioxidants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10798—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing silicone
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/0481—Encapsulation of modules characterised by the composition of the encapsulation material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/0488—Double glass encapsulation, e.g. photovoltaic cells arranged between front and rear glass sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/12—Photovoltaic modules
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31627—Next to aldehyde or ketone condensation product
- Y10T428/3163—Next to acetal of polymerized unsaturated alcohol [e.g., formal butyral, etc.]
Landscapes
- Engineering & Computer Science (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Joining Of Glass To Other Materials (AREA)
- Photovoltaic Devices (AREA)
Abstract
Description
後述するように、ポリビニルアセタール樹脂に所定量のゴムを混合することで、貯蔵弾性率及び圧縮せん断強さを維持したまま、JIS R 3212の耐貫通性試験に準じて、鋼球を高さ2mから落下させた場合に貫通しない、充分な耐衝撃性を有する上記の太陽電池用封止材又は合わせガラス用中間膜を得ることが可能となる。ここで、鋼球としては、質量2260±20g、直径約82mmの表面が滑らかなものを用いる。
さらに、ポリビニルアセタール樹脂を主成分とする上記の太陽電池用封止材又は合わせガラス用中間膜の製造においては、本発明の趣旨に反しない限り、ポリビニルアセタール樹脂と、それ以外の樹脂とを混合することも可能であり、ポリビニルアセタール樹脂とそれ以外の樹脂との積層体を太陽電池用封止材又は合わせガラス用中間膜とすることも可能である。また、無機物(酸化チタン、タルク等)を混合することも可能である。
上記のような成分を添加・混合等して使用することにより、これらの成分を含む太陽電池用封止材又は合わせガラス用中間膜を得ることができる。
平均重合度約900、アセタール化度約69モル%のポリビニルブチラール樹脂を合成し、圧力100Kgf/cm2、熱板温度150℃にて10分プレスし、厚さ0.76mmのポリビニルブチラールシートを作製した。なお、アセタール化度はJIS K 6728「ポリビニルブチラール試験方法」に基づいて測定した。
JIS K 7244−4(1999年制定)に基づいて測定した。測定条件は周波数0.3Hzである。0℃〜100℃まで1℃/minの定速昇温で実施した。上記ポリビニルブチラールシートは、25℃での貯蔵弾性率が1920MPaであり、50℃での貯蔵弾性率が1530MPaであった。
上に述べた方法で、圧縮せん断強さ測定を25℃および50℃で実施した。なお、合わせガラスサンプル24としては、市販のフロートガラス(厚さ3mm、大きさ25mm×25mm)2枚に上記ポリビニルブチラールシートを挟んだうえで、真空バック法(条件:30℃から160℃に60分間で昇温し、その後160℃で30分間保持)により作製されたもの(12サンプル)を用いた。試験は各サンプルを用いて、25℃および50℃のそれぞれにおいて6回ずつ行った。測定結果の平均値は、25℃では52MPaであり、50℃では28MPaであった。
市販のフロートガラス(厚さ2.8mm、大きさ26mm×76mm)2枚に上記ポリビニルブチラールシートを挟んだうえで、真空バック法(条件:30℃から160℃に60分間で昇温し、その後160℃で30分間保持)によって、合わせガラスを作製した。その後、オ−トグラフAG−5000Bを用いて合わせガラスの3点曲げ試験を実施し、破断強度を測定した。なお、試験速度は0.25mm/minで行った。25℃では0.80kNであり、50℃では0.70kNであった。
市販のフロートガラス(厚さ3.2mm、大きさ1100mm×1300mm)2枚に上記ポリビニルブチラールシートを挟んだうえで、真空ラミネーター(日清紡メカトロニクス株式会社製 1522N)を用いて以下の条件で合わせガラスを作製した。得られた合わせガラスのラミネート適性を以下の基準により判定したところ、「◎」であった。
<条件>
熱板温度 :165℃
真空引き時間:12分
プレス圧力 :50kPa
プレス時間 :17分
<判断基準>
◎:気泡、密着不良などの外観欠点はなく、密着良好
×:気泡、密着不良などの外観欠点あり
上記ポリビニルブチラールから大きさ1cm×8cmかつ標線間距離4cmのサンプルを切り出し、クリープ試験機(株式会社安田精機製作所製 No.145クリープテスター)を使用して、85℃、85%RH、荷重なしの条件下で5時間引張試験を行った。試験後の標線間距離は4.2cmであり、伸び率は105%であり、以下の基準から「◎」と判定された。
<判定基準>
◎:伸び率120%以下
○:伸び率120%を超え、200%以下
×:200%を超える
市販のフロートガラス(厚さ2.8mm、大きさ300mm×300mm)2枚に上記ポリビニルブチラールシートを挟んだうえで、真空ラミネータ(日清紡メカトロニクス株式会社製;1522N)を用いて合わせガラスを作製した。その後、JIS R 3212の耐貫通性試験に準じて高さ2mから2260gの鋼球を落下させた。その結果、鋼球が貫通した(不合格である)ことを確認した。実施例1の合わせガラスは、高さ2mからの耐貫通性試験に不合格であったため、高さ3mから2260gの鋼球を落下させる耐貫通性試験は行わなかった。なお、高さ3mからの耐貫通性試験は実施例12〜21についてのみ行った。
市販のフロートガラス(厚さ3.2mm、大きさ864mm(幅方向)×1300mm(長手方向)2枚に上記ポリビニルブチラールシートを挟んだうえで、真空ラミネーター(日清紡メカトロニクス株式会社製;1522N)を用いて合わせガラスを作製し、これを太陽電池モジュールとみなした。この合わせガラスを用いて太陽電池モジュールの安全性適合認定(IEC61730−2)のMST32衝撃破壊試験を、図6のようなフレームレス施工で実施したところ、高さ1220mmで不合格であった。次に、フロートガラスの厚さを4mmとしたこと以外は同様の方法により衝撃破壊試験を行ったところ、合格であった。なお、フロートガラスの厚さ4mmにおける衝撃破壊試験は実施例1〜11についてのみ行った。以下、図6について説明する。支持用基礎土台41は略直線状に成形されたものであり、合わせガラス43を支持するための土台となるものである。2本の支持用基礎土台41は、合わせガラス43の長手方向の両端からそれぞれ325mmの位置において、合わせガラス43と接することなく幅方向(合わせガラス43に平行で且つ前記長手方向に垂直な方向)に平行に配置されている。クランプ42(長さ200mm×幅10mm(幅方向にガラスと接触している距離))は、本支持用基礎土台41に約864mmの間隔で、1本の支持用基礎土台41につき、2つずつ設置されており、合計4つのクランプ42が、合わせガラス43の幅方向の両端で、かつ、クランプ42の中央が合わせガラス43の長手方向における端部から325mmの位置となるように、合わせガラス43を固定している。
表1に示す組成の材料(ポリビニルブチラール樹脂)を用いて、実施例1と同様の方法によりポリビニルブチラールシートを作製し、貯蔵弾性率、ガラスへの接着性、破断強度、ラミネート適性、耐クリープ物性、耐貫通性試験及び衝撃破壊試験を評価した。結果を表1に示す。
平均重合度約900、アセタール化度約69モル%のポリビニルブチラール樹脂を合成し、ポリビニルブチラール樹脂100質量部に対して、可塑剤として3GO(トリエチレングリコール−ジ(2−エチルヘキサノエート))を2質量部加え、圧力100Kgf/cm2、熱板温度150℃にて10分プレスし、厚さ0.76mmのポリビニルブチラールシートを作製した。作製したポリビニルブチラールシートを用いて、実施例1と同様の方法により、貯蔵弾性率、ガラスへの接着性、破断強度、ラミネート適性、耐クリープ物性、耐貫通性試験及び衝撃破壊試験を評価した。結果を表2に示す。
表2に示す平均重合度とアセタール化度を有するポリビニルブチラール樹脂100質量部に対して、可塑剤として3GOを表2に示す量を用いたこと以外は、実施例8と同様にして、ポリビニルブチラールシートを作製した。作製したポリビニルブチラールシートを用いて、実施例1と同様の方法により、貯蔵弾性率、ガラスへの接着性、破断強度、ラミネート適性、耐クリープ物性、耐貫通性試験及び衝撃破壊試験を評価した。結果を表2に示す。
平均重合度約1000、アセタール化度約69モル%のポリビニルブチラール樹脂100質量部に対して、シリコーン・アクリル複合ゴム(三菱レイヨン株式会社製;メタブレンS2006、ガラス転移温度−39℃、平均粒子径200nm)を5質量部混合して得られたペレットを、圧力100Kgf/cm2、熱板温度150℃にて10分プレスし、厚さ0.76mmのポリビニルブチラールシートを作製した。なお、ポリビニルブチラール樹脂のアセタール化度はJIS K 6728「ポリビニルブチラール試験方法」に基づいて測定した。また、シリコーン・アクリル複合ゴムのガラス転移温度は、JIS K 7244−4:1999年に基づいて測定しtanδのピーク値とした。測定条件は周波数0.3Hzである。−150℃〜100℃まで1℃/minの定速昇温で実施した。
作製したポリビニルブチラールシートを用いて、実施例1と同様の方法により、貯蔵弾性率、ガラスへの接着性、破断強度、ラミネート適性、耐クリープ物性、耐貫通性試験及び衝撃破壊試験を評価した。また、使用したポリビニルブチラール樹脂およびゴムの屈折率と上記ポリビニルブチラールシートを用いた合わせガラスのヘイズを以下の方法により評価した。結果を表3に示す。
JIS K 7142に基づいて測定した。
JIS K 7136に基づいて、ガラスへの接着性(圧縮せん断強さ)を測定する際に用いた合わせガラスサンプルと同様の合わせガラスサンプルを用いて測定した。
表3及び表4に示す組成の材料(ポリビニルブチラール樹脂およびゴム)を用いて、実施例12と同様の方法によりポリビニルブチラールシートを作製し、貯蔵弾性率、ガラスへの接着性、破断強度、ヘイズ、ラミネート適性、耐クリープ物性、耐貫通性試験及び衝撃破壊試験を評価した。結果を表3及び表4に示す。なお、実施例13〜16及び実施例18〜21においては、ゴムとして、実施例12で用いたシリコーン・アクリル複合ゴムを用いた。実施例17においては、ゴムとして、市販のアクリル系ゴム(三菱レイヨン株式会社製;メタブレンW377、ガラス転移温度−18℃、平均粒子径200nm)を用いた。
平均重合度約1700、アセタール化度約69モル%のポリビニルブチラール樹脂を合成し、ポリビニルブチラール樹脂100質量部に対して、可塑剤として3GOを20質量部加え、圧力100Kgf/cm2、熱板温度140℃にて10分プレスし、厚さ0.76mmのポリビニルブチラールシートを作製した。作製したポリビニルブチラールシートを用いて、実施例1と同様の方法により、貯蔵弾性率、ガラスへの接着性、破断強度、ラミネート適性、耐クリープ物性、耐貫通性試験及び衝撃破壊試験を評価した。結果を表5に示す。
平均重合度約1700、アセタール化度約69モル%のポリビニルブチラール樹脂を合成し、ポリビニルブチラール樹脂100質量部に対して、可塑剤として3GOを35質量部加え、圧力100Kgf/cm2、熱板温度140℃にて10分プレスし、厚さ0.76mmのポリビニルブチラールシートを作製した。作製したポリビニルブチラールシートを用いて、実施例1と同様の方法により、貯蔵弾性率、ガラスへの接着性、破断強度、ラミネート適性、耐クリープ物性、耐貫通性試験及び衝撃破壊試験を評価した。結果を表5に示す。
平均重合度約1000、アセタール化度約69モル%のポリビニルブチラール樹脂100質量部に対して、シリコーン・アクリル複合ゴム(三菱レイヨン株式会社製;メタブレンS2006、ガラス転移温度−39℃、平均粒子径200nm)を300質量部混合して得られたペレットを、圧力100Kgf/cm2、熱板温度180℃にて10分プレスし、厚さ0.76mmのポリビニルブチラールシートを作製した。作製したポリビニルブチラールシートを用いて、実施例1と同様の方法により、貯蔵弾性率、ガラスへの接着性、破断強度及びラミネート適性を評価した。さらに、耐貫通性試験を行うため、耐貫通性試験用の合わせガラスサンプルの作製を試みたが、上記ポリビニルブチラールシートの流動性が不充分であっため合わせガラスサンプルを作製することができなかった。結果を表5に示す。
アイオノマー樹脂シート(DuPont社製;SentryGlas(登録商標)Plus(SGP))について、実施例1と同様の方法により、貯蔵弾性率、ガラスへの接着性、破断強度、ラミネート適性、耐貫通性試験及び衝撃破壊試験を評価した。結果を表5に示す。
太陽電池用EVAシート(株式会社ブリヂストン製;EVASAFE)について、実施例1と同様の方法により、貯蔵弾性率、ガラスへの接着性、破断強度、ラミネート適性、耐クリープ物性、耐貫通性試験及び衝撃破壊試験を評価した。結果を表5に示す。
PMMA樹脂(株式会社クラレ製;クラレパラペット HR−L)を圧力100Kgf/cm2、熱板温度200℃にて10分プレスし、厚さ0.76mmのシートを作製した。作製したシートを用いて、実施例1と同様の方法により、貯蔵弾性率、ガラスへの接着性、破断強度、ラミネート適性及び耐クリープ物性を評価した。結果を表5に示す。
12 裏面側保護部材
13 封止材
13A 表面封止材
13B 裏面封止材
14 太陽電池セル
15 フレーム
16 太陽電池セル
21 封止材
22 ガラス
23 ガラス
24 合わせガラスサンプル
31 圧縮せん断強さ測定ジグ(下部)
31a 凹部
31b 斜面
32 圧縮せん断強さ測定ジグ(上部)
32a 凹部
41 支持用基礎土台
42 クランプ
43 合わせガラス
Claims (13)
- JIS K 7244−4により周波数0.3Hzおよび25℃で測定された貯蔵弾性率が1000〜4000MPaであり、ガラスを両面に接着させた積層体について25℃で測定した圧縮せん断強さが5〜80MPaである太陽電池用封止材又は合わせガラス用中間膜。
- JIS K 7244−4により周波数0.3Hzおよび50℃で測定された貯蔵弾性率が、50〜4000MPaであり、ガラスを両面に接着させた積層体について50℃で測定した圧縮せん断強さが5〜80MPaである太陽電池用封止材又は合わせガラス用中間膜。
- 厚さ2.8mmのガラスを両面に接着させた積層体についてJIS R 3212の耐貫通性試験に準じて、鋼球を高さ2mから落下させた場合に貫通しない、請求項1又は2に記載の太陽電池用封止材又は合わせガラス用中間膜。
- ポリビニルアセタール樹脂を40質量%以上含む請求項1〜3のいずれかに記載の太陽電池用封止材又は合わせガラス用中間膜。
- 可塑剤の含有量が前記ポリビニルアセタール樹脂100質量部に対して10質量部以下である請求項4に記載の太陽電池用封止材又は合わせガラス用中間膜。
- ポリビニルアセタール樹脂を40質量%以上含み、可塑剤の含有量が前記ポリビニルアセタール樹脂100質量部に対して10質量部以下である太陽電池用封止材又は合わせガラス用中間膜。
- 前記ポリビニルアセタール樹脂の平均重合度が600〜1100である請求項4〜6のいずれかに記載の太陽電池用封止材又は合わせガラス用中間膜。
- さらにゴムを含む請求項4〜7のいずれかに記載の太陽電池用封止材又は合わせガラス用中間膜。
- 前記ゴムの含有量が前記ポリビニルアセタール樹脂100質量部に対して1〜100質量部である請求項8に記載の太陽電池用封止材又は合わせガラス用中間膜。
- 前記ゴムのガラス転移温度が−10℃以下である請求項8又は9に記載の太陽電池用封止材又は合わせガラス用中間膜。
- 前記ゴムと前記ポリビニルアセタール樹脂との屈折率の差が0.04以下である請求項8〜10のいずれかに記載の太陽電池用封止材又は合わせガラス用中間膜。
- 請求項1〜11のいずれかに記載の太陽電池用封止材を用いた太陽電池モジュール。
- 請求項1〜11のいずれかに記載の合わせガラス用中間膜を用いた合わせガラス。
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TWI549816B (zh) * | 2012-06-08 | 2016-09-21 | 長春石油化學股份有限公司 | 夾層玻璃用之中間膜及含其之夾層玻璃 |
JP5967593B2 (ja) * | 2012-06-27 | 2016-08-10 | パナソニックIpマネジメント株式会社 | 太陽電池モジュールの製造方法及び太陽電池モジュール |
WO2014090895A1 (de) * | 2012-12-15 | 2014-06-19 | Kuraray Europe Gmbh | Formkörper aus polyvinyl(iso)acetalen |
JP6096220B2 (ja) * | 2012-12-17 | 2017-03-15 | 株式会社クラレ | ゴム含有グラフト重合体粉体、並びにそれを含有する太陽電池用封止材及び合わせガラス用中間膜 |
JP6253240B2 (ja) * | 2013-03-28 | 2017-12-27 | 株式会社クラレ | 太陽電池用封止材および合わせガラス用中間膜 |
JP6324813B2 (ja) * | 2013-05-31 | 2018-05-16 | 株式会社クラレ | 太陽電池モジュールおよびその製造方法 |
RU2646641C2 (ru) * | 2013-09-30 | 2018-03-06 | Секисуй Кемикал Ко., Лтд. | Промежуточная пленка для многослойного стекла и многослойное стекло |
KR102470383B1 (ko) | 2014-01-15 | 2022-11-25 | 세키스이가가쿠 고교가부시키가이샤 | 접합 유리용 중간막 및 접합 유리 |
CN106103377B (zh) * | 2014-03-10 | 2018-10-30 | Agc株式会社 | 窗用层叠基板具备窗用层叠基板的汽车以及窗用层叠基板用中间层结构体 |
EP3127386A1 (en) * | 2014-04-01 | 2017-02-08 | Telefonaktiebolaget LM Ericsson (publ) | System and method for obtaining and using device-to-device frequency-related capability and configuration preferences |
EP3159372A4 (en) * | 2014-06-17 | 2017-12-27 | Mitsubishi Chemical Corporation | Rubber-containing graft polymer powder, solar cell sealing material containing same, and interlayer for laminated glass |
US20170266927A1 (en) * | 2014-09-30 | 2017-09-21 | Sekisui Chemical Co., Ltd. | Intermediate film for laminated glass, and laminated glass |
US10427384B2 (en) | 2014-11-10 | 2019-10-01 | Kuraray Co., Ltd. | Interlayer film for laminated glass and laminated glass |
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JP6558022B2 (ja) * | 2015-03-27 | 2019-08-14 | 三菱ケミカル株式会社 | 薄膜太陽電池モジュール |
JP6908365B2 (ja) * | 2015-10-07 | 2021-07-28 | 積水化学工業株式会社 | ポリビニルアセタール樹脂組成物 |
CN108290786B (zh) * | 2015-11-30 | 2021-03-09 | Agc株式会社 | 夹层玻璃 |
US10538063B2 (en) | 2016-05-09 | 2020-01-21 | Kuraray America, Inc. | Multilayer interlayer and glass laminate |
JP6792614B2 (ja) * | 2016-05-18 | 2020-11-25 | 株式会社クラレ | 合わせガラス用中間膜および合わせガラス |
US10926516B2 (en) | 2016-06-21 | 2021-02-23 | Solutia Inc. | Polymeric interlayers and multiple layer panels made therefrom exhibiting enhanced properties and performance |
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US10668691B2 (en) | 2016-06-21 | 2020-06-02 | Solutia Inc. | Polymeric interlayers and multiple layer panels made therefrom exhibiting enhanced properties and performance |
US10737470B2 (en) | 2016-06-21 | 2020-08-11 | Solutia Inc. | Polymeric interlayers and multiple layer panels made therefrom exhibiting enhanced properties and performance |
JP7010241B2 (ja) * | 2016-12-22 | 2022-02-10 | 日本ゼオン株式会社 | 合わせガラス |
CN106677438A (zh) * | 2017-02-06 | 2017-05-17 | 江苏友科太阳能科技有限公司 | 一种新型高增益构件式光伏瓦 |
CN106877796A (zh) * | 2017-02-06 | 2017-06-20 | 江苏友科太阳能科技有限公司 | 新型高增益构件式光伏瓦 |
WO2018198678A1 (ja) * | 2017-04-28 | 2018-11-01 | 積水化学工業株式会社 | 合わせガラス |
CN107722875A (zh) * | 2017-09-27 | 2018-02-23 | 东莞市联洲知识产权运营管理有限公司 | 一种耐高低温的太阳能电池封装材料的制备方法 |
JP6903569B2 (ja) * | 2017-12-28 | 2021-07-14 | 株式会社クラレ | 合わせガラス用中間膜、合わせガラス及び合わせガラスの製造方法 |
US20210394491A1 (en) * | 2018-11-30 | 2021-12-23 | Showa Denko Materials Co., Ltd. | Laminated glass for vehicle |
US20220009205A1 (en) * | 2018-12-21 | 2022-01-13 | Sekisui Chemical Co., Ltd. | Interlayer for laminated glass and laminated glass |
CN113871380B (zh) * | 2021-10-30 | 2022-09-23 | 广州市祺虹电子科技有限公司 | 一种光电光伏玻璃 |
CN114744068B (zh) * | 2022-03-30 | 2024-03-19 | 天津南玻节能玻璃有限公司 | 一种光伏建筑一体化组件及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005041747A (ja) * | 2003-07-24 | 2005-02-17 | Japan U-Pica Co Ltd | 合わせガラス注入用硬化性樹脂組成物 |
JP2005219726A (ja) * | 2004-01-09 | 2005-08-18 | Sekisui Chem Co Ltd | 車両用ガラス |
JP2009298046A (ja) * | 2008-06-13 | 2009-12-24 | Du Pont Mitsui Polychem Co Ltd | 多層シート |
WO2010055731A1 (ja) * | 2008-11-13 | 2010-05-20 | 積水化学工業株式会社 | ポリビニルアセタール樹脂組成物 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2330157A1 (en) | 1998-05-14 | 1999-11-18 | E.I. Du Pont De Nemours And Company | Glass laminates for threat resistant window systems |
DE19951444A1 (de) | 1999-10-25 | 2001-04-26 | Huels Troisdorf | Verfahren und Folie zur Herstellung von Verbundsicherheitsscheiben |
DE10003511A1 (de) * | 2000-01-27 | 2001-08-02 | Basf Ag | Verfahren zur Herstellung schlagzäher Kunststoffe |
DE10150091A1 (de) | 2001-10-11 | 2003-04-17 | Huels Troisdorf | PVB-Folie für Verbundsicherheitsglas und Verbundsicherheitsglas |
JP2004067414A (ja) * | 2002-08-02 | 2004-03-04 | Sekisui Chem Co Ltd | 合わせガラス用中間膜および合わせガラス |
JP4339745B2 (ja) * | 2003-08-22 | 2009-10-07 | 積水化学工業株式会社 | 合わせガラス及び合わせガラス用中間膜 |
AU2006221440A1 (en) * | 2005-03-09 | 2006-09-14 | Sekisui Chemical Co., Ltd. | Interlayer for laminated glass and laminated glass |
US20080044666A1 (en) * | 2006-08-17 | 2008-02-21 | Anderson Jerrel C | Amine-neutralized ethylene acid copolymers, shaped articles and laminates produced therefrom |
US8197928B2 (en) * | 2006-12-29 | 2012-06-12 | E. I. Du Pont De Nemours And Company | Intrusion resistant safety glazings and solar cell modules |
CN101795990B (zh) * | 2007-09-27 | 2013-03-27 | 日本电气硝子株式会社 | 夹层玻璃及夹层玻璃部件 |
JP2011522419A (ja) | 2008-05-27 | 2011-07-28 | ソルティア・インコーポレーテッド | 薄膜光起電モジュール |
-
2011
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005041747A (ja) * | 2003-07-24 | 2005-02-17 | Japan U-Pica Co Ltd | 合わせガラス注入用硬化性樹脂組成物 |
JP2005219726A (ja) * | 2004-01-09 | 2005-08-18 | Sekisui Chem Co Ltd | 車両用ガラス |
JP2009298046A (ja) * | 2008-06-13 | 2009-12-24 | Du Pont Mitsui Polychem Co Ltd | 多層シート |
WO2010055731A1 (ja) * | 2008-11-13 | 2010-05-20 | 積水化学工業株式会社 | ポリビニルアセタール樹脂組成物 |
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EP2610225A4 (en) | 2016-11-16 |
US20140014178A1 (en) | 2014-01-16 |
CN103080035A (zh) | 2013-05-01 |
KR20130100777A (ko) | 2013-09-11 |
EP2610225A1 (en) | 2013-07-03 |
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