JPS63317306A - 残留塩化ビニルモノマ−の少ない低重合度塩化ビニル重合体粉末及びその製造方法 - Google Patents
残留塩化ビニルモノマ−の少ない低重合度塩化ビニル重合体粉末及びその製造方法Info
- Publication number
- JPS63317306A JPS63317306A JP15310387A JP15310387A JPS63317306A JP S63317306 A JPS63317306 A JP S63317306A JP 15310387 A JP15310387 A JP 15310387A JP 15310387 A JP15310387 A JP 15310387A JP S63317306 A JPS63317306 A JP S63317306A
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- polymer powder
- chloride polymer
- polymerization
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 115
- 229920000642 polymer Polymers 0.000 title claims abstract description 91
- 239000000843 powder Substances 0.000 title claims abstract description 77
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 49
- 239000000178 monomer Substances 0.000 title claims abstract description 47
- 238000012360 testing method Methods 0.000 claims abstract description 16
- 239000003381 stabilizer Substances 0.000 claims abstract description 6
- 239000006185 dispersion Substances 0.000 claims description 87
- 238000000034 method Methods 0.000 claims description 24
- 238000001035 drying Methods 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 230000018044 dehydration Effects 0.000 claims description 7
- 238000006297 dehydration reaction Methods 0.000 claims description 7
- 150000002894 organic compounds Chemical class 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 238000010557 suspension polymerization reaction Methods 0.000 claims description 3
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 3
- 235000013305 food Nutrition 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 description 34
- 230000000694 effects Effects 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 description 5
- 238000000605 extraction Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000007127 saponification reaction Methods 0.000 description 4
- 239000000375 suspending agent Substances 0.000 description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 238000010793 Steam injection (oil industry) Methods 0.000 description 3
- 238000007664 blowing Methods 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 229910001873 dinitrogen Inorganic materials 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000003505 polymerization initiator Substances 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 2
- PMNLUUOXGOOLSP-UHFFFAOYSA-N 2-mercaptopropanoic acid Chemical compound CC(S)C(O)=O PMNLUUOXGOOLSP-UHFFFAOYSA-N 0.000 description 2
- VXVUDUCBEZFQGY-UHFFFAOYSA-N 4,4-dimethylpentanenitrile Chemical compound CC(C)(C)CCC#N VXVUDUCBEZFQGY-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000004815 dispersion polymer Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- -1 mercaptoethanol Chemical class 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- NOBYOEQUFMGXBP-UHFFFAOYSA-N (4-tert-butylcyclohexyl) (4-tert-butylcyclohexyl)oxycarbonyloxy carbonate Chemical compound C1CC(C(C)(C)C)CCC1OC(=O)OOC(=O)OC1CCC(C(C)(C)C)CC1 NOBYOEQUFMGXBP-UHFFFAOYSA-N 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 241000156978 Erebia Species 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- BLCKNMAZFRMCJJ-UHFFFAOYSA-N cyclohexyl cyclohexyloxycarbonyloxy carbonate Chemical compound C1CCCCC1OC(=O)OOC(=O)OC1CCCCC1 BLCKNMAZFRMCJJ-UHFFFAOYSA-N 0.000 description 1
- BSVQJWUUZCXSOL-UHFFFAOYSA-N cyclohexylsulfonyl ethaneperoxoate Chemical compound CC(=O)OOS(=O)(=O)C1CCCCC1 BSVQJWUUZCXSOL-UHFFFAOYSA-N 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010130 dispersion processing Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- PJUIMOJAAPLTRJ-UHFFFAOYSA-N monothioglycerol Chemical compound OCC(O)CS PJUIMOJAAPLTRJ-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 210000004492 nuclear pore Anatomy 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- NJRXVEJTAYWCQJ-UHFFFAOYSA-N thiomalic acid Chemical compound OC(=O)CC(S)C(O)=O NJRXVEJTAYWCQJ-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- VSRBKQFNFZQRBM-UHFFFAOYSA-N tuaminoheptane Chemical compound CCCCCC(C)N VSRBKQFNFZQRBM-UHFFFAOYSA-N 0.000 description 1
- 229960003986 tuaminoheptane Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Processes Of Treating Macromolecular Substances (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15310387A JPS63317306A (ja) | 1987-06-19 | 1987-06-19 | 残留塩化ビニルモノマ−の少ない低重合度塩化ビニル重合体粉末及びその製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15310387A JPS63317306A (ja) | 1987-06-19 | 1987-06-19 | 残留塩化ビニルモノマ−の少ない低重合度塩化ビニル重合体粉末及びその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63317306A true JPS63317306A (ja) | 1988-12-26 |
| JPH0444884B2 JPH0444884B2 (cg-RX-API-DMAC7.html) | 1992-07-23 |
Family
ID=15555038
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15310387A Granted JPS63317306A (ja) | 1987-06-19 | 1987-06-19 | 残留塩化ビニルモノマ−の少ない低重合度塩化ビニル重合体粉末及びその製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63317306A (cg-RX-API-DMAC7.html) |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51140985A (en) * | 1975-05-16 | 1976-12-04 | Hoechst Ag | Method of removing monomer from aqueous dispersion of polymer |
| JPS5272787A (en) * | 1975-12-16 | 1977-06-17 | Ryonichi Kk | Process for polymerizing vinyl chloride |
| JPS5313515A (en) * | 1976-07-24 | 1978-02-07 | Senzou Yamamoto | Sheathing method |
| JPS5334888A (en) * | 1976-07-27 | 1978-03-31 | Ici Australia Ltd | Method of removing vinyl chloride monomer |
| JPS5372089A (en) * | 1976-12-09 | 1978-06-27 | Nippon Zeon Co Ltd | Preparation of polyvinyl chloride type resin |
| JPS541397A (en) * | 1977-06-03 | 1979-01-08 | Kanegafuchi Chem Ind Co Ltd | Suspension polymerization of vinyl chloride |
| JPS5533804A (en) * | 1978-08-29 | 1980-03-10 | Toshiba Corp | Method and apparatus for roll forming of bellows |
| JPS5622305A (en) * | 1979-08-01 | 1981-03-02 | Chisso Corp | Monomer removal from vinyl chloride resin slurry by steaming and apparatus therefor |
| JPS5645489A (en) * | 1979-08-22 | 1981-04-25 | Continental Oil Co | Manufacture of purified alkylaluminum |
| JPS6111241A (ja) * | 1984-06-28 | 1986-01-18 | 住友ベークライト株式会社 | 多層プリント配線板 |
-
1987
- 1987-06-19 JP JP15310387A patent/JPS63317306A/ja active Granted
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51140985A (en) * | 1975-05-16 | 1976-12-04 | Hoechst Ag | Method of removing monomer from aqueous dispersion of polymer |
| JPS5272787A (en) * | 1975-12-16 | 1977-06-17 | Ryonichi Kk | Process for polymerizing vinyl chloride |
| JPS5313515A (en) * | 1976-07-24 | 1978-02-07 | Senzou Yamamoto | Sheathing method |
| JPS5334888A (en) * | 1976-07-27 | 1978-03-31 | Ici Australia Ltd | Method of removing vinyl chloride monomer |
| JPS5372089A (en) * | 1976-12-09 | 1978-06-27 | Nippon Zeon Co Ltd | Preparation of polyvinyl chloride type resin |
| JPS541397A (en) * | 1977-06-03 | 1979-01-08 | Kanegafuchi Chem Ind Co Ltd | Suspension polymerization of vinyl chloride |
| JPS5533804A (en) * | 1978-08-29 | 1980-03-10 | Toshiba Corp | Method and apparatus for roll forming of bellows |
| JPS5622305A (en) * | 1979-08-01 | 1981-03-02 | Chisso Corp | Monomer removal from vinyl chloride resin slurry by steaming and apparatus therefor |
| JPS5645489A (en) * | 1979-08-22 | 1981-04-25 | Continental Oil Co | Manufacture of purified alkylaluminum |
| JPS6111241A (ja) * | 1984-06-28 | 1986-01-18 | 住友ベークライト株式会社 | 多層プリント配線板 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0444884B2 (cg-RX-API-DMAC7.html) | 1992-07-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4920202A (en) | Method for production of hydrophilic polymer from hydrated gel polymer | |
| US4625001A (en) | Method for continuous production of cross-linked polymer | |
| CA1089146A (en) | Monomer removal from the slurry of vinyl chloride resin with steam by using improved plate tower | |
| JP4767940B2 (ja) | 高内相エマルションの硬化方法 | |
| GB2146343A (en) | Cross-linked polymers | |
| JPS5813563B2 (ja) | 塩化ビニルの水性分散液から未反応モノマ−を除去する方法およびその装置 | |
| TWI731942B (zh) | 提供用於製備經氯化之聚氯乙烯之聚氯乙烯粒子之方法 | |
| KR100449195B1 (ko) | 잔류단량체제거장치및방법 | |
| EP0949276B1 (en) | Methods and apparatus for removing residual monomers | |
| IE42595B1 (en) | Process and apparatus for reducing the content of volatile constituents of vinyl chloride polymers | |
| DE2141770A1 (de) | Verfahren und vorrichtung zur herstellung von polymerisaten oder copolymerisaten von vinylchlorid durch kontinuierliche polymerisation in masse | |
| JPS63317306A (ja) | 残留塩化ビニルモノマ−の少ない低重合度塩化ビニル重合体粉末及びその製造方法 | |
| CN2688709Y (zh) | 聚合反应中脱除残留单体的设备 | |
| JP4363940B2 (ja) | 塩化ビニル系樹脂スラリーから塩化ビニルモノマーを除去する方法 | |
| KR20130025515A (ko) | 현탁 중합에 의한 염화비닐 중합체의 제조방법 및 이에 사용되는 장치 | |
| EP0051945B1 (en) | Improved suspension process for the polymerization of vinyl chloride monomer | |
| KR102869580B1 (ko) | 염화비닐계 중합체의 제조방법 | |
| KR101510930B1 (ko) | 현탁 중합에 의한 염화비닐 중합체의 건조방법 및 이에 사용되는 건조장치 | |
| DE2615200A1 (de) | Verfahren zur verbesserung der eigenschaften von pulverfoermigem polyvinylchlorid | |
| JP2896272B2 (ja) | 塩素化塩化ビニル系樹脂の後処理方法 | |
| JPH0243902A (ja) | 気液接触装置及び合成樹脂粉粒体から揮発性成分を徐去する方法 | |
| JP4080782B2 (ja) | ビーズ状重合物の製造方法 | |
| NO162726B (no) | Fremgangsmaate for suspensjonspolymerisering av vinylkloridmonomer og eventuelle komonomerer. | |
| JPS59213711A (ja) | シロツプの連続調整方法 | |
| HK1023133A (en) | Methods and apparatus for removing residual monomers |