JPS6278209A - アクリロニトリル系合成繊維の製法 - Google Patents
アクリロニトリル系合成繊維の製法Info
- Publication number
- JPS6278209A JPS6278209A JP21613485A JP21613485A JPS6278209A JP S6278209 A JPS6278209 A JP S6278209A JP 21613485 A JP21613485 A JP 21613485A JP 21613485 A JP21613485 A JP 21613485A JP S6278209 A JPS6278209 A JP S6278209A
- Authority
- JP
- Japan
- Prior art keywords
- acrylonitrile
- spinning
- polymer
- value
- melt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title claims description 40
- 229920002994 synthetic fiber Polymers 0.000 title claims description 9
- 239000012209 synthetic fiber Substances 0.000 title claims description 9
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 239000000835 fiber Substances 0.000 claims description 23
- 229920001577 copolymer Polymers 0.000 claims description 7
- 230000009477 glass transition Effects 0.000 claims description 7
- 229920002239 polyacrylonitrile Polymers 0.000 description 20
- 238000002074 melt spinning Methods 0.000 description 18
- 238000000034 method Methods 0.000 description 18
- 229920000642 polymer Polymers 0.000 description 17
- 238000009987 spinning Methods 0.000 description 14
- 238000004736 wide-angle X-ray diffraction Methods 0.000 description 8
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 239000000155 melt Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 3
- -1 sulfoalkyl acrylate Chemical compound 0.000 description 3
- 238000005979 thermal decomposition reaction Methods 0.000 description 3
- 238000002166 wet spinning Methods 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- XEEYSDHEOQHCDA-UHFFFAOYSA-N 2-methylprop-2-ene-1-sulfonic acid Chemical compound CC(=C)CS(O)(=O)=O XEEYSDHEOQHCDA-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 1
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21613485A JPS6278209A (ja) | 1985-10-01 | 1985-10-01 | アクリロニトリル系合成繊維の製法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21613485A JPS6278209A (ja) | 1985-10-01 | 1985-10-01 | アクリロニトリル系合成繊維の製法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6278209A true JPS6278209A (ja) | 1987-04-10 |
| JPH0133566B2 JPH0133566B2 (enExample) | 1989-07-13 |
Family
ID=16683796
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21613485A Granted JPS6278209A (ja) | 1985-10-01 | 1985-10-01 | アクリロニトリル系合成繊維の製法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6278209A (enExample) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH037524A (ja) * | 1989-06-06 | 1991-01-14 | Haruhiko Akiyama | 加熱蒸散装置 |
| US5304590A (en) * | 1992-01-21 | 1994-04-19 | Solcas Polymer, Inc. | Acrylonitrile polymer compositions and articles and methods for their preparation |
| US5434205A (en) * | 1992-01-21 | 1995-07-18 | Solcas Polymer Limited Partnership | Acrylonitrile polymer compositions and articles and methods for their preparation |
| EP0780498A1 (en) * | 1995-12-18 | 1997-06-25 | The Standard Oil Company | Melt spun acrylonitrile olefinically unsaturated fibers and a process to make fibers |
| EP1223023A1 (en) * | 2001-01-16 | 2002-07-17 | Zahir Bashir | Method of solventless processing PAN homopolymers or high acrylonitrile content PAN copolymers |
| JP2006281387A (ja) * | 2005-04-01 | 2006-10-19 | Senjo Seiki Kk | 加工装置 |
| JP2019523833A (ja) * | 2016-05-11 | 2019-08-29 | フラウンホーファー−ゲゼルシャフト ツゥア フェアデルング デア アンゲヴァンドテン フォァシュング エー．ファウ． | マルチフィラメント糸の製造方法及びマルチフィラメント糸 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4955921A (enExample) * | 1972-09-29 | 1974-05-30 | ||
| JPS6285012A (ja) * | 1985-10-04 | 1987-04-18 | Mitsubishi Rayon Co Ltd | アクリロニトリル系合成繊維の製造方法 |
-
1985
- 1985-10-01 JP JP21613485A patent/JPS6278209A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4955921A (enExample) * | 1972-09-29 | 1974-05-30 | ||
| JPS6285012A (ja) * | 1985-10-04 | 1987-04-18 | Mitsubishi Rayon Co Ltd | アクリロニトリル系合成繊維の製造方法 |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH037524A (ja) * | 1989-06-06 | 1991-01-14 | Haruhiko Akiyama | 加熱蒸散装置 |
| US5304590A (en) * | 1992-01-21 | 1994-04-19 | Solcas Polymer, Inc. | Acrylonitrile polymer compositions and articles and methods for their preparation |
| US5434205A (en) * | 1992-01-21 | 1995-07-18 | Solcas Polymer Limited Partnership | Acrylonitrile polymer compositions and articles and methods for their preparation |
| US5589520A (en) * | 1992-01-21 | 1996-12-31 | Solcas Polymer, Limited Partnership | Acrylonitrile polymer composition and articles and methods for their preparation |
| EP0780498A1 (en) * | 1995-12-18 | 1997-06-25 | The Standard Oil Company | Melt spun acrylonitrile olefinically unsaturated fibers and a process to make fibers |
| US6114034A (en) * | 1995-12-18 | 2000-09-05 | The Standard Oil Company | Melt spun acrylonitrile olefinically unsaturated fibers and a process to make fibers |
| EP1223023A1 (en) * | 2001-01-16 | 2002-07-17 | Zahir Bashir | Method of solventless processing PAN homopolymers or high acrylonitrile content PAN copolymers |
| JP2006281387A (ja) * | 2005-04-01 | 2006-10-19 | Senjo Seiki Kk | 加工装置 |
| JP2019523833A (ja) * | 2016-05-11 | 2019-08-29 | フラウンホーファー−ゲゼルシャフト ツゥア フェアデルング デア アンゲヴァンドテン フォァシュング エー．ファウ． | マルチフィラメント糸の製造方法及びマルチフィラメント糸 |
| US11649567B2 (en) | 2016-05-11 | 2023-05-16 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Method for producing a multifilament yarn |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0133566B2 (enExample) | 1989-07-13 |
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