JPS6256170B2 - - Google Patents
Info
- Publication number
- JPS6256170B2 JPS6256170B2 JP53019514A JP1951478A JPS6256170B2 JP S6256170 B2 JPS6256170 B2 JP S6256170B2 JP 53019514 A JP53019514 A JP 53019514A JP 1951478 A JP1951478 A JP 1951478A JP S6256170 B2 JPS6256170 B2 JP S6256170B2
- Authority
- JP
- Japan
- Prior art keywords
- formula
- acrylic resin
- range
- unit represented
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004925 Acrylic resin Substances 0.000 claims description 27
- 229920000178 Acrylic resin Polymers 0.000 claims description 27
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 17
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical group COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 6
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical group CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical group CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000011347 resin Substances 0.000 description 14
- 229920005989 resin Polymers 0.000 description 14
- 238000006116 polymerization reaction Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000000178 monomer Substances 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 238000000137 annealing Methods 0.000 description 5
- 238000005336 cracking Methods 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000012986 chain transfer agent Substances 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 3
- 239000003505 polymerization initiator Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000006082 mold release agent Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- -1 alkyl mercaptan Chemical compound 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- ZWEDFBKLJILTMC-UHFFFAOYSA-N ethyl 4,4,4-trifluoro-3-hydroxybutanoate Chemical compound CCOC(=O)CC(O)C(F)(F)F ZWEDFBKLJILTMC-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical compound CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1951478A JPS54112987A (en) | 1978-02-22 | 1978-02-22 | Solvent-resistant acrylic resin |
| US05/957,887 US4246382A (en) | 1977-11-11 | 1978-11-06 | Solvent resistent acrylic resin and process for producing the same |
| GB7843494A GB2008130B (en) | 1977-11-11 | 1978-11-07 | Solcent resistant acrylic resin and process for producing the same |
| DE2848906A DE2848906C2 (de) | 1977-11-11 | 1978-11-10 | Methacrylsäuremethylester-Polymerisate und Verfahren zu ihrer Herstellung |
| FR7831834A FR2408627A1 (fr) | 1977-11-11 | 1978-11-10 | Resine acrylique resistant au solvant et son procede de preparation |
| IT29681/78A IT1100098B (it) | 1977-11-11 | 1978-11-10 | Resina acrilica resistente ai solventi e procedimento per produrla |
| US06/126,117 US4369299A (en) | 1977-11-11 | 1980-02-29 | Acrylic resin having excellent solvent resistance and moldability |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1951478A JPS54112987A (en) | 1978-02-22 | 1978-02-22 | Solvent-resistant acrylic resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS54112987A JPS54112987A (en) | 1979-09-04 |
| JPS6256170B2 true JPS6256170B2 (US06623731-20030923-C00052.png) | 1987-11-24 |
Family
ID=12001459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1951478A Granted JPS54112987A (en) | 1977-11-11 | 1978-02-22 | Solvent-resistant acrylic resin |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS54112987A (US06623731-20030923-C00052.png) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0225052U (US06623731-20030923-C00052.png) * | 1988-08-02 | 1990-02-19 |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55116711A (en) * | 1979-03-05 | 1980-09-08 | Asahi Chem Ind Co Ltd | Acrylic resin molding material and its preparation |
| JPS57138601A (en) * | 1981-02-20 | 1982-08-27 | Mitsubishi Rayon Co Ltd | Methacrylic resin molding material for optical apparatus |
| FR2501213A1 (fr) * | 1981-03-05 | 1982-09-10 | Altulor Sa | Prepolymere acrylique et son application a l'encapsulation de photopiles |
| JPS59102947A (ja) * | 1982-12-02 | 1984-06-14 | Mitsubishi Rayon Co Ltd | メタクリル樹脂組成物 |
| US4593081A (en) * | 1985-04-25 | 1986-06-03 | Phillips Petroleum Company | Chain-transfer agents for emulsion polymerization and polymer products produced therewith |
| US6730741B1 (en) | 1999-05-19 | 2004-05-04 | Mitsubishi Rayon Co., Ltd. | Processing aid, vinyl chloride resin composition containing the same, and process for producing molded article with the same |
| WO2013161265A1 (ja) * | 2012-04-27 | 2013-10-31 | 株式会社クラレ | （メタ）アクリル樹脂組成物 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB971673A (en) * | 1963-01-03 | 1964-09-30 | Ici Ltd | Thermoplastic moulding materials |
| US3383448A (en) * | 1963-05-04 | 1968-05-14 | Degussa | Polymerization process |
-
1978
- 1978-02-22 JP JP1951478A patent/JPS54112987A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB971673A (en) * | 1963-01-03 | 1964-09-30 | Ici Ltd | Thermoplastic moulding materials |
| US3383448A (en) * | 1963-05-04 | 1968-05-14 | Degussa | Polymerization process |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0225052U (US06623731-20030923-C00052.png) * | 1988-08-02 | 1990-02-19 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS54112987A (en) | 1979-09-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4246382A (en) | Solvent resistent acrylic resin and process for producing the same | |
| JPH07258340A (ja) | 熱可塑性に加工可能なポリメタクリレート成形材料から製造された押出成形したプレート及びシート、射出成形部品、成形体及び工作部品 | |
| JPS6256170B2 (US06623731-20030923-C00052.png) | ||
| JP5301459B2 (ja) | 耐変色性及び透明性に優れたメタクリレート樹脂及びその製造方法 | |
| US3984499A (en) | Thermally stable high nitrile resins and method for producing the same | |
| JPS5815490B2 (ja) | 耐溶剤性に優れたアクリル樹脂成形材料 | |
| EP0287668B1 (en) | Process for producing a heat resistant resin composition | |
| EP0741150B1 (en) | A process for making a polymer of acrylonitrile, methacrylonitrile and olefinically unsaturated monomers | |
| JPH01203451A (ja) | ゴム状熱可塑性ポリマー混合物 | |
| JPS58455B2 (ja) | 耐溶剤性アクリル樹脂の製造方法 | |
| JPS6234046B2 (US06623731-20030923-C00052.png) | ||
| JPS6256171B2 (US06623731-20030923-C00052.png) | ||
| CA1130497A (en) | Process for the preparation of vulcanizable acrylic elastomers | |
| JP3061551B2 (ja) | メタクリル系樹脂の製造方法 | |
| JPH0696658B2 (ja) | 耐熱性樹脂組成物 | |
| JPS6214565B2 (US06623731-20030923-C00052.png) | ||
| JPS63199710A (ja) | 耐熱性、透明性に優れた新規メチルメタクリレ−ト−スチレン系樹脂 | |
| JP3580908B2 (ja) | 透明耐熱性樹脂 | |
| JPS6272710A (ja) | アクリル酸エステル系ポリマ−コンポジツトの製造法 | |
| JPH08127626A (ja) | 高ニトリル含有ビニル系共重合体およびその製造方法 | |
| JPH01289812A (ja) | 共重合体を含有する熱変形安定な熱可塑性成形材料、この成形材料の製法及びその用途 | |
| JPH0221402B2 (US06623731-20030923-C00052.png) | ||
| JP2754780B2 (ja) | メタクリル酸系単量体の重合方法 | |
| JPH07216007A (ja) | メタクリル系樹脂の製造方法 | |
| JPH01289815A (ja) | 熱変形安定な透明な熱可塑性成形材料、その製法及びその用途 |
