JPS62129161A - 鉱物の泡沫浮遊選鉱のための捕集剤 - Google Patents
鉱物の泡沫浮遊選鉱のための捕集剤Info
- Publication number
- JPS62129161A JPS62129161A JP61207633A JP20763386A JPS62129161A JP S62129161 A JPS62129161 A JP S62129161A JP 61207633 A JP61207633 A JP 61207633A JP 20763386 A JP20763386 A JP 20763386A JP S62129161 A JPS62129161 A JP S62129161A
- Authority
- JP
- Japan
- Prior art keywords
- omega
- alkyl
- hydrocarbyl
- group
- minerals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims description 69
- 239000011707 mineral Substances 0.000 title claims description 69
- 238000005188 flotation Methods 0.000 title claims description 51
- 239000006260 foam Substances 0.000 title claims description 41
- 239000000203 mixture Substances 0.000 claims description 70
- 229910052751 metal Inorganic materials 0.000 claims description 57
- 239000002184 metal Substances 0.000 claims description 57
- 125000000217 alkyl group Chemical group 0.000 claims description 42
- 238000000034 method Methods 0.000 claims description 38
- -1 xanthine ester Chemical class 0.000 claims description 36
- 239000002516 radical scavenger Substances 0.000 claims description 29
- 239000010949 copper Substances 0.000 claims description 28
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 21
- 229910052802 copper Inorganic materials 0.000 claims description 21
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 21
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 19
- 150000003973 alkyl amines Chemical class 0.000 claims description 18
- 229930195733 hydrocarbon Natural products 0.000 claims description 15
- 239000004215 Carbon black (E152) Substances 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 13
- 239000011701 zinc Substances 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 229910052759 nickel Inorganic materials 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 10
- 239000011133 lead Substances 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 9
- 229910052725 zinc Inorganic materials 0.000 claims description 9
- 150000002430 hydrocarbons Chemical class 0.000 claims description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 7
- 239000004615 ingredient Substances 0.000 claims description 7
- 229910052750 molybdenum Inorganic materials 0.000 claims description 7
- 239000011733 molybdenum Substances 0.000 claims description 7
- 229920006395 saturated elastomer Polymers 0.000 claims description 7
- 229910052709 silver Inorganic materials 0.000 claims description 7
- 239000004332 silver Substances 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 125000000623 heterocyclic group Chemical group 0.000 claims description 6
- 229910052770 Uranium Inorganic materials 0.000 claims description 5
- 125000003342 alkenyl group Chemical group 0.000 claims description 5
- 125000005499 phosphonyl group Chemical group 0.000 claims description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- SUEKLQICDHYPAC-UHFFFAOYSA-N 2-hexylsulfanylethanamine Chemical compound CCCCCCSCCN SUEKLQICDHYPAC-UHFFFAOYSA-N 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 4
- LRFVTYWOQMYALW-UHFFFAOYSA-N Xanthine Natural products O=C1NC(=O)NC2=C1NC=N2 LRFVTYWOQMYALW-UHFFFAOYSA-N 0.000 claims description 4
- 125000004448 alkyl carbonyl group Chemical group 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 229910052949 galena Inorganic materials 0.000 claims description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052737 gold Inorganic materials 0.000 claims description 4
- 239000010931 gold Substances 0.000 claims description 4
- 125000000743 hydrocarbylene group Chemical group 0.000 claims description 4
- XCAUINMIESBTBL-UHFFFAOYSA-N lead(ii) sulfide Chemical compound [Pb]=S XCAUINMIESBTBL-UHFFFAOYSA-N 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 229910052954 pentlandite Inorganic materials 0.000 claims description 4
- 229910052950 sphalerite Inorganic materials 0.000 claims description 4
- 229940075420 xanthine Drugs 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 229910052948 bornite Inorganic materials 0.000 claims description 3
- 229910052951 chalcopyrite Inorganic materials 0.000 claims description 3
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims description 3
- 229910052961 molybdenite Inorganic materials 0.000 claims description 3
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical group S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052785 arsenic Inorganic materials 0.000 claims description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 125000005648 substituted hydrocarbylene group Chemical group 0.000 claims description 2
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical group [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 claims 3
- 125000004916 (C1-C6) alkylcarbonyl group Chemical group 0.000 claims 2
- AHNVIKAHAZJYGD-UHFFFAOYSA-N N-ethyl-2-hexylsulfanylethanamine Chemical compound CCCCCCSCCNCC AHNVIKAHAZJYGD-UHFFFAOYSA-N 0.000 claims 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- FCSHMCFRCYZTRQ-UHFFFAOYSA-N N,N'-diphenylthiourea Chemical compound C=1C=CC=CC=1NC(=S)NC1=CC=CC=C1 FCSHMCFRCYZTRQ-UHFFFAOYSA-N 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 claims 1
- 235000010755 mineral Nutrition 0.000 description 63
- 238000011084 recovery Methods 0.000 description 37
- 229910052569 sulfide mineral Inorganic materials 0.000 description 26
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 24
- 229910052592 oxide mineral Inorganic materials 0.000 description 17
- 239000012141 concentrate Substances 0.000 description 15
- 239000004088 foaming agent Substances 0.000 description 14
- 229910052742 iron Inorganic materials 0.000 description 12
- 239000007787 solid Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 230000003750 conditioning effect Effects 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 229910052952 pyrrhotite Inorganic materials 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 5
- 239000013589 supplement Substances 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical class OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 239000012990 dithiocarbamate Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 4
- KOPMZTKUZCNGFY-UHFFFAOYSA-N 1,1,1-triethoxybutane Chemical compound CCCC(OCC)(OCC)OCC KOPMZTKUZCNGFY-UHFFFAOYSA-N 0.000 description 3
- JLLYLQLDYORLBB-UHFFFAOYSA-N 5-bromo-n-methylthiophene-2-sulfonamide Chemical compound CNS(=O)(=O)C1=CC=C(Br)S1 JLLYLQLDYORLBB-UHFFFAOYSA-N 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- 238000003723 Smelting Methods 0.000 description 3
- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 150000001924 cycloalkanes Chemical class 0.000 description 3
- 150000001925 cycloalkenes Chemical class 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 150000002019 disulfides Chemical class 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 239000004571 lime Substances 0.000 description 3
- 239000005077 polysulfide Substances 0.000 description 3
- 229920001021 polysulfide Polymers 0.000 description 3
- 150000008117 polysulfides Polymers 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052683 pyrite Inorganic materials 0.000 description 3
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 3
- 239000011028 pyrite Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000012989 trithiocarbonate Substances 0.000 description 3
- 239000012991 xanthate Substances 0.000 description 3
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 2
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 2
- AFWVZAABPOHYMD-UHFFFAOYSA-N 5-butoxy-1,4,2,3,5lambda5-dioxadithiaphospholane 5-oxide Chemical compound P1(=O)(OCCCC)OSSO1 AFWVZAABPOHYMD-UHFFFAOYSA-N 0.000 description 2
- KDCGOANMDULRCW-UHFFFAOYSA-N 7H-purine Chemical compound N1=CNC2=NC=NC2=C1 KDCGOANMDULRCW-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 244000303965 Cyamopsis psoralioides Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229910002555 FeNi Inorganic materials 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000001345 alkine derivatives Chemical class 0.000 description 2
- 125000000304 alkynyl group Chemical group 0.000 description 2
- 150000001412 amines Chemical group 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 230000002079 cooperative effect Effects 0.000 description 2
- 229910000365 copper sulfate Inorganic materials 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- 125000000392 cycloalkenyl group Chemical group 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- XENQEXCDJPMSRF-UHFFFAOYSA-N ethyl(2-methylpropyl)carbamothioic S-acid Chemical compound CCN(C(S)=O)CC(C)C XENQEXCDJPMSRF-UHFFFAOYSA-N 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical compound C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910001120 nichrome Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- YIBBMDDEXKBIAM-UHFFFAOYSA-M potassium;pentoxymethanedithioate Chemical compound [K+].CCCCCOC([S-])=S YIBBMDDEXKBIAM-UHFFFAOYSA-M 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- NVQOVQBDGGEXER-UHFFFAOYSA-M sodium;2-methylpropoxymethanethioate Chemical compound [Na+].CC(C)COC([S-])=O NVQOVQBDGGEXER-UHFFFAOYSA-M 0.000 description 2
- ZKDDJTYSFCWVGS-UHFFFAOYSA-M sodium;diethoxy-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Na+].CCOP([S-])(=S)OCC ZKDDJTYSFCWVGS-UHFFFAOYSA-M 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 239000011135 tin Substances 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical class C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 1
- JECYNCQXXKQDJN-UHFFFAOYSA-N 2-(2-methylhexan-2-yloxymethyl)oxirane Chemical compound CCCCC(C)(C)OCC1CO1 JECYNCQXXKQDJN-UHFFFAOYSA-N 0.000 description 1
- GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 description 1
- ZOLACKDSSUBCNN-UHFFFAOYSA-N 5,6-dimethylcyclohexa-2,4-diene-1-carboxylic acid Chemical compound CC1C(C(O)=O)C=CC=C1C ZOLACKDSSUBCNN-UHFFFAOYSA-N 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- GNPBVBKOCFHWRK-UHFFFAOYSA-N CCC(C)N(C)C(=O)S Chemical compound CCC(C)N(C)C(=O)S GNPBVBKOCFHWRK-UHFFFAOYSA-N 0.000 description 1
- DONVQRPRXWADKF-UHFFFAOYSA-N CCC(C)N(CC)C(S)=O Chemical compound CCC(C)N(CC)C(S)=O DONVQRPRXWADKF-UHFFFAOYSA-N 0.000 description 1
- 229910018076 Cu4(OH)6SO4 Inorganic materials 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 244000166124 Eucalyptus globulus Species 0.000 description 1
- 229910000616 Ferromanganese Inorganic materials 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- 241000530268 Lycaena heteronea Species 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
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- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
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- LHQNFTGLYHOYOW-UHFFFAOYSA-M potassium;2-methylpropoxymethanethioate Chemical compound [K+].CC(C)COC([S-])=O LHQNFTGLYHOYOW-UHFFFAOYSA-M 0.000 description 1
- IRLQBIZKDCDEQE-UHFFFAOYSA-M potassium;2-methylpropylsulfanylmethanethioate Chemical compound [K+].CC(C)CSC([S-])=O IRLQBIZKDCDEQE-UHFFFAOYSA-M 0.000 description 1
- WNVZCNDFBUPCTL-UHFFFAOYSA-M potassium;ethoxymethanethioate Chemical compound [K+].CCOC([O-])=S WNVZCNDFBUPCTL-UHFFFAOYSA-M 0.000 description 1
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- AIPYPNIKBYARBC-UHFFFAOYSA-M potassium;pentylsulfanylmethanethioate Chemical compound [K+].CCCCCSC([S-])=O AIPYPNIKBYARBC-UHFFFAOYSA-M 0.000 description 1
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- SVJCFWZQQNYGMQ-UHFFFAOYSA-M potassium;propan-2-yloxymethanethioate Chemical compound [K+].CC(C)OC([S-])=O SVJCFWZQQNYGMQ-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
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- 238000012545 processing Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PBMFSQRYOILNGV-UHFFFAOYSA-N pyridazine Chemical compound C1=CC=NN=C1 PBMFSQRYOILNGV-UHFFFAOYSA-N 0.000 description 1
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- 238000005201 scrubbing Methods 0.000 description 1
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- FSJWWSXPIWGYKC-UHFFFAOYSA-M silver;silver;sulfanide Chemical compound [SH-].[Ag].[Ag+] FSJWWSXPIWGYKC-UHFFFAOYSA-M 0.000 description 1
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- MXWLPOQBCCHRIR-UHFFFAOYSA-M sodium bis(3-methylbutoxy)-oxido-sulfanylidene-lambda5-phosphane Chemical compound [Na+].CC(C)CCOP([O-])(=S)OCCC(C)C MXWLPOQBCCHRIR-UHFFFAOYSA-M 0.000 description 1
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- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- FSFACTZWHMNCPB-UHFFFAOYSA-M sodium;2-methylpropylsulfanylmethanedithioate Chemical compound [Na+].CC(C)CSC([S-])=S FSFACTZWHMNCPB-UHFFFAOYSA-M 0.000 description 1
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- YZLQFRKSOZCHCJ-UHFFFAOYSA-M sodium;3-methylbutoxy-(3-methylbutylsulfanyl)-oxido-sulfanylidene-$l^{5}-phosphane Chemical compound [Na+].CC(C)CCOP([O-])(=S)SCCC(C)C YZLQFRKSOZCHCJ-UHFFFAOYSA-M 0.000 description 1
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- YMPPRYJBYFNJTO-UHFFFAOYSA-M sodium;diethoxy-oxido-sulfanylidene-$l^{5}-phosphane Chemical compound [Na+].CCOP([O-])(=S)OCC YMPPRYJBYFNJTO-UHFFFAOYSA-M 0.000 description 1
- SCEWVYKGCFYQDU-UHFFFAOYSA-M sodium;ethoxymethanethioate Chemical compound [Na+].CCOC([S-])=O SCEWVYKGCFYQDU-UHFFFAOYSA-M 0.000 description 1
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- CNKUJLXIJWGWGU-UHFFFAOYSA-M sodium;pentoxymethanethioate Chemical compound [Na+].CCCCCOC([S-])=O CNKUJLXIJWGWGU-UHFFFAOYSA-M 0.000 description 1
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- XQTKKXWWPWOCPF-UHFFFAOYSA-M sodium;propan-2-ylsulfanylmethanethioate Chemical compound [Na+].CC(C)SC([S-])=O XQTKKXWWPWOCPF-UHFFFAOYSA-M 0.000 description 1
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- 239000010421 standard material Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052959 stibnite Inorganic materials 0.000 description 1
- IHBMMJGTJFPEQY-UHFFFAOYSA-N sulfanylidene(sulfanylidenestibanylsulfanyl)stibane Chemical compound S=[Sb]S[Sb]=S IHBMMJGTJFPEQY-UHFFFAOYSA-N 0.000 description 1
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- 229930192474 thiophene Natural products 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- HIZCIEIDIFGZSS-UHFFFAOYSA-L trithiocarbonate Chemical compound [S-]C([S-])=S HIZCIEIDIFGZSS-UHFFFAOYSA-L 0.000 description 1
- 229910000442 triuranium octoxide Inorganic materials 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/01—Organic compounds containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/014—Organic compounds containing phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; specified applications
- B03D2203/02—Ores
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US80302685A | 1985-11-29 | 1985-11-29 | |
| US803026 | 1985-11-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62129161A true JPS62129161A (ja) | 1987-06-11 |
Family
ID=25185373
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61207633A Pending JPS62129161A (ja) | 1985-11-29 | 1986-09-03 | 鉱物の泡沫浮遊選鉱のための捕集剤 |
Country Status (15)
| Country | Link |
|---|---|
| JP (1) | JPS62129161A (pl) |
| CN (1) | CN86101573A (pl) |
| AU (1) | AU586471B2 (pl) |
| BR (1) | BR8607003A (pl) |
| ES (1) | ES8706047A1 (pl) |
| FI (1) | FI873287A0 (pl) |
| PH (1) | PH24537A (pl) |
| PL (1) | PL147930B1 (pl) |
| RU (1) | RU1837985C (pl) |
| SE (1) | SE8702988L (pl) |
| WO (1) | WO1987003221A1 (pl) |
| YU (1) | YU45765B (pl) |
| ZA (1) | ZA861171B (pl) |
| ZM (1) | ZM1486A1 (pl) |
| ZW (1) | ZW4286A1 (pl) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES8706045A1 (es) * | 1985-11-29 | 1987-06-01 | Dow Chemical Co | Un procedimiento para recuperar minerales que contienen metales a partir de una mena |
| EP0298392A3 (de) * | 1987-07-07 | 1991-01-09 | Henkel Kommanditgesellschaft auf Aktien | Verfahren zur Gewinnung von Mineralen aus sulfidischen aus Erzen durch Flotation und Mittel zu seiner Durchführung |
| ZA906138B (en) * | 1989-08-04 | 1991-05-29 | Broken Hill Pty Co Ltd | Ion flotation with non-ionic reagents |
| US5700369A (en) * | 1997-01-14 | 1997-12-23 | Guangzhou Institute Of Geochemistry Chinese Academy Of Sciences | Process for adsorboaggregational flotation of Carlin type natural gold ore dressing |
| CN101455996B (zh) * | 2007-12-10 | 2012-04-25 | 北京有色金属研究总院 | 单斜磁黄铁矿与方铅矿浮选分离工艺 |
| CN101337206B (zh) * | 2008-08-13 | 2011-02-02 | 中南大学 | 硫化矿浮选捕收剂及二酰基双硫脲应用方法和制备方法 |
| CN101549326B (zh) * | 2009-05-15 | 2012-07-04 | 江西理工大学 | 一种难选铜锌硫化矿浮选分离的工艺 |
| FR2994534B1 (fr) * | 2012-08-20 | 2015-06-26 | Ceca Sa | Collecteurs pour enrichissement de minerais |
| AU2014331945B2 (en) * | 2013-10-09 | 2018-03-01 | Georgia-Pacific Chemicals Llc | Collector compositions and methods for making and using same |
| CN104624384B (zh) * | 2015-02-02 | 2017-02-22 | 山东建筑大学 | 一种低温型铁矿浮选捕收剂及其制备方法和应用 |
| CN104826742B (zh) * | 2015-05-19 | 2016-12-07 | 烟台恒邦化工助剂有限公司 | 一种硫化矿的复合捕收剂及其制备方法 |
| CN108160336B (zh) * | 2017-12-26 | 2020-11-03 | 中国地质科学院矿产综合利用研究所 | 一种碲铋矿浮选抑制剂及其制备方法和应用 |
| CN109158217A (zh) * | 2018-06-29 | 2019-01-08 | 昆明理工大学 | 一种硫化铜矿的浮选捕收剂 |
| CN113692318B (zh) * | 2019-04-19 | 2023-06-06 | 诺力昂化学品国际有限公司 | 包含n-酰化氨基酸的捕集剂组合物和处理非硫化矿的方法 |
| CN111266195B (zh) * | 2020-03-05 | 2021-09-07 | 中南大学 | 一种氧化锌矿浮选组合捕收剂及其应用 |
| CN112657682B (zh) * | 2021-03-16 | 2021-07-09 | 矿冶科技集团有限公司 | 硫化矿浮选捕收剂及其应用和硫化矿浮选方法 |
| CN113262882B (zh) * | 2021-07-21 | 2021-09-17 | 北京矿冶研究总院 | 阳离子捕收剂、制备方法及在磷矿反浮选中的应用 |
| CN115155824B (zh) * | 2022-07-05 | 2024-01-26 | 中南大学 | 一种从含锡细泥中回收锡的选矿方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1833740A (en) * | 1926-03-19 | 1931-11-24 | Peter C Reilly | Process of ore flotation |
| US2011176A (en) * | 1930-03-01 | 1935-08-13 | Minerals Separation North Us | Ore concentration |
| US2070634A (en) * | 1935-07-05 | 1937-02-16 | Du Pont | Xanthic formates |
| US2185591A (en) * | 1938-08-24 | 1940-01-02 | American Cyanamid Co | Dispersible thiocarbanilide |
| US2501269A (en) * | 1946-06-26 | 1950-03-21 | Minerec Corp | Froth flotation of sulfide ores |
| US2691635A (en) * | 1953-05-20 | 1954-10-12 | Dow Chemical Co | Process for the manufacture of dialkyl thionocarbamates |
| US3328442A (en) * | 1963-12-18 | 1967-06-27 | Massachusetts College Of Pharm | Anti-radiation compounds and their preparation |
| US3397238A (en) * | 1965-11-16 | 1968-08-13 | Pfizer & Co C | Process for the preparation of alkyl ethers of amino-alcohols |
| US4086273A (en) * | 1976-04-14 | 1978-04-25 | The Dow Chemical Company | Process for making beta-aminoethyl sulfides from aliphatic mercaptans and 2-oxazolines |
| CA1105156A (en) * | 1978-10-11 | 1981-07-14 | William A. Rickelton | Flotation of sulfide minerals |
| US4326067A (en) * | 1980-12-03 | 1982-04-20 | The Dow Chemical Company | Process for making N-(2-aminoethyl)amides |
| CN85107378A (zh) * | 1984-09-13 | 1987-03-18 | 陶氏化学公司 | 从原煤中回收有用煤的起泡剂组合物和泡沫浮选方法 |
| ES8706045A1 (es) * | 1985-11-29 | 1987-06-01 | Dow Chemical Co | Un procedimiento para recuperar minerales que contienen metales a partir de una mena |
-
1986
- 1986-02-14 ES ES552034A patent/ES8706047A1/es not_active Expired
- 1986-02-14 PH PH33416A patent/PH24537A/en unknown
- 1986-02-17 ZW ZW42/86A patent/ZW4286A1/xx unknown
- 1986-02-17 CN CN198686101573A patent/CN86101573A/zh active Pending
- 1986-02-17 PL PL1986257990A patent/PL147930B1/pl unknown
- 1986-02-17 ZM ZM14/86A patent/ZM1486A1/xx unknown
- 1986-02-17 ZA ZA861171A patent/ZA861171B/xx unknown
- 1986-02-17 YU YU22986A patent/YU45765B/sh unknown
- 1986-02-18 BR BR8607003A patent/BR8607003A/pt not_active IP Right Cessation
- 1986-02-18 AU AU54598/86A patent/AU586471B2/en not_active Ceased
- 1986-02-18 WO PCT/US1986/000341 patent/WO1987003221A1/en active Application Filing
- 1986-09-03 JP JP61207633A patent/JPS62129161A/ja active Pending
-
1987
- 1987-07-24 RU SU874203123A patent/RU1837985C/ru active
- 1987-07-28 FI FI873287A patent/FI873287A0/fi not_active Application Discontinuation
- 1987-07-28 SE SE8702988A patent/SE8702988L/xx not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| PL257990A1 (en) | 1987-06-15 |
| RU1837985C (ru) | 1993-08-30 |
| ZW4286A1 (en) | 1987-09-09 |
| PH24537A (en) | 1990-08-03 |
| BR8607003A (pt) | 1987-12-01 |
| YU45765B (sh) | 1992-07-20 |
| YU22986A (en) | 1988-06-30 |
| SE8702988D0 (sv) | 1987-07-28 |
| CN86101573A (zh) | 1987-06-03 |
| ZM1486A1 (en) | 1988-01-29 |
| AU5459886A (en) | 1987-07-01 |
| FI873287A (fi) | 1987-07-28 |
| SE8702988L (sv) | 1987-07-28 |
| ES8706047A1 (es) | 1987-06-01 |
| ES552034A0 (es) | 1987-06-01 |
| AU586471B2 (en) | 1989-07-13 |
| FI873287A0 (fi) | 1987-07-28 |
| PL147930B1 (en) | 1989-08-31 |
| ZA861171B (en) | 1987-10-28 |
| WO1987003221A1 (en) | 1987-06-04 |
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