JPS6168481A - ３−アリ−ル−５−ジ置換−アミノ−１，４，２−ジチアゾリウム塩の製造法 - Google Patents
３−アリ−ル−５−ジ置換−アミノ−１，４，２−ジチアゾリウム塩の製造法Info
- Publication number
- JPS6168481A JPS6168481A JP59190158A JP19015884A JPS6168481A JP S6168481 A JPS6168481 A JP S6168481A JP 59190158 A JP59190158 A JP 59190158A JP 19015884 A JP19015884 A JP 19015884A JP S6168481 A JPS6168481 A JP S6168481A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- aryl
- disubstituted
- formula
- dithiazolium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 150000003839 salts Chemical class 0.000 title description 8
- 239000002253 acid Substances 0.000 claims abstract description 13
- 125000001424 substituent group Chemical group 0.000 claims abstract description 9
- XQIJUNRYEIASNK-UHFFFAOYSA-N amino carbamodithioate Chemical class NSC(N)=S XQIJUNRYEIASNK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 125000003118 aryl group Chemical group 0.000 claims abstract description 5
- 239000000126 substance Substances 0.000 claims abstract description 5
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 3
- 238000006210 cyclodehydration reaction Methods 0.000 claims description 4
- 150000007522 mineralic acids Chemical class 0.000 claims description 3
- SYBMFSCJUKHJQP-UHFFFAOYSA-N dithiazol-1-ium Chemical class S1[S+]=NC=C1 SYBMFSCJUKHJQP-UHFFFAOYSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 abstract description 11
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 abstract description 9
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 abstract description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract description 4
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 3
- 239000003905 agrochemical Substances 0.000 abstract description 2
- 125000002091 cationic group Chemical group 0.000 abstract description 2
- 238000006297 dehydration reaction Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 238000007363 ring formation reaction Methods 0.000 abstract 2
- 230000018044 dehydration Effects 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 11
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 230000009102 absorption Effects 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- -1 cyclic cationic compounds Chemical class 0.000 description 5
- 238000000921 elemental analysis Methods 0.000 description 4
- 238000000862 absorption spectrum Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- MNNJLAZJQBWSST-UHFFFAOYSA-N 1,4,2-dithiazole Chemical class C1SC=NS1 MNNJLAZJQBWSST-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 229910001914 chlorine tetroxide Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- 239000012776 electronic material Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- XAXHKWTTZYWNOU-UHFFFAOYSA-N perchloric acid;1,3-thiazole Chemical compound C1=CSC=[NH+]1.[O-]Cl(=O)(=O)=O XAXHKWTTZYWNOU-UHFFFAOYSA-N 0.000 description 1
- 230000000144 pharmacologic effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
Landscapes
- Nitrogen- Or Sulfur-Containing Heterocyclic Ring Compounds With Rings Of Six Or More Members (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59190158A JPS6168481A (ja) | 1984-09-11 | 1984-09-11 | ３−アリ−ル−５−ジ置換−アミノ−１，４，２−ジチアゾリウム塩の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59190158A JPS6168481A (ja) | 1984-09-11 | 1984-09-11 | ３−アリ−ル−５−ジ置換−アミノ−１，４，２−ジチアゾリウム塩の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6168481A true JPS6168481A (ja) | 1986-04-08 |
| JPS6241713B2 JPS6241713B2 (OSRAM) | 1987-09-04 |
Family
ID=16253386
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59190158A Granted JPS6168481A (ja) | 1984-09-11 | 1984-09-11 | ３−アリ−ル−５−ジ置換−アミノ−１，４，２−ジチアゾリウム塩の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6168481A (OSRAM) |
-
1984
- 1984-09-11 JP JP59190158A patent/JPS6168481A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6241713B2 (OSRAM) | 1987-09-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |