JPS6149406B2 - - Google Patents
Info
- Publication number
- JPS6149406B2 JPS6149406B2 JP7704979A JP7704979A JPS6149406B2 JP S6149406 B2 JPS6149406 B2 JP S6149406B2 JP 7704979 A JP7704979 A JP 7704979A JP 7704979 A JP7704979 A JP 7704979A JP S6149406 B2 JPS6149406 B2 JP S6149406B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- vinyl
- fiber
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000835 fiber Substances 0.000 claims description 86
- 229920002554 vinyl polymer Polymers 0.000 claims description 58
- 229920002301 cellulose acetate Polymers 0.000 claims description 40
- 229920006243 acrylic copolymer Polymers 0.000 claims description 34
- 239000000178 monomer Substances 0.000 claims description 24
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 23
- 229920000642 polymer Polymers 0.000 claims description 22
- 229920002994 synthetic fiber Polymers 0.000 claims description 22
- 239000012209 synthetic fiber Substances 0.000 claims description 22
- 239000011148 porous material Substances 0.000 claims description 20
- 238000001035 drying Methods 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 11
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 7
- 239000003960 organic solvent Substances 0.000 claims description 7
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 5
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 3
- 230000021736 acetylation Effects 0.000 claims 1
- 238000006640 acetylation reaction Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 44
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 37
- 238000009987 spinning Methods 0.000 description 23
- 238000010521 absorption reaction Methods 0.000 description 22
- 230000007423 decrease Effects 0.000 description 17
- 239000000203 mixture Substances 0.000 description 16
- 229920002821 Modacrylic Polymers 0.000 description 14
- 239000011550 stock solution Substances 0.000 description 12
- 238000005345 coagulation Methods 0.000 description 10
- 230000015271 coagulation Effects 0.000 description 10
- 238000005191 phase separation Methods 0.000 description 9
- 229920000058 polyacrylate Polymers 0.000 description 8
- LGXVIGDEPROXKC-UHFFFAOYSA-N 1,1-dichloroethene Chemical compound ClC(Cl)=C LGXVIGDEPROXKC-UHFFFAOYSA-N 0.000 description 7
- 229920002972 Acrylic fiber Polymers 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- 238000002788 crimping Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 210000004243 sweat Anatomy 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- XEEYSDHEOQHCDA-UHFFFAOYSA-N 2-methylprop-2-ene-1-sulfonic acid Chemical compound CC(=C)CS(O)(=O)=O XEEYSDHEOQHCDA-UHFFFAOYSA-N 0.000 description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 206010013082 Discomfort Diseases 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical class CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- -1 propylene alcohol Chemical compound 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
Priority Applications (14)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7704979A JPS564711A (en) | 1979-06-18 | 1979-06-18 | Porous vinyl synthetic fiber and its production |
| US06/156,993 US4351879A (en) | 1979-06-18 | 1980-06-06 | Porous acrylic synthetic fibers comprising cellulose acetate in an acrylic matrix |
| US06/156,994 US4346146A (en) | 1979-06-18 | 1980-06-06 | Porous flame retardant acrylic synthetic fibers and a method for producing these fibers |
| DE3021889A DE3021889C2 (de) | 1979-06-18 | 1980-06-11 | Poröse schwer entflammbare synthetische Acrylfasern und Verfahren zu deren Herstellung |
| DE3050231A DE3050231C2 (en, 2012) | 1979-06-18 | 1980-06-16 | |
| DE3050897A DE3050897C2 (en, 2012) | 1979-06-18 | 1980-06-16 | |
| DE3022537A DE3022537C2 (de) | 1979-06-18 | 1980-06-16 | Poröse synthetische Acrylfaser aus Celluloseacetat und Acrylpolymeren und Verfahren zu deren Herstellung |
| GB8019925A GB2053790B (en) | 1979-06-18 | 1980-06-18 | Porous acrylic fibres |
| GB8019886A GB2054450B (en) | 1979-06-18 | 1980-06-18 | Porous flame retardant acrylic fibres |
| IT22874/80A IT1141004B (it) | 1979-06-18 | 1980-06-18 | Fibre sintetiche acriliche porose,a ritardo di fiamma,e procedimento per la produzione di esse |
| US06/397,280 US4460648A (en) | 1979-06-18 | 1982-07-12 | Porous bicomponent acrylic synthetic fibers comprising cellulose acetate in an acrylic matrix and method for producing said fibers |
| US06/397,282 US4395377A (en) | 1979-06-18 | 1982-07-12 | Porous acrylic synthetic fibers comprising cellulose acetate in an acrylic matrix and method for producing said fibers |
| GB08228954A GB2108040B (en) | 1979-06-18 | 1982-10-11 | Making porous acrylic fibres |
| GB08230406A GB2105253B (en) | 1979-06-18 | 1982-10-25 | Production of porous flame retardant acrylic fibres |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7704979A JPS564711A (en) | 1979-06-18 | 1979-06-18 | Porous vinyl synthetic fiber and its production |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS564711A JPS564711A (en) | 1981-01-19 |
| JPS6149406B2 true JPS6149406B2 (en, 2012) | 1986-10-29 |
Family
ID=13622916
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7704979A Granted JPS564711A (en) | 1979-06-18 | 1979-06-18 | Porous vinyl synthetic fiber and its production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS564711A (en, 2012) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2524498B1 (fr) * | 1982-04-01 | 1985-08-16 | Rhovyl | Fils et fibres a base de melanges de polychlorure de vinyle et acetate de cellulose et leur procede d'obtention |
| DE3773189D1 (de) * | 1987-03-25 | 1991-10-24 | Sekisui Chemical Co Ltd | Harz zur anwendung bei magnetischen aufzeichnungstraegern und verfahren zu seiner herstellung. |
| JP4646301B2 (ja) * | 2005-06-10 | 2011-03-09 | 旭化成ケミカルズ株式会社 | 多孔性成形体およびその製造方法 |
-
1979
- 1979-06-18 JP JP7704979A patent/JPS564711A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS564711A (en) | 1981-01-19 |
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