JPS6128690B2 - - Google Patents
Info
- Publication number
- JPS6128690B2 JPS6128690B2 JP3843281A JP3843281A JPS6128690B2 JP S6128690 B2 JPS6128690 B2 JP S6128690B2 JP 3843281 A JP3843281 A JP 3843281A JP 3843281 A JP3843281 A JP 3843281A JP S6128690 B2 JPS6128690 B2 JP S6128690B2
- Authority
- JP
- Japan
- Prior art keywords
- curing agent
- resin
- flame
- acidic curing
- producing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- 229920003180 amino resin Polymers 0.000 claims description 18
- 239000005011 phenolic resin Substances 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 17
- 239000002966 varnish Substances 0.000 claims description 17
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 16
- 229920001568 phenolic resin Polymers 0.000 claims description 16
- 230000002378 acidificating effect Effects 0.000 claims description 15
- 239000003063 flame retardant Substances 0.000 claims description 15
- 229920000877 Melamine resin Polymers 0.000 claims description 14
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 150000003863 ammonium salts Chemical class 0.000 claims 1
- 238000010030 laminating Methods 0.000 claims 1
- 229920005989 resin Polymers 0.000 description 14
- 239000011347 resin Substances 0.000 description 14
- 239000000123 paper Substances 0.000 description 9
- 239000004640 Melamine resin Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 238000011221 initial treatment Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- -1 phosphorus compound Chemical class 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 150000002896 organic halogen compounds Chemical class 0.000 description 5
- 150000002903 organophosphorus compounds Chemical class 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- 150000002484 inorganic compounds Chemical class 0.000 description 4
- 229910010272 inorganic material Inorganic materials 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 229920001187 thermosetting polymer Polymers 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 150000002366 halogen compounds Chemical class 0.000 description 3
- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 239000011889 copper foil Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- GEHMBYLTCISYNY-UHFFFAOYSA-N Ammonium sulfamate Chemical compound [NH4+].NS([O-])(=O)=O GEHMBYLTCISYNY-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 235000010678 Paulownia tomentosa Nutrition 0.000 description 1
- 240000002834 Paulownia tomentosa Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- STIAPHVBRDNOAJ-UHFFFAOYSA-N carbamimidoylazanium;carbonate Chemical compound NC(N)=N.NC(N)=N.OC(O)=O STIAPHVBRDNOAJ-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000000625 cyclamic acid and its Na and Ca salt Substances 0.000 description 1
- HCAJEUSONLESMK-UHFFFAOYSA-N cyclohexylsulfamic acid Chemical compound OS(=O)(=O)NC1CCCCC1 HCAJEUSONLESMK-UHFFFAOYSA-N 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- MSYLJRIXVZCQHW-UHFFFAOYSA-N formaldehyde;6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound O=C.NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 MSYLJRIXVZCQHW-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000012796 inorganic flame retardant Substances 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical class O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- JYIZNFVTKLARKT-UHFFFAOYSA-N phenol;1,3,5-triazine-2,4,6-triamine Chemical compound OC1=CC=CC=C1.NC1=NC(N)=NC(N)=N1 JYIZNFVTKLARKT-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Landscapes
- Reinforced Plastic Materials (AREA)
- Laminated Bodies (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3843281A JPS57151626A (en) | 1981-03-16 | 1981-03-16 | Preparation of flame-retardant laminate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3843281A JPS57151626A (en) | 1981-03-16 | 1981-03-16 | Preparation of flame-retardant laminate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57151626A JPS57151626A (en) | 1982-09-18 |
| JPS6128690B2 true JPS6128690B2 (US20080293856A1-20081127-C00150.png) | 1986-07-02 |
Family
ID=12525142
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3843281A Granted JPS57151626A (en) | 1981-03-16 | 1981-03-16 | Preparation of flame-retardant laminate |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57151626A (US20080293856A1-20081127-C00150.png) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS637581U (US20080293856A1-20081127-C00150.png) * | 1986-07-03 | 1988-01-19 |
-
1981
- 1981-03-16 JP JP3843281A patent/JPS57151626A/ja active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS637581U (US20080293856A1-20081127-C00150.png) * | 1986-07-03 | 1988-01-19 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57151626A (en) | 1982-09-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS6128690B2 (US20080293856A1-20081127-C00150.png) | ||
| JP3315082B2 (ja) | 難燃性樹脂組成物、これを用いたプリプレグ及び積層板 | |
| JP2975349B1 (ja) | ガラスエポキシ銅張積層板用樹脂組成物 | |
| JP2931262B2 (ja) | ガラスエポキシ銅張積層板の製造方法 | |
| JP3179145B2 (ja) | フェノール樹脂組成物 | |
| JPS6063251A (ja) | 難燃性フエノ−ル樹脂組成物 | |
| JP2846964B2 (ja) | ハロゲンフリーの難燃性エポキシ樹脂組成物、並びにそれを含有するプリプレグ及び積層板 | |
| JPH0859860A (ja) | 難燃性フェノール樹脂積層板の製造方法 | |
| JPH05339468A (ja) | フェノール樹脂組成物 | |
| JP3982507B2 (ja) | プリプレグおよび金属張り積層板 | |
| JP4017801B2 (ja) | 難燃性コンポジット積層板 | |
| JP3315085B2 (ja) | 難燃性樹脂組成物、これを用いたプリプレグ及び積層板 | |
| JP3331774B2 (ja) | フェノール樹脂組成物、このフェノール樹脂組成物を用いた積層板 | |
| JP4470260B2 (ja) | 積層板 | |
| JP2000344861A (ja) | 難燃性樹脂組成物、これを用いたプリプレグ及び積層板 | |
| JPS6364306B2 (US20080293856A1-20081127-C00150.png) | ||
| JPS6054860B2 (ja) | 銅張フエノ−ル樹脂積層板 | |
| JPH0239928A (ja) | フェノール樹脂積層板 | |
| JP2001163956A (ja) | 難燃性樹脂組成物、これを用いたプリプレグ及び積層板 | |
| JPH093302A (ja) | フェノール樹脂組成物、そのフェノール樹脂組成物を用いたプリプレグ、及び積層板 | |
| JPS61236833A (ja) | 積層板 | |
| JPS5957744A (ja) | 難燃性不飽和ポリエステル樹脂−銅張積層板及びその製造方法 | |
| JPH06287329A (ja) | プリプレグの製造方法及びこのプリプレグを用いた電気用積層板の製造方法 | |
| JPH07316394A (ja) | フェノール樹脂組成物、このフェノール樹脂組成物を用いたプリプレグ、及び積層板 | |
| JPS61236834A (ja) | 積層板 |
