JPS6031584A - 固体酸素キャリヤ−の再生法 - Google Patents
固体酸素キャリヤ−の再生法Info
- Publication number
- JPS6031584A JPS6031584A JP13781383A JP13781383A JPS6031584A JP S6031584 A JPS6031584 A JP S6031584A JP 13781383 A JP13781383 A JP 13781383A JP 13781383 A JP13781383 A JP 13781383A JP S6031584 A JPS6031584 A JP S6031584A
- Authority
- JP
- Japan
- Prior art keywords
- oxygen
- carrier
- reaction
- oxygen carrier
- regeneration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 239000001301 oxygen Substances 0.000 title claims abstract description 51
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 51
- 230000008929 regeneration Effects 0.000 title claims abstract description 18
- 238000011069 regeneration method Methods 0.000 title claims abstract description 18
- 239000007787 solid Substances 0.000 title claims abstract description 10
- 239000007789 gas Substances 0.000 claims abstract description 17
- 238000005839 oxidative dehydrogenation reaction Methods 0.000 claims abstract description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims description 15
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- 230000001172 regenerating effect Effects 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 abstract description 39
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract description 21
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 abstract description 12
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 9
- 150000004706 metal oxides Chemical class 0.000 abstract description 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000010298 pulverizing process Methods 0.000 abstract description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 3
- 239000003054 catalyst Substances 0.000 abstract description 3
- 230000006866 deterioration Effects 0.000 abstract 1
- 230000008646 thermal stress Effects 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 19
- 229910052751 metal Inorganic materials 0.000 description 14
- 239000002184 metal Substances 0.000 description 14
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 11
- 229910001882 dioxygen Inorganic materials 0.000 description 11
- 239000002994 raw material Substances 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 239000000969 carrier Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 238000006356 dehydrogenation reaction Methods 0.000 description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 4
- 229910052737 gold Inorganic materials 0.000 description 4
- 239000010931 gold Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000006208 butylation Effects 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 230000008642 heat stress Effects 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 241000605059 Bacteroidetes Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229910000417 bismuth pentoxide Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000004455 differential thermal analysis Methods 0.000 description 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- -1 etc. Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13781383A JPS6031584A (ja) | 1983-07-29 | 1983-07-29 | 固体酸素キャリヤ−の再生法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13781383A JPS6031584A (ja) | 1983-07-29 | 1983-07-29 | 固体酸素キャリヤ−の再生法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6031584A true JPS6031584A (ja) | 1985-02-18 |
| JPH0144227B2 JPH0144227B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1989-09-26 |
Family
ID=15207453
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13781383A Granted JPS6031584A (ja) | 1983-07-29 | 1983-07-29 | 固体酸素キャリヤ−の再生法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6031584A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012077074A (ja) * | 2010-09-07 | 2012-04-19 | Mitsubishi Chemicals Corp | 共役ジエンの製造方法 |
| WO2016056404A1 (ja) * | 2014-10-08 | 2016-04-14 | Ｊｘ日鉱日石エネルギー株式会社 | ジエンの製造方法及び脱水素触媒 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55100323A (en) * | 1979-01-18 | 1980-07-31 | Inst Fuizuikoooruganichiesukoi | Unsaturated hydrocarbon manufacturing process |
-
1983
- 1983-07-29 JP JP13781383A patent/JPS6031584A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55100323A (en) * | 1979-01-18 | 1980-07-31 | Inst Fuizuikoooruganichiesukoi | Unsaturated hydrocarbon manufacturing process |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012077074A (ja) * | 2010-09-07 | 2012-04-19 | Mitsubishi Chemicals Corp | 共役ジエンの製造方法 |
| WO2016056404A1 (ja) * | 2014-10-08 | 2016-04-14 | Ｊｘ日鉱日石エネルギー株式会社 | ジエンの製造方法及び脱水素触媒 |
| JP2016074642A (ja) * | 2014-10-08 | 2016-05-12 | Ｊｘ日鉱日石エネルギー株式会社 | ジエンの製造方法及び脱水素触媒 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0144227B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1989-09-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2773844A (en) | Method for making supported silver catalysts | |
| US9511356B2 (en) | Regeneration of spent paraffin dehydrogenation catalyst | |
| US5194417A (en) | Pretreatment of palladium-gold catalysts useful in vinyl acetate synthesis | |
| US2627527A (en) | Oxidation of olefins to alkenals | |
| US2383711A (en) | Preparation of alkenals and alkenones | |
| JPS621455A (ja) | 有機化合物の酸化転化方法 | |
| US1678627A (en) | Method of regenerating catalysts | |
| US2342856A (en) | Regeneration of a contact catalyst | |
| KR20100072254A (ko) | 개선된 말레산 무수물 제조용 산화촉매 | |
| US4317919A (en) | Recovery of bromine from effluent gases in the oxidation of substituted aromatics to form aromatic carboxylic acids | |
| JPS6031584A (ja) | 固体酸素キャリヤ−の再生法 | |
| US5480853A (en) | Phosphorus/vanadium catalyst preparation | |
| CH452493A (fr) | Procédé pour l'oxydation d'oléfines | |
| US4649205A (en) | Process for the manufacture of maleic anhydride utilizing catalysts reactivated with alkyl esters of orthophosphoric acid in the presence of water | |
| US3216801A (en) | Process for producing hydrogen | |
| US2624713A (en) | Iron fluoride-manganese fluoride aromatizing catalyst | |
| JPS58128327A (ja) | オレフインの製法 | |
| KR20010021870A (ko) | 스티렌의 제조방법 | |
| US2917565A (en) | Isomerization of paraffinic hydrocarbons and method of activating the isomerization catalyst | |
| JPS63147549A (ja) | 触媒の再生方法およびこの方法を応用した酸化脱水素方法 | |
| JPS6332338B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| JPS6019722A (ja) | 酸素キヤリヤ−を使用する反応方法 | |
| JP2991684B2 (ja) | 無水マレイン酸へのｎブタンの選択的気相酸化方法およびＶ／Ｐ／Ｏ触媒のか焼方法 | |
| US3437690A (en) | Vapor phase process for preparing unsaturated aliphatic aldehydes and monocarboxylic acids | |
| JPS6312114B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |