JPS6028803A - 選択性透過膜及びその製造方法 - Google Patents
選択性透過膜及びその製造方法Info
- Publication number
- JPS6028803A JPS6028803A JP58135143A JP13514383A JPS6028803A JP S6028803 A JPS6028803 A JP S6028803A JP 58135143 A JP58135143 A JP 58135143A JP 13514383 A JP13514383 A JP 13514383A JP S6028803 A JPS6028803 A JP S6028803A
- Authority
- JP
- Japan
- Prior art keywords
- membrane
- polyethyleneimine
- water
- acidic group
- permeable membrane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012528 membrane Substances 0.000 title claims abstract description 62
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 229920002873 Polyethylenimine Polymers 0.000 claims abstract description 27
- 230000002378 acidificating effect Effects 0.000 claims abstract description 14
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 11
- 238000004132 cross linking Methods 0.000 claims abstract description 9
- 150000001491 aromatic compounds Chemical class 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 abstract description 13
- 238000005373 pervaporation Methods 0.000 abstract description 11
- 238000000926 separation method Methods 0.000 abstract description 9
- 239000003960 organic solvent Substances 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 19
- 239000000243 solution Substances 0.000 description 19
- 239000000203 mixture Substances 0.000 description 18
- 239000007788 liquid Substances 0.000 description 16
- 239000007864 aqueous solution Substances 0.000 description 15
- 238000000034 method Methods 0.000 description 13
- 229920002125 Sokalan® Polymers 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 235000019441 ethanol Nutrition 0.000 description 8
- 239000004584 polyacrylic acid Substances 0.000 description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 7
- 239000002131 composite material Substances 0.000 description 6
- 239000010408 film Substances 0.000 description 6
- 229920002492 poly(sulfone) Polymers 0.000 description 6
- -1 polyethylene Polymers 0.000 description 5
- FDQSRULYDNDXQB-UHFFFAOYSA-N benzene-1,3-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=CC(C(Cl)=O)=C1 FDQSRULYDNDXQB-UHFFFAOYSA-N 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 3
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 3
- 229940005642 polystyrene sulfonic acid Drugs 0.000 description 3
- 230000008016 vaporization Effects 0.000 description 3
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N isopropyl alcohol Natural products CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 125000002560 nitrile group Chemical group 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 125000000542 sulfonic acid group Chemical group 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- IJVRPNIWWODHHA-UHFFFAOYSA-N 2-cyanoprop-2-enoic acid Chemical compound OC(=O)C(=C)C#N IJVRPNIWWODHHA-UHFFFAOYSA-N 0.000 description 1
- ONPJWQSDZCGSQM-UHFFFAOYSA-N 2-phenylprop-2-enoic acid Chemical compound OC(=O)C(=C)C1=CC=CC=C1 ONPJWQSDZCGSQM-UHFFFAOYSA-N 0.000 description 1
- UITKHKNFVCYWNG-UHFFFAOYSA-N 4-(3,4-dicarboxybenzoyl)phthalic acid Chemical compound C1=C(C(O)=O)C(C(=O)O)=CC=C1C(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 UITKHKNFVCYWNG-UHFFFAOYSA-N 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241001648319 Toronia toru Species 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229910000039 hydrogen halide Inorganic materials 0.000 description 1
- 239000012433 hydrogen halide Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229920000831 ionic polymer Polymers 0.000 description 1
- 229940035429 isobutyl alcohol Drugs 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 210000003734 kidney Anatomy 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- LXEJRKJRKIFVNY-UHFFFAOYSA-N terephthaloyl chloride Chemical compound ClC(=O)C1=CC=C(C(Cl)=O)C=C1 LXEJRKJRKIFVNY-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/125—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58135143A JPS6028803A (ja) | 1983-07-26 | 1983-07-26 | 選択性透過膜及びその製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58135143A JPS6028803A (ja) | 1983-07-26 | 1983-07-26 | 選択性透過膜及びその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6028803A true JPS6028803A (ja) | 1985-02-14 |
| JPS6260924B2 JPS6260924B2 (enrdf_load_stackoverflow) | 1987-12-18 |
Family
ID=15144808
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58135143A Granted JPS6028803A (ja) | 1983-07-26 | 1983-07-26 | 選択性透過膜及びその製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6028803A (enrdf_load_stackoverflow) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63182005A (ja) * | 1987-01-22 | 1988-07-27 | Agency Of Ind Science & Technol | ポリイオンコンプレツクス分離膜 |
| JPH0214725A (ja) * | 1988-07-01 | 1990-01-18 | Tsusho Sangiyoushiyou Kiso Sangiyoukiyokuchiyou | 有機物分離用中空糸複合膜 |
| JPH0256224A (ja) * | 1988-08-23 | 1990-02-26 | Tsusho Sangiyoushiyou Kiso Sangiyoukiyokuchiyou | 複合中空糸膜の製造方法 |
| US4978430A (en) * | 1986-12-06 | 1990-12-18 | Ube Industries, Ltd. | Method for dehydration and concentration of aqueous solution containing organic compound |
| EP0753337A3 (en) * | 1995-07-12 | 1997-09-10 | Bend Res Inc | Vapor permeable hollow fiber membranes and modules |
| WO1999010089A1 (en) * | 1997-08-26 | 1999-03-04 | Bpt - Biopure Technologies Ltd. | A process for repairing membrane imperfections |
| JPWO2021039309A1 (enrdf_load_stackoverflow) * | 2019-08-26 | 2021-03-04 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49117370A (enrdf_load_stackoverflow) * | 1973-03-13 | 1974-11-09 | ||
| JPS49133282A (enrdf_load_stackoverflow) * | 1972-09-19 | 1974-12-20 |
-
1983
- 1983-07-26 JP JP58135143A patent/JPS6028803A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49133282A (enrdf_load_stackoverflow) * | 1972-09-19 | 1974-12-20 | ||
| JPS49117370A (enrdf_load_stackoverflow) * | 1973-03-13 | 1974-11-09 |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4978430A (en) * | 1986-12-06 | 1990-12-18 | Ube Industries, Ltd. | Method for dehydration and concentration of aqueous solution containing organic compound |
| JPS63182005A (ja) * | 1987-01-22 | 1988-07-27 | Agency Of Ind Science & Technol | ポリイオンコンプレツクス分離膜 |
| JPH0214725A (ja) * | 1988-07-01 | 1990-01-18 | Tsusho Sangiyoushiyou Kiso Sangiyoukiyokuchiyou | 有機物分離用中空糸複合膜 |
| JPH0256224A (ja) * | 1988-08-23 | 1990-02-26 | Tsusho Sangiyoushiyou Kiso Sangiyoukiyokuchiyou | 複合中空糸膜の製造方法 |
| EP0753337A3 (en) * | 1995-07-12 | 1997-09-10 | Bend Res Inc | Vapor permeable hollow fiber membranes and modules |
| WO1999010089A1 (en) * | 1997-08-26 | 1999-03-04 | Bpt - Biopure Technologies Ltd. | A process for repairing membrane imperfections |
| JPWO2021039309A1 (enrdf_load_stackoverflow) * | 2019-08-26 | 2021-03-04 | ||
| WO2021039309A1 (ja) * | 2019-08-26 | 2021-03-04 | 住友化学株式会社 | 酸性ガス分離膜、酸性ガス分離装置、酸性ガス分離膜の製造方法、及び酸性ガス分離方法 |
| CN114340771A (zh) * | 2019-08-26 | 2022-04-12 | 住友化学株式会社 | 酸性气体分离膜、酸性气体分离装置、酸性气体分离膜的制造方法以及酸性气体分离方法 |
| EP4023327A4 (en) * | 2019-08-26 | 2023-09-20 | Sumitomo Chemical Company Limited | ACID GAS SEPARATION MEMBRANE, ACID GAS SEPARATION DEVICE, METHOD FOR PRODUCING AN ACID GAS SEPARATION MEMBRANE AND METHOD FOR SEPARATING ACID GAS |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6260924B2 (enrdf_load_stackoverflow) | 1987-12-18 |
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